CN106685355A - A photovoltaic photothermal integrated device - Google Patents

A photovoltaic photothermal integrated device Download PDF

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Publication number
CN106685355A
CN106685355A CN201710073979.9A CN201710073979A CN106685355A CN 106685355 A CN106685355 A CN 106685355A CN 201710073979 A CN201710073979 A CN 201710073979A CN 106685355 A CN106685355 A CN 106685355A
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heat
solar cell
photovoltaic
collecting plate
blue film
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吕静
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Chengdu Poly Technology Co Ltd
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Chengdu Poly Technology Co Ltd
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    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02SGENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
    • H02S40/00Components or accessories in combination with PV modules, not provided for in groups H02S10/00 - H02S30/00
    • H02S40/40Thermal components
    • H02S40/44Means to utilise heat energy, e.g. hybrid systems producing warm water and electricity at the same time
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02SGENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
    • H02S40/00Components or accessories in combination with PV modules, not provided for in groups H02S10/00 - H02S30/00
    • H02S40/40Thermal components
    • H02S40/42Cooling means
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F19/00Integrated devices, or assemblies of multiple devices, comprising at least one photovoltaic cell covered by group H10F10/00, e.g. photovoltaic modules
    • H10F19/80Encapsulations or containers for integrated devices, or assemblies of multiple devices, having photovoltaic cells
    • H10F19/85Protective back sheets
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/60Thermal-PV hybrids

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  • Photovoltaic Devices (AREA)

Abstract

The present invention relates to a photovoltaic and photo-thermal integrated device. The device comprises a solar cell piece array, one side of the solar cell piece array is provided with an armorplate glass, the other side of the solar cell piece array is provided with a backboard, EVA cushions are pasted between the solar cell piece array and the armorplate glass and between the solar cell piece array and the backboard, the solar cell piece array comprises a plurality of solar cell pieces which are connected through a solder strip and arranged in the array mode, and there is a gap between each two adjacent solar cell pieces; the backboard is a transparent backboard; a blue film heat-collection plate is arranged at the lower portion of the transparent backboard, and the blue film heat-collection plate comprises a heat-collection plate core and a blue film coating plated at the upper surface of the heat-collection plate core. The photovoltaic and photo-thermal integrated device can effectively reduce the work temperature of the solar cell piece array to allow the solar cell piece array to be located at a stable work state so as to improve the solar energy photoelectric conversion efficiency, improve the solar energy photo-thermal conversion efficiency and improve the solar energy integration utilization efficiency.

Description

一种光伏光热一体化装置A photovoltaic photothermal integrated device

技术领域technical field

本发明涉及太阳能光伏光热技术领域,特别是涉及一种光伏光热一体化装置。The invention relates to the field of solar photovoltaic photothermal technology, in particular to a photovoltaic photothermal integrated device.

背景技术Background technique

太阳能是一种清洁、经济、稳定的能源。我国的太阳能资源相对丰富,光伏发电和太阳能热水器产业经过几年的快速发展已经形成了产业化生产,技术不断创新,产品性能得到不断的改进优化,目前正在被广泛的应用。在光伏发电过程中,太阳能利用效率只有百分之十几,大量能量被电池吸收转换为热能,若对这些能量进行回收,可大大提高太阳能的利用率。Solar energy is a clean, economical and stable energy source. Our country is relatively rich in solar energy resources. After several years of rapid development, the photovoltaic power generation and solar water heater industries have formed industrialized production, with continuous technological innovation and continuous improvement and optimization of product performance. They are currently being widely used. In the process of photovoltaic power generation, the utilization efficiency of solar energy is only more than ten percent, and a large amount of energy is absorbed by the battery and converted into heat energy. If the energy is recovered, the utilization rate of solar energy can be greatly improved.

