CN106630924A - Ferronickel slag magnesium phosphate binding material and application thereof - Google Patents
Ferronickel slag magnesium phosphate binding material and application thereof Download PDFInfo
- Publication number
- CN106630924A CN106630924A CN201611150069.8A CN201611150069A CN106630924A CN 106630924 A CN106630924 A CN 106630924A CN 201611150069 A CN201611150069 A CN 201611150069A CN 106630924 A CN106630924 A CN 106630924A
- Authority
- CN
- China
- Prior art keywords
- ferronickel slag
- magnesium phosphate
- binding material
- parts
- ferronickel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/34—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing cold phosphate binders
- C04B28/344—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing cold phosphate binders the phosphate binder being present in the starting composition solely as one or more phosphates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/14—Waste materials; Refuse from metallurgical processes
- C04B18/141—Slags
- C04B18/144—Slags from the production of specific metals other than iron or of specific alloys, e.g. ferrochrome slags
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Abstract
The invention discloses a ferronickel slag magnesium phosphate binding material and application thereof. The binding material is prepared from 6-12 parts of ferronickel slag, 12-25 parts of dead burned magnesia, 3-12 parts of phosphate and 1-10 parts of retarder. The ferronickel slag magnesium phosphate binding material is used in structural members requiring high strength in early age period and rush-repair work. The ferronickel slag magnesium phosphate binding material has the advantages of achieving rapid hardening and early strengthening, and being high in strength and small in shrinkage deformation, the interior structure is more compact, the porosity is low, and the durability including water tolerance is improved. Moreover, according to the ferronickel slag magnesium phosphate binding material, innocent treatment of the ferronickel slag is achieved, high-efficiency resource utilization of industrial waste residues is promoted, and on the premise that the mechanical properties of the binding material is guaranteed, the consumption of dead burned magnesia is reduced, the consumption of a non-renewable resource, namely magnesite, and energy loss are reduced, the production cost of the magnesium phosphate binding material is decreased, and therefore, economic benefits and environmental benefits are remarkable.
Description
Technical field
The invention belongs to building material technical field, is related to a kind of Binder Materials, specially using trade waste ferronickel
The ferronickel slag magnesium phosphate cement that slag is prepared, and the application of the Binder Materials.
Background technology
Magnesium phosphate cement has that fast hard, early strong, adhesion strength is high, the dry-shrinkage deformed premium properties such as little, used as one kind
Novel gelled material is received more and more attention, it is adaptable to have component, salvaging of high request etc. to early strength.Phosphoric acid
One of the component that magnesium Binder Materials is used dead burned magnesia is obtained by 1700 DEG C or so high-temperature calcinations of magnesite Jing, due to forging
Burn temperature high, so, from production of construction materials technique, dead burned magnesia is carbon isotopes.
Ferronickel slag is to produce the Water Quenching Slag that ferronickel is discharged using pyrometallurgical smelting process, and liquidus temperature is up to during smelting ferronickel
More than 1700 DEG C.In China, ferronickel slag is the fourth-largest trade waste after scum, slag, red mud, annual generation at present
About 30,000,000 tons of ferronickel slag.But, the utilization rate of ferronickel slag is extremely low, and the overwhelming majority is simply stored up in outdoor mode, is not only taken up
Valuable land resource, and underground water pollution and dust pollution can be brought.The innocuity treatment problem of ferronickel slag is urgently to solve
One of environmental issue certainly.
The content of the invention
The technical problem of solution：In order to overcome the defect of prior art, trade waste ferronickel slag of dissolving realizes ferronickel slag
Resource application, reduce the consumption of dead burned magnesia in magnesium phosphate cement, and still ensure that the gelling material for preparing
Material has the finer and close premium properties of high-early-strength, high bond strength, dry-shrinkage deformed little, internal structure, the invention provides
A kind of ferronickel slag magnesium phosphate cement and its application.
Technical scheme：A kind of ferronickel slag magnesium phosphate cement, by weight, the Binder Materials includes ferronickel slag 6
～12 parts, 12～25 parts of dead burned magnesia, 3～12 parts of phosphate, 1～10 part of retarder.
Preferably, each group is divided into powder body material in the Binder Materials, and moisture content is below 1%.
Preferably, the ferronickel slag is Water Quenching Slag, and specific surface area is 350m2/ more than kg, wherein content of MgO be 25% with
On.
Preferably, the dead burned magnesia specific surface area is 300m2/ more than kg, wherein content of MgO are more than 90%.
Preferably, the phosphate is at least one in potassium dihydrogen phosphate, ammonium di-hydrogen phosphate, sodium dihydrogen phosphate；It is described
Phosphatic specific surface area is 300m2/ more than kg.
Preferably, the retarder is at least one in borax, boric acid, sodium tripolyphosphate；The ratio table of the retarder
Area is 300m2/ more than kg.
Arbitrary described ferronickel slag magnesium phosphate cement is in structural member, the salvaging that early age has high intensity to require
Application.
