CN106614645A - Rice antibacterial and insecticidal composition containing buprofezin - Google Patents

Rice antibacterial and insecticidal composition containing buprofezin Download PDF

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Publication number
CN106614645A
CN106614645A CN201611241490.XA CN201611241490A CN106614645A CN 106614645 A CN106614645 A CN 106614645A CN 201611241490 A CN201611241490 A CN 201611241490A CN 106614645 A CN106614645 A CN 106614645A
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China
Prior art keywords
rice
buprofezin
amide
composition
ether amide
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CN201611241490.XA
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Chinese (zh)
Inventor
金加明
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Chengdu Geruisaisi Technology Co Ltd
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Chengdu Geruisaisi Technology Co Ltd
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Priority to CN201611241490.XA priority Critical patent/CN106614645A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/88Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention belongs to the technical field of pesticides and relates to a rice antibacterial and insecticidal composition. The effective components of the composition are chlorine phenylate amide or fluorine phenylate amide and buprofezin; preferably, the mass percentage of chlorine phenylate amide or fluorine phenylate amide is 2-20%, and the mass percentage of buprofezin is 2-20%. The compound pesticide overcomes defects of original pesticides with single components, the complementary and synergistic effects are obvious, rice blast, sheath blight and rice leaf roller can be effectively prevented at the same time, and the composition is convenient for farmers to use. The composition has the advantages of taking effect quickly and being wide in spectrum and low in cost, can be prepared into suspending agents, wettable powder, water dispersible granules and other conventional preparations, and is high in prevention effect and long in lasting time. The consumption can be reduced, insecticide resistance is delayed, environment pollution is reduced, and the practicality is high.

