CN106731541A - Low temperature plasma waste gas cleaning device and purification method - Google Patents

Low temperature plasma waste gas cleaning device and purification method Download PDF

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Publication number
CN106731541A
CN106731541A CN201611042400.4A CN201611042400A CN106731541A CN 106731541 A CN106731541 A CN 106731541A CN 201611042400 A CN201611042400 A CN 201611042400A CN 106731541 A CN106731541 A CN 106731541A
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CN
China
Prior art keywords
waste gas
low temperature
temperature plasma
lacquer spraying
photocatalysis
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Pending
Application number
CN201611042400.4A
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Chinese (zh)
Inventor
王海波
王卫星
王中元
陈作桥
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Hubei Chain Co Ltd
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Hubei Chain Co Ltd
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Application filed by Hubei Chain Co Ltd filed Critical Hubei Chain Co Ltd
Priority to CN201611042400.4A priority Critical patent/CN106731541A/en
Publication of CN106731541A publication Critical patent/CN106731541A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/10Particle separators, e.g. dust precipitators, using filter plates, sheets or pads having plane surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/007Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by irradiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/32Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
    • B01D53/323Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00 by electrostatic effects or by high-voltage electric fields
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/75Multi-step processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8678Removing components of undefined structure
    • B01D53/8687Organic components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/88Handling or mounting catalysts
    • B01D53/885Devices in general for catalytic purification of waste gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20707Titanium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/80Type of catalytic reaction
    • B01D2255/802Photocatalytic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/90Physical characteristics of catalysts
    • B01D2255/903Multi-zoned catalysts
    • B01D2255/9032Two zones
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702Hydrocarbons
    • B01D2257/7027Aromatic hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0258Other waste gases from painting equipments or paint drying installations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/80Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
    • B01D2259/804UV light
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/80Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
    • B01D2259/818Employing electrical discharges or the generation of a plasma

Abstract

The invention discloses a kind of low temperature plasma waste gas cleaning device and purification method, purifier includes the cylinder with purification cavity, and filter layer, the first photochemical catalytic oxidation mechanism, reaction of low temperature plasma device and the second photochemical catalytic oxidation mechanism purified in cavity are sequentially arranged in along lacquer spraying waste gas flow direction;First photochemical catalytic oxidation mechanism includes the first ultraviolet lamp layers and the first photocatalyst layer that set gradually, and the second photochemical catalytic oxidation mechanism includes the second ultraviolet lamp layers, the second photocatalyst layer and the 3rd ultraviolet lamp layers that set gradually;It carries out filtration treatment, photocatalysis pretreatment, oxidative degradation treatment, photocatalysis advanced treating to lacquer spraying waste gas successively.One aspect of the present invention combination photocatalysis and non-thermal plasma trap, improve the purification efficiency of lacquer spraying waste gas, on the other hand it is respectively provided with the order of uviol lamp and photochemical catalyst in photocatalysis pretreatment and advanced treatment to be engaged in order to low-temperature plasma reactor, and then realizes further improving lacquer spraying waste gas treatment effeciency.