The present invention principle be：Active component in ferronickel ground-slag participates in hydration reaction, cementing properties water in increase system
Change product formation, it is ensured that the Binder Materials physical mechanics property；Additionally, ferronickel ground-slag also has filing effect, ensureing gelling
Internal structure compactness is improved while Material Physics mechanical property, porosity is reduced.
Beneficial effect：(1) ferronickel slag magnesium phosphate cement of the present invention has fast hard, early strong, high-strength, dry-shrinkage deformed
Little advantage；(2) ferronickel slag magnesium phosphate cement internal structure of the present invention is fine and close, and porosity is low, including resistance to water exists
Interior endurance quality is improved；(3) ferronickel slag magnesium phosphate cement of the present invention realizes the process of ferronickel slag harmlessness,
Promote the high-efficiency resource recycling of industrial residue；(4) ferronickel slag magnesium phosphate cement of the present invention is ensureing gelling material
On the premise of material mechanical property, the consumption of dead burned magnesia is reduced, reduce consumption and the energy of non-renewable resources magnesite
Loss, reduces the production cost of magnesium phosphate cement, thus with significant economic benefit and environmental benefit.
Specific embodiment
Following examples further illustrate present disclosure, but should not be construed as limiting the invention.Without departing substantially from
In the case of spirit of the invention and essence, the modification made to the inventive method, step or condition and replacement belong to the present invention
Scope.If not specializing, the conventional meanses that technological means used is well known to those skilled in the art in embodiment.
Embodiment 1
Ferronickel slag magnesium phosphate cement match ratio：Specific surface area 350m28 parts of the ferronickel slag of/kg, content of MgO 28%, nickel
Scum is Water Quenching Slag；Specific area 350m225 parts of the dead burned magnesia of/kg, content of MgO 90%；Technical grade, specific surface area 300m2/
10 parts of the potassium dihydrogen phosphate of kg；Technical grade, specific surface area 300m22 parts of/kg boraxs are used as retarder；Each component moisture content is
Less than 1%, uniformly it is mixed to prepare.
Presetting period and intensity test are carried out to the Binder Materials, when the ratio of mud is 0.18, at the beginning of the Binder Materials
The solidifying time is 50min, and 3h compression strength is 37.3MPa, and 3d compression strength is intensity 58.4MPa.
Embodiment 2
Ferronickel slag magnesium phosphate cement match ratio：Specific surface area 350m212 parts of the ferronickel slag of/kg, content of MgO 28%,
Ferronickel slag is Water Quenching Slag；Specific area 320m225 parts of the dead burned magnesia of/kg, content of MgO 90%；Technical grade, specific surface area
350m210 parts of the potassium dihydrogen phosphate of/kg；Technical grade, specific surface area 350m23 parts of the boric acid of/kg is used as retarder；Each component is aqueous
Rate is less than 1%, is uniformly mixed to prepare.
Presetting period and intensity test are carried out to the Binder Materials, when the ratio of mud is 0.20, at the beginning of the Binder Materials
The solidifying time is 65min, and 3h compression strength is 22.9MPa, and 3d compression strength is intensity 35.7MPa.
Embodiment 3
Ferronickel slag magnesium phosphate cement match ratio：Specific surface area 350m26 parts of the ferronickel slag of/kg, content of MgO 26%, nickel
Scum is Water Quenching Slag；Specific area 300m215 parts of the dead burned magnesia of/kg, content of MgO 90%；Technical grade, specific surface area 300m2/
8 parts of the ammonium di-hydrogen phosphate of kg；Technical grade, specific surface area 300m21.5 parts of the sodium tripolyphosphate of/kg is used as retarder；Each component contains
Water rate is less than 1%, is uniformly mixed to prepare.
Presetting period and intensity test are carried out to the Binder Materials, when the ratio of mud is 0.16, at the beginning of the Binder Materials
The solidifying time is 55min, and 3h compression strength is 38.1MPa, and 3d compression strength is intensity 43.2MPa.
Embodiment 4
Ferronickel slag magnesium phosphate cement match ratio：Specific surface area 350m210 parts of the ferronickel slag of/kg, content of MgO 26%,
Ferronickel slag is Water Quenching Slag；Specific area 350m225 parts of the dead burned magnesia of/kg, content of MgO 90%；Technical grade, specific surface area
300m2The potassium dihydrogen phosphate of/kg, sodium dihydrogen phosphate are each 6 parts；Technical grade, specific surface area 300m2The borax of/kg, boric acid are each 1.5 parts
As retarder；Each component moisture content is less than 1%, is uniformly mixed to prepare.
Presetting period and intensity test are carried out to the Binder Materials, when the ratio of mud is 0.16, at the beginning of the Binder Materials
The solidifying time is 60min, and 3h compression strength is 33.9MPa, and 3d compression strength is intensity 38.4MPa.
Embodiment 5
Ferronickel slag magnesium phosphate cement match ratio：Specific surface area 350m26 parts of the ferronickel slag of/kg, content of MgO 25%, nickel
Scum is Water Quenching Slag；Specific area 300m224 parts of the dead burned magnesia of/kg, content of MgO 90%；Technical grade, specific surface area 300m2/
The potassium dihydrogen phosphate of kg, sodium dihydrogen phosphate, ammonium di-hydrogen phosphate are each 3 parts；Technical grade, specific surface area 300m2/ kg boraxs, boric acid, three
Polyphosphate sodium it is each 1 part as retarder；Each component moisture content is less than 1%, is uniformly mixed to prepare.