对于平板晶硅太阳能电池,工作电压(Vmp)的温度系数约为-0.0045/℃;开路电压(Voc)的温度系数约为-0.0034/℃。对于薄膜太阳能电池,工作电压(Vmp)的温度系数约为-0.0028/℃(折合70℃的系数为0.874);开路电压Voc的温度系数约为-0.0028/℃(折合-10℃时的系数为1.1)。 在光伏发电过程中,随着太阳能电池结温,温度上升使太阳能电池开路电压Voc下降,短路电流Isc则轻微增大,总体会造成太阳能电池的输出功率下降。For flat crystalline silicon solar cells, the temperature coefficient of the operating voltage (Vmp) is about -0.0045/°C; the temperature coefficient of the open circuit voltage (Voc) is about -0.0034/°C. For thin-film solar cells, the temperature coefficient of the working voltage (Vmp) is about -0.0028/°C (the coefficient at 70°C is 0.874); the temperature coefficient of the open circuit voltage Voc is about -0.0028/°C (the coefficient at -10°C is 1.1). In the process of photovoltaic power generation, as the solar cell junction temperature rises, the open-circuit voltage Voc of the solar cell decreases, and the short-circuit current Isc increases slightly, which generally causes the output power of the solar cell to decrease.

针对太阳能电池温度升高会造成太阳能电池的输出功率下降的问题,对光电产业是一个重要的课题。Aiming at the problem that the output power of the solar cell will decrease due to the temperature rise of the solar cell, it is an important subject for the photovoltaic industry.

发明内容Contents of the invention

本发明的目的是克服上述现有技术的不足,提供一种光伏光热一体化装置,旨在提高太阳能光电转换效率的同时,提高太阳能的光热转化效率,从而提高太阳能的综合利用效率。The purpose of the present invention is to overcome the shortcomings of the above-mentioned prior art and provide a photovoltaic photothermal integrated device, which aims at improving the photoelectric conversion efficiency of solar energy and at the same time improving the photothermal conversion efficiency of solar energy, thereby improving the comprehensive utilization efficiency of solar energy.

为实现上述目的,本发明提出的一种光伏光热一体化装置,包括太阳能电池片阵列,所述太阳能电池片阵列的一侧设有钢化玻璃板,另一侧设有背板,所述太阳能电池片阵列与所述钢化玻璃板之间以及所述背板之间均粘结有EVA垫层,所述太阳能电池片阵列包括多个依次通过焊带相连呈阵列布置的太阳能电池片,每相邻的两个所述太阳能电池片之间均设有间隙;所述背板为透明背板;所述透明背板的下面粘结有蓝膜集热板,所述蓝膜集热板包括集热板芯和镀设于所述集热板芯上表面的蓝膜镀层,所述太阳能电池片包括依次层叠的衬底、金属钼背电极层、CIGS吸收层、CdS缓冲层、ZnO本征窗口层、连接层、CGS吸收层、CdS缓冲层、ZnO本征窗口层、ITO导电窗口层以及银电极层。In order to achieve the above object, the present invention proposes a photovoltaic photothermal integrated device, including a solar cell array, one side of the solar cell array is provided with a tempered glass plate, and the other side is provided with a back plate, and the solar cell array An EVA gasket is bonded between the cell array and the tempered glass plate and between the back plate, and the solar cell array includes a plurality of solar cells connected in sequence by welding ribbons and arranged in an array, each phase There are gaps between the two adjacent solar cell sheets; the backboard is a transparent backboard; a blue film heat collecting plate is bonded under the transparent back plate, and the blue film heat collecting plate includes a heat collecting plate The heat plate core and the blue film coating layer plated on the upper surface of the heat collecting plate core, the solar cell sheet includes a sequentially stacked substrate, a metal molybdenum back electrode layer, a CIGS absorbing layer, a CdS buffer layer, and a ZnO intrinsic window layer, connection layer, CGS absorber layer, CdS buffer layer, ZnO intrinsic window layer, ITO conductive window layer and silver electrode layer.

作为一种改进的方案,所述太阳能电池片与所述间隙之间的分布比例为横向1:3~1:5,纵向1:2~1:3。As an improved solution, the distribution ratio between the solar cells and the gap is 1:3-1:5 in the transverse direction and 1:2-1:3 in the longitudinal direction.

作为一种改进的方案,所述太阳能电池片与所述间隙之间的分布比例为横向1:4,纵向1:2.5。As an improved solution, the distribution ratio between the solar cells and the gap is 1:4 in the horizontal direction and 1:2.5 in the vertical direction.

作为一种改进的方案,所述集热板芯为铝合金集热板芯。As an improved solution, the heat collecting plate core is an aluminum alloy heat collecting plate core.

