CN106746838A - A kind of aluminate modified high-efficient liquid accelerator - Google Patents
A kind of aluminate modified high-efficient liquid accelerator Download PDFInfo
- Publication number
- CN106746838A CN106746838A CN201611065103.1A CN201611065103A CN106746838A CN 106746838 A CN106746838 A CN 106746838A CN 201611065103 A CN201611065103 A CN 201611065103A CN 106746838 A CN106746838 A CN 106746838A
- Authority
- CN
- China
- Prior art keywords
- aluminate
- mass fraction
- modification liquid
- liquid
- accelerator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/10—Accelerators; Activators
- C04B2103/12—Set accelerators
Abstract
The invention discloses a kind of aluminate modified high-efficient liquid accelerator, by aluminate solution and modification liquid with 24:1 weight ratio is formulated, and the mass fraction of aluminate is 30% in aluminate solution, and in modification liquid, the mass fraction of silicate is 20%, and the mass fraction of organic alcohols is 0.8%;Its preparation method is as follows:1) aluminate is inserted in reactor to add water and is stirred, prepare aluminate solution;2) silicate, organic alcohols are weighed and prepares modification liquid;3) with aluminate solution:Modification liquid=24:1 weight obtains finished product than dispensing after stirring 30min;Accelerator alkalinity of the invention is low, without sodium ion corrosion, non-stimulated smell;Low production cost, energy consumption is low, energy-conserving and environment-protective;Caking property is good, and springback capacity is low, and later strength storage rate is high, impervious rank is high, concrete can be made rapidly to condense in a short time, change to microstructure of concrete is little, is adapted to the special engineerings such as sprayed construction technique and repairing, sealing leak stopping, and market application foreground is wide.
Description
Technical field
The present invention relates to technical field of concrete additives, specifically a kind of aluminate modified high-efficient liquid accelerator.
Background technology
Accelerator be mix concrete in concrete is condensed the additive of hardening rapidly, with reach repairing or roadway in mix
The purpose of solidifying soil rapid condensation, is indispensable additive in construction of shotcrete engineering method, and the effect of accelerator is to accelerate
The hydration and hardening of cement, forms enough intensity in a short period of time, to ensure special construction requirement;Use in the prior art
Perhafnate:Carbonate=5:0.5 weight than preparation raw material, using aluminium hydroxide:NaOH=1:1.2 weight ratio is matched somebody with somebody
Dispensing processed, its specific preparation method is:The NaOH and aluminium hydroxide of formula ratio are stirred into a few hours under the high temperature conditions, after
Carbonate aluminate is added to continue to obtain accelerator product after reacting 1 hour, its preparation technology needs specified conditions, and prepares week
Phase is long, and the accelerator that production is obtained does not adapt to construction process requirement, so as to the engineering of concrete in work progress cannot be ensured
Quality;And because preparation time is long, precipitate many, it is necessary to carry out under the high temperature conditions, and energy consumption and cost of manufacture are increased, compel to be essential
Carry out technological improvement and improvement.
The content of the invention
Low it is an object of the invention to provide a kind of alkalinity, without sodium ion corrosion, the aluminate of non-stimulated smell is modified
Efficient liquid accelerator, to solve the problems, such as to be proposed in above-mentioned background technology.
To achieve the above object, the present invention provides following technical scheme:
A kind of aluminate modified high-efficient liquid accelerator, by aluminate solution and modification liquid with 24:1 weight is than preparation
Into the mass fraction of aluminate is 30% in aluminate solution, and in modification liquid, the mass fraction of silicate is 20%, Organic Alcohol
The mass fraction of class is 0.8%.
As further scheme of the invention:The preparation method of the aluminate modified high-efficient liquid accelerator includes following
Step:
1) aluminate of formula ratio is weighed, is inserted to be added water in reactor and is stirred, it is 30% to be configured to mass fraction
Aluminate solution;
2) silicate, organic alcohols are hybridly prepared into modification liquid, in terms of mass fraction, silicate content is 20%, is had
Machine alcohol content is 0.8%;
3) in step 1) reactor in be added dropwise step 2) prepare modification liquid, aluminate solution and modification liquid in reactor
Mass ratio be 24:1,30min is stirred after adding modification liquid, obtain finished product aluminate modified high-efficient liquid accelerator..
As further scheme of the invention:The step 3) in, stir speed (S.S.) is 60r/min, reaction temperature control
At 90 DEG C.
