CN106567816A - Metal hydride hydrogen-pressurizing device with full-automatic multi-stage compression function - Google Patents

Metal hydride hydrogen-pressurizing device with full-automatic multi-stage compression function Download PDF

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Publication number
CN106567816A
CN106567816A CN201510668612.2A CN201510668612A CN106567816A CN 106567816 A CN106567816 A CN 106567816A CN 201510668612 A CN201510668612 A CN 201510668612A CN 106567816 A CN106567816 A CN 106567816A
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China
Prior art keywords
metal hydride
hydrogen
full
compression
unit
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Pending
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CN201510668612.2A
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Chinese (zh)
Inventor
张沛龙
朱永国
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Whole Win (beijing) Materials Sci & Tech Co Ltd
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Whole Win (beijing) Materials Sci & Tech Co Ltd
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Priority to CN201510668612.2A priority Critical patent/CN106567816A/en
Publication of CN106567816A publication Critical patent/CN106567816A/en
Pending legal-status Critical Current

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Abstract

The invention provides a metal hydride hydrogen-pressurizing device with a full-automatic multi-stage compression function. The metal hydride hydrogen-pressurizing device with the full-automatic multi-stage compression function comprises two or more metal hydride compression units, a heat exchange unit and a control unit. The metal hydride compression units are arranged inside the heat exchange unit, the pressure, flow and temperature of a system are detected through the control unit, and thus automatic operation of the metal hydride hydrogen-pressurizing device is achieved. The metal hydride hydrogen-pressurizing device with the full-automatic multi-stage compression function is small in occupied space, free of noise, low in compression cost, easy to operate and convenient to maintain, has a hydrogen purification function, is an economical and efficient hydrogen compressor product, and can replace a traditional mechanical compressor.

Description

The metal hydride hydrogen pressurizer of full-automatic multistage compression
Technical field
The present invention relates to a kind of method of hydrogen compression, puts at a lower temperature hydrogen platform and press relatively low using metal hydride, the higher principle of hydrogen platform pressure is put at relatively high temperatures, reach the purpose of hydrogen pressurization.
Background technology
According to macroscopic property, metal hydride puts hydrogen pressure variation with temperature and follows Van ' t Hoff equations:lnPd=△H0/RT-△S0/ R, wherein, Pd is to put hydrogen balance pressure, △ H0With △ S0For the enthalpy change and Entropy Changes of reaction.
After hydrogen bearing alloy inhales hydrogen saturation under lower temperature and lower pressure, metal hydride temperature is increased to into higher temperature, now metal hydride will release the hydrogen of high pressure.Metal hydride hydrogen compressor is different according to the hydrogen storage material for selecting i.e. using the characteristic work of hydrogen bearing alloy, is capable of achieving different degrees of pressurized effect.
In the market ripe hydrogen compressor is mechanical compressor, this compressor typically all needs multi-stage booster to reach elevated pressures because of the restriction of compressed ratio, there is the shortcomings of volume is big, weight is heavy, power consumption is high, and a certain degree of reduction hydrogen purity of meeting, also need to set up hydrogen purification equipment.
Metal hydride hydrogen compressor compact conformation, substantially, hydrogen purity is unaffected, has great application prospect for pressurized effect.At present the metal hydride hydrogen compressor of exploitation mostly is single stage compress, and pressurized effect is limited, and is all that, by artificial operation, the regulation because being related to temperature, pressure etc., operation is complex, and its popularization and application is very restricted.
The content of the invention
For problem above, the present invention provides a kind of metal hydride hydrogen pressurizer simple to operate, Automated condtrol operation, including metal hydride compression unit, heat exchange unit, control unit, metal hydride compression unit is two or more, metal hydride compression unit is placed in inside heat exchange unit, and by control unit the automatic running of metal hydride hydrogen pressurizer is realized.
Metal hydride compression unit inside filling Rare Earth, titanium system or magnesium microalloying, hydrogen is stored in solid form.
Heat exchange unit interior media is one kind of water, oil, paraffin or fused salt.
Control unit regulates and controls temperature, the temperature control time of heat exchange unit, monitors the input of metal hydride compression unit, the flow of output and pressure.
Using the hydrogen pressurizer, hydrogen compressed efficiency is greatly improved, it is low, simple to operate, easy to maintenance and with hydrogen purification function to take up an area little, noiseless, cost squeeze, be a kind of hydrogen compressor product of economical and efficient, alternative traditional mechanical formula compressor.
Description of the drawings
Metal hydride hydrogen pressurizer schematic diagram in Fig. 1 embodiments 1.
Metal hydride hydrogen pressurizer schematic diagram in Fig. 2 embodiments 2.
Specific embodiment
Further description is launched to the present invention below in conjunction with specific embodiment, but the present invention is not limited to this, can suitably change in the range of its main points not changing.
Embodiment 1
The metal hydride hydrogen pressurizer of two-stage compression, including two metal hydride compression units 2 and 2 ', heat exchange unit 3, control unit 5, the internal filling lanthanon hydrogen storage material of metal hydride compression unit 2 and 2 ', metal hydride compression unit 2 and 2 ' is placed in inside heat exchange unit 3;Hydrogen source 1 is input into pressure hydrogen into metal hydride compression unit 2, first it is stored in buffer container 4 through the hydrogen of one stage of compression, after reaching specified pressure, into in metal hydride compression unit 2 ', after two-stage compression, the exportable High Pressure Hydrogen 6 of the device, by control unit 5 automatic running of metal hydride hydrogen pressurizer is realized.
Embodiment 2
The metal hydride hydrogen pressurizer of three stage compression, including three metal hydride compression units 2,2 ' and 2 ' ', heat exchange unit 3, control unit 5, the internal filling titanium system hydrogen storage material of metal hydride compression unit 2,2 ' and 2 ' ', metal hydride compression unit 2,2 ' and 2 ' ' is placed in inside heat exchange unit 3;Hydrogen source 1 is input into pressure hydrogen into metal hydride compression unit 2, enter back in metal hydride compression unit 2 ' through the hydrogen of one stage of compression, so after three stage compression, the exportable High Pressure Hydrogen 5 of the device realizes the automatic running of metal hydride hydrogen pressurizer by control unit 4.