作为一种改进的方案,所述透明背板与所述蓝膜集热板之间通过导热胶粘结在一起。As an improved solution, the transparent back plate and the blue film heat collecting plate are bonded together by thermally conductive glue.

作为一种改进的方案,所述集热板芯包括并行设置的多根热管,多根所述热管的进水口共同连通有进水管,多根所述热管的出水口共同连通有出水管,所述热管靠近所述蓝膜集热板的一侧固定连接有上盖板,所述热管远离所述蓝膜集热板的一侧固定连接有下盖板。As an improved solution, the heat collecting plate core includes a plurality of heat pipes arranged in parallel, the water inlets of the plurality of heat pipes are connected to a water inlet pipe, and the water outlets of the plurality of heat pipes are connected to a water outlet pipe, so The side of the heat pipe close to the blue film heat collecting plate is fixedly connected with an upper cover plate, and the side of the heat pipe away from the blue film heat collecting plate is fixedly connected with a lower cover plate.

作为一种改进的方案,所述蓝膜集热板的下面覆设有保温层。As an improved solution, the underside of the blue film heat collecting plate is covered with an insulating layer.

作为一种改进的方案,所述衬底为玻璃衬底、柔性金属箔衬底或柔性聚酰亚胺衬底,所述连接层包括层叠设置的透明金属氧化物导电层和纳米金属导电层,所述透明金属氧化物导电层为Al、Ga 或In掺杂ZnO构成的TCO薄膜,或ITO薄膜之一种;所述纳米金属导电层为Mo薄膜。As an improved solution, the substrate is a glass substrate, a flexible metal foil substrate or a flexible polyimide substrate, and the connection layer includes a transparent metal oxide conductive layer and a nano-metal conductive layer that are stacked, The transparent metal oxide conductive layer is a TCO thin film made of Al, Ga or In doped ZnO, or one of ITO thin films; the nano metal conductive layer is a Mo thin film.

本发明提供的光伏光热一体化装置,由于其在相邻的两个太阳能电池片之间均设置了间隙,提升了太阳能电池片的散热能力,并且使用透明背板,不仅能提高太阳光的光透率,还可高效地传递太阳能电池板进行光电转换过程中产生的热量;而透明背板下面粘结的蓝膜集热板,则能够快速且高效地吸收透明背板传递的太阳能电池片在光电转换过程中所产生的热量及透过太阳能电池板之间的间隙的太阳光直射光热,并迅速进行光热转换,而后通过集热板芯将其吸收和转换的热量传递出去,并被人们回收利用。The photovoltaic-photothermal integrated device provided by the present invention has a gap between two adjacent solar cells, which improves the heat dissipation capacity of the solar cells, and uses a transparent back plate, which can not only improve the solar radiation The light transmittance can also efficiently transfer the heat generated during the photoelectric conversion process of the solar cell panel; while the blue film heat collector plate bonded under the transparent back sheet can quickly and efficiently absorb the solar cells transferred by the transparent back sheet The heat generated during the photoelectric conversion process and the sunlight passing through the gap between the solar panels are directly irradiated with light and heat, and the light-to-heat conversion is carried out rapidly, and then the heat absorbed and converted is transferred out through the heat-collecting plate core, and being recycled by people.

本发明提供的光伏光热一体化装置,有效地降低太阳能电池片阵列的工作温度,使其处于稳定的工作状态,提高光电转化效率;而且利用蓝膜集热板芯将太阳能电池片产生的热量及透过太阳能电池板之间的间隙的太阳光直射光热转化吸收,还解决了因空间的限制,实施了光伏发电系统,而无法实施光热系统,造成太阳能利用率低的现象,大大的提高了光能的利用率。尤其在使用屋顶式或墙体式光伏发电系统,并需求热水的地区或工程,可广泛实用,适于批量生产。The photovoltaic photothermal integrated device provided by the present invention can effectively reduce the working temperature of the solar cell array, make it in a stable working state, and improve the photoelectric conversion efficiency; And through the gap between the solar panels, the direct sunlight light-to-heat conversion absorption also solves the problem of low solar energy utilization rate due to the implementation of photovoltaic power generation system due to space constraints, which greatly improves The utilization rate of light energy is improved. Especially in areas or projects that use roof-mounted or wall-mounted photovoltaic power generation systems and require hot water, it can be widely used and suitable for mass production.

