CN106477670A - A kind of oil-containing emulsifies sewage breaking device - Google Patents
A kind of oil-containing emulsifies sewage breaking device Download PDFInfo
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- CN106477670A CN106477670A CN201610964308.7A CN201610964308A CN106477670A CN 106477670 A CN106477670 A CN 106477670A CN 201610964308 A CN201610964308 A CN 201610964308A CN 106477670 A CN106477670 A CN 106477670A
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- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/40—Devices for separating or removing fatty or oily substances or similar floating material
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- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
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Abstract
本发明公开了一种含油乳化污水破乳装置,其特征在于:破乳装置包括用于污水破乳处理的污水处理箱,污水处理箱箱体侧壁上设有污水进口、污物排出口和净水出口,内盛满污水,内设有气液混合系统、高速喷射系统、聚结分离系统、若干隔板。本发明通过气液混溶系统,将氧气或者臭氧与自来水进行混溶,形成气液混流液,切向进入高效喷射系统,在锥形液体通道内旋转上升,到达出口与污水混合,冲破乳化油,使得水包油乳化破乳,小油滴聚集,并且向上浮动,到达聚结分离系统,油滴不断在聚结板聚结,并到达聚结板的顶部,比重较大的水回落至污水箱的下部,并经过隔板流动至出口,本发明设计合理,低能耗的实现乳化油的破乳。
The invention discloses an oil-containing emulsified sewage demulsification device, which is characterized in that the demulsification device includes a sewage treatment tank for demulsification treatment of sewage, and the side wall of the sewage treatment tank is provided with a sewage inlet, a sewage discharge outlet and The clean water outlet is filled with sewage, and is equipped with a gas-liquid mixing system, a high-speed injection system, a coalescence separation system, and several partitions. The invention mixes oxygen or ozone with tap water through a gas-liquid miscibility system to form a gas-liquid mixed flow liquid, which enters the high-efficiency injection system tangentially, rotates and rises in the conical liquid channel, reaches the outlet and mixes with sewage, and breaks through the emulsified oil , so that the oil-in-water emulsification and demulsification, small oil droplets gather, and float upward, reach the coalescence separation system, the oil droplets continue to coalesce on the coalescence plate, and reach the top of the coalescence plate, and the water with a larger specific gravity falls back to the sewage The lower part of the tank, and flows to the outlet through the partition. The invention has a reasonable design and realizes the demulsification of the emulsified oil with low energy consumption.
Description
技术领域technical field
本发明涉及环保处理工业,具体涉及一种含油乳化污水破乳装置。The invention relates to the environmental protection treatment industry, in particular to an oil-containing emulsified sewage demulsification device.
背景技术Background technique
石油开采、化工生产、都市生活、轮船运行等都会产生深度乳化含油污水,此污水必须经过净化处理方可回用或外排。本发明所述含油污水油污主要以水包油形式存在,由于乳化油粒径极其微小(约为0.1~10微米),具有一定的稳定性,仅靠重力沉降方法难于实现油水分离。传统成熟的处理方法多以加药、絮凝等方式进行,因投资高昂、流程复杂、后续产生大量污泥,给用户带来巨大负担;另外,现有其它如聚结、旋流、超声波等处理方式,虽然一定程度解决了油水分离难题,但很难稳定实现污水处理达标排放。我国石油、石化生产中,会产生有大量含油乳化废水,据资料显示,大庆油田每年可采出数亿立方米含油污水,而净化处理这部分污水需要大量的药剂、高昂的费用;因此如何找到可靠、简单的物理方法处理污水,是环保人员急待面对的问题。鉴于所述,本发明含油乳化污水破乳装置成功解决了以上相关难题,社会效益、经济效益显著,适合工业化应用。Petroleum exploration, chemical production, urban life, ship operation, etc. will produce deeply emulsified oily sewage, which must be purified before being reused or discharged. The oily sewage in the present invention mainly exists in the form of oil-in-water. Since the particle size of the emulsified oil is extremely small (about 0.1-10 microns) and has certain stability, it is difficult to separate oil from water only by gravity sedimentation. Traditional and mature treatment methods are mostly carried out by means of dosing, flocculation, etc., because of high investment, complicated process, and subsequent generation of a large amount of sludge, which brings a huge burden to users; in addition, other existing treatments such as coalescence, cyclone, and ultrasonic Although the problem of oil-water separation has been solved to a certain extent, it is difficult to achieve stable sewage treatment and discharge. In my country's petroleum and petrochemical production, a large amount of oily emulsified wastewater will be produced. According to data, Daqing Oilfield can produce hundreds of millions of cubic meters of oily wastewater every year, and the purification of this part of the wastewater requires a lot of chemicals and high costs; so how to find Reliable and simple physical methods to treat sewage is an urgent problem for environmental protection personnel. In view of the above, the oil-containing emulsified sewage demulsification device of the present invention successfully solves the above related problems, has remarkable social and economic benefits, and is suitable for industrial applications.