Claims (4)

1. the metal hydride hydrogen pressurizer of full-automatic multistage compression, including metal hydride compression unit, heat exchange unit, control unit, metal hydride compression unit is two or more, metal hydride compression unit is placed in inside heat exchange unit, and by control unit the automatic running of metal hydride hydrogen pressurizer is realized.
2. the metal hydride hydrogen pressurizer of full-automatic multistage compression according to claim 1, it is characterised in that metal hydride compression unit inside filling Rare Earth, titanium system or magnesium microalloying.
3. the metal hydride hydrogen pressurizer of full-automatic multistage compression according to claim 1, it is characterised in that heat exchange unit interior media is one kind of water, oil, paraffin or fused salt.
4. the metal hydride hydrogen pressurizer of full-automatic multistage compression according to claim 1, it is characterised in that control unit regulates and controls temperature, the temperature control time of heat exchange unit, monitors the input of metal hydride compression unit, the flow of output and pressure.
CN201510668612.2A 2015-10-13 2015-10-13 Metal hydride hydrogen-pressurizing device with full-automatic multi-stage compression function Pending CN106567816A (en)

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CN201510668612.2A CN106567816A (en) 2015-10-13 2015-10-13 Metal hydride hydrogen-pressurizing device with full-automatic multi-stage compression function

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CN201510668612.2A CN106567816A (en) 2015-10-13 2015-10-13 Metal hydride hydrogen-pressurizing device with full-automatic multi-stage compression function

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CN106567816A true CN106567816A (en) 2017-04-19

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114087160A (en) * 2021-11-25 2022-02-25 浙江大学 Cascade type static hydrogen pressurization system and method based on hydrogen storage material
CN114542953A (en) * 2022-01-18 2022-05-27 华南理工大学 Metal hydride hydrogen compressor system and method for waste heat utilization

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104671199A (en) * 2013-11-29 2015-06-03 北京有色金属研究总院 Device for preparing high-pressure hydrogen by using metal hydrides
CN205036524U (en) * 2015-10-13 2016-02-17 北京浩运金能科技有限公司 Full -automatic multi -stage compression's metal hydride hydrogen supercharging device

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104671199A (en) * 2013-11-29 2015-06-03 北京有色金属研究总院 Device for preparing high-pressure hydrogen by using metal hydrides
CN205036524U (en) * 2015-10-13 2016-02-17 北京浩运金能科技有限公司 Full -automatic multi -stage compression's metal hydride hydrogen supercharging device

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
张琰: "用于金属氢化物化学氢压缩的储氢合金的研究", 《浙江大学硕士学位论文》 *
胡晓晨: "基于金属氢化物的两级氢气压缩机特性研究", 《上海交通大学硕士学位论文》 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114087160A (en) * 2021-11-25 2022-02-25 浙江大学 Cascade type static hydrogen pressurization system and method based on hydrogen storage material
CN114087160B (en) * 2021-11-25 2022-11-25 浙江大学 Cascade type static hydrogen pressurization system and method based on hydrogen storage material
CN114542953A (en) * 2022-01-18 2022-05-27 华南理工大学 Metal hydride hydrogen compressor system and method for waste heat utilization
CN114542953B (en) * 2022-01-18 2023-06-16 华南理工大学 Waste heat utilization metal hydride hydrogen compressor system and method

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