附图说明Description of drawings

图1是本发明的光伏光热一体化装置的结构示意图;图2是本发明的集热板芯的管道分布图;图3是本发明的太阳能电池片的结构示意图。Fig. 1 is a schematic structural view of a photovoltaic photothermal integrated device of the present invention; Fig. 2 is a pipeline distribution diagram of a heat collector core of the present invention; Fig. 3 is a structural schematic view of a solar battery sheet of the present invention.

具体实施方式detailed description

为了使本发明的目的、技术方案及优点更加清楚明白,以下结合附图及实施例,对本发明进行进一步详细说明。应当理解,此处所描述的具体实施例仅仅用以解释本发明,并不用于限定本发明。In order to make the object, technical solution and advantages of the present invention clearer, the present invention will be further described in detail below in conjunction with the accompanying drawings and embodiments. It should be understood that the specific embodiments described here are only used to explain the present invention, not to limit the present invention.

本发明提供一种光伏光热一体化装置,包括太阳能电池片阵列,所述太阳能电池片阵列的一侧设有钢化玻璃板,另一侧设有背板,所述太阳能电池片阵列与所述钢化玻璃板之间以及所述背板之间均粘结有EVA垫层,所述太阳能电池片阵列包括多个依次通过焊带相连呈阵列布置的太阳能电池片,每相邻的两个所述太阳能电池片之间均设有间隙;所述背板为透明背板;所述透明背板的下面粘结有蓝膜集热板,所述蓝膜集热板包括集热板芯和镀设于所述集热板芯上表面的蓝膜镀层,所述太阳能电池片包括依次层叠的衬底、金属钼背电极层、CIGS吸收层、CdS缓冲层、ZnO本征窗口层、连接层、CGS吸收层、CdS缓冲层、ZnO本征窗口层、ITO导电窗口层以及银电极层。The present invention provides a photovoltaic photothermal integrated device, which includes a solar cell array, one side of the solar cell array is provided with a toughened glass plate, and the other side is provided with a back plate, and the solar cell array is connected to the solar cell array. EVA pads are bonded between the tempered glass plates and between the back plates, and the solar cell array includes a plurality of solar cell sheets connected in sequence by welding ribbons and arranged in an array, and every two adjacent There are gaps between the solar cells; the back plate is a transparent back plate; a blue film heat collecting plate is bonded under the transparent back plate, and the blue film heat collecting plate includes a heat collecting plate core and a plated plate. The blue film coating on the upper surface of the heat collector core, the solar cell sheet includes a sequentially stacked substrate, metal molybdenum back electrode layer, CIGS absorber layer, CdS buffer layer, ZnO intrinsic window layer, connection layer, CGS absorption layer, CdS buffer layer, ZnO intrinsic window layer, ITO conductive window layer and silver electrode layer.

图1示出了本发明提供的光伏光热一体化装置的结构示意图,为了便于说明,本图仅提供与本发明有关的结构部分。Fig. 1 shows a schematic structural diagram of a photovoltaic photothermal integrated device provided by the present invention. For convenience of description, this figure only provides structural parts related to the present invention.