Description

Low temperature plasma waste gas cleaning device and purification method
Technical field
The present invention relates to waste gas purification technology, more particularly, to a kind of low temperature plasma waste gas cleaning device and purification side Method.
Background technology
In industry is sprayed, usually using " wet process technique ", i.e., resin organic solvent is first made into glue, then To be painted by oil supply system then carries out levelling and drying by spray gun uniform fold to workpiece surface.It is organic in due to paint Solvent contains the substantial amounts of VOC with benzene,toluene,xylene etc. as main component.In levelling and drying course In, substantial amounts of VOC can be evaporated, if the VOC that will be evaporated is direct from paint spray booth Discharge, then it can mix with air, and rapidly diffuse into the live surrounding enviroment of production operation.
Because lacquer spraying waste gas main component is the organic exhaust gas such as benzene,toluene,xylene, it has penetrating odor, and logical Cross and breathe or directly act on human body, and then harm is produced to skin, blood, cardiopulmonary, liver, nerve, eyes, so that serious shadow Ring health.
Lower temperature plasma technology has treatment effeciency higher to the dusty gas of atm number, low concentration, is non-cost performance Effective treatment technology often high.The method has that efficiency high, low cost, apparatus adaptability are strong, floor space is small, is easy to operation to control System, start-stop are convenient, synchronous with lacquer spraying technique, the advantages of can be upgraded according to pollutants emission intensity.
At present, there is the treatment that lower temperature plasma technology is applied to lacquer spraying waste gas, but it is to lacquer spraying waste gas Treatment effeciency is relatively low, it is impossible to meet existing lacquer spraying waste gas processing requirement.
The content of the invention
It is an object of the invention to overcome above-mentioned technical deficiency, a kind of low temperature plasma waste gas cleaning device and purification are proposed Method, solves the low technical problem of lacquer spraying waste gas treatment effeciency in the prior art.
To reach above-mentioned technical purpose, technical scheme provides a kind of low temperature plasma waste gas cleaning device, bag The cylinder with purification cavity is included, filter layer, first in the purification cavity are set in turn in along lacquer spraying waste gas flow direction Photochemical catalytic oxidation mechanism, reaction of low temperature plasma device and the second photochemical catalytic oxidation mechanism;The first photochemical catalytic oxidation mechanism The first ultraviolet lamp layers and the first photocatalyst layer including being set gradually along lacquer spraying waste gas flow direction, second photocatalytic-oxidation Changing mechanism includes the second ultraviolet lamp layers, the second photocatalyst layer and the 3rd uviol lamp that are set gradually along lacquer spraying waste gas flow direction Layer.
Preferably, the described first ultraviolet lamp layers, the second ultraviolet lamp layers and the 3rd ultraviolet lamp layers include along the cylinder Wall multiple uviol lamps circumferentially.
Preferably, the reaction of low temperature plasma device includes the first reaction of low temperature plasma device for being arranged in series and the Two reaction of low temperature plasma devices.
Preferably, first photocatalyst layer and the second photocatalyst layer are network structure.
Preferably, the filter layer is that mineral wool filters felt material.
Meanwhile, the present invention also provides a kind of low temperature plasma waste gas cleaning method, comprises the following steps:
(1) lacquer spraying waste gas are carried out tentatively filtering to remove the coating cloud in lacquer spraying waste gas;
(2) lacquer spraying waste gas after step (1) treatment are carried out into photocatalysis pretreatment;
(3) the pretreated lacquer spraying waste gas of photocatalysis are carried out into discharge oxidation degradation treatment;
(4) lacquer spraying waste gas after oxidative degradation is processed carry out photocatalysis advanced treating.
Preferably, time of the photocatalysis pretreatment, oxidative degradation treatment and photocatalysis advanced treating and be 3.16 seconds.
Compared with prior art, one aspect of the present invention combination photocatalysis and non-thermal plasma trap, improve lacquer spraying waste gas Purification efficiency, be on the other hand respectively provided with photocatalysis pretreatment and advanced treatment the order of uviol lamp and photochemical catalyst with It is easy to be engaged with low-temperature plasma reactor, and then realizes further improving lacquer spraying waste gas treatment effeciency.
Brief description of the drawings
Fig. 1 is the attachment structure schematic diagram of low temperature plasma waste gas cleaning device of the invention.
Specific embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, it is right below in conjunction with drawings and Examples The present invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, and It is not used in the restriction present invention.
Fig. 1 is referred to, technical scheme provides a kind of low temperature plasma waste gas cleaning device, including with purification The cylinder 1 of cavity, filter layer 2, the first photocatalytic-oxidation in the purification cavity are set in turn in along lacquer spraying waste gas flow direction Change mechanism 3, the photochemical catalytic oxidation mechanism 5 of reaction of low temperature plasma device 4 and second;The first photochemical catalytic oxidation mechanism 3 includes The the first ultraviolet lamp layers 31 set gradually along lacquer spraying waste gas flow direction and the first photocatalyst layer 32, second photocatalytic-oxidation Changing mechanism 5 includes the second ultraviolet lamp layers 51, the second photocatalyst layer 52 and the 3rd that are set gradually along lacquer spraying waste gas flow direction Ultraviolet lamp layers 53.
