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Composite fertilizer producing technology and equipment by dissolving spraying and pelletizing ammonium nitrate

Abstract

The present invention discloses a composite fertilizer production technique and device by using an ammonium nitrate dissolving spraying and pelletizing method, which relates to an ammonium nitrate compound fertilizer production method and device. In the technique, the measured ammonium nitrate after crushed is conveyed to a dissolving tank, an ammonium nitrate solution after dissolved is conveyed to a granulating machine by buffering and is sprayed on the materials of phosphorus fertilizers and potassium fertilizers which are pulverized and uniformly mixed, and finished products are collected. A dissolving device is composed of the dissolving tank internally provided with a steam coiled pipe and stirring slurry, and a buffer tank internally provided with a steam coiled pipe, wherein the dissolving tank is communicated with the buffer tank by an overflow pipe. The technique overcomes the negative factors for producing ammonium nitrate compound fertilizers by using a dry mixing method and a melting method, and various ammonium nitrate compound fertilizers with high quality and required proportion can be produced.

Classifications

C05G5/12 Granules or flakes

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CN1064657C

China

Other languages
Chinese
Inventor
刘斌
彭锡源
董安成
姜虎
Current Assignee
HELONGJIANG PROV AGRICULTURAL PRODUCTION MEANS CO

Worldwide applications
1997 CN

Application CN97115687A events
2001-04-18
Application granted
Anticipated expiration
Expired - Fee Related