发明内容Contents of the invention
针对上述问题,本发明的目的提供一种含油乳化污水破乳装置,实现含油乳化污水破乳处理,破乳后的污水进行油水分离,达到排放标准。In view of the above problems, the object of the present invention is to provide an oil-containing emulsified sewage demulsification device, which can realize the demulsification treatment of oil-containing emulsified sewage, and the demulsified sewage is separated from oil and water to meet the discharge standard.
本发明解决上述技术问题所采用的技术方案是:一种含油乳化污水破乳装置,其特征在于:破乳装置包括用于污水破乳处理的污水处理箱,所述污水处理箱箱体侧壁上设有污水进口、污物排出口和净水出口,所述污水处理箱内盛满污水,内设有气液混合系统、高速喷射系统、聚结分离系统、若干隔板,所述聚结分离系统设置在污水处理箱的箱体内的上部,气液混合系统、高效喷射系统和若干隔板设置在聚结分离系统的下面,所述气液混合系统将臭氧与水混溶,混溶后的气液流进入高速喷射系统,所述高速喷射系统将气液流提速,由高速喷,与污水处理箱内的污水均匀混合、破乳,聚结分离系统聚结油污,并由污物口排出,水经过若干隔板后由净水出口排出。The technical solution adopted by the present invention to solve the above technical problems is: an oily emulsified sewage demulsification device, characterized in that the demulsification device includes a sewage treatment tank for sewage demulsification treatment, and the side wall of the sewage treatment tank There are sewage inlets, sewage outlets and water purification outlets above. The sewage treatment tank is filled with sewage, and is equipped with a gas-liquid mixing system, a high-speed injection system, a coalescence separation system, and several partitions. The coalescence The separation system is set in the upper part of the sewage treatment tank, and the gas-liquid mixing system, high-efficiency injection system and several partitions are set under the coalescence separation system. The gas-liquid mixing system mixes ozone with water, and after mixing The gas-liquid flow enters the high-speed injection system. The high-speed injection system speeds up the gas-liquid flow. The high-speed spray system mixes evenly with the sewage in the sewage treatment tank and breaks the emulsion. The water is discharged from the clean water outlet after passing through several partitions.
优选为,所述高速喷射系统内为锥形液体通道,经过气液混合系统后的混气液切向进入,螺旋加速后高速喷出,高速喷射系统出口设置在污水处理箱的底部,与污水处理箱固定连接,所述聚结分离系统与污水处理箱的内壁四周固定连接,包括若干聚结板,若干所述隔板设置在高速喷射系统的一侧和聚结分离系统的下面,并且交替设置。Preferably, the high-speed injection system is a conical liquid channel, and the gas-mixed liquid after passing through the gas-liquid mixing system enters tangentially, and is ejected at high speed after spiral acceleration. The treatment box is fixedly connected, and the coalescing and separation system is fixedly connected with the inner wall of the sewage treatment tank, including several coalescing plates, and several partitions are arranged on one side of the high-speed injection system and below the coalescing and separating system, and alternately set up.
优选为,所述气液混合系统为圆筒状的管路,内部设有喷入单元,所述喷入单元的外壁上设有若干喷入孔,所述喷入单元与气液混合系统的内壁形成喷入空腔,气体经过喷入空腔经由喷入孔喷入,与液体混合。Preferably, the gas-liquid mixing system is a cylindrical pipeline with an injection unit inside, and a number of injection holes are arranged on the outer wall of the injection unit, and the injection unit and the gas-liquid mixing system The inner wall forms an injection cavity, through which the gas is injected through the injection hole and mixed with the liquid.
优选为,所述喷入孔的开孔方向倾斜与液体流动方向,并且与液体流动方向逆向倾斜设置。Preferably, the opening direction of the injection hole is inclined to the direction of liquid flow, and is arranged to be opposite to the direction of liquid flow.