When specifically carrying out lacquer spraying waste gas and processing, lacquer spraying waste gas are filtered by filter layer 2 first with removing waste gas Coating cloud, photocatalysis pretreatment is then carried out by the first photochemical catalytic oxidation mechanism 3, it is produced by the first ultraviolet lamp layers 31 first Raw uviol lamp is irradiated to lacquer spraying waste gas, and then by the oxidation processes of the first photocatalyst layer 32, it is conducive to raising light to urge Change the efficiency of oxidation, so as to the escaping gases such as part dimethylbenzene, butyl acetate, propylene glycol methyl ether acetate be urged in ultraviolet light CO is decomposed into the presence of change2、H2O and small organic molecule;Thereafter lacquer spraying waste gas enter reaction of low temperature plasma device 4, low temperature Plasma reactor 4 discharges and the air in waste gas is ionized, and forms active particle, and then promotes most of volatility The small organic molecule that gas and photocatalysis pretreatment unit are produced is decomposed into CO2And H2O;Finally, lacquer spraying waste gas enter the second light Catalysis oxidation mechanism 5 simultaneously carries out photocatalysis advanced treating, and the second photochemical catalytic oxidation mechanism 5 be set to first pass through second it is ultraviolet Lamp layers 51 produce ultraviolet light, then the oxidation processes of the second photocatalyst layer 52, then again by the 3rd ultraviolet lamp layers 53 Ultraviolet light is produced, it is conducive to further improving the treatment effeciency of lacquer spraying waste gas, it is to avoid excessive pollution gas enter In air.
Wherein, the first ultraviolet lamp layers 31, the second ultraviolet lamp layers 51 and the 3rd ultraviolet lamp layers 53 include described in the present embodiment Along the inwall of the cylinder 1 multiple uviol lamps circumferentially, on the one hand produced by the uviol lamp arranged along the inwall of cylinder 1 ultraviolet Lacquer spraying waste gas in cylinder 1 are irradiated by light, on the other hand avoid uviol lamp from stopping the flowing velocity of lacquer spraying waste gas, it is ensured that tool There is lacquer spraying waste gas treatment effeciency higher.
Because exhaust treatment efficiency is higher, waste gas flow velocity is higher in purification cavity, is easily caused at partial contamination gas Reason is discharged by purification cavity, therefore reaction of low temperature plasma device 4 described in the present embodiment is including the first low temperature being arranged in series etc. The reaction of low temperature plasma device 42 of plasma reactor 41 and second, is processed by continuity, is conducive to low temperature plasma anti- The secondary oxidation degradation treatment of device 4 is answered, escaping gas and small organic molecule are degraded completely.
Wherein, when specifically setting, the first photocatalyst layer 32 described in the present embodiment and the second photocatalyst layer 52 are net Shape structure, consequently facilitating the circulation of gas, improves exhaust treatment efficiency, specifically, first photocatalyst layer 32 and second Photocatalyst layer 52 is the cellular Titanium Dioxide net of aluminium base, and the filter layer 2 is then preferably arranged to mineral wool filter felt Material.
During lacquer spraying waste gas treatment, typically one is set in the outlet side of the present embodiment low temperature plasma waste gas cleaning device The air-introduced machine of 7.5kW, in order to promote lacquer spraying waste gas quickly to be flowed along purification cavity, and in order to guarantee to have lacquer spraying waste gas Effect purification, the settable interior airduct through for 0.32m is connected with the inlet end of the present embodiment low temperature plasma waste gas cleaning device, wind The intake of pipe is 5000m3/h, after lacquer spraying waste gas filtering, photocatalysis pretreatment, oxidative degradation treatment, photocatalysis is carried out successively Advanced treating, its process time is 3.16 seconds.For the ease of describing the treatment of the present embodiment low temperature plasma waste gas cleaning device Efficiency, the general volatile gas concentration that the present embodiment chooses manual painting workshop brattice air outlet is 600mg/m3Lacquer spraying waste gas Processed, because the present embodiment carries out exhausting using high-power air-introduced machine so that enter low temperature plasma waste gas cleaning device The escaping gas concentration of lacquer spraying waste gas be reduced to 495.9mg/m3, and the specific data such as following table after processing:
As seen from the above table, dimethylbenzene and total VOCs concentration are respectively from the 193.9mg/m of import3、495.9mg/m3Drop to 38.6mg/m3、61.3mg/m3, more than 80%, it can reach related discharging standards to clearance.
Compared with prior art, one aspect of the present invention combination photocatalysis and non-thermal plasma trap, improve lacquer spraying waste gas Purification efficiency, be on the other hand respectively provided with photocatalysis pretreatment and advanced treatment the order of uviol lamp and photochemical catalyst with It is easy to be engaged with low-temperature plasma reactor, and then realizes further improving lacquer spraying waste gas treatment effeciency.
The specific embodiment of present invention described above, is not intended to limit the scope of the present invention..Any basis Various other corresponding change and deformation that technology design of the invention is made, should be included in the guarantor of the claims in the present invention In the range of shield.