光伏光热一体化装置包括太阳能电池片阵列,太阳能电池片阵列的一侧设有钢化玻璃板1,另一侧设有背板,太阳能电池片阵列与钢化玻璃板1之间以及背板之间均粘结有EVA垫层2,太阳能电池片阵列包括多个依次通过焊带3相连呈阵列布置的太阳能电池片4,每相邻的两个太阳能电池片4之间均设有间隙;背板为透明背板5;透明背板5的下面粘结有蓝膜集热板,蓝膜集热板包括集热板芯8和镀设于集热板芯上表面的蓝膜镀层7。在该实施例中,采用铝合金材质的集热板芯则可提高其导热性能,提高导热效率。由于在相邻的两个太阳能电池片4之间均设置了间隙,提升了太阳能电池片4的散热能力,并且使用透明背板5,不仅能提高太阳光的光透率,还可高效地传递太阳能电池片4进行光电转换过程中产生的热量;而透明背板下面粘结的蓝膜集热板,则能够快速且高效地吸收透明背板传递的太阳能电池片4在光电转换过程中所产生的热量及透过太阳能电池片4之间的间隙的太阳光直射光热,并迅速进行光热转换,而后通 过集热板芯8将其吸收和转换的热量传递出去,并被人们回收利用。The photovoltaic photothermal integrated device includes a solar cell array, one side of the solar cell array is provided with a tempered glass plate 1, and the other side is provided with a back plate, and the space between the solar cell array and the tempered glass plate 1 and between the back plate Both are bonded with an EVA cushion layer 2, and the solar cell array includes a plurality of solar cell sheets 4 that are connected in an array through welding ribbons 3 in sequence, and gaps are provided between every two adjacent solar cell sheets 4; It is a transparent backboard 5; a blue film heat collecting plate is bonded to the bottom of the transparent back plate 5, and the blue film heat collecting plate includes a heat collecting plate core 8 and a blue film coating 7 plated on the upper surface of the heat collecting plate core. In this embodiment, the heat-collecting plate core made of aluminum alloy can improve its heat conduction performance and heat conduction efficiency. Since gaps are provided between two adjacent solar cells 4, the heat dissipation capacity of the solar cells 4 is improved, and the use of a transparent back plate 5 not only improves the light transmittance of sunlight, but also efficiently transmits The heat generated during the photoelectric conversion process of the solar cells 4; and the blue film heat collector plate bonded under the transparent back plate can quickly and efficiently absorb the heat generated by the solar cells 4 transmitted by the transparent back plate during the photoelectric conversion process. The heat from the solar cells 4 and the sunlight passing through the gaps between the solar cells 4 are directly irradiated with light and heat, and the light and heat are quickly converted, and then the heat absorbed and converted is transferred out through the heat collector plate core 8, and is recycled by people.

以太阳能电池板阵列整体的长度方向为横向,宽度方向为纵向,将太阳能电池片4与该间隙之间的分布比例设置为横向1:3~1:5,纵向1:2~1:3,则可使太阳能的总体利用率达到较佳状态,其中将该分布比例设置为横向1:4和纵向1:2.5,则可使太阳能的总体利用率达到最高。当然,将该分部比例设置为横向1:3或1:5,纵向1:2或1:3也能取得相近或相似的技术效果。Taking the overall length direction of the solar cell panel array as the horizontal direction and the width direction as the vertical direction, the distribution ratio between the solar cells 4 and the gap is set to be 1:3 to 1:5 in the horizontal direction and 1:2 to 1:3 in the vertical direction, Then the overall utilization rate of solar energy can reach a better state, where the distribution ratio is set to 1:4 in the horizontal direction and 1:2.5 in the vertical direction, then the overall utilization rate of the solar energy can be maximized. Of course, setting the division ratio to 1:3 or 1:5 in the horizontal direction and 1:2 or 1:3 in the vertical direction can also achieve similar or similar technical effects.

使用导热胶6将用透明背板5与蓝膜集热板粘结在一起,则有利于透明背板5与蓝膜集热板之间的光热传递,提高光能利用率。Using the heat-conducting adhesive 6 to bond the transparent back plate 5 and the blue film heat collecting plate together is beneficial to the light and heat transfer between the transparent back plate 5 and the blue film heat collecting plate, and improves the utilization rate of light energy.

