CN106699094B - A kind of building decoration engineering ardealite based self-leveling material - Google Patents
A kind of building decoration engineering ardealite based self-leveling material Download PDFInfo
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- CN106699094B CN106699094B CN201611222203.0A CN201611222203A CN106699094B CN 106699094 B CN106699094 B CN 106699094B CN 201611222203 A CN201611222203 A CN 201611222203A CN 106699094 B CN106699094 B CN 106699094B
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- ardealite
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- building decoration
- decoration engineering
- based self
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- 239000000463 material Substances 0.000 title claims abstract description 32
- 238000005034 decoration Methods 0.000 title claims abstract description 21
- 239000000843 powder Substances 0.000 claims abstract description 43
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 33
- 239000004816 latex Substances 0.000 claims abstract description 26
- 229920000126 latex Polymers 0.000 claims abstract description 26
- 239000006004 Quartz sand Substances 0.000 claims abstract description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000004568 cement Substances 0.000 claims abstract description 22
- 239000010440 gypsum Substances 0.000 claims abstract description 21
- 229910052602 gypsum Inorganic materials 0.000 claims abstract description 21
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 17
- 239000012744 reinforcing agent Substances 0.000 claims abstract description 17
- 230000008719 thickening Effects 0.000 claims abstract description 12
- 239000002270 dispersing agent Substances 0.000 claims abstract description 11
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims abstract description 6
- 235000011941 Tilia x europaea Nutrition 0.000 claims abstract description 6
- 239000004571 lime Substances 0.000 claims abstract description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 38
- -1 polyoxyethylene Polymers 0.000 claims description 21
- 235000019353 potassium silicate Nutrition 0.000 claims description 14
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 14
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 11
- 239000002893 slag Substances 0.000 claims description 10
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 10
- CDOUZKKFHVEKRI-UHFFFAOYSA-N 3-bromo-n-[(prop-2-enoylamino)methyl]propanamide Chemical compound BrCCC(=O)NCNC(=O)C=C CDOUZKKFHVEKRI-UHFFFAOYSA-N 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 claims description 9
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 9
- 235000006040 Prunus persica var persica Nutrition 0.000 claims description 8
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims description 8
- 235000015393 sodium molybdate Nutrition 0.000 claims description 8
- 239000011684 sodium molybdate Substances 0.000 claims description 8
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 7
- 229940120146 EDTMP Drugs 0.000 claims description 7
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 7
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims description 7
- MDFFNEOEWAXZRQ-UHFFFAOYSA-N aminyl Chemical compound [NH2] MDFFNEOEWAXZRQ-UHFFFAOYSA-N 0.000 claims description 7
- 238000009833 condensation Methods 0.000 claims description 7
- 230000005494 condensation Effects 0.000 claims description 7
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 claims description 7
- 239000001630 malic acid Substances 0.000 claims description 7
- 235000011090 malic acid Nutrition 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- 238000009628 steelmaking Methods 0.000 claims description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 6
- 239000005977 Ethylene Substances 0.000 claims description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 6
- 229920002472 Starch Polymers 0.000 claims description 6
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 6
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims description 6
- GLVVKKSPKXTQRB-UHFFFAOYSA-N ethenyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC=C GLVVKKSPKXTQRB-UHFFFAOYSA-N 0.000 claims description 6
- 239000008107 starch Substances 0.000 claims description 6
- 235000019698 starch Nutrition 0.000 claims description 6
- 229920001897 terpolymer Polymers 0.000 claims description 6
- 230000032683 aging Effects 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 235000005074 zinc chloride Nutrition 0.000 claims description 5
- 239000011592 zinc chloride Substances 0.000 claims description 5
- 108010010803 Gelatin Proteins 0.000 claims description 4
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 claims description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 4
- 229920000159 gelatin Polymers 0.000 claims description 4
- 239000008273 gelatin Substances 0.000 claims description 4
