CN106635465A - Alkaline foaming detergent and preparation method thereof - Google Patents
Alkaline foaming detergent and preparation method thereof Download PDFInfo
- Publication number
- CN106635465A CN106635465A CN201610841108.2A CN201610841108A CN106635465A CN 106635465 A CN106635465 A CN 106635465A CN 201610841108 A CN201610841108 A CN 201610841108A CN 106635465 A CN106635465 A CN 106635465A
- Authority
- CN
- China
- Prior art keywords
- preparation
- alkaline
- foam cleaner
- alkaline foam
- foaming detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 238000005187 foaming Methods 0.000 title abstract description 11
- 239000003599 detergent Substances 0.000 title abstract 5
- 239000006260 foam Substances 0.000 claims abstract description 30
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000003756 stirring Methods 0.000 claims abstract description 12
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims abstract description 8
- SZHQPBJEOCHCKM-UHFFFAOYSA-N 2-phosphonobutane-1,2,4-tricarboxylic acid Chemical compound OC(=O)CCC(P(O)(O)=O)(C(O)=O)CC(O)=O SZHQPBJEOCHCKM-UHFFFAOYSA-N 0.000 claims description 12
- VPTUPAVOBUEXMZ-UHFFFAOYSA-N (1-hydroxy-2-phosphonoethyl)phosphonic acid Chemical compound OP(=O)(O)C(O)CP(O)(O)=O VPTUPAVOBUEXMZ-UHFFFAOYSA-N 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 5
- 235000009754 Vitis X bourquina Nutrition 0.000 claims 1
- 235000012333 Vitis X labruscana Nutrition 0.000 claims 1
- 235000014787 Vitis vinifera Nutrition 0.000 claims 1
- 240000006365 Vitis vinifera Species 0.000 claims 1
- IDAGXRIGDWCIET-SDFKWCIISA-L disodium;(2s,3s,4s,5r)-2,3,4,5-tetrahydroxyhexanedioate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O IDAGXRIGDWCIET-SDFKWCIISA-L 0.000 claims 1
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 abstract description 7
- 239000000176 sodium gluconate Substances 0.000 abstract description 7
- 229940005574 sodium gluconate Drugs 0.000 abstract description 7
- 235000012207 sodium gluconate Nutrition 0.000 abstract description 7
- 238000004140 cleaning Methods 0.000 abstract description 5
- OHMBHFSEKCCCBW-OLQVQODUSA-N (2r,5s)-hexane-2,5-diol Chemical compound C[C@@H](O)CC[C@H](C)O OHMBHFSEKCCCBW-OLQVQODUSA-N 0.000 abstract description 4
- -1 alkyl glycoside Chemical class 0.000 abstract 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- HWHYRENKEFOPMV-UHFFFAOYSA-N P(=O)#CCCC(C(=O)O)(C(=O)O)C(=O)O Chemical compound P(=O)#CCCC(C(=O)O)(C(=O)O)C(=O)O HWHYRENKEFOPMV-UHFFFAOYSA-N 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 229930182470 glycoside Natural products 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 abstract 1
- 239000012459 cleaning agent Substances 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 230000008595 infiltration Effects 0.000 description 4
- 238000001764 infiltration Methods 0.000 description 4
- MXYOPVWZZKEAGX-UHFFFAOYSA-N 1-phosphonoethylphosphonic acid Chemical compound OP(=O)(O)C(C)P(O)(O)=O MXYOPVWZZKEAGX-UHFFFAOYSA-N 0.000 description 3
- 238000005202 decontamination Methods 0.000 description 2
- 230000003588 decontaminative effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- JJJOZVFVARQUJV-UHFFFAOYSA-N 2-ethylhexylphosphonic acid Chemical compound CCCCC(CC)CP(O)(O)=O JJJOZVFVARQUJV-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0094—High foaming compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/365—Organic compounds containing phosphorus containing carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C11D2111/20—
Abstract
The invention relates to an alkaline foaming detergent and a preparation method thereof. The preparation method for the alkaline foaming detergent comprises the following steps: adding water into a dosing tank; starting to stir; adding alkyl glycoside, alkyl sodium sulfonate MERSOLAT H95, sodium gluconate, sodium hydroxide, hydroxyethylidene, phosphoryl butane tricarboxylic acid and EDTA-4Na into the dosing tank; uniformly stirring; and settling for 24 hours and filtering. The alkaline foaming detergent is a highly concentrated alkaline foaming detergent and is rich in foam, high in cleaning capacity and low in dosage.
Description
Technical field
The present invention relates to a kind of alkaline foam cleaner and preparation method thereof.
Background technology
Food industry production equipment assembles in use collection spot, with the appearance of common cleaning agent cleaning equipment
Face, because the wall built-up time of cleaning agent it is short, it is difficult to clean up.Alkaline foam cleaning agent forms when in use fine and smooth abundant bubble
Foam, can be attached on device outer surface the long period, fully penetrate into inside dirt, reduce the adhesive force of dirt, stand several minutes
With clear water that flush with foam is clean afterwards, the spot of equipment surface is also with being rinsed totally.So foam type cleaning agent into
The first-selected cleaning agent of food industry cleaning equipment outer surface.