如图1和图2所示,集热板芯8包括并行设置的多根热管81,多根热管81的进水口共同连通有进水管82,多根热管81的出水口共同连通有出水管83,热管81靠近蓝膜集热板的一侧固定连接有上盖板84,热管81远离蓝膜集热板的一侧固定连接有下盖板85。利用带有多跟热管81的集热板芯8,将蓝模镀层7吸收和转化的热量传递至导热工质,再通过导热工质导出,不仅能够有效地降低太阳能电池片4的工作温度,提高广电转化效率,还有利于太阳光能的充分利用,提高光热转化效率。而且,通过出水管83将热水输送到热水器箱,提供生活用水,从而实现,太阳光能的充分利用,减少能源消耗。在蓝膜集热板的下面覆设有保温层9,则可防止集热板芯8内的热量散发到外界环境中,提高热能回收利用率。As shown in Figures 1 and 2, the heat collecting plate core 8 includes a plurality of heat pipes 81 arranged in parallel, the water inlets of the plurality of heat pipes 81 are connected to a water inlet pipe 82, and the water outlets of the plurality of heat pipes 81 are connected to a water outlet pipe 83. The heat pipe 81 is fixedly connected with an upper cover plate 84 near the blue film heat collecting plate, and the heat pipe 81 is fixedly connected with a lower cover plate 85 at a side away from the blue film heat collecting plate. Using the heat collector plate core 8 with multiple heat pipes 81, the heat absorbed and converted by the blue mold coating 7 is transferred to the heat-conducting working medium, and then exported through the heat-conducting working medium, which can not only effectively reduce the working temperature of the solar cell 4, Improving the conversion efficiency of broadcasting and television is also conducive to the full utilization of solar energy and improving the conversion efficiency of light and heat. Moreover, the hot water is delivered to the water heater tank through the water outlet pipe 83 to provide domestic water, thereby achieving full utilization of solar energy and reducing energy consumption. The heat preservation layer 9 is covered under the blue film heat collecting plate, which can prevent the heat in the heat collecting plate core 8 from dissipating in the external environment, and improve the heat energy recycling rate.

如图1和图3所示,所述太阳能电池片4包括依次层叠的衬底41、金属钼背电极层42、CIGS吸收层43、CdS缓冲层44、ZnO本征窗口层45、连接层46、CGS吸收层47、CdS缓冲层48、ZnO本征窗口层49、ITO导电窗口层50以及银电极层51。所述衬底41为玻璃衬底、柔性金属箔衬底或柔性聚酰亚胺衬底,所述连接层46包括层叠设置的透明金属氧化物导电层和纳米金属导电层,所述透明金属氧化物导电层为Al、Ga 或In掺杂ZnO构成的TCO薄膜,或ITO薄膜之一种;所述纳米金属导电层为Mo薄膜。As shown in Figures 1 and 3, the solar cell 4 includes a substrate 41, a metal molybdenum back electrode layer 42, a CIGS absorber layer 43, a CdS buffer layer 44, a ZnO intrinsic window layer 45, and a connection layer 46 stacked in sequence. , CGS absorption layer 47, CdS buffer layer 48, ZnO intrinsic window layer 49, ITO conductive window layer 50 and silver electrode layer 51. The substrate 41 is a glass substrate, a flexible metal foil substrate or a flexible polyimide substrate, and the connection layer 46 includes a transparent metal oxide conductive layer and a nano-metal conductive layer stacked, and the transparent metal oxide The material conductive layer is a TCO thin film made of Al, Ga or In doped ZnO, or one of ITO thin films; the nanometer metal conductive layer is a Mo thin film.

本发明提供的光伏光热一体化装置,由于其在相邻的两个太阳能电池片之间均设置了间隙,提升了太阳能电池片的散热能力,并且使用透明背板,不仅能提高太阳光的光透率,还可高效地传递太阳能电池板进行光电转换过程中产生的热量;而透明背板下面粘结的蓝膜集热板,则能够快速且高效地吸收透明背板传递的太阳能电池片在光电转换过程中所产生的热量及透过太阳能电池板之间的间隙的太阳光直射光热,并迅速进行光热转换,而后通过集热板芯将其吸收和转换的热量传递出去,并被人们回收利用。The photovoltaic-photothermal integrated device provided by the present invention has a gap between two adjacent solar cells, which improves the heat dissipation capacity of the solar cells, and uses a transparent back plate, which can not only improve the solar radiation The light transmittance can also efficiently transfer the heat generated during the photoelectric conversion process of the solar cell panel; while the blue film heat collector plate bonded under the transparent back sheet can quickly and efficiently absorb the solar cells transferred by the transparent back sheet The heat generated during the photoelectric conversion process and the sunlight passing through the gap between the solar panels are directly irradiated with light and heat, and the light-to-heat conversion is carried out rapidly, and then the heat absorbed and converted is transferred out through the heat-collecting plate core, and being recycled by people.