本发明的优点在于:The advantages of the present invention are:
1、本发明通过气液混溶系统,将氧气或者臭氧与自来水进行混溶,形成气液混流液,切向进入高速喷射系统,螺旋加速后,射入污水中,均匀混合,使得水包油乳化破乳,小油滴聚集、上浮,到达聚结分离系统,油滴不断在聚结板聚结,并到达聚结板的顶部,比重较大的水回落至污水箱的下部,并经过隔板流动至出口,本发明设计合理,低能耗的实现含油污水破乳;1. The present invention mixes oxygen or ozone with tap water through a gas-liquid miscible system to form a gas-liquid mixed flow liquid, which enters the high-speed injection system tangentially, and after spiral acceleration, it is injected into the sewage and mixed evenly to make the oil-in-water Emulsification and demulsification, small oil droplets gather, float up, and reach the coalescence separation system. The oil droplets continue to coalesce on the coalescence plate and reach the top of the coalescence plate. The water with a larger specific gravity falls back to the lower part of the sewage tank and passes through the separation The plate flows to the outlet, the design of the invention is reasonable, and the demulsification of oily sewage is realized with low energy consumption;
2、采用高效喷射系统,切向引入混合液,使混合液在锥形通道内螺旋加速,实现高速旋转射出,在喷出口设置补气体导管,补充微量氧气或臭氧,提高混流液能量,设计合理;2. The high-efficiency injection system is adopted to introduce the mixed liquid tangentially, so that the mixed liquid is spirally accelerated in the conical channel to realize high-speed rotary injection. A supplementary gas conduit is installed at the ejection outlet to supplement trace amounts of oxygen or ozone to increase the energy of the mixed liquid. The design is reasonable ;
3、喷入部设有若干个喷入孔,使得气体通过喷入孔喷入后直接与液体混合,并且设置的喷入孔的倾斜角度正好与液体流向相反,使气体逆向喷入,达到高效混溶的效果;3. The injection part is equipped with several injection holes, so that the gas can be directly mixed with the liquid after being sprayed through the injection holes, and the inclination angle of the set injection holes is just opposite to the flow direction of the liquid, so that the gas can be injected in reverse to achieve high-efficiency mixing. melting effect;
附图说明Description of drawings
为了更清楚地说明本发明具体实施方式或现有技术中的技术方案,下面将对具体实施方式或现有技术描述所需使用的附图作简单介绍。In order to more clearly illustrate the specific embodiments of the present invention or the technical solutions in the prior art, the following will briefly introduce the accompanying drawings required for the description of the specific embodiments or the prior art.
图1为本发明的结构示意图。Fig. 1 is a structural schematic diagram of the present invention.
图2为本发明气液混合系统的结构示意图。Fig. 2 is a schematic structural diagram of the gas-liquid mixing system of the present invention.
图3为本发明高速喷射系统的结构示意图。Fig. 3 is a structural schematic diagram of the high-speed injection system of the present invention.
其中:in:
1、污水处理箱 2、污水进口 3、污物排出口 4、净水出口 5、气液混合系统 6、高速喷射系统 7、聚结分离系统 8、隔板1. Sewage treatment tank 2. Sewage inlet 3. Sewage outlet 4. Clean water outlet 5. Gas-liquid mixing system 6. High-speed injection system 7. Coalescence separation system 8. Baffle
501、喷入单元 502、高压扰流板 503、喷入孔 504、喷入空腔 505、法兰 506、固定边缘 507、喷入部 508、减压阀 509、压力表501, injection unit 502, high pressure spoiler 503, injection hole 504, injection cavity 505, flange 506, fixed edge 507, injection part 508, pressure reducing valve 509, pressure gauge
601、锥形液体通道 602、切向入口 603、旋转出口 604、补充气体出口 605、气体管路601, tapered liquid channel 602, tangential inlet 603, swivel outlet 604, make-up gas outlet 605, gas line
具体实施方式detailed description
下面将结合附图对本发明的技术方案进行清楚、完整地描述,显然,所描述的实施例是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The technical solutions of the present invention will be clearly and completely described below in conjunction with the accompanying drawings. Apparently, the described embodiments are part of the embodiments of the present invention, but not all of them. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the protection scope of the present invention.
在本发明的描述中,需要说明的是,术语“中心”、“上”、“下”、“左”、“右”、“竖直”、“水平”、“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。此外,术语“第一”、“第二”、“第三”仅用于描述目的,而不能理解为指示或暗示相对重要性。In the description of the present invention, it should be noted that the terms "center", "upper", "lower", "left", "right", "vertical", "horizontal", "inner", "outer" etc. The indicated orientation or positional relationship is based on the orientation or positional relationship shown in the drawings, and is only for the convenience of describing the present invention and simplifying the description, rather than indicating or implying that the referred device or element must have a specific orientation, or in a specific orientation. construction and operation, therefore, should not be construed as limiting the invention. In addition, the terms "first", "second", and "third" are used for descriptive purposes only, and should not be construed as indicating or implying relative importance.