Presetting period and intensity test are carried out to the Binder Materials, when the ratio of mud is 0.17, at the beginning of the Binder Materials
The solidifying time is 65min, and 3h compression strength is 40.1MPa, and 3d compression strength is intensity 49.7MPa.
Claims (7)
1. a kind of ferronickel slag magnesium phosphate cement, it is characterised in that by weight, the Binder Materials includes ferronickel slag 6
～12 parts, 12～25 parts of dead burned magnesia, 3～12 parts of phosphate, 1～10 part of retarder.
2. a kind of ferronickel slag magnesium phosphate cement according to claim 1, it is characterised in that each in the Binder Materials
Component is powder body material, and moisture content is below 1%.
3. a kind of ferronickel slag magnesium phosphate cement according to claim 1, it is characterised in that the ferronickel slag is water quenching
Slag, specific surface area is 350m2/ more than kg, wherein content of MgO are more than 25%.
4. a kind of ferronickel slag magnesium phosphate cement according to claim 1, it is characterised in that the dead burned magnesia ratio
Surface area is 300m2/ more than kg, wherein content of MgO are more than 90%.
5. a kind of ferronickel slag magnesium phosphate cement according to claim 1, it is characterised in that the phosphate is phosphoric acid
At least one in potassium dihydrogen, ammonium di-hydrogen phosphate, sodium dihydrogen phosphate；The phosphatic specific surface area is 300m2/ more than kg.
6. a kind of ferronickel slag magnesium phosphate cement according to claim 1, it is characterised in that the retarder is boron
At least one in sand, boric acid, sodium tripolyphosphate；The specific surface area of the retarder is 300m2/ more than kg.
7. the arbitrary described ferronickel slag magnesium phosphate cement of claim 1～6 early age have the structural member that high intensity requires,
Application in salvaging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611150069.8A CN106630924A (en) | 2016-12-14 | 2016-12-14 | Ferronickel slag magnesium phosphate binding material and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611150069.8A CN106630924A (en) | 2016-12-14 | 2016-12-14 | Ferronickel slag magnesium phosphate binding material and application thereof |
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| Publication Number | Publication Date |
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| CN106630924A true CN106630924A (en) | 2017-05-10 |
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ID=58825109
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611150069.8A Pending CN106630924A (en) | 2016-12-14 | 2016-12-14 | Ferronickel slag magnesium phosphate binding material and application thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107827381A (en) * | 2017-11-27 | 2018-03-23 | 固岩科技发展有限公司 | A kind of magnesium phosphate gelling agent and binder materials |
| CN108286455A (en) * | 2017-12-18 | 2018-07-17 | 固岩科技发展有限公司 | A kind of method of magnesium phosphate cement consolidated fill metal mine |
| CN108421805A (en) * | 2018-02-24 | 2018-08-21 | 昆明理工大学 | A kind of electrolytic manganese residues solidification and stabilization processing method |
| CN110713374A (en) * | 2019-11-21 | 2020-01-21 | 衡阳县海华水泥有限责任公司 | Ferronickel slag-based magnesium phosphate cement and preparation method thereof |
| CN113165030A (en) * | 2018-12-18 | 2021-07-23 | 欧安诺核退役公司 | Method for conditioning acid waste by cementation |
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| CN105800979A (en) * | 2016-03-14 | 2016-07-27 | 同济大学 | Magnesium phosphate cement with good hydrolytic resistance and using method thereof |
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| CN104150858A (en) * | 2014-07-18 | 2014-11-19 | 东南大学 | Magnesium sodium phosphate cement base material and preparation method thereof |
| CN104386929A (en) * | 2014-10-27 | 2015-03-04 | 武汉钢铁(集团)公司 | Production method of cementing material from steel slag and cementing material |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107827381A (en) * | 2017-11-27 | 2018-03-23 | 固岩科技发展有限公司 | A kind of magnesium phosphate gelling agent and binder materials |
| CN108286455A (en) * | 2017-12-18 | 2018-07-17 | 固岩科技发展有限公司 | A kind of method of magnesium phosphate cement consolidated fill metal mine |
| CN108421805A (en) * | 2018-02-24 | 2018-08-21 | 昆明理工大学 | A kind of electrolytic manganese residues solidification and stabilization processing method |
| CN113165030A (en) * | 2018-12-18 | 2021-07-23 | 欧安诺核退役公司 | Method for conditioning acid waste by cementation |
| CN113165030B (en) * | 2018-12-18 | 2023-09-19 | 欧安诺核退役公司 | Method for conditioning acid waste by cementing |
| CN110713374A (en) * | 2019-11-21 | 2020-01-21 | 衡阳县海华水泥有限责任公司 | Ferronickel slag-based magnesium phosphate cement and preparation method thereof |
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Application publication date: 20170510 |