Description

A kind of paddy rice Fungicidal insecticidal composition containing Buprofezin
Technical field
The invention belongs to pesticide field, is related to a kind of synergistic sterilization for preventing and treating rice pest of energy generation and kills Worm composition, the specifically composition containing bactericide chlorobenzene ether amide or fluorobenzene ether amide and insecticide Buprofezin.
Background technology
Also known as moire disease, popular name spends sufficient stalk, rotten pin pest, features spot to rice sheath blight disease.It is to be fallen ill by Rhizoctonia solani Kuhn infection, It is many to occur under high temperature, super-humid conditions.Banded sclerotial blight causes harm seriously in South Rice Region of China, be Major Diseases in current Rice Production it One.The disease prevents paddy rice from earing, or the not plump paddy of heading is more, and grain declines again.
Rice blast be paddy rice on important disease, be distributed in national each paddy rice producing region, paddy rice whole breeding time all Occur;Rice leaf roller is the important pests on paddy rice, and the two all has a strong impact on rice yield.Annual June-August is rice blast With the rice leaf roller simultaneous time, be also paddy rice prevention and elimination of disease and pests ensure yield important period, finding one kind can Preventing and treating rice blast can prevent and treat the medicament of rice leaf roller again becomes problem demanding prompt solution.
Chlorobenzene ether amide or fluorobenzene ether amide are Central China Normal University's pyrazol acid amide compounds newly developed, to cucumber, The diseases such as epidemic disease, downy mildew, the tikka of the plants such as tomato, potato have good prevention effect, while to paddy rice and wheat Banded sclerotial blight, powdery mildew etc. have good preventive effect.Field test shows do not have cross resistance with existing bactericide.Chlorobenzene ether amide (I)Or fluorobenzene ether amide(II)Structural formula it is as follows.
Buprofezin (english common name buprofezin, other Chinese buprofezins, buprofezin, the spirit of rice lice, rice Lice is net, is a kind of new selective insecticide of suppression insect growth development, and action of contace poison is strong, also there is stomach poison function.Effect machine It is made as suppressing insect chitin synthesis and disturbs metabolism, causes nymph to cast off a skin deformity or wing deformity and slow dead.Typically Effect can just be found out within 3-7 days after dispenser, there is no direct killing power to adult, but its life-span can be shortened, reduce egg laying amount, and The mostly of output are addle-eggs, even if larva hatching is also dead quickly.Double wing purpose plant hopper, leafhopper, aleyrodid and shell insects evil Worm has good prevention effect, and the lasting period is up to more than 30 days.Safer to natural enemy, comprehensive effect is good.Suitable for paddy rice, fruit Tree, tea tree, vegetables.But in actual application, exclusive use Buprofezin single dose quick-acting is poor, and insect is also easy to produce resistance, Use cost is raised increasingly.Structure formula (III) is as follows.
In the prior art, China is mainly single pest control or single controlling disease for the agricultural chemicals of rice seedling, Can be while pest control and the product development of disease be little.Therefore, the pesticide-germicide combination of exploitation preventing and treating rice seedling pest and disease damage Thing, for the agriculture large-scale development of propulsion has positive effect.
By the Searches of Patent Literature, the sterilization of chlorobenzene ether amide or fluorobenzene ether amide and Buprofezin is there is presently no both at home and abroad The patent of Pesticidal combination, therefore, chlorobenzene ether amide or fluorobenzene ether amide have certain novelty and reality with buprofezin compound The property used.
The content of the invention
Present invention aims to the shortcoming of above-mentioned technology, there is provided a kind of component is reasonable, pesticide-germicide spectrum is wide, preventing and treating Effect is good, low cost, lasting period length and the convenient paddy rice insecticidal and bactericidal composition of dispenser.
The technical scheme for realizing the object of the invention is:
A kind of paddy rice insecticidal and bactericidal composition, its active ingredient is chlorobenzene ether amide or fluorobenzene ether amide and Buprofezin.
Described insecticidal and bactericidal composition, it is characterised in that the quality percentage containing chlorobenzene ether amide or fluorobenzene ether amide contains Measure as 1%~50%, the weight/mass percentage composition 1%~50% of Buprofezin.
Described insecticidal and bactericidal composition, it is characterised in that the preferred mass percentage of chlorobenzene ether amide or fluorobenzene ether amide contains Measure as 2%~20%, the preferred mass percentage composition of Buprofezin is 2%~20%.
Described insecticidal and bactericidal composition, it is characterised in that add appropriate auxiliary agent, filler, water in its composition as needed Deng being configured to suspending agent, wettable powder, water dispersible granules.
By the present invention, it is possible to provide while improving the effect of preventing and treating rice insect pest and preventing and treating fungus-caused rice disease New antifungal and/insecticidal mixtures and its prevention and controls of effect.
Antifungal and/insecticidal mixtures and rice crop the pest control method discovery of rice crop of the present invention, The composition of chlorobenzene ether amide or fluorobenzene ether amide and Buprofezin, for the disease such as paddy rice rice blast that phytopathogenic fungi causes Disease, helminthosporium leaf spot, banded sclerotial blight etc. and rice-stem borer, rice leaf roller, thrips etc. can play synergistic effect.The present invention Composition and its method, for the effect of the preventing and treating with synergy of phytopathogenic fungi and insect.The effect has from each list The various disease and insects that medicament has prevent and kill off the unpredictable effect for arriving in characteristic.
The present invention has the following advantages that compared with prior art
(1)Expand the preventing and treating spectrum of rice pest;
(2)Delay and administer the resistance to the action of a drug of paddy rice harmful organism;
(3)Significantly lower than similar kind in price with consumption.