Claims (7)

1. a kind of low temperature plasma waste gas cleaning device, it is characterised in that including the cylinder (1) with purification cavity, along spray painting Exhaust gas flow direction is set in turn in filter layer (2), the first photochemical catalytic oxidation mechanism (3), low temperature in the purification cavity etc. Plasma reactor (4) and the second photochemical catalytic oxidation mechanism (5);The first photochemical catalytic oxidation mechanism (3) is including useless along spray painting The first ultraviolet lamp layers (31) and the first photocatalyst layer (32) that flow of air direction sets gradually, the second photochemical catalytic oxidation machine Structure (5) includes the second ultraviolet lamp layers (51), the second photocatalyst layer (52) and that are set gradually along lacquer spraying waste gas flow direction Three ultraviolet lamp layers (53).
2. low temperature plasma waste gas cleaning device according to claim 1, it is characterised in that the first ultraviolet lamp layers (31), the second ultraviolet lamp layers (51) and the 3rd ultraviolet lamp layers (53) include the multiple along the cylinder (1) inwall circumferentially Uviol lamp.
3. low temperature plasma waste gas cleaning device according to claim 2, it is characterised in that the low temperature plasma is anti- Answering device (4) includes the first reaction of low temperature plasma device (41) (4) being arranged in series and the second reaction of low temperature plasma device (42)(4)。
4. low temperature plasma waste gas cleaning device according to claim 3, it is characterised in that first photocatalyst layer And the second photocatalyst layer (52) is network structure (32).
5. low temperature plasma waste gas cleaning device according to claim 4, it is characterised in that the filter layer (2) is glass Glass cotton filters felt material.
6. a kind of low temperature plasma waste gas cleaning method, it is characterised in that comprise the following steps:
(1) lacquer spraying waste gas are carried out tentatively filtering to remove the coating cloud in lacquer spraying waste gas;
(2) lacquer spraying waste gas after step (1) treatment are carried out into photocatalysis pretreatment;
(3) the pretreated lacquer spraying waste gas of photocatalysis are carried out into discharge oxidation degradation treatment;
(4) lacquer spraying waste gas after oxidative degradation is processed carry out photocatalysis advanced treating.
7. low temperature plasma waste gas cleaning method according to claim 6, it is characterised in that the photocatalysis pretreatment, Time of oxidative degradation treatment and photocatalysis advanced treating and be 3.16 seconds.
CN201611042400.4A 2016-11-21 2016-11-21 Low temperature plasma waste gas cleaning device and purification method Pending CN106731541A (en)

Priority Applications (1)

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CN201611042400.4A CN106731541A (en) 2016-11-21 2016-11-21 Low temperature plasma waste gas cleaning device and purification method

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Application Number Priority Date Filing Date Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107115790A (en) * 2017-07-07 2017-09-01 中山市中开环保设备制造有限公司 A kind of VOCs emission-control equipments
CN107224849A (en) * 2017-07-29 2017-10-03 陈锦霖 A kind of low temperature plasma waste gas cleaning device
CN110302668A (en) * 2019-07-26 2019-10-08 中科新天地(合肥)环保科技有限公司 A kind of plasma body cooperative photocatalysis charging crane of organic exhaust gas reaction unit

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2778371Y (en) * 2005-03-17 2006-05-10 上海锦惠复洁环境工程有限公司 Plasma and light catalyzing combined air purifier device
CN103056155A (en) * 2012-12-25 2013-04-24 浙江工商大学 Reactor for treating contaminated soil with low-temperature plasma and photocatalysis and treatment method thereof
CN204447756U (en) * 2015-02-02 2015-07-08 广东东日环保有限公司 The device of photocatalysis cooperating with low-temperature plasma treatment organic exhaust gas
CN205760626U (en) * 2016-06-29 2016-12-07 山东昊威环保科技有限公司 Photoelectric integral emission-control equipment

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2778371Y (en) * 2005-03-17 2006-05-10 上海锦惠复洁环境工程有限公司 Plasma and light catalyzing combined air purifier device
CN103056155A (en) * 2012-12-25 2013-04-24 浙江工商大学 Reactor for treating contaminated soil with low-temperature plasma and photocatalysis and treatment method thereof
CN204447756U (en) * 2015-02-02 2015-07-08 广东东日环保有限公司 The device of photocatalysis cooperating with low-temperature plasma treatment organic exhaust gas
CN205760626U (en) * 2016-06-29 2016-12-07 山东昊威环保科技有限公司 Photoelectric integral emission-control equipment

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107115790A (en) * 2017-07-07 2017-09-01 中山市中开环保设备制造有限公司 A kind of VOCs emission-control equipments
CN107224849A (en) * 2017-07-29 2017-10-03 陈锦霖 A kind of low temperature plasma waste gas cleaning device
CN110302668A (en) * 2019-07-26 2019-10-08 中科新天地(合肥)环保科技有限公司 A kind of plasma body cooperative photocatalysis charging crane of organic exhaust gas reaction unit

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