CN106675281A - 一种石墨接枝聚苯胺具有电磁屏蔽效果的多彩岩片涂料 - Google Patents

一种石墨接枝聚苯胺具有电磁屏蔽效果的多彩岩片涂料 Download PDF

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CN106675281A
CN106675281A CN201611122125.7A CN201611122125A CN106675281A CN 106675281 A CN106675281 A CN 106675281A CN 201611122125 A CN201611122125 A CN 201611122125A CN 106675281 A CN106675281 A CN 106675281A
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孟广科
李强
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Anhui Fuyang Fujian Building Materials Co Ltd
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Abstract

本发明公开了一种石墨接枝聚苯胺具有电磁屏蔽效果的多彩岩片涂料,将氧化石墨利用硅烷偶联剂KH550改性后在其表面引入胺基,进而接枝聚苯胺,制备聚苯胺接枝改性石墨,添加到涂料中,不仅增强了涂膜的机械强度、耐磨性,同时提高了涂膜的导电性;本发明制成的多彩岩片涂料不仅具有花岗岩的外观,同时涂膜附着力佳、结实耐磨、致密性好、贮存稳定性好,同时具有良好的导电性,电磁屏蔽性能优异,能够抵抗电磁辐射,用于室内墙面,安全无毒美观大方,对人体无害。

