CN106459335B - 用于制造含聚异氰脲酸酯泡沫体的异氰酸酯三聚催化剂 - Google Patents

用于制造含聚异氰脲酸酯泡沫体的异氰酸酯三聚催化剂 Download PDF

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CN106459335B
CN106459335B CN201580018197.4A CN201580018197A CN106459335B CN 106459335 B CN106459335 B CN 106459335B CN 201580018197 A CN201580018197 A CN 201580018197A CN 106459335 B CN106459335 B CN 106459335B
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isocyanate
polyisocyanurate
group
trimerization
trimerization catalyst
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CN106459335A (zh
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H.维贝克
A.A.范哈尔勒
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Huntsman International LLC
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Huntsman International LLC
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/09—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture
    • C08G18/092—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture oligomerisation to isocyanurate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/14—Manufacture of cellular products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/161—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22
    • C08G18/163—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22 covered by C08G18/18 and C08G18/22
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1808—Catalysts containing secondary or tertiary amines or salts thereof having alkylene polyamine groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1875—Catalysts containing secondary or tertiary amines or salts thereof containing ammonium salts or mixtures of secondary of tertiary amines and acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/225—Catalysts containing metal compounds of alkali or alkaline earth metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
    • C08G18/3842—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring
    • C08G18/3851—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring containing three nitrogen atoms in the ring
    • C08G18/3853—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring containing three nitrogen atoms in the ring containing cyanurate and/or isocyanurate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4829—Polyethers containing at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/61—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/127—Mixtures of organic and inorganic blowing agents
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    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
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    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00—Fireproofing materials
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/0058—≥50 and <150kg/m3
    • C—CHEMISTRY; METALLURGY
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    • C08G2115/00—Oligomerisation
    • C08G2115/02—Oligomerisation to isocyanurate groups
    • C—CHEMISTRY; METALLURGY
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2330/00—Thermal insulation material
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    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/18—Binary blends of expanding agents
    • C08J2203/182—Binary blends of expanding agents of physical blowing agents, e.g. acetone and butane
    • C—CHEMISTRY; METALLURGY
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    • C08J2205/00—Foams characterised by their properties
    • C08J2205/04—Foams characterised by their properties characterised by the foam pores
    • C08J2205/052—Closed cells, i.e. more than 50% of the pores are closed
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    • C08J2205/00—Foams characterised by their properties
    • C08J2205/10—Rigid foams
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C08J2375/08—Polyurethanes from polyethers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
CN201580018197.4A 2014-04-03 2015-03-31 用于制造含聚异氰脲酸酯泡沫体的异氰酸酯三聚催化剂 Active CN106459335B (zh)

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Application Number Priority Date Filing Date Title
EP14163431 2014-04-03
EP14163431.1 2014-04-03
PCT/EP2015/057079 WO2015150408A1 (en) 2014-04-03 2015-03-31 Isocyanate trimerization catalyst for making polyisocyanurate comprising foams

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CN106459335A CN106459335A (zh) 2017-02-22
CN106459335B true CN106459335B (zh) 2020-02-14

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US (1) US11548973B2 (https=)
EP (1) EP3126423B1 (https=)
CN (1) CN106459335B (https=)
BR (1) BR112016021581B1 (https=)
CA (1) CA2941348C (https=)
PL (1) PL3126423T3 (https=)
RU (1) RU2707290C2 (https=)
WO (1) WO2015150408A1 (https=)

Families Citing this family (6)

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Publication number Priority date Publication date Assignee Title
CN107627527B (zh) * 2017-09-30 2019-09-13 中国科学院长春应用化学研究所 带有亲水性单元的共聚聚合物泡沫的制备方法
BR112020022108A2 (pt) * 2018-05-14 2021-01-26 Huntsman International Llc composição reativa, método para reduzir a viscosidade de uma composição reativa, processo para produzir uma espuma rígida, espuma rígida, e, uso da espuma rígida.
KR102065251B1 (ko) 2018-06-07 2020-01-10 대한폴리텍(주) 준불연 단열재의 제조방법
JP2022517512A (ja) 2019-01-22 2022-03-09 コベストロ・インテレクチュアル・プロパティ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング・アンド・コー・カーゲー 二重硬化ウレタンポリマーおよび二重硬化イソシアヌレートポリマーに基づく複合材料
EP3997146A1 (en) * 2019-07-12 2022-05-18 Dow Global Technologies LLC Transition metal chelating polyol blend for use in a polyurethane polymer
WO2024133871A1 (en) 2022-12-23 2024-06-27 Recticel Pir chemical recycling by alkaline cleavage

Citations (7)

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GB1498506A (en) * 1975-04-14 1978-01-18 Eurane Europ Polyurethan Flexible cellular polyurethane foam compositions having increased flame retardance
US4256841A (en) * 1978-06-10 1981-03-17 Basf Aktiengesellschaft Manufacture of light-stable polyurethane integral foams
US4568703A (en) * 1984-07-27 1986-02-04 Bp Chemicals Limited Process for the production of polymers containing isocyanurate and or oxazolidone linkages
CN1031383A (zh) * 1987-05-26 1989-03-01 帝国化学工业公司 聚异氰脲酸酯硬质泡沫
US5151216A (en) * 1991-11-12 1992-09-29 Martin Marietta Corporation High temperature ablative foam
CN102203156A (zh) * 2008-10-22 2011-09-28 陶氏环球技术有限责任公司 闭孔刚性聚氨酯泡沫体的制备方法
CN103619904A (zh) * 2011-06-29 2014-03-05 陶氏环球技术有限责任公司 用于改进聚异氰脲酸酯刚性泡沫体的原始强度的多元醇制剂

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RU2010808C1 (ru) * 1992-03-18 1994-04-15 Научно-исследовательский институт механики и физики при Саратовском государственном университете Композиция для получения жесткого пенополиуретана
US5958990A (en) 1998-11-23 1999-09-28 Air Products And Chemicals, Inc. Trimerization catalysts for making polyisocyanurate foams
US20050245629A1 (en) 2002-07-18 2005-11-03 Grigsby Robert A Jr Catalyst combinations for increasing trimer content in foam
UA80927C2 (en) * 2006-08-04 2007-11-12 Composition for the preparation of rigid polyurethane foam
ES2561042T3 (es) 2008-11-10 2016-02-24 Dow Global Technologies Llc Un sistema catalítico de trimerización de isocianato, una formulación