The invention provides a kind of desinsection, bactericidal composition, including chlorobenzene ether amide or fluorobenzene ether amide and Buprofezin Combination.It is found by experiment that, the composition of the present invention there can not only be additive property to the action spectrum of plant pathogenic fungi and/or insect Strengthen, but also the action spectrum that can expand compound Buprofezin, chlorobenzene ether amide or fluorobenzene ether amide is realized at two aspects Cooperative effect, the rate of application of compound Buprofezin and chlorobenzene ether amide or fluorobenzene ether amide maintains like good while reduction Effect.The present composition is particularly well-suited to prevent and treat rice blast, banded sclerotial blight and striped rice borer, rice leaf roller.And with Exclusive use is compared, and has the synergy prevention effect of reinforcing to both.
Specific embodiment
The following examples are the several specific embodiments for illustrating the present invention, but do not limit the invention to this A little specific embodiments.One skilled in the art would recognize that present invention encompasses institute may bag in Claims scope All alternatives, improvement project and the equivalents for including.
Material prescription selects to suit measures to local conditions in following embodiments, on result without substantial impact.In these embodiments In, unless otherwise indicated, all percentages are weight percentage.
1st, the preparation of wettable powder
According to the proportion requirement of formula, it is separately added into wetting agent, dispersant, active compound, spreader-sticker, inserts and is well mixed, mixes Crushing obtains final product wettable powder product, sees embodiment 1-2.
The mass ratio of each component in the wettable powder of embodiment 1
Chlorobenzene ether amide 5%
Buprofezin 5%
Neopelex 80%
Calcium lignosulfonate 6%
Polyvinyl alcohol 2.5%
White carbon 12%
Diatomite surplus/2
Kaolin surplus/2
The mass ratio of each component in the wettable powder of embodiment 2
Fluorobenzene ether amide 5%
Buprofezin 5%
Neopelex 80%
Calcium lignosulfonate 6%
Polyvinyl alcohol 2.5%
White carbon 12%
Diatomite surplus/2
Kaolin surplus/2
2nd, the preparation of water dispersible granules
According to the proportion requirement of formula, it is separately added into wetting agent, dispersant, active compound, bleeding agent, spreader-sticker, diffusant, filler and mixes Close uniform, crush, add appropriate purified water, after being well mixed, extruder grain after drying, obtains final product water dispersible granules product, sees Embodiment 3-4.
The weight ratio of each component in the water dispersible granules of embodiment 3
Chlorobenzene ether amide 5%
Buprofezin 5%
Neopelex 10%
Ethoxylated dodecyl alcohol 4%
Polyvinyl alcohol 2.5%
Ammonium sulfate 8%
NNO 5%
White carbon 12%
Diatomite surplus/2
Kaolin surplus/2
The weight ratio of each component in the water dispersible granules of embodiment 4
Fluorobenzene ether amide 5%
Buprofezin 5%
Neopelex 10%
Ethoxylated dodecyl alcohol 4%
Polyvinyl alcohol 2.5%
Ammonium sulfate 8%
NNO 5%
White carbon 12%
Diatomite surplus/2
Kaolin surplus/2
3. the preparation of suspending agent
According to the proportion requirement of formula, wetting agent, dispersant, active compound, bleeding agent, defoamer, thickener, antifreeze is separately added into Agent, water are well mixed, and are fully ground to product average grain diameter less than 2 microns, obtain final product suspending agent product, see embodiment 5-6.
The weight ratio of each component in the suspending agent of embodiment 5
Chlorobenzene ether amide 5%
Buprofezin 5%
Neopelex 7%
JFC 4.5%
Polyvinyl alcohol 2.5%
NNO 6%
Xanthans 0.5%
Propane diols 1%
S-29 0.5%
Water complements to 100%
The weight ratio of each component in the suspending agent of embodiment 6
Fluorobenzene ether amide 5%
Buprofezin 5%
Neopelex 7%
JFC 4.5%
Polyvinyl alcohol 2.5%
NNO 6%
Xanthans 0.5%
Propane diols 1%
S-29 0.5%
Water complements to 100%
Application Example
In July, 2016, the test of pesticide effectiveness is carried out on paddy rice, be banded sclerotial blight early stage during test, there is scab, the vertical volume of rice on blade The medium generation of leaf snout moth's larva, medicament formula, 5% chlorobenzene ether amide suspending agent, 5% fluorobenzene ether amide suspending agent, 5% Buprofezin from more than Wettable powder.Second dispenser after lOd is spaced after first time dispenser, 15d investigation insecticidal effects and sterilization after second dispenser Effect.
The investigation method of banded sclerotial blight is:Each cell selects 5 fixed point observations, per 2 clumps of paddy rice that disease is investigated before dispenser Refer to, the sick leaf rate of 15d investigation, disease index, calculate the prevention effect of each medicament after last time dispenser.
Banded sclerotial blight grade scale:
0 grade:It is disease-free;
1 grade:Leaf spot lesion is less than 5, and length is less than 1 cm;
3 grades:Leaf spot lesion 6-10, part scab length is more than 1 cm;
5 grades:Leaf spot lesion 11-25, part scab is linked to be piece, accounts for leaf area 10-25%;
7 grades:Leaf spot lesion more than 26, scab is linked to be piece, accounts for leaf area 26-50%;
9 grades:Scab is linked to be piece, accounts for leaf area more than 50% or full leaf is withered.
Disease index=[∑ (the sick number of sheets × relative series)/(investigation total number of sheets × total series)] × 100
Prevention effect (%)=[1- (CKoSick index × pt1Sick index/CK1×ptoSick index)] × 100
CkoFor the disease index of the front check plot of dispenser;ck1For the disease index of check plot after dispenser;
ptoFor the disease index before treatment region dispenser;pt1For the disease index of dispenser post processing zone;
The investigation method of rice leaf roller is:15d investigation leaf roll number, calculates prevention effect after last time dispenser.
Leaf roll rate (%)=(investigation leaf roll number/investigation total number of sheets) × 100
Prevention effect (%)=[(blank district leaf roll rate-treatment region leaf roll rate)/blank district leaf roll rate] × 100
The chlorobenzene ether amide of table 1 or fluorobenzene ether amide, Buprofezin test of pesticide effectiveness result
From test, chlorobenzene ether amide or fluorobenzene ether amide and Buprofezin are (after compounding, to rice sheath blight disease and rice leaf roller Have good prevention effect, after second dispenser 15d to the preventive effect of banded sclerotial blight and rice leaf roller all more than 85%.Peasant one Secondary medication can effectively prevent and treat banded sclerotial blight and rice leaf roller, because chlorobenzene ether amide or fluorobenzene ether amide and Buprofezin (have height Effect Uptake and translocation, can significantly extend the lasting period of medicament, reduce times for spraying, reduce planting cost.