Description

一种石墨接枝聚苯胺具有电磁屏蔽效果的多彩岩片涂料
技术领域
[0001] 本发明涉及涂料技术领域,尤其涉及一种石墨接枝聚苯胺具有电磁屏蔽效果的多彩岩片涂料。
背景技术
[0002] 水性复合岩片仿花岗岩涂料也叫岩片漆、花岗岩石漆,属新型纯水性化的不含任何溶剂型物质的砂壁状建筑涂料,富有花岗岩的风格,花岗岩的内涵,花岗岩的高贵,花岗岩的品位,是传统天然真石漆的升级换代品种。随着新型涂料在建筑市场上的广泛应用,对建筑涂料中复合岩片的配方的研究越来越受到广大研究工作者的关注。水性复合岩片仿花岗岩涂料是以优质合成树脂乳液、涂料用彩色复合岩片、填料、助剂等配制而成,与传统合成树脂乳液砂壁状涂料相比,其施工性、低温热存稳定性、耐水和耐碱性、涂层耐温变性优良,施工初期不裂,耐冲击,耐沾污,耐候、粘结强度高,涂层酷似天然花岗岩,可用于建筑内墙和外墙的装饰,也可作为建筑外墙外保温系统的饰面层,以替代质重的天然花岗岩干挂,减轻建筑物负重,减少花岗岩矿的开釆,有利于生态环境的保护。
[0003]多彩复合岩片由高分子聚合物合成,因此具有超强耐水、耐候性,能与各类水性石漆紧密结合。复合岩片的耐拉强度以及吸液率决定复合岩片的质量,从而决定水性涂料的质量。《外墙建筑涂料中复合岩片配方的改进》一文中通过对配方进行改性,添加润湿剂、分散剂、消泡剂、增稠剂、成膜助剂、防霉防腐剂、PH值调节剂,配合醋丙乳液与苯丙乳液复配,制成耐候性优异的复合岩片。虽然苯丙乳液与醋丙乳液复合能够提升制成复合岩片的耐候性,但是对于复合岩片的抗拉强度、吸液率的提升改性有限,需要进一步对复合岩片配方中的乳液进行进一步改性,以满足高质量复合岩片的需求,同时对水性涂料进行一系列功能型改性,以满足内墙用多彩岩片涂料发展的需求。
发明内容
[0004] 本发明目的就是为了弥补已有技术的缺陷,提供一种石墨接枝聚苯胺具有电磁屏蔽效果的多彩岩片涂料。
[0005] 本发明是通过以下技术方案实现的:
一种石墨接枝聚苯胺具有电磁屏蔽效果的多彩岩片涂料,由下列重量份的原料制备制成:苯乙烯4-4.5、丙烯酸正丁酯6-6.5、十二碳醇酯1-1.1、聚丙烯酸钠0.45-0.5、柠檬酸三辛酯0.5-0.55、超细天然颜填料60-65、去离子水适量、水性聚氨酯预聚体5-6、过硫酸钾0.6-0.65、消泡剂NXZ1-1.2、乙二醇丁醚4_5、丙二醇2.5-3、纯丙乳液75-80、可再分散胶粉8-10、灰钙粉14-16、氧化石墨4-5、甲苯80-85、丙酮适量、硅烷偶联剂KH5500.2-2.3、苯胺4-5、过硫酸铵0.34-0.35、浓度为20wt%的盐酸溶液12-13;
所述超细天然颜填料包括超细碳酸钙、超细硫酸钡、超细云母粉、超细硅藻土中的两种或者几种。
[0006] 所述一种石墨接枝聚苯胺具有电磁屏蔽效果的多彩岩片涂料,由以下具体步骤制成:
(1)将水性聚氨酯预聚体放入反应釜中,常温下加入苯乙烯、丙烯酸正丁酯以及总量4倍量的去离子水,以800-1000转/分的速度下搅拌乳化40-50分钟,然后加入过硫酸钾,加热至80-85°C,保温反应90-120分钟,冷却后出料,得到改性苯丙乳液;将改性苯丙乳液加入分散机中,以1500-1800转/分的速度搅拌,边搅拌边加入十二碳醇酯、聚丙烯酸钠、柠檬酸三辛酯以及总量等量的去离子水,继续搅拌10-15分钟后加入超细天然颜填料,继续搅拌8-10分钟后制成厚度为18-19微米的薄膜,在温度为155-160°C条件下烘干,产品冷却后,进行破碎,然后用7-9毫米网孔的网筛筛分,得到改性多彩复合岩片;
(2)将氧化石墨分散于甲苯中,加入硅烷偶联剂KH550,加热至85-90 °C反应4_5小时,冷却到室温后,抽滤,用水和丙酮各洗涤2-3次,真空干燥得硅烷偶联剂改性氧化石墨;将上述改性石墨分散于20-24倍量的去离子水中,然后加入苯胺4、过硫酸铵、浓度为20wt%的盐酸溶液,以500-600r/min的速度匀速搅拌,反应10-12小时后抽滤,去离子水洗涤至中性,真空干燥得石墨接枝聚苯胺;
(3)将可再分散胶粉加入总量12-14倍量的去离子水,加热至50-60°C,以500-600转/分的速度搅拌15-20分钟后冷却至室温,加入纯丙乳液、丙二醇、乙二醇丁醚,继续以800-1000转/分的速度搅拌10-15分钟后加入步骤(2)产物以及其余剩余成分,搅拌20-30分钟;
(4)在750-1000转/分搅拌的状态下向步骤(3)得到的产物中缓慢加入步骤(I)得到的改性多彩复合岩片,充分搅拌10-15分钟后即得。
[0007] 本发明的优点是:本发明首先利用水性聚氨酯预聚体添加到苯丙乳液的制备中,不添加任何乳化剂,使用水性聚氨酯预聚体作为乳化剂,提升了乳液的断裂伸长率、耐水性,增强了复合岩片的抗拉强度以及降低了吸液率,同时由于添加柠檬酸三辛酯与十二碳醇酯的相互配合,提高了复合岩片的成型形,不易破碎;本发明将符合岩片与纯丙乳液相结合,制备出的内墙涂料仿花岗岩效果好、自重轻、贮存稳定性高,全水性安全无毒,同时减少花岗岩的开采,有利于生态保护。
[0008] 本发明将氧化石墨利用硅烷偶联剂KH550改性后在其表面引入胺基,进而接枝聚苯胺,制备聚苯胺接枝改性石墨,添加到涂料中,不仅增强了涂膜的机械强度、耐磨性,同时提高了涂膜的导电性;本发明制成的多彩岩片涂料不仅具有花岗岩的外观,同时涂膜附着力佳、结实耐磨、致密性好、贮存稳定性好,同时具有良好的导电性,电磁屏蔽性能优异,能够抵抗电磁福射,用于室内墙面,安全无毒美观大方,对人体无害。
具体实施方式
[0009] —种石墨接枝聚苯胺具有电磁屏蔽效果的多彩岩片涂料,由下列重量份(公斤)的原料制备制成:苯乙烯4、丙烯酸正丁酯6、十二碳醇酯1、聚丙烯酸钠0.45、柠檬酸三辛酯
0.5、超细天然颜填料60、去离子水适量、水性聚氨酯预聚体5、过硫酸钾0.6、消泡剂NXZl、乙二醇丁醚4、丙二醇2.5、纯丙乳液75、可再分散胶粉8、灰钙粉14、氧化石墨4、甲苯80、丙酮适量、硅烷偶联剂KH5500.2、苯胺4、过硫酸铵0.34、浓度为20wt%的盐酸溶液12;
所述超细天然颜填料包括超细碳酸钙、超细硫酸钡、超细云母粉、超细硅藻土中的两种或者几种。
[0010] 所述一种石墨接枝聚苯胺具有电磁屏蔽效果的多彩岩片涂料,由以下具体步骤制成:
(1)将水性聚氨酯预聚体放入反应釜中,常温下加入苯乙烯、丙烯酸正丁酯以及总量4倍量的去离子水,以800转/分的速度下搅拌乳化40分钟,然后加入过硫酸钾,加热至80°C,保温反应90分钟,冷却后出料,得到改性苯丙乳液;将改性苯丙乳液加入分散机中,以1500转/分的速度搅拌,边搅拌边加入十二碳醇酯、聚丙烯酸钠、柠檬酸三辛酯以及总量等量的去离子水,继续搅拌10分钟后加入超细天然颜填料,继续搅拌8分钟后制成厚度为18微米的薄膜,在温度为155°C条件下烘干,产品冷却后,进行破碎,然后用7毫米网孔的网筛筛分,得到改性多彩复合岩片;
(2)将氧化石墨分散于甲苯中,加入硅烷偶联剂KH550,加热至85°C反应4小时,冷却到室温后,抽滤,用水和丙酮各洗涤2次,真空干燥得硅烷偶联剂改性氧化石墨;将上述改性石墨分散于20倍量的去离子水中,然后加入苯胺4、过硫酸铵、浓度为20wt%的盐酸溶液,以500r/min的速度勾速搅拌,反应1小时后抽滤,去离子水洗涤至中性,真空干燥得石墨接枝聚苯胺;
(3)将可再分散胶粉加入总量12倍量的去离子水,加热至50°C,以500转/分的速度搅拌15分钟后冷却至室温,加入纯丙乳液、丙二醇、乙二醇丁醚,继续以800转/分的速度搅拌10分钟后加入步骤(2)产物以及其余剩余成分,搅拌20分钟;
(4)在750转/分搅拌的状态下向步骤(3)得到的产物中缓慢加入步骤(I)得到的改性多彩复合岩片,充分搅拌10分钟后即得。
[0011] 本发明实施例制得的涂料搅拌后均匀无影快、施工性良好,易喷涂,流平性良好,低温贮存无结块,热贮存无结块、霉变、凝聚及组成物的变化,表干时间小于4小时;涂膜耐水、耐碱48小时无起鼓、开裂、脱落;粘结强度大于0.5MPa,符合国家标准。