Compared with prior art, the beneficial effects of the invention are as follows:Accelerator alkalinity of the invention is low, rotten without sodium ion
Erosion, non-stimulated smell;Without being carried out under hot conditions again when it is prepared, degraded production cost significantly, reduces energy consumption, energy-conservation
Environmental protection;Caking property is good, and springback capacity is low, and later strength storage rate is high, impervious rank is high, ensure that the raising of construction quality, it is ensured that
Late strength of concrete;Concrete can be made rapidly to condense in a short time, the change to microstructure of concrete is little, is adapted to spray
The special engineerings such as construction technology and repairing, sealing leak stopping are penetrated, market application foreground is wide.
Specific embodiment
The technical scheme of this patent is described in more detail with reference to specific embodiment.
A kind of aluminate modified high-efficient liquid accelerator, by aluminate solution and modification liquid with 24:1 weight is than preparation
Into the mass fraction of aluminate is 30% in aluminate solution, and in modification liquid, the mass fraction of silicate is 20%, Organic Alcohol
The mass fraction of class is 0.8%, and the preparation method of the aluminate modified high-efficient liquid accelerator is comprised the following steps:
1) aluminate of formula ratio is weighed, is inserted to be added water in reactor and is stirred, it is 30% to be configured to mass fraction
Aluminate solution;
2) silicate, organic alcohols are hybridly prepared into modification liquid, in terms of mass fraction, silicate content is 20%, is had
Machine alcohol content is 0.8%;
3) in step 1) reactor in be added dropwise step 2) prepare modification liquid, aluminate solution and modification liquid in reactor
Mass ratio be 24:1, reaction temperature is controlled at 90 DEG C, with the stir speed (S.S.) 30min of 60r/min after addition modification liquid, is obtained into
Product aluminate modified high-efficient liquid accelerator..
The better embodiment to this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party
Formula, in the ken that one skilled in the relevant art possesses, can also be on the premise of this patent objective not be departed from
Make a variety of changes.
Claims (2)
1. a kind of aluminate modified high-efficient liquid accelerator, by aluminate solution and modification liquid with 24:1 weight is than preparation
Into, it is characterised in that the mass fraction of aluminate is 30% in aluminate solution, and in modification liquid, the mass fraction of silicate is
20%, the mass fraction of organic alcohols is 0.8%;The preparation method of the aluminate modified high-efficient liquid accelerator includes following
Step:
1) aluminate of formula ratio is weighed, is inserted to be added water in reactor and is stirred, be configured to the aluminic acid that mass fraction is 30%
Salting liquid;
2) silicate, organic alcohols are hybridly prepared into modification liquid, in terms of mass fraction, silicate content is 20%, Organic Alcohol
Class content is 0.8%;
3) in step 1) reactor in step 2 is added dropwise) modification liquid for preparing, the matter of aluminate solution and modification liquid in reactor
Amount is than being 24:1,30min is stirred after adding modification liquid, obtain finished product aluminate modified high-efficient liquid accelerator.
2. aluminate modified high-efficient liquid accelerator according to claim 1, it is characterised in that the step 3) in, stir
Speed is mixed for 60r/min, reaction temperature is controlled at 90 DEG C.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201611065103.1A CN106746838A (en) | 2016-11-28 | 2016-11-28 | A kind of aluminate modified high-efficient liquid accelerator |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201611065103.1A CN106746838A (en) | 2016-11-28 | 2016-11-28 | A kind of aluminate modified high-efficient liquid accelerator |
Publications (1)
Publication Number | Publication Date |
---|---|
CN106746838A true CN106746838A (en) | 2017-05-31 |
Family
ID=58904505
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201611065103.1A Pending CN106746838A (en) | 2016-11-28 | 2016-11-28 | A kind of aluminate modified high-efficient liquid accelerator |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN106746838A (en) |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1283128A (en) * | 1969-12-02 | 1972-07-26 | Progil | Setting accelerators for cements, mortars and concretes |
JPS54141819A (en) * | 1978-04-26 | 1979-11-05 | Denki Kagaku Kogyo Kk | Production of quick setting cement mortar or concrete |