The content of the invention
In order to solve above-mentioned technical problem, first purpose of the present invention is to provide a kind of alkaline foam cleaner, this
Second purpose of invention is to provide the preparation method of above-mentioned alkaline foam cleaner.The present invention is that highly enriched alkaline foam is clear
Clean dose, foaming abundancy, strong cleaning force, consumption is few.
In order to realize above-mentioned first purpose, following technical scheme is present invention employs：
A kind of alkaline foam cleaner, the alkaline foam cleaner is made up of by weight percentage following components：
Balance of water.
Preferably, the alkaline foam cleaner is made up of by weight percentage following components：
Balance of water.
In order to realize above-mentioned second purpose, following technical scheme is present invention employs：
The preparation method of above-mentioned alkaline foam cleaner, the method comprises the following steps：First add water to material-compound tank
In, stirring is opened, APG, SAS MERSOLAT H95, sodium gluconate, NaOH, hydroxyl Asia second
Base di 2 ethylhexyl phosphonic acid, phosphonobutane tricarboxylic acid, EDTA-4Na add material-compound tank, stir, and settle 24 hours and filter.
The present invention due to using above-mentioned technical scheme, being highly enriched alkaline foam cleaner, foaming abundancy, cleaning force
By force, consumption is few.
Specific embodiment
Embodiment 1
A kind of alkaline foam cleaner, the alkaline foam cleaner is made up of by weight percentage following components：
| Raw material | Formula, % | Single component effect |
| APG | 3.0 | Foaming infiltration |
| MERSOLAT H95 (SAS) | 3.0 | Foaming infiltration |
| Sodium gluconate | 6.0 | Chelating |
| EDTA-4Na | 2.5 | Chelating |
| HEDP (hydroxy ethylene diphosphonic acid) | 4.0 | Corrosion-mitigation scale-inhibition |
| PBTCA (phosphonobutane tricarboxylic acid) | 3.0 | Corrosion-mitigation scale-inhibition |
| NaOH | 15 | Decontamination |
| Water | Surplus | Solvent |
The preparation method of above-mentioned alkaline foam cleaner, the method comprises the following steps：First add water to material-compound tank
In, stirring is opened, APG, MERSOLAT H95 (SAS), sodium gluconate, NaOH, HEDP (hydroxyls
Base ethylidene diphosphonic acid), PBTCA (phosphonobutane tricarboxylic acid), EDTA-4Na add material-compound tank, stir, sedimentation is 24 little
When filter.
Embodiment 2
A kind of alkaline foam cleaner, the alkaline foam cleaner is made up of by weight percentage following components：
The preparation method of above-mentioned alkaline foam cleaner, the method comprises the following steps：First add water to material-compound tank
In, stirring is opened, APG, SAS MERSOLAT H95, sodium gluconate, NaOH, HEDP (hydroxyls
Ethylidene diphosphonic acid), PBTCA (phosphonobutane tricarboxylic acid), EDTA-4Na add material-compound tank, stir, settle 24 hours
Filter.
Embodiment 3
A kind of alkaline foam cleaner, the alkaline foam cleaner is made up of by weight percentage following components：
| Raw material | Formula, % | Single component effect |
| APG | 3.0 | Foaming infiltration |
| SAS MERSOLAT H95 | 4.0 | Foaming infiltration |
| Sodium gluconate | 6.0 | Chelating |
| EDTA-4Na | 2.5 | Chelating |
| HEDP (hydroxy ethylene diphosphonic acid) | 4.0 | Corrosion-mitigation scale-inhibition |
| PBTCA (phosphonobutane tricarboxylic acid) | 3.0 | Corrosion-mitigation scale-inhibition |
| NaOH | 25 | Decontamination |
| Water | Surplus | Solvent |
The preparation method of above-mentioned alkaline foam cleaner, the method comprises the following steps：First add water to material-compound tank
In, stirring is opened, APG, SAS MERSOLAT H95, sodium gluconate, NaOH, HEDP (hydroxyls
Ethylidene diphosphonic acid), PBTCA (phosphonobutane tricarboxylic acid), EDTA-4Na add material-compound tank, stir, settle 24 hours
Filter.
The detection data of alkaline foam cleaner physical and chemical index prepared by above-described embodiment 1～3 is as follows：
Claims (3)
1. a kind of alkaline foam cleaner, it is characterised in that the alkaline foam cleaner is by weight percentage by following components structure
Into：
Balance of water.
2. a kind of alkaline foam cleaner according to claim 1, it is characterised in that the alkaline foam cleaner is by weight
Percentages are made up of following components：
Balance of water.