- 235000019322 gelatine Nutrition 0.000 claims description 4
- 235000011852 gelatine desserts Nutrition 0.000 claims description 4
- 229960003330 pentetic acid Drugs 0.000 claims description 4
- 159000000000 sodium salts Chemical class 0.000 claims description 4
- 229940117958 vinyl acetate Drugs 0.000 claims description 4
- MSWMMJONWLTTGS-UHFFFAOYSA-N 2-hydroxy-2-oxoacetate;triethylazanium Chemical compound OC(=O)C(O)=O.CCN(CC)CC MSWMMJONWLTTGS-UHFFFAOYSA-N 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 229920003086 cellulose ether Polymers 0.000 claims description 3
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 3
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 3
- 229960001763 zinc sulfate Drugs 0.000 claims description 3
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 3
- 229920000388 Polyphosphate Polymers 0.000 claims description 2
- 239000001205 polyphosphate Substances 0.000 claims description 2
- 235000011176 polyphosphates Nutrition 0.000 claims description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 1
- 240000006413 Prunus persica var. persica Species 0.000 claims 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical group CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims 1
- 229910052796 boron Inorganic materials 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims 1
- 206010063385 Intellectualisation Diseases 0.000 abstract description 2
- 239000003638 chemical reducing agent Substances 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 244000144730 Amygdalus persica Species 0.000 description 6
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 6
- 239000005329 float glass Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 6
- WPJGWJITSIEFRP-UHFFFAOYSA-N 1,3,5-triazine-2,4,6-triamine;hydrate Chemical compound O.NC1=NC(N)=NC(N)=N1 WPJGWJITSIEFRP-UHFFFAOYSA-N 0.000 description 5
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 5
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 5
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 5
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical group OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 5
- ZMANZCXQSJIPKH-UHFFFAOYSA-O triethylammonium ion Chemical compound CC[NH+](CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-O 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 3
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 239000000292 calcium oxide Substances 0.000 description 3
- 235000012255 calcium oxide Nutrition 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000006266 etherification reaction Methods 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical group O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- KBIWNQVZKHSHTI-UHFFFAOYSA-N 4-n,4-n-dimethylbenzene-1,4-diamine;oxalic acid Chemical compound OC(=O)C(O)=O.CN(C)C1=CC=C(N)C=C1 KBIWNQVZKHSHTI-UHFFFAOYSA-N 0.000 description 1
- JKTORXLUQLQJCM-UHFFFAOYSA-N 4-phosphonobutylphosphonic acid Chemical compound OP(O)(=O)CCCCP(O)(O)=O JKTORXLUQLQJCM-UHFFFAOYSA-N 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Natural products OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- 240000005809 Prunus persica Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 235000011132 calcium sulphate Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000011507 gypsum plaster Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000002686 phosphate fertilizer Substances 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
- C04B28/142—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements
- C04B28/143—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements the synthetic calcium sulfate being phosphogypsum
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B11/00—Calcium sulfate cements
- C04B11/26—Calcium sulfate cements strating from chemical gypsum; starting from phosphogypsum or from waste, e.g. purification products of smoke
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention belongs to building intellectualization installing engineering technical fields, disclose a kind of building decoration engineering building decoration engineering ardealite based self-leveling material, weight percentage of each component is as follows: modified ardealite 50%-60%, cement 10%-15%, lime 0-5%, redispersable latex powder 1%-5%, retarder 0.03%-0.2%, thickening water-retaining agent 0.05%-0.1%, gypsum reinforcing agent 0.5%-1%, levelling dispersing agent 0.5%-1%, defoaming agent 0.005%-0.01%, surplus are quartz sand tailing.Ardealite utilization rate of the present invention is high, material property is good, has good economical and environmentally friendly benefit.
Description
Technical field
The invention belongs to building intellectualization installing engineering technical fields, and in particular to a kind of building decoration engineering building dress
Adorn engineering ardealite based self-leveling material.
