CN106630903A - High-durability geopolymer concrete foundation - Google Patents

High-durability geopolymer concrete foundation Download PDF

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Publication number
CN106630903A
CN106630903A CN201610905797.9A CN201610905797A CN106630903A CN 106630903 A CN106630903 A CN 106630903A CN 201610905797 A CN201610905797 A CN 201610905797A CN 106630903 A CN106630903 A CN 106630903A
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CN
China
Prior art keywords
parts
durability
concrete foundation
geopolymer concrete
geopolymer
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Pending
Application number
CN201610905797.9A
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Chinese (zh)
Inventor
陈树东
丁天庭
李启华
蒋学
柯凯
俞建锋
李淼晨
黄茂林
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Zhejiang College of Construction
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Zhejiang College of Construction
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Priority to CN201610905797.9A priority Critical patent/CN106630903A/en
Publication of CN106630903A publication Critical patent/CN106630903A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/006Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mineral polymers, e.g. geopolymers of the Davidovits type
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/10Production of cement, e.g. improving or optimising the production methods; Cement grinding

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  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention relates to a high-durability geopolymer concrete foundation. The high-durability geopolymer concrete foundation comprises, by weight, 200-277 parts of fly ash, 55-92 parts of smelt slag, 35-70 parts of ultrafine powder, 570-600 parts of fine aggregate, 1100-1180 parts of coarse aggregate, 30-40 parts of water glass and 150-200 parts of water. The high-durability geopolymer concrete foundation has the advantages that the high-durability geopolymer concrete foundation does not need to be compounded and used with water reducing agents, and geopolymer gelation materials which are mixtures are constructed from the fly ash, the smelt slag and the water glass and have high-durability characteristics of erosion resistance and high and low temperature resistance owing to characteristics of geopolymers; coordination and auxiliary adjustment effects can be realized by the ultrafine powder for the water retention, the wrapping property and the cohesiveness of the geopolymer concrete mixtures, and certain self-curing effects further can be realized by porous structures of the ultrafine powder; improvement effects can be realized by the smelt slag for the compactness and the mechanical strength of hardened concrete.

Description

A kind of high-durability geopolymer concrete foundation
Technical field
The present invention relates to building material technical field, especially a kind of high-durability geopolymer concrete foundation.
Background technology
In the world is started to the research of geopolymer the eighties in last century.Generally with metakaolin as primary raw material, By the effect of alkali-activator, about 100 DEG C obtained by synthesis.If replacing metakaolin with flyash, aggregate velocity is limited, Intensity is relatively low.Trace it to its cause, be characterized in particular in how guaranteeing the high activity of Si-Al materials, it is ensured that powder body can dissolve rapidly There is reconstruct, tissue in alkaline solution in Si, Al monomer that can move freely, the monomer being dissolved down, be built into it is a kind of by AlO4And SiO4The cancellated inorganic polymer aluminum silicate cross-linking type hydrated product of tetrahedral structural unit composition 3 D stereo, Condense hardening.
Basement process generally refers to the bearing capacity for improving the ground (soil or rock) of supporting building, improves its change The project slash that shape performance or impermeability are taken.Concrete belongs to fragile material, for a long time under load action, easily Generation cracking destruction.Geopolymer is in itself oxide network structural system, do not aoxidize between l000~1200 DEG C, regardless of Solution;On the other hand, it is not oxidized that closely knit oxide network system can completely cut off air, protection inner material.
The content of the invention
The invention solves the problems that the shortcoming of above-mentioned prior art, there is provided a kind of without the need for water reducer compound use, with good The high-durability geopolymer concrete foundation of water-retaining property, encapsulation, cohesiveness and mechanical strength.
The present invention solves the technical scheme that its technical problem is adopted:This high-durability geopolymer concrete foundation, it It is made up of the raw material of following portions by weight:200~277 parts of flyash, 55~92 parts of smelted furnace cinder, micropowders 35~70 Part, 570~600 parts of fine aggregate, 1100~1180 parts of coarse aggregate, 30~40 parts of waterglass, 150~200 parts of water.
The flyash is high-calcium fly ass, preferably one-level flyash.
The smelted furnace cinder is the Industry Waste that slag, carbide slag, alkaline residue, phosphorus slag, chromium slag, boron slag etc. possess thermal history process Slag, preferably up to《The ground granulated blast furnace slag that GBT 18046-2008 are used in cement and concrete》The smelting of S75 standards Slag.
The fine aggregate is to meet national standard《Building sand》The fine aggregate of (GB/T 14684-2011), preferably carefully Fluvial sand of the degree modulus 2.2~2.5.
The coarse aggregate is to meet national standard《Cobble for building, rubble》(GB/T14685-2011) particle diameter is more than The compositionss of the aggregate that the aggregate of 5mm, preferably 5~20mm, 20~40mm, two kinds of levels are matched somebody with somebody.
Described waterglass is the waterglass powder body that modulus is 2.30-2.50.
The micropowders are one or two mixture in triple superphosphate, fine particle calcium carbonate, zeolite powder, cenosphere, silicon ash, preferably For powder of the unit weight less than 2.0g/cm3, i.e. one or two mixture of zeolite powder, cenosphere.
Invention has the advantages that:The present invention is without the need for water reducer compound use, flyash, smelted furnace cinder, waterglass structure Build geopolymer gelled material, geopolymer its own feature give this mixture resistant to corrosion, high-low temperature resistant high-durability it is special Point;Over the ground the water-retaining property of polymer concrete mixture, encapsulation, cohesiveness have coordination auxiliary Accommodation to micropowders, surpass The porous structure of trickle powder also has certain Self-curing effect;Smelted furnace cinder is strong to the density of concrete, mechanics after hardening Degree there is also amplification effect.
Specific embodiment
Below the invention will be further described:
Embodiment one:
A kind of high-durability geopolymer concrete foundation, it is made up of the raw material of following portions by weight:High calcium fine coal 250 parts of ash;70 parts of slag;30 parts of triple superphosphate;30 parts of zeolite powder;580 parts of the fluvial sand of modulus 2.4;600 parts of melon rice;560 parts of rubble; 35 parts of waterglass;180 parts of water.
Embodiment two:
A kind of high-durability geopolymer concrete foundation, it is made up of the raw material of following portions by weight:High calcium fine coal 265 parts of ash;20 parts of carbide slag;10 parts of alkaline residue;50 parts of slag;30 parts of zeolite powder;40 parts of fine particle calcium carbonate;600 parts of the fluvial sand of modulus 2.5; 200 parts of little melon rice;950 parts of rubble;38 parts of waterglass;190 parts of water.
Embodiment three:
A kind of high-durability geopolymer concrete foundation, it is made up of the raw material of following portions by weight:High calcium fine coal 270 parts of ash;20 parts of phosphorus slag;50 parts of slag;50 parts of triple superphosphate;15 parts of cenosphere;595 parts of the fluvial sand of modulus 2.4;Little melon rice 300 Part;850 parts of rubble;40 parts of waterglass;195 parts of water.
In addition to the implementation, the present invention can also have other embodiment.All employing equivalents or equivalent transformation shape Into technical scheme, all fall within the protection domain of application claims.