CN1216293A (en) * | 1993-09-24 | 1999-05-12 | 格雷斯公司 | Set-accelerating admixture for hydraulic cement composition |
CN101139183A (en) * | 2007-08-14 | 2008-03-12 | 陕西金石混凝土科技发展有限公司 | Low-alkali liquor accelerator for spraying concrete |
CN101659527A (en) * | 2009-09-21 | 2010-03-03 | 江苏博特新材料有限公司 | Modified aluminate low-alkali liquid quick-setting agent |
CN101665336A (en) * | 2009-09-23 | 2010-03-10 | 江苏博特新材料有限公司 | Preparation method of low-alkaline liquid accelerating agent |
CN103819122A (en) * | 2014-01-24 | 2014-05-28 | 江西省交通工程集团公司 | Preparation method of low-alkaline liquid setting accelerator for sprayed concrete |
CN103819114A (en) * | 2014-02-17 | 2014-05-28 | 山东大学 | Preparation method of low-alkali polymer high-efficient liquid setting-accelerator for sprayed concrete |
-
2016
- 2016-11-28 CN CN201611065103.1A patent/CN106746838A/en active Pending
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1283128A (en) * | 1969-12-02 | 1972-07-26 | Progil | Setting accelerators for cements, mortars and concretes |
JPS54141819A (en) * | 1978-04-26 | 1979-11-05 | Denki Kagaku Kogyo Kk | Production of quick setting cement mortar or concrete |
CN1216293A (en) * | 1993-09-24 | 1999-05-12 | 格雷斯公司 | Set-accelerating admixture for hydraulic cement composition |
CN101139183A (en) * | 2007-08-14 | 2008-03-12 | 陕西金石混凝土科技发展有限公司 | Low-alkali liquor accelerator for spraying concrete |
CN101659527A (en) * | 2009-09-21 | 2010-03-03 | 江苏博特新材料有限公司 | Modified aluminate low-alkali liquid quick-setting agent |
CN101665336A (en) * | 2009-09-23 | 2010-03-10 | 江苏博特新材料有限公司 | Preparation method of low-alkaline liquid accelerating agent |
CN103819122A (en) * | 2014-01-24 | 2014-05-28 | 江西省交通工程集团公司 | Preparation method of low-alkaline liquid setting accelerator for sprayed concrete |
CN103819114A (en) * | 2014-02-17 | 2014-05-28 | 山东大学 | Preparation method of low-alkali polymer high-efficient liquid setting-accelerator for sprayed concrete |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN104356300B (en) | Efficient retardation water reducing agent of a kind of modification of chitosan and preparation method thereof and using method | |
CN106082750B (en) | Gunite concrete low resilience liquid accelerator and preparation method thereof | |
CN104193212B (en) | Sprayed concrete low resilience low-alkali liquid quick-setting agent and preparation method thereof | |
CN107200497A (en) | A kind of chlorine-free alkali-free liquid accelerating agent and preparation method thereof | |
CN103396027B (en) | A kind of preparation method of novel alkali-free liquid accelerator | |
CN106186777A (en) | A kind of broad spectrum activity for reinforcing oil well cement is without chlorine coagulant early strength agent | |
CN110963732A (en) | Environment-friendly alkali-free liquid accelerator and normal-temperature preparation method thereof | |
CN103570259A (en) | Geopolymer dry powder material as well as preparation method thereof | |
CN104496350A (en) | Corrosion-resistant polymer modified cement mortar and preparation method thereof | |
CN106477943A (en) | A kind of composite cement admixture | |
CN109111145A (en) | A kind of high stability low-alkali liquid quick-setting agent and preparation method thereof | |
CN103288375B (en) | Concrete additive and preparation method thereof | |
CN106630725A (en) | Liquid accelerated agent for sprayed concrete and preparation method of liquid accelerated agent | |
CN114105513A (en) | Alkali-free accelerator and preparation method and application thereof | |
CN104478285B (en) | A kind of it is applied to the activation reinforcing agent of cement concrete, purposes and preparation method thereof | |
CN109399996B (en) | Concrete expanding agent and preparation process thereof | |
CN104591660A (en) | Modified inorganic waterproof plugging material | |
CN102173712A (en) | Ardealite concrete aerated block | |
CN103911160A (en) | High-titanium slag soft soil stabilizer | |
CN106746838A (en) | A kind of aluminate modified high-efficient liquid accelerator | |
CN110015862A (en) | Waterproof and anticorrosion ardealite compound additive and waterproof and anticorrosion ardealite construction material | |
CN111003964A (en) | Alkali-free liquid accelerator and production process thereof | |
CN106365548A (en) | Compounded soil curing agent and preparation method thereof | |
CN102249594B (en) | Alkali-activated slag cement retarder and application method thereof | |
CN108689664A (en) | A kind of environment-friendly concrete and preparation method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170531 |
|
RJ01 | Rejection of invention patent application after publication |