Background technique
Ardealite is that wet process manufactures the waste residue being discharged when phosphoric acid in phosphorous chemical industry, and 1 ton of phosphoric acid of every production is (with P2O5Meter) it generates about
4.5~5.5 tons of by-product ardealite, about 80,000,000 tons of China's ardealite yield in 2015, while there is also about 2.5 hundred million in China
The ardealite history stockpiling of ton.The accumulation not only land occupation, but also waste of resource of a large amount of ardealite, wherein the acidity that contains and its
His harmful substance is easy to pollute surrounding enviroment, endangers ecological environment.Leaching Properties of Soluble Phosphorus, fluorine, organic matter in ardealite etc. are miscellaneous
Matter is made the building gypsum plaster prepared using ardealite the adverse consequences such as setting time is long, intensity is low occur, seriously restricts phosphorus stone
The extensive application of cream.The improvement of ardealite and Utilizing question are a global problems.Many phosphate fertilizer producers bear heavy thus
Weight, ardealite problem have become the world-famous puzzle of the sustainable development of relationship phosphorous chemical industry and environmental protection.
Main component in ardealite is calcium sulphate dihydrate, production gypsum base building materials be now efficiently use in fact it is main
Approach.Self-leveling material is one kind using cementitious material as base-material, and various additives modifications are added is used for the novel of floor leveling
Earth material.Chinese patent CN102643065A discloses a kind of ardealite self-leveling material, changes in the invention self-leveling material
Property ardealite has only accounted for 30%.
Summary of the invention
The purpose of the present invention is to provide a kind of ardealite dosage be more than 50% building decoration engineering with ardealite base from
Levelling material reduces land seizure caused by due to ardealite discharge and the problem of environmental pollution.
In order to achieve the above objectives, the present invention uses following technical scheme, a kind of building decoration engineering ardealite base gravity flow
Flat material, weight percentage of each component are as follows:
Modified ardealite: 50%-60%
Cement: 10%-15%
Lime: 0-5%
Latex powder: 2%-5%
Retarder: 0.03%-0.2%
Thicken water-retaining agent: 0.05%-0.1%
Gypsum reinforcing agent: 0.5%-1%
Levelling dispersing agent: 0.5%-1%
Defoaming agent: 0.005%-0.01%
Quartz sand tailing: surplus
The preparation method of the modified ardealite is: by ardealite and the modifying agent for accounting for ardealite total weight 5%-6%
Ageing reaction 20h-25h, then dries at 160 DEG C -180 DEG C and both obtained after being mixed with water.
The modifying agent is by steel-making slag powder, waterglass, ethanedioic acid triethylammonium tetrakis and ethylenediamine tetramethylene phosphonic acid according to weight
It is formed than 100:2-5:0.1-0.5:0.1-0.5.
The waterglass solid content 38%-42%, modulus 2.5-3.2.
The cement is PO42.5 cement
The latex powder is ethylene and vinyl chloride and vinyl laurate terpolymer latex powder, vinylacetate homopolymerization
One of latex powder.
The retarder is malic acid, citric acid, the five sodium-salt of diethylene-triamine pentaacetic acid, polyphosphate, chlorination
One of zinc, zinc sulfate or more than one.
Preferably, the retarder is made of malic acid and zinc chloride by weight 1:8.
The thickening water-retaining agent is one of fish-bone albumen, cellulose ether, gelatin, peach gum, carboxymethyl starch ether or one
Kind or more.
Preferably, institute's cellulose ether is hydroxypropyl methyl cellulose ether of the degree of etherification falling between 1.2-1.5.
The gypsum reinforcing agent is one of line borate, calgon, aluminum phosphate, sodium molybdate or more.
Preferably, the gypsum reinforcing agent is made of aluminum phosphate and sodium molybdate according to weight ratio 1:1.
The levelling dispersing agent is made of water-reducing agent, desugar condensation sodium lignin sulfonate, dioctyl sodium sulfosuccinate.
Preferably, the levelling agent by water-reducing agent, desugar condensation sodium lignin sulfonate, dioctyl sodium sulfosuccinate by being pressed
Weight ratio 7:2:1 composition.
It is furthermore preferred that the water-reducing agent is powder melamine water reducing agent.
The defoaming agent be one of tributyl phosphate, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether or
More than.
The quartz sand tailing is by the float glass tailing generated in quartz sand powder process of manufacture, and fineness is
- 150 mesh of 120 mesh.