Description

The production method of ammonium nitrate fertilizer and equipment
The present patent application relates to a kind of technology and equipment of producing ammonium nitrate fertilizer, and is particularly a kind of with technology and the equipment of ammonium nitrate solution as main nitrogen raw material production composite fertilizer.
The method of producing at present ammonium nitrate fertilizer all adopts ammonium nitrate and pulverizing such as other material fertilizer such as phosphate fertilizer, potash fertilizer, do to mix and make granular complex fertilizer again and claim dry mix or adopt ammonium nitrate fusion the interpolation then other phosphate fertilizer, potash fertilizer etc. to make composite fertilizer to claim to melt molten method.The problem that dry mix exists is that the powdery difficulty is big, danger is also big if will be ground into ammonium nitrate, and is thinless if powder gets, composite fertilizer's nutrient inequality of being produced.The problem that scorification exists is because the ammonium nitrate unstable chemcial property easily decomposes under the high temperature, and has explosion hazard, needs to add stablizer.Also have, ammonium nitrate fertilizer moisture absorption in the transportation storage process, agglomeration problems do not have fine solution.
The object of the present invention is to provide a kind of technology and relevant device that utilizes ammonium nitrate dissolving spray granulating method to produce ammonium nitrate fertilizer, avoid the unfavorable factor that dry mix and scorification are produced ammonium nitrate fertilizer in the above-mentioned prior art, can make many kinds of required ratio, high-quality ammonium nitrate fertilizer.
The present invention realizes with following technical scheme: a kind of production method of ammonium nitrate fertilizer; it is characterized in that utilizing ammonium nitrate dissolving spray pelleting process to make composite fertilizer; the processing step that comprises following order: earlier the solid ammonium nitrate is measured; coarse breaking then; be transported to again in the ammonium nitrate dissolution system and in 85~115 ℃ of temperature, be dissolved into ammonium nitrate solution; after buffering, the ammonium nitrate solution of desired concn is transported under 85~115 ℃ of keeping warm modes and is sprayed in the tablets press through pulverizing; the phosphorus that mixes after the metering; spray granulating on the potash fertilizer mixture; granulation moisture content is controlled at 3.5-5.5%, collects finished product and makes.
A kind of production unit of ammonium nitrate fertilizer, comprise the wolf's fang crusher, the industry pulverizer, horizontal chain grinding machine, the measuring belt machine, chapelet, rotary conveyor, rotary drum granulator, combination flight formula whizzer, cooler, vibratory screening apparatus, the drum-type packing machine, automatic quantitative packing machine, it is characterized in that also comprising the ammonium nitrate dissolution system, the ammonium nitrate dissolution system is made of dissolver and snubber assembly, described dissolver is by dissolving tank 1, the steam coil 2 of band steam-gas inlet C is installed in dissolving tank 1, dissolving tank 1 top is provided with import 3 and the water-in W of ammonium nitrate solid material S, the stirring arm 7 that is driven by reducing motor is installed in the dissolving tank 1, through type vapour pipe 6 is installed the upflow tube 5 that is communicated with snubber assembly at dissolving tank 1 upper end sidewall and is constituted; Described snubber assembly is by dashpot 9, and the steam coil 10 of mounting strap steam-gas inlet C is provided with the export mixes of ammonium nitrate solution A at the lower end of dashpot 9 sidewall in the dashpot 9, and the water in the system, vapour, liquid level are controlled by robot control system(RCS).
The beneficial effect that the present invention had: 1, owing to adopt ammonium nitrate dissolving mortar jetting method to produce ammonium nitrate fertilizer, made full use of ammonium nitrate solubleness to the very sensitive characteristics of temperature, ammonium nitrate dissolves in the specific range of temperatures in dissolving tank, avoid ammonium nitrate to pulverize difficulty and reached dangerous problem greatly, be used by even whitewashing of the ammonium nitrate solution of desired concn and high-temperature vapour, granulation is more prone to, the granulating rate height, the finished product outward appearance is good, the particle nutrient content is even, thereby has improved ammonium nitrate fertilizer quality and productivity.2, because ammonium nitrate is very responsive to temperature, controlled temperature can make the ammonium nitrate solution of different concns in dissolving tank, therefore can change composite fertilizer's prescription in process of production on demand, the ammonium nitrate fertilizer that makes the present invention be easy to realize to produce many kinds satisfies the different demands of agriculture production.3, because big air quantity cryodrying has not only improved drying efficiency, cut down the consumption of energy, and security is protected.4, because finished product adopts parcel oil (octadecane amine and tensio-active agent the are main component) parcel of the emperor of Qin board Huaxing-No. 2 coating agent preparation, solved the moisture absorption and the agglomeration problems of ammonium nitrate fertilizer preferably.5, whole process flow has realized automatic production line substantially, has improved production efficiency.
Description of drawings:
Fig. 1 is the process flow sheet of ammonium nitrate dissolving spray granulating method production composite fertilizer;
Fig. 2 is an ammonium nitrate dissolution system apparatus structure synoptic diagram for the specific equipment of ammonium nitrate dissolving spray granulating method production composite fertilizer.
Describe the present invention in detail below in conjunction with drawings and Examples; Fig. 1 has provided the technical process of the best of the present invention; at first ammonium nitrate is measured; slightly broken with the wolf's fang crusher; be transported to dissolving in the dissolving tank 1 in the ammonium nitrate dissolution system device then; here be to utilize ammonium nitrate solubleness to the very sensitive characteristics of temperature; its solvent temperature is controlled in 85~115 ℃ of scopes; ammonium nitrate solution after the dissolving enters dashpot 9; the temperature of dashpot is controlled within 85~115 ℃; then required ammonium nitrate solution is transported to granulation on the pulverulent solids material fertilizer that quantitatively sprays uniformly in the tablets press within it by the insulation of ammonium nitrate pump; the pulverulent solids material fertilizer by solid phosphate fertilizer and potash fertilizer and trace element fertilizer respectively after pulverizer is pulverized; after mixing in required ratio metering, measuring apparatus delivers in the tablets press; selected tablets press is a rotary drum granulator; on rotary drum granulator, be provided with ammonium nitrate shower nozzle and steam shower nozzle; helping ammonium nitrate solution evenly sprays and infiltration; make the particle nutrient more even; improve balling ratio; meanwhile; can spray steam on demand; steam plays regulates granulation water and temperature action; its moisture content is controlled at 3.5-5.5%; dry under the effect of the big air quantity gaseous media of low temperature with combination flight formula drying machine then; make the more all even safety of dry materials; the oven dry material temperature is about 60 ℃; again through cooling; cooling back temperature of charge is controlled at below 40 ℃; sieve out finished particle; finished particle evenly wraps up with aforementioned parcel oil on the parcel tube; prevent moisture absorption of ammonium nitrate fertilizer material and caking; defective particle after the screening is pulverized the back and is returned tablets press as returning charge with fine powder, measures finished product packing at last.Fig. 2 has provided ammonium nitrate dissolution system apparatus structure synoptic diagram, and it is made of dissolver and snubber assembly.Described dissolver is by dissolving tank 1, the steam coil 2 of band steam-gas inlet C is installed in the dissolving tank 1, dissolving tank 1 top is provided with import 3 and the water-in W of ammonium nitrate solid material S, the stirring arm 7 that is driven by reducing motor is installed in the dissolving tank 1, through type vapour pipe 6 is installed the upflow tube 5 that is communicated with snubber assembly at dissolving tank 1 upper end sidewall and is constituted; Described snubber assembly is by dashpot 9, and the steam coil 10 of mounting strap steam-gas inlet C in the dashpot 9 is provided with the export mixes of ammonium nitrate solution A at the lower end of dashpot 9 sidewall, and the water in the system, vapour, liquid level are controlled by robot control system(RCS).Solid ammonium nitrate through the metering coarse breaking continuously adds dissolving tank 1 from opening for feed 3, quantitatively add water W from water-in, under the effect of steam coil 2 well heaters and straight-through steam, make solution temperature in 85~115 ℃ of scopes, keep selected temperature constant state by robot control system(RCS), under the effect of stirring arm 7, the solid ammonium nitrate is dissolved rapidly, constantly flow in the dashpot 9, also be provided with the temperature that steam coil 10 well heaters keep solution in the dashpot 9, constantly supply with the ammonium nitrate solution of the required flow of granulating system certain pressure again by the ammonium nitrate pump.Production technique provided by the invention and equipment can be used for producing the universal or special composite fertilizer of any prescription.Below with paddy rice
Embodiment one: paddy rice composite fertilizer (by % weight) ammonium nitrate 43%, monoammonium phosphate 34%, Repone K 20%, surplus is the trace element fertilizer material formula.Its production process: become fine powder below monoammonium phosphate, Repone K and micro-separated pulverizing become 20 orders, metering according to the above ratio enters rotary drum granulator after mixing; Ammonium nitrate metering, broken back are dissolved at dissolution system; solvent temperature is at 100~115 ℃, the insulation of ammonium nitrate solution is delivered to carries out spray granulating on the rotary drum granulator, and granulation water is about 5%; enter drying on the whizzer behind the granulating, drying temperature is that temperature of charge is controlled at 60 ℃.On the rotating cylinder cooler, cool off then,, grain is wrapped up after telling at 1~4.5 millimeter particle, carry out metering packing at last by bolting.Remain and return granulating system as returning charge with fine powder after defective particle is pulverized.
Embodiment two: corn composite fertilizer: (by % weight) ammonium nitrate 48.5%, monoammonium phosphate 34%, Repone K 16.2%, surplus is a trace element formula.Its production process is same as paddy rice composite fertilizer production process.
Embodiment three: tobacco compound fertilizer: (by % weight) ammonium nitrate 15%, coarse whiting 20%, general calcium 23%, vitriolate of tartar 34% prescription.Its production process is for to become fine powder with coarse whiting, general calcium, vitriolate of tartar separated pulverizing, and metering according to the above ratio enters rotary drum granulator after the uniform mixing; With ammonium nitrate metering, the broken dissolving at dissolution system afterwards; solvent temperature is at 85~95 ℃; ammonium nitrate solution insulation is delivered to carries out spray granulating on the rotary drum granulator; granulation water is about 4%; enter behind the granulating and carry out drying on the whizzer; drying temperature is that temperature of charge is controlled at about 60 ℃, and it is described that all the other production processes are same as embodiment one.

