CN106479011A - A kind of PE composite - Google Patents

A kind of PE composite Download PDF

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Publication number
CN106479011A
CN106479011A CN201510526279.1A CN201510526279A CN106479011A CN 106479011 A CN106479011 A CN 106479011A CN 201510526279 A CN201510526279 A CN 201510526279A CN 106479011 A CN106479011 A CN 106479011A
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CN
China
Prior art keywords
composite
screw extruder
parts
double screw
filler
Prior art date
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Pending
Application number
CN201510526279.1A
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Chinese (zh)
Inventor
储照良
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Individual
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Individual
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Priority to CN201510526279.1A priority Critical patent/CN106479011A/en
Publication of CN106479011A publication Critical patent/CN106479011A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/016Additives defined by their aspect ratio

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)

Abstract

The invention belongs to technical field of composite materials, it is related to a kind of PE composite.PE composite is mainly made up of following component (in terms of parts by weight):PE:100 parts, POM:5-30 part, reinforcing fiber:20-40 part, filler:10-25 part, fire retardant:15-30 part, coupling agent:1-5 part, antioxidant:1-3 part, age resister:1-3 part.The combination properties such as the intensity of PE composite of the present invention, toughness are more preferable.

Description

A kind of PE composite
Technical field
The invention belongs to technical field of composite materials, it is related to a kind of PE composite.
Background technology
Polyethylene is a kind of thermoplastic resin.Industrially, concrete odorless, nontoxic, strong Degree height, good toughness, excellent resistance to low temperature (minimum use temperature up to - 100~-70 DEG C), chemical stability is good, be resistant to the performance such as erosions of most of soda acids. Therefore, being industrially widely used of polyethylene, meanwhile, polyethylene is combined The development of material is more perfect.
Content of the invention
The purpose of the present invention is to there are the problems referred to above for existing technology it is proposed that a kind of The combination properties such as intensity, toughness more preferable PE composite.
The purpose of the present invention can be realized by following technical proposal:A kind of PE composite wood Material, is mainly made up of following component (in terms of parts by weight):PE:100 parts, POM: 5-30 part, reinforcing fiber:20-40 part, filler:10-25 part, fire retardant:15-30 Part, coupling agent:1-5 part, antioxidant:1-3 part, age resister:1-3 part.
In a kind of above-mentioned PE composite, reinforcing fiber is carbon fiber, glass fibers Dimension one of or two kinds.
In a kind of above-mentioned PE composite, 20 μm of the diameter < of reinforcing fiber, long Footpath ratio is (50-100):1.
In a kind of above-mentioned PE composite, filler is particle diameter < 100nm.
In a kind of above-mentioned PE composite, filler be aluminium sesquioxide, magnesium oxide, One or more of Muscovitum, Pulvis Talci, Calcium Carbonate, white carbon, potassium titanate.
Further object is that providing the preparation method of above-mentioned PE composite, Preparation method comprises the following steps:
S1, the constituent by PE composite and its parts by weight weigh raw material, throw Enter in high-speed mixer mix homogeneously, obtain material;
S2, the material of above-mentioned mix homogeneously is put into double screw extruder feed hopper, By in feed hopper feeding double screw extruder, from the head extrusion of double screw extruder, PE composite pellet is obtained by granulator granulation.
In a kind of preparation method of above-mentioned PE composite, twin screw in step S2 At 180-220 DEG C, screw speed is 30-60r/min to the temperature control of extruder.
Compared with prior art, PE composite of the present invention has more preferable intensity, tough The combination properties such as property.
Specific embodiment
The following is the specific embodiment of the present invention, technical scheme is made further Description, but the present invention is not limited to these embodiments.
Table 1:The constituent of PE composite of the present invention and its parts by weight
Embodiment 1:
Weigh by the constituent and its parts by weight of embodiment 1PE composite in table 1 Raw material.Wherein, POM drying is processed;Reinforcing fiber is carbon fiber, 20 μm of diameter <, Draw ratio is (50-100):1;Filler is the Al of particle diameter < 100nm2O3.Afterwards will Mix homogeneously in high-speed mixer put into by all raw materials, obtains material.Then by material Put into double screw extruder feed hopper, feed in double screw extruder by feed hopper, At 180 DEG C, screw speed is 30r/min to the temperature control of double screw extruder, from double spiral shells The head extrusion of bar extruder.Again PE composite pellet is obtained by granulator granulation.
Embodiment 2:
Weigh by the constituent and its parts by weight of embodiment 2PE composite in table 1 Raw material.Wherein, POM drying is processed;Reinforcing fiber is glass fibre, 20 μm of diameter <, Draw ratio is (50-100):1;Filler is the Al of particle diameter < 100nm2O3.Afterwards will Mix homogeneously in high-speed mixer put into by all raw materials, obtains material.Then by material Put into double screw extruder feed hopper, feed in double screw extruder by feed hopper, At 180 DEG C, screw speed is 30r/min to the temperature control of double screw extruder, from double spiral shells The head extrusion of bar extruder.Again PE composite pellet is obtained by granulator granulation.
Embodiment 3:
Weigh by the constituent and its parts by weight of embodiment 3PE composite in table 1 Raw material.Wherein, POM drying is processed;Reinforcing fiber is carbon fiber, 20 μm of diameter <, Draw ratio is (50-100):1;Filler is the magnesium oxide of particle diameter < 100nm.Afterwards will Mix homogeneously in high-speed mixer put into by all raw materials, obtains material.Then by material Put into double screw extruder feed hopper, feed in double screw extruder by feed hopper, At 180 DEG C, screw speed is 30r/min to the temperature control of double screw extruder, from double spiral shells The head extrusion of bar extruder.Again PE composite pellet is obtained by granulator granulation.
Embodiment 4:
Weigh by the constituent and its parts by weight of embodiment 4PE composite in table 1 Raw material.Wherein, POM drying is processed;Reinforcing fiber is carbon fiber, 20 μm of diameter <, Draw ratio is (50-100):1;Filler is the Pulvis Talci of particle diameter < 100nm.Afterwards will Mix homogeneously in high-speed mixer put into by all raw materials, obtains material.Then by material Put into double screw extruder feed hopper, feed in double screw extruder by feed hopper, At 180 DEG C, screw speed is 30r/min to the temperature control of double screw extruder, from double spiral shells The head extrusion of bar extruder.Again PE composite pellet is obtained by granulator granulation.
The PE composite that embodiment of the present invention 1-4 is made carries out performance test, test Result is as shown in table 2.
Table 2
This place embodiment to the claimed non-limit of technical scope midrange it Place, equally all in the scope of protection of present invention.
Specific embodiment described herein is only theory for example to present invention spirit Bright.Those skilled in the art can be to described specific embodiment Make various modifications or supplement or substituted using similar mode, but without departing from The spirit of the present invention or surmount scope defined in appended claims.