Steel-making slag powder in the present invention in phosphogypsum modification agent can provide alkaline environment for system, in such circumstances steel slag and phosphorus
Gypsum is capable of forming entringite and C-S-H gel, forms spacial framework, calcium and aluminium therein can be with the sulfuric acid in ardealite
Calcium reaction, forms the lower hydrated calcium aluminate sulfate class hydrated product of solubility, to be dissolved into being adsorbed on calcium sulfate in ardealite
The impurity such as phosphorus, the fluorine on surface；Waterglass can react the salt for generating indissoluble with the fluorine in ardealite；Ethanedioic acid triethylammonium tetrakis and second two
With calcium ion complex reaction can occur for amine tetramethylene phosphonic acid, generate stable complex compound, this complex compound is attached to crystal table
Face increases the surface energy of crystal, slows down crystalline growth velocity, make crystal Surface Generation Velocity difference, adjust crystal form.Peach gum
There are thickening, water conservation with carboxymethyl starch ether, avoids isolation, the bleeding problem of self-leveling material of the present invention.Defoaming agent can
Material internal defect is eliminated, the strength of materials is improved.
Beneficial effects of the present invention:
(1) ardealite utilization rate is high, can reduce land seizure caused by ardealite, steel slag stacking and cause to ambient enviroment
Pollution, reduce the consumption of the natural gypsum, with circular economy, low-carbon economy dual characteristics.
(2) rational proportion of various raw material has building decoration engineering ardealite based self-leveling material of the present invention
Good performance.
Specific embodiment
Son illustrates the present invention with reference to embodiments.
Embodiment 1
A kind of building decoration engineering ardealite based self-leveling material, weight percentage of each component are as follows: modified ardealite
50%, cement 10%, latex powder 2%, retarder 0.03%, thickening water-retaining agent 0.05%, gypsum reinforcing agent 0.5%, levelling point
Powder 0.5%, defoaming agent 0.005%, surplus are quartz sand tailing；
The preparation method of the modified ardealite is: ardealite is added water with the modifying agent for accounting for ardealite total weight 5%
Ageing reaction 20h after mixing, then dries at 160 DEG C and both obtained, the modifying agent is by steel-making slag powder, waterglass, second two
Sour triethylammonium tetrakis and ethylenediamine tetramethylene phosphonic acid are formed according to weight ratio 100:2:0.5:0.1, the waterglass solid content 38%,
Modulus 2.5.
The cement is PO42.5 cement.
The latex powder is ethylene and vinyl chloride and vinyl laurate terpolymer latex powder.
The retarder is malic acid.
The thickening water-retaining agent is fish-bone albumen.
The gypsum reinforcing agent is line borate.
The levelling dispersing agent is by water-reducing agent, desugar condensation sodium lignin sulfonate, dioctyl sodium sulfosuccinate according to weight
Amount is formed than 5:2:1.
The defoaming agent is tributyl phosphate.
The quartz sand tailing is by the float glass tailing generated in quartz sand powder process of manufacture, and fineness is
- 150 mesh of 120 mesh.
Embodiment 2
A kind of building decoration engineering ardealite based self-leveling material, weight percentage of each component are as follows: modified ardealite
60%, cement 15%, lime 5%, latex powder 5%, retarder 0.2%, thickening water-retaining agent 0.1%, gypsum reinforcing agent 1%, stream
Dividing powder 1%, defoaming agent 0.01%, surplus equally is quartz sand tailing；
The preparation method of the modified ardealite is: ardealite is added water with the modifying agent for accounting for ardealite total weight 6%
Ageing reaction 25h after mixing, then dries at 180 DEG C and both obtained, the modifying agent is by steel-making slag powder, waterglass, second two
Sour triethylammonium tetrakis and ethylenediamine tetramethylene phosphonic acid are formed according to weight ratio 100:5:0.1:0.5.
The waterglass solid content 42%, modulus 3.2.
The cement is PO42.5 cement.
The latex powder is vinylacetate homopolymerization latex powder.