如图1-3所示的一种含油乳化污水破乳装置,其特征在于:破乳装置包括用于污水破乳处理的污水处理箱1,所述污水处理箱1箱体侧壁上设有污水进口2、污物排出口3和净水出口4,所述污物排出口3设置在污水处理箱1的顶部,所述污水处理箱1内盛满污水,内设有气液混合系统5、高速喷射系统6、聚结分离系统7、若干隔板8,所述气液混合系统5为圆筒状的管路,内部设有喷入单元501,所述喷入单元501为中空结构,设有轴向相同的圆柱状的水路通道,所述喷入单元501的外壁上设有若干喷入孔503,所述喷入单元501与气液混合系统5的内壁形成喷入空腔504,所述喷入空腔504连接气体管路605;气体经过喷入单元的喷入孔高速喷入,迅速与经过的液体混合,实现气液混流,所述气液混合系统5与高速喷射系统6固定连接,所述高速喷射系统6内为锥形液体通道601,经过气液混合系统5后的混溶液由切向入口602进入锥形液体通道601,所述锥形液体通道601的顶端为旋转出口603,低速进入高喷射系统的气液混流切向进入后沿内部高速旋转上升,由于离心力的作用,在气液混流不断上升的过程速度逐渐加快,到达旋转出口时,速度可达进口时的数倍,由旋转出口喷射出的气液混流与污水处理箱内的含乳化的污水混合碰撞、混合,打破乳化的液体,冲破水包油的液滴,使得油水分离,完成破乳,破乳后的油滴由于密度较小,向上不断聚集浮动,到达聚结分离系统,所述高速喷射系统6设置在污水处理箱1的底部,与污水处理箱1固定连接,所述聚结分离系统7设置在雾化系统的上方,包括若干聚结板,所述聚结分离系统7与污水处理箱1的内壁四周固定连接,油滴在聚结分离系统内的聚结板上聚集,并且因为密度小,逐渐上浮,而水相逐渐下沉,完成破乳后的分离,若干所述隔板8设置在高速喷射系统6的一侧和聚结分离系统7的下面,并且交替设置。An oil-containing emulsified sewage demulsification device as shown in Figure 1-3 is characterized in that: the demulsification device includes a sewage treatment tank 1 for sewage demulsification treatment, and the side wall of the sewage treatment tank 1 is provided with Sewage inlet 2, sewage outlet 3 and clean water outlet 4, said sewage outlet 3 is arranged on the top of sewage treatment tank 1, said sewage treatment tank 1 is filled with sewage, and is equipped with a gas-liquid mixing system 5 , a high-speed injection system 6, a coalescence separation system 7, a plurality of partitions 8, the gas-liquid mixing system 5 is a cylindrical pipeline, and an injection unit 501 is provided inside, and the injection unit 501 is a hollow structure, A cylindrical water channel with the same axial direction is provided, and a number of injection holes 503 are provided on the outer wall of the injection unit 501, and the injection unit 501 and the inner wall of the gas-liquid mixing system 5 form an injection cavity 504, The injection cavity 504 is connected to the gas pipeline 605; the gas is injected at high speed through the injection hole of the injection unit, and quickly mixes with the passing liquid to realize gas-liquid mixed flow. The gas-liquid mixing system 5 and the high-speed injection system 6 Fixed connection, the high-speed injection system 6 is a conical liquid channel 601, the mixed solution after passing through the gas-liquid mixing system 5 enters the conical liquid channel 601 from the tangential inlet 602, and the top of the conical liquid channel 601 is a rotating Outlet 603, the gas-liquid mixed flow entering the high-injection system at a low speed enters tangentially and then rotates up at high speed inside. Due to the centrifugal force, the speed of the gas-liquid mixed flow is gradually accelerated during the rising process, and when it reaches the rotating outlet, the speed can reach that of the inlet. Several times, the gas-liquid mixed flow ejected from the rotating outlet collides and mixes with the emulsified sewage in the sewage treatment tank, breaking the emulsified liquid, breaking through the oil-in-water droplets, separating the oil and water, and completing the demulsification. Due to the low density, the final oil droplets continuously gather and float upwards and reach the coalescence separation system. The high-speed injection system 6 is arranged at the bottom of the sewage treatment tank 1 and is fixedly connected with the sewage treatment tank 1. The coalescence separation system 7 Set above the atomization system, including several coalescing plates, the coalescing and separating system 7 is fixedly connected with the inner wall of the sewage treatment tank 1, the oil droplets gather on the coalescing plates in the coalescing and separating system, and because of the density small, gradually float up, while the water phase gradually sinks to complete the separation after demulsification, and several partitions 8 are arranged on one side of the high-speed injection system 6 and below the coalescence separation system 7, and are arranged alternately.