Claims (2)

1.一种石墨接枝聚苯胺具有电磁屏蔽效果的多彩岩片涂料,其特征在于,由下列重量份的原料制备制成:苯乙烯4-4.5、丙烯酸正丁酯6-6.5、十二碳醇酯1-1.1、聚丙烯酸钠0.45-0.5、柠檬酸三辛酯0.5-0.55、超细天然颜填料60-65、去离子水适量、水性聚氨酯预聚体5-6、过硫酸钾0.6-0.65、消泡剂NXZ1-1.2、乙二醇丁醚4-5、丙二醇2.5-3、纯丙乳液75-80、可再分散胶粉8-10、灰钙粉14-16、氧化石墨4-5、甲苯80-85、丙酮适量、硅烷偶联剂KH5500.2-2.3、苯胺4-5、过硫酸铵0.34-0.35、浓度为20wt%的盐酸溶液12-13; 所述超细天然颜填料包括超细碳酸钙、超细硫酸钡、超细云母粉、超细硅藻土中的两种或者几种。
2.根据权利要求1所述一种石墨接枝聚苯胺具有电磁屏蔽效果的多彩岩片涂料,其特征在于,由以下具体步骤制成: (1)将水性聚氨酯预聚体放入反应釜中,常温下加入苯乙烯、丙烯酸正丁酯以及总量4倍量的去离子水,以800-1000转/分的速度下搅拌乳化40-50分钟,然后加入过硫酸钾,加热至80-85°C,保温反应90-120分钟,冷却后出料,得到改性苯丙乳液;将改性苯丙乳液加入分散机中,以1500-1800转/分的速度搅拌,边搅拌边加入十二碳醇酯、聚丙烯酸钠、柠檬酸三辛酯以及总量等量的去离子水,继续搅拌10-15分钟后加入超细天然颜填料,继续搅拌8-10分钟后制成厚度为18-19微米的薄膜,在温度为155-160°C条件下烘干,产品冷却后,进行破碎,然后用7-9毫米网孔的网筛筛分,得到改性多彩复合岩片; (2)将氧化石墨分散于甲苯中,加入硅烷偶联剂KH550,加热至85-90°C反应4-5小时,冷却到室温后,抽滤,用水和丙酮各洗涤2-3次,真空干燥得硅烷偶联剂改性氧化石墨;将上述改性石墨分散于20-24倍量的去离子水中,然后加入苯胺4、过硫酸铵、浓度为20wt%的盐酸溶液,以500-600r/min的速度匀速搅拌,反应10-12小时后抽滤,去离子水洗涤至中性,真空干燥得石墨接枝聚苯胺; (3)将可再分散胶粉加入总量12-14倍量的去离子水,加热至50-60°C,以500-600转/分的速度搅拌15-20分钟后冷却至室温,加入纯丙乳液、丙二醇、乙二醇丁醚,继续以800-1000转/分的速度搅拌10-15分钟后加入步骤(2)产物以及其余剩余成分,搅拌20-30分钟; (4)在750-1000转/分搅拌的状态下向步骤(3)得到的产物中缓慢加入步骤⑴得到的改性多彩复合岩片,充分搅拌10-15分钟后即得。
CN201611122125.7A 2016-12-08 2016-12-08 一种石墨接枝聚苯胺具有电磁屏蔽效果的多彩岩片涂料 Pending CN106675281A (zh)

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