The retarder is by the five sodium-salt, tripolyphosphate, zinc sulfate of diethylene-triamine pentaacetic acid according to weight ratio 1:
2:2 composition.
The thickening water-retaining agent is made of gelatin and peach gum according to weight ratio 1:1.
The gypsum reinforcing agent is made of line borate, aluminum phosphate, sodium molybdate according to weight ratio 1:1:1.
The levelling dispersing agent is condensed sodium lignin sulfonate, dioctyl sodium sulfosuccinate by weight by water-reducing agent, desugar
It is formed than 5:3:1.
The defoaming agent is made of polyoxyethylene polyoxy propyl alcohol amidogen ether and polypropylene glycerol aether by weight 1:1.
The quartz sand tailing is by the float glass tailing generated in quartz sand powder process of manufacture, and fineness is
- 150 mesh of 120 mesh.
Embodiment 3
A kind of building decoration engineering ardealite based self-leveling material, weight percentage of each component are as follows: modified ardealite
58%, cement 14%, quick lime 2%, latex powder 3%, retarder 0.15%, thickening water-retaining agent 0.08%, gypsum reinforcing agent
0.7%, levelling dispersing agent 0.8%, defoaming agent 0.008%, surplus are quartz sand tailing；
The preparation method of the modified ardealite is: ardealite is added with the modifying agent for accounting for ardealite total weight 5.5%
Water is aged reaction for 24 hours after mixing, then dries at 170 DEG C and both obtained, the modifying agent is by steel-making slag powder, waterglass, second
Diacid triethylammonium tetrakis and ethylenediamine tetramethylene phosphonic acid are formed according to weight ratio 100:3:0.5:0.5.
The waterglass solid content 40%, modulus 3.0.
The cement is PO42.5 cement.
The latex powder is ethylene and vinyl chloride and vinyl laurate terpolymer latex powder.
The retarder is made of malic acid and zinc chloride by weight 1:8.
It is described thickening water-retaining agent by hydroxypropyl methyl cellulose ether, peach gum, carboxymethyl starch ether according to 1:3:1 weight ratio
Composition, the degree of etherification falling of the hydroxypropyl methyl cellulose ether is between 1.2-1.5.
The gypsum reinforcing agent is made of aluminum phosphate and sodium molybdate according to weight ratio 1:1.
The levelling agent is pressed by melamine water reducing agent, desugar condensation sodium lignin sulfonate, dioctyl sodium sulfosuccinate
Weight ratio 7:2:1 composition.
The defoaming agent is by tributyl phosphate, polyoxyethylene polyoxy propyl alcohol amidogen ether and polypropylene glycerol aether by weight 1:
1:1 composition.
The quartz sand tailing is by the float glass tailing generated in quartz sand powder process of manufacture, and fineness is
- 150 mesh of 120 mesh.
Embodiment 4
A kind of building decoration engineering ardealite based self-leveling material, weight percentage of each component are as follows: modified ardealite
60%, cement 12%, white lime 1%, latex powder 3%, melamine water reducing agent 0.6%, retarder: 0.03%-0.2%, increasing
Thick water-retaining agent: 0.05%-0.1%, gypsum reinforcing agent: 0.5%-1%, levelling dispersing agent: 0.5%-1%, defoaming agent
0.007%, surplus is quartz sand tailing.
Embodiment 5
A kind of building decoration engineering ardealite based self-leveling material, weight percentage of each component are as follows: modified ardealite
55%, cement 14%, lime 1%, vinylacetate homopolymerization latex powder 3%, citric acid 0.05%, diethylene-triamine pentaacetic acid
Five sodium-salt 0.05%, gelatin 0.05%, peach gum 0.02%, calgon 0.6%, sodium molybdate 0.1%, polycarboxylate water-reducer
0.5%, desugar is condensed sodium lignin sulfonate 0.1%, dioctyl sodium sulfosuccinate 0.05%, tributyl phosphate 0.002%, gathers
Ethylene oxide polyoxy propyl alcohol amidogen ether 0.003%, polypropylene glycerol aether 0.001%, peach gum 0.03%-0.08%, carboxymethyl starch
Ether 0.03%-0.08%, surplus are quartz sand tailing；
The preparation method of the modified ardealite is: by ardealite and the modifying agent for accounting for ardealite total weight 5%-6%
Ageing reaction 20h-25h, then dries at 160 DEG C -180 DEG C and both obtained after being mixed with water.The modifying agent is by steel slag
Powder, waterglass, ethanedioic acid triethylammonium tetrakis and ethylenediamine tetramethylene phosphonic acid are according to weight ratio 100:2-5:0.1-0.5:0.1-0.5 group
At.