优选为,所述旋转出口603的周围设有若干补充气体出口604,所述补充气体出口604与气体管路605连通,所述液体进口设置在锥形液体通道601的靠近敞口端的外壁上,并且液体的进入方向与锥形液体通道601相切。Preferably, several supplementary gas outlets 604 are provided around the rotating outlet 603, the supplementary gas outlets 604 communicate with the gas pipeline 605, and the liquid inlet is arranged on the outer wall of the tapered liquid channel 601 near the open end, And the entering direction of the liquid is tangent to the tapered liquid channel 601 .
优选为,所述高速喷射系统6包括若干个锥形液体通道601,每个锥形液体通道601配有液体进口,并且液体的进入方向与锥形液体通道601相切。Preferably, the high-speed injection system 6 includes several conical liquid channels 601 , each conical liquid channel 601 is equipped with a liquid inlet, and the liquid entering direction is tangent to the conical liquid channel 601 .
优选为,所述气液混合系统5两端焊接有法兰505,一端通过法兰505与自来水管路连接,另一端通过封盖封闭。Preferably, two ends of the gas-liquid mixing system 5 are welded with flanges 505, one end is connected to the tap water pipeline through the flange 505, and the other end is closed with a cover.
优选为,若干所述气液混合系统5通过法兰505串联。Preferably, several gas-liquid mixing systems 5 are connected in series through the flange 505 .
优选为,所述污水进口2和净水出口4分设在污水处理箱1箱体两个互相远离的侧壁上。Preferably, the sewage inlet 2 and the clean water outlet 4 are respectively arranged on two side walls of the sewage treatment tank 1 that are far away from each other.
优选为,所述喷入单元501为“工”字状,包括上下的固定边缘506和中部的喷入部507,所述喷入单元501为中空结构,设有轴向相同的圆柱状的通道,通道内供液体流通,所述固定边缘506的外径与混溶主体的内径相同,通过外力将喷入单元501镶入混溶主体内,使喷入单元501与混溶主体过硬配合,所述喷入单元501的外环与混溶主体的内壁形成分布的环状的喷入空腔504,所述喷入部507上设有若干喷入孔503,所述喷入孔503与通道连通,所述混溶主体对应喷入空腔504的外壁上设有气体进入口,所述高压扰流板502沿液体流动反向设置在喷入单元501的下游,与气液混合系统5固定连接。Preferably, the injection unit 501 is in the shape of an "I", including upper and lower fixed edges 506 and a central injection part 507. The injection unit 501 is a hollow structure with cylindrical channels with the same axial direction. The channel is for liquid circulation, the outer diameter of the fixed edge 506 is the same as the inner diameter of the miscible body, and the injection unit 501 is inserted into the miscible body by external force, so that the injection unit 501 is perfectly matched with the miscible body, and the The outer ring of the injection unit 501 and the inner wall of the miscible body form a distributed annular injection cavity 504. The injection part 507 is provided with a number of injection holes 503, and the injection holes 503 communicate with the channel. A gas inlet is provided on the outer wall of the miscible body corresponding to the injection cavity 504 , and the high-pressure spoiler 502 is arranged downstream of the injection unit 501 along the reverse flow of the liquid, and is fixedly connected with the gas-liquid mixing system 5 .
优选为,所述喷入孔503的开孔方向倾斜与液体流动方向,并且与液体流动方向逆向倾斜设置。Preferably, the opening direction of the injection hole 503 is inclined to the direction of liquid flow, and is arranged to be opposite to the direction of liquid flow.
优选为,破乳装置还包括前置的快速过滤装置,避免污水中的固体废物堵塞破乳。Preferably, the demulsification device further includes a pre-fast filter device to prevent solid waste in the sewage from clogging the demulsification.
最后应说明的是:以上各实施例仅用以说明本发明的技术方案,而非对其限制;尽管参照前述各实施例对本发明进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分或者全部技术特征进行等同替换;而这些修改或者替换,并不使相应技术方案的本质脱离本发明各实施例技术方案的范围。Finally, it should be noted that: the above embodiments are only used to illustrate the technical solutions of the present invention, rather than limiting them; although the present invention has been described in detail with reference to the foregoing embodiments, those of ordinary skill in the art should understand that: It is still possible to modify the technical solutions described in the foregoing embodiments, or perform equivalent replacements for some or all of the technical features; and these modifications or replacements do not make the essence of the corresponding technical solutions deviate from the technical solutions of the various embodiments of the present invention. scope.
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