Claims (2)
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1, a kind of production method of ammonium nitrate fertilizer; it is characterized in that utilizing ammonium nitrate dissolving spray pelleting process to make composite fertilizer; the processing step that comprises following order: earlier with solid ammonium nitrate metering back coarse breaking; be transported to again in the ammonium nitrate dissolution system and in 85~115 ℃ of temperature, be dissolved into ammonium nitrate solution; be sprayed at spray granulating on the phosphorus of pulverizing, mix after the metering, potash fertilizer mixture in the tablets press through after the buffering ammonium nitrate solution of desired concn being transported under 85~115 ℃ of keeping warm modes; granulation moisture content is controlled at 3.5-5.5%, collects finished product.
2, a kind of production unit of ammonium nitrate fertilizer, comprise the wolf's fang crusher, the industry pulverizer, horizontal chain grinding machine, the measuring belt machine, chapelet, rotary conveyor, rotary drum granulator, combination flight formula whizzer, cooler, vibratory screening apparatus, the drum-type packing machine, automatic quantitative packing machine, it is characterized in that also comprising the ammonium nitrate dissolution system, the ammonium nitrate dissolution system is made of dissolver and snubber assembly, described dissolver is by dissolving tank (1), the steam coil (2) of band steam-gas inlet (C) is installed in dissolving tank (1), dissolving tank (1) top is provided with import (3) and the water-in (W) of ammonium nitrate solid material (S), the stirring arm (7) that is driven by reducing motor is installed in the dissolving tank (1), through type vapour pipe (6) is installed the upflow tube (5) that is communicated with snubber assembly at dissolving tank (1) upper end sidewall and is constituted; Described snubber assembly is by dashpot (9), the steam coil (10) of the interior mounting strap steam-gas inlet of dashpot (9) (C), lower end sidewall at dashpot (9) is provided with ammonium nitrate solution (A) export mixes, and the water in the system, vapour, liquid level are controlled by robot control system(RCS).