本发明提供的光伏光热一体化装置,有效地降低太阳能电池片阵列的工作温度,使其处于稳定的工作状态,提高光电转化效率;而且利用蓝膜集热板芯将太阳能电池片产生的热量及透过太阳能电池板之间的间隙的太阳光直射光热转化吸收,还解决了因空间的限制,实施了光伏发电系统,而无法实施光热系统,造成太阳能利用率低的现象,大大的提高了光能的利用率。尤其在使用屋顶式或墙体式光伏发电系统,并需求热水的地区或工程,可广泛实用,适于批量生产。The photovoltaic photothermal integrated device provided by the present invention can effectively reduce the working temperature of the solar cell array, make it in a stable working state, and improve the photoelectric conversion efficiency; And through the gap between the solar panels, the direct sunlight light-to-heat conversion absorption also solves the problem of low solar energy utilization rate due to the implementation of photovoltaic power generation system due to space constraints, which greatly improves The utilization rate of light energy is improved. Especially in areas or projects that use roof-mounted or wall-mounted photovoltaic power generation systems and require hot water, it can be widely used and suitable for mass production.

以上所述是本发明的优选实施方式,应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明原理的前提下,还可以做出若干改进和润饰,这些改进和润饰也视为本发明的保护范围。The above description is a preferred embodiment of the present invention, and it should be pointed out that for those skilled in the art, without departing from the principle of the present invention, some improvements and modifications can also be made, and these improvements and modifications are also considered Be the protection scope of the present invention.

Claims (8)

1. a kind of photovoltaic and photothermal integral device, it is characterised in that:Including solar cell chip arrays, the solar battery sheet The side of array is provided with armorplate glass, and opposite side is provided with backboard, the solar cell chip arrays and the armorplate glass Between and the backboard between be bonded with EVA bed courses, the solar cell chip arrays pass sequentially through welding including multiple The solar battery sheet being connected in array arrangement, gap is equipped between every two adjacent solar battery sheets;It is described Backboard is transparent back panel;Blue film collecting plate is bonded with below the transparent back panel, the blue film collecting plate includes heat-collecting plate core With plating located at the heat-collecting plate core upper surface blue film coating, the solar battery sheet includes the substrate, the metal that stack gradually Molybdenum dorsum electrode layer, CIGS absorbed layers, CdS cushions, the intrinsic Window layers of ZnO, articulamentum, CGS absorbed layers, CdS cushions, ZnO Intrinsic Window layer, ITO conducting window layers and silver electrode layer.
2. photovoltaic and photothermal integral device as claimed in claim 1, it is characterised in that:The solar battery sheet and it is described between Distribution proportion between gap is horizontal 1:3~1:5, longitudinal direction 1:2~1:3.
3. photovoltaic and photothermal integral device as claimed in claim 2, it is characterised in that:The solar battery sheet and it is described between Distribution proportion between gap is horizontal 1:4, longitudinal direction 1:2.5.
4. photovoltaic and photothermal integral device as claimed in claim 1, it is characterised in that:The heat-collecting plate core is aluminium alloy thermal-arrest Plate core.
5. photovoltaic and photothermal integral device as claimed in claim 1, it is characterised in that:The transparent back panel and the blue film collection It is bonded together by heat-conducting glue between hot plate.
6. the photovoltaic and photothermal integral device as described in any one of claim 1 to 5, it is characterised in that:The heat-collecting plate core bag Parallel arrangement of many heat pipes are included, the water inlet of many heat pipes is communicated with water inlet pipe, many water outlets of the heat pipe jointly Mouth is communicated with outlet pipe jointly, and the heat pipe is fixedly connected with upper cover plate, the heat pipe near the side of the blue film collecting plate Side away from the blue film collecting plate is fixedly connected with lower cover.
7. photovoltaic and photothermal integral device as claimed in claim 6, it is characterised in that:Covered below the blue film collecting plate There is heat-insulation layer.
8. photovoltaic and photothermal integral device as claimed in claim 1, it is characterised in that:The substrate is glass substrate, flexibility Metal foil substrate or flexible polyimide substrate, the articulamentum include the transparent metal oxide conductive layer being stacked and receive Rice metal conducting layer, the TCO thin film that the transparent metal oxide conductive layer is constituted for Al, Ga or In doping ZnO, or ITO is thin One kind of film;The nano metal conductive layer is Mo films.
CN201710073979.9A 2017-02-10 2017-02-10 A photovoltaic photothermal integrated device Pending CN106685355A (en)

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Application publication date: 20170517