The waterglass solid content 38%-42%, modulus 2.5-3.2.
Comparative example 1
A kind of building decoration engineering ardealite based self-leveling material, weight percentage of each component are as follows: original state ardealite
58%, cement 14%, quick lime 2%, latex powder 3%, retarder 0.15%, thickening water-retaining agent 0.08%, gypsum reinforcing agent
0.7%, levelling dispersing agent 0.8%, defoaming agent 0.008%, surplus are quartz sand tailing；
The cement is PO42.5 cement.
The latex powder is ethylene and vinyl chloride and vinyl laurate terpolymer latex powder.
The retarder is made of malic acid and zinc chloride by weight 1:8.
It is described thickening water-retaining agent by hydroxypropyl methyl cellulose ether, peach gum, carboxymethyl starch ether according to 1:3:1 weight ratio
Composition, the degree of etherification falling of the hydroxypropyl methyl cellulose ether is between 1.2-1.5.
The gypsum reinforcing agent is made of aluminum phosphate and sodium molybdate according to weight ratio 1:1.
The levelling agent is pressed by melamine water reducing agent, desugar condensation sodium lignin sulfonate, dioctyl sodium sulfosuccinate
Weight ratio 7:2:1 composition.
The defoaming agent is by tributyl phosphate, polyoxyethylene polyoxy propyl alcohol amidogen ether and polypropylene glycerol aether by weight 1:
1:1 composition.
The quartz sand tailing is by the float glass tailing generated in quartz sand powder process of manufacture, and fineness is
- 150 mesh of 120 mesh.
Comparative example 2
A kind of building decoration engineering ardealite based self-leveling material, weight percentage of each component are as follows: modified ardealite
58%, cement 14%, quick lime 2%, latex powder 3%, retarder 0.15%, gypsum reinforcing agent 0.7%, levelling dispersing agent
0.8%, defoaming agent 0.008%, surplus are quartz sand tailing；
The preparation method of the modified ardealite is: ardealite is added with the modifying agent for accounting for ardealite total weight 5.5%
Water is aged reaction for 24 hours after mixing, then dries at 170 DEG C and both obtained, the modifying agent is by steel-making slag powder, waterglass, second
Diacid triethylammonium tetrakis and ethylenediamine tetramethylene phosphonic acid are formed according to weight ratio 100:3:0.5:0.5.
The waterglass solid content 40%, modulus 3.0.
The cement is PO42.5 cement.
The latex powder is ethylene and vinyl chloride and vinyl laurate terpolymer latex powder.
The retarder is made of malic acid and zinc chloride by weight 1:8.
The gypsum reinforcing agent is made of aluminum phosphate and sodium molybdate according to weight ratio 1:1.
The levelling agent is pressed by melamine water reducing agent, desugar condensation sodium lignin sulfonate, dioctyl sodium sulfosuccinate
Weight ratio 7:2:1 composition.
The defoaming agent is by tributyl phosphate, polyoxyethylene polyoxy propyl alcohol amidogen ether and polypropylene glycerol aether by weight 1:
1:1 composition.
The quartz sand tailing is by the float glass tailing generated in quartz sand powder process of manufacture, and fineness is
- 150 mesh of 120 mesh.
Performance test
Reference standard JC/T1023-2007 " gypsum based self-leveling mortar " is to 1-5 of the embodiment of the present invention and comparative example 1-2
Some main performances of self-leveling material be tested, as a result see the table below 1.