Claims (6)

1. a kind of PE composite it is characterised in that described PE composite mainly by Following component (in terms of parts by weight) forms:PE:100 parts, POM:5-30 part, Reinforcing fiber:20-40 part, filler:10-25 part, fire retardant:15-30 part, is coupled Agent:1-5 part, antioxidant:1-3 part, age resister:1-3 part.
2. a kind of PE composite according to claim 1 is it is characterised in that institute Stating reinforcing fiber is one of carbon fiber, glass fibre or two kinds.
3. a kind of PE composite according to claim 1 and 2 it is characterised in that 20 μm of the diameter < of described reinforcing fiber, draw ratio is (50-100):1.
4. a kind of PE composite according to claim 1 is it is characterised in that institute Stating filler is particle diameter < 100nm.
5. a kind of PE composite according to claim 1 or 4 it is characterised in that Described filler is aluminium sesquioxide, magnesium oxide, Muscovitum, Pulvis Talci, Calcium Carbonate, Linesless charcoal One or more of black, potassium titanate.
6. a kind of preparation method of PE composite is it is characterised in that described preparation method Comprise the following steps:
S1, the constituent by PE composite and its parts by weight weigh raw material, throw Enter in high-speed mixer mix homogeneously, obtain material;
S2, the material of above-mentioned mix homogeneously is put into double screw extruder feed hopper, By in feed hopper feeding double screw extruder, from the head extrusion of double screw extruder, PE composite pellet is obtained by granulator granulation.
CN201510526279.1A 2015-08-25 2015-08-25 A kind of PE composite Pending CN106479011A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510526279.1A CN106479011A (en) 2015-08-25 2015-08-25 A kind of PE composite

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510526279.1A CN106479011A (en) 2015-08-25 2015-08-25 A kind of PE composite

Publications (1)

Publication Number Publication Date
CN106479011A true CN106479011A (en) 2017-03-08

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510526279.1A Pending CN106479011A (en) 2015-08-25 2015-08-25 A kind of PE composite

Country Status (1)

Country Link
CN (1) CN106479011A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107828110A (en) * 2017-11-14 2018-03-23 安徽同力新材料有限公司 A kind of high-strength engineering plastic

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102241849A (en) * 2011-06-16 2011-11-16 上海邦中新材料有限公司 Carbon-fiber-reinforced polyethylene composite material

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102241849A (en) * 2011-06-16 2011-11-16 上海邦中新材料有限公司 Carbon-fiber-reinforced polyethylene composite material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107828110A (en) * 2017-11-14 2018-03-23 安徽同力新材料有限公司 A kind of high-strength engineering plastic

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