Claims (9)

1. a kind of high-durability geopolymer concrete foundation, it is made up of the raw material of following portions by weight:
200~277 parts of flyash, 55~92 parts of smelted furnace cinder, 35~70 parts of micropowders, 570~600 parts of fine aggregate, thick bone 1100~1180 parts of material, 30~40 parts of waterglass, 150~200 parts of water.
2. high-durability geopolymer concrete foundation according to claim 1, is characterized in that:The flyash is high calcium Flyash.
3. high-durability geopolymer concrete foundation according to claim 1, is characterized in that:The smelted furnace cinder is steel Slag, carbide slag, alkaline residue, phosphorus slag, chromium slag or boron slag.
4. high-durability geopolymer concrete foundation according to claim 1, is characterized in that:The fine aggregate is using thin Fluvial sand of the degree modulus 2.2~2.5.
5. high-durability geopolymer concrete foundation according to claim 1, is characterized in that:The coarse aggregate is particle diameter Aggregate more than 5mm.
6. high-durability geopolymer concrete foundation according to claim 5, is characterized in that:The coarse aggregate adopts 5 The compositionss of the aggregate that~20mm, 20~40mm, two kinds of levels are matched somebody with somebody.
7. high-durability geopolymer concrete foundation according to claim 1, is characterized in that:Described waterglass is mould Number is 2.30~2.50 waterglass powder body.
8. high-durability geopolymer concrete foundation according to claim 1, is characterized in that:The micropowders are attached most importance to One or two mixture in calcium, fine particle calcium carbonate, zeolite powder, cenosphere, silicon ash.
9. high-durability geopolymer concrete foundation according to claim 8, is characterized in that:The micropowders unit weight Less than 2.0g/cm3
CN201610905797.9A 2016-10-18 2016-10-18 High-durability geopolymer concrete foundation Pending CN106630903A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610905797.9A CN106630903A (en) 2016-10-18 2016-10-18 High-durability geopolymer concrete foundation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610905797.9A CN106630903A (en) 2016-10-18 2016-10-18 High-durability geopolymer concrete foundation

Publications (1)

Publication Number Publication Date
CN106630903A true CN106630903A (en) 2017-05-10

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112125633A (en) * 2020-10-26 2020-12-25 燕山大学 C30 grade full-solid waste concrete and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103370287A (en) * 2010-12-17 2013-10-23 天主教美利坚大学 Geopolymer composite for ultra high performance concrete
CN103435313A (en) * 2013-08-26 2013-12-11 温州大学 Strength controllable coal ash-based polymer concrete and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103370287A (en) * 2010-12-17 2013-10-23 天主教美利坚大学 Geopolymer composite for ultra high performance concrete
CN103435313A (en) * 2013-08-26 2013-12-11 温州大学 Strength controllable coal ash-based polymer concrete and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112125633A (en) * 2020-10-26 2020-12-25 燕山大学 C30 grade full-solid waste concrete and preparation method thereof
CN112125633B (en) * 2020-10-26 2021-07-30 燕山大学 C30 grade full-solid waste concrete and preparation method thereof

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