Claims (4)

1. a kind of paddy rice insecticidal and bactericidal composition, its active ingredient is bactericide chlorobenzene ether amide or fluorobenzene ether amide and thiazine Ketone.
2. insecticidal and bactericidal composition according to claim 1, it is characterised in that containing chlorobenzene ether amide or fluorobenzene ether amide Weight/mass percentage composition be 1%~50%, the weight/mass percentage composition 1%~50% of Buprofezin.
3. insecticidal and bactericidal composition according to claim 2, it is characterised in that chlorobenzene ether amide or fluorobenzene ether amide it is excellent Weight/mass percentage composition is selected to be 2%~20%, the preferred mass percentage composition of Buprofezin is 2%~20%.
4. insecticidal and bactericidal composition according to claim 1, it is characterised in that add as needed in its composition appropriate Auxiliary agent, filler, water etc., are configured to suspending agent, wettable powder, water dispersible granules.
CN201611241490.XA 2016-12-29 2016-12-29 Rice antibacterial and insecticidal composition containing buprofezin Pending CN106614645A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN119073316A (en) * 2024-08-31 2024-12-06 中国农业科学院植物保护研究所 Buprofezin as a chitin synthase inhibitor of fungi and oomycetes and its application in bactericidal treatment

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101606523A (en) * 2009-07-23 2009-12-23 北京燕化永乐农药有限公司 A kind of paddy rice desinsection, bactericidal composition
CN101755767A (en) * 2009-11-17 2010-06-30 陕西汤普森生物科技有限公司 Pesticidal composition containing buprofezin and flubendiamide
CN104396962A (en) * 2014-12-03 2015-03-11 北京燕化永乐生物科技股份有限公司 Pesticide composition
CN104488913A (en) * 2014-12-23 2015-04-08 安徽众邦生物工程有限公司 Buprofezin-containing insecticidal composition
CN104557709A (en) * 2013-10-23 2015-04-29 华中师范大学 Pyrazole amide compound containing diphenyl ether, and application and pesticide composition of pyrazole amide compound

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101606523A (en) * 2009-07-23 2009-12-23 北京燕化永乐农药有限公司 A kind of paddy rice desinsection, bactericidal composition
CN101755767A (en) * 2009-11-17 2010-06-30 陕西汤普森生物科技有限公司 Pesticidal composition containing buprofezin and flubendiamide
CN104557709A (en) * 2013-10-23 2015-04-29 华中师范大学 Pyrazole amide compound containing diphenyl ether, and application and pesticide composition of pyrazole amide compound
CN104396962A (en) * 2014-12-03 2015-03-11 北京燕化永乐生物科技股份有限公司 Pesticide composition
CN104488913A (en) * 2014-12-23 2015-04-08 安徽众邦生物工程有限公司 Buprofezin-containing insecticidal composition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN119073316A (en) * 2024-08-31 2024-12-06 中国农业科学院植物保护研究所 Buprofezin as a chitin synthase inhibitor of fungi and oomycetes and its application in bactericidal treatment
CN119073316B (en) * 2024-08-31 2025-09-05 中国农业科学院植物保护研究所 Buprofezin as a chitin synthase inhibitor of fungi and oomycetes and its application in bactericidal treatment

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