3. a kind of preparation method of the alkaline foam cleaner prepared described in claim 1 or 2, it is characterised in that the method includes
Below step：First add water in material-compound tank, stirring is opened, APG, SAS MERSOLAT H95, Portugal
Grape sodium saccharate, NaOH, hydroxy ethylene diphosphonic acid, phosphonobutane tricarboxylic acid, EDTA-4Na add material-compound tank, and stirring is equal
It is even, settle 24 hours and filter.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610841108.2A CN106635465A (en) | 2016-09-22 | 2016-09-22 | Alkaline foaming detergent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610841108.2A CN106635465A (en) | 2016-09-22 | 2016-09-22 | Alkaline foaming detergent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106635465A true CN106635465A (en) | 2017-05-10 |
Family
ID=58852285
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610841108.2A Withdrawn CN106635465A (en) | 2016-09-22 | 2016-09-22 | Alkaline foaming detergent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106635465A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110079402A (en) * | 2019-05-30 | 2019-08-02 | 陕西汉隆清洁消毒产品有限公司 | Compound alkaline foam cleaning agent of a kind of environment-friendly type and preparation method thereof |
| CN111334807A (en) * | 2018-12-19 | 2020-06-26 | 深圳市天正隆科技有限公司 | Online cleaning agent for automobile radiator welding, preparation and radiator welding process |
| CN113943613A (en) * | 2021-11-08 | 2022-01-18 | 河南华美万邦生物科技集团有限公司 | Foam cleaning agent for farm |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1092099A (en) * | 1994-02-05 | 1994-09-14 | 武汉通达控制研究所 | Cleaning agent for beer fermentation tank and compound method thereof |
| EP0670883A1 (en) * | 1992-10-16 | 1995-09-13 | Unilever Plc | Improvements in general purpose cleaning compositions. |
| WO2004053043A1 (en) * | 2002-12-05 | 2004-06-24 | Ecolab Inc. | Solid alkaline foaming cleaning compositions with encapsulated bleaches |
| CN1788072A (en) * | 2003-05-19 | 2006-06-14 | 约翰逊迪瓦西公司 | High caustic foaming contact cleaner |
| CN102660414A (en) * | 2012-05-29 | 2012-09-12 | 上海弗杏康生物科技有限公司 | Composite alkaline concentrating agent for cleaning food industrial equipment and preparation method of composite alkaline concentrating agent |
| CN103074179A (en) * | 2012-12-14 | 2013-05-01 | 内蒙古河西航天科技发展有限公司 | Alkaline cleaner for food contact surface of liquid milk equipment |
| CN103756815A (en) * | 2013-12-23 | 2014-04-30 | 李艳妮 | Enzyme-containing cleaning agent used for food and beverage industry and composition and preparation method thereof |
-
2016
- 2016-09-22 CN CN201610841108.2A patent/CN106635465A/en not_active Withdrawn
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0670883A1 (en) * | 1992-10-16 | 1995-09-13 | Unilever Plc | Improvements in general purpose cleaning compositions. |
| CN1092099A (en) * | 1994-02-05 | 1994-09-14 | 武汉通达控制研究所 | Cleaning agent for beer fermentation tank and compound method thereof |
| WO2004053043A1 (en) * | 2002-12-05 | 2004-06-24 | Ecolab Inc. | Solid alkaline foaming cleaning compositions with encapsulated bleaches |
| CN1788072A (en) * | 2003-05-19 | 2006-06-14 | 约翰逊迪瓦西公司 | High caustic foaming contact cleaner |
| CN102660414A (en) * | 2012-05-29 | 2012-09-12 | 上海弗杏康生物科技有限公司 | Composite alkaline concentrating agent for cleaning food industrial equipment and preparation method of composite alkaline concentrating agent |
| CN103074179A (en) * | 2012-12-14 | 2013-05-01 | 内蒙古河西航天科技发展有限公司 | Alkaline cleaner for food contact surface of liquid milk equipment |
| CN103756815A (en) * | 2013-12-23 | 2014-04-30 | 李艳妮 | Enzyme-containing cleaning agent used for food and beverage industry and composition and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111334807A (en) * | 2018-12-19 | 2020-06-26 | 深圳市天正隆科技有限公司 | Online cleaning agent for automobile radiator welding, preparation and radiator welding process |
| CN110079402A (en) * | 2019-05-30 | 2019-08-02 | 陕西汉隆清洁消毒产品有限公司 | Compound alkaline foam cleaning agent of a kind of environment-friendly type and preparation method thereof |
| CN110079402B (en) * | 2019-05-30 | 2021-03-19 | 陕西汉隆清洁消毒产品有限公司 | Environment-friendly composite alkaline foam cleaning agent and preparation method thereof |
| CN113943613A (en) * | 2021-11-08 | 2022-01-18 | 河南华美万邦生物科技集团有限公司 | Foam cleaning agent for farm |
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|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170510 |
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| WW01 | Invention patent application withdrawn after publication |