1 material property of table
Claims (6)
1. a kind of building decoration engineering ardealite based self-leveling material, which is characterized in that weight percentage of each component is as follows: changing
Property ardealite 50%-60%, cement 10%-15%, lime 0-5%, latex powder 1%-5%, retarder 0.03%-0.2%, increase
Thick water-retaining agent 0.05%-0.1%, gypsum reinforcing agent 0.5%-1%, levelling dispersing agent 0.5%-1%, defoaming agent 0.005%-
0.01%, surplus is quartz sand tailing；
The preparation method of the modified ardealite is: ardealite is added water with the modifying agent for accounting for ardealite total weight 5%-6%
Ageing reaction 20h-25h after mixing, it is then obtained by drying at 160 DEG C -180 DEG C；The modifying agent is by steel-making slag powder, water
Glass, ethanedioic acid triethylammonium tetrakis and ethylenediamine tetramethylene phosphonic acid are formed according to weight ratio 100:2-5:0.1-0.5:0.1-0.5；Institute
State thickening water-retaining agent be one of fish-bone albumen, cellulose ether, gelatin, peach gum, carboxymethyl starch ether or more than one.
2. building decoration engineering according to claim 1 ardealite based self-leveling material, the latex powder be ethylene with
One of vinyl chloride and vinyl laurate terpolymer latex powder, vinylacetate homopolymerization latex powder.
3. building decoration engineering according to claim 1 ardealite based self-leveling material, the retarder be malic acid,
One of citric acid, the five sodium-salt of diethylene-triamine pentaacetic acid, polyphosphate, zinc chloride, zinc sulfate or more than one.
4. building decoration engineering according to claim 1 ardealite based self-leveling material, the gypsum reinforcing agent are boron
One of sour calcium, calgon, aluminum phosphate, sodium molybdate or more.
5. building decoration engineering according to claim 1 ardealite based self-leveling material, the levelling dispersing agent is by subtracting
Aqua, desugar condensation sodium lignin sulfonate, dioctyl sodium sulfosuccinate composition.
6. building decoration engineering according to claim 1 ardealite based self-leveling material, the defoaming agent is tricresyl phosphate
One of butyl ester, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether or more.
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| CN109851307A (en) * | 2019-03-15 | 2019-06-07 | 四川轻化工大学 | Phosphogypsum matrix building material and preparation method thereof |
| CN111606647A (en) * | 2019-04-29 | 2020-09-01 | 中建材创新科技研究院有限公司 | Phosphogypsum self-leveling mortar and preparation method thereof |
| CN112390607B (en) * | 2020-11-18 | 2022-06-07 | 中国建筑科学研究院有限公司 | A kind of geotechnical solidifying agent prepared by utilizing low-grade raw materials and preparation method thereof |
| CN115677315A (en) * | 2022-11-14 | 2023-02-03 | 贵州砂浆博士科技有限公司 | Phosphogypsum anti-cracking mortar and preparation method thereof |
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| CN102643065A (en) * | 2011-02-17 | 2012-08-22 | 徐迅 | Phosphogypsum self-leveling material |
| CN102731047A (en) * | 2012-06-11 | 2012-10-17 | 西南科技大学 | Self-leveling mortar material with phosphogypsum as filling material, and preparation method thereof |
| CN103274659A (en) * | 2013-05-13 | 2013-09-04 | 武汉理工大学 | Ardealite-based self-leveling material |
| CN104692755A (en) * | 2015-02-02 | 2015-06-10 | 武汉理工大学 | Phosphogypsum-base self-leveling material and preparation method thereof |
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| CN102643065A (en) * | 2011-02-17 | 2012-08-22 | 徐迅 | Phosphogypsum self-leveling material |
| CN102731047A (en) * | 2012-06-11 | 2012-10-17 | 西南科技大学 | Self-leveling mortar material with phosphogypsum as filling material, and preparation method thereof |
| CN103274659A (en) * | 2013-05-13 | 2013-09-04 | 武汉理工大学 | Ardealite-based self-leveling material |
| CN104692755A (en) * | 2015-02-02 | 2015-06-10 | 武汉理工大学 | Phosphogypsum-base self-leveling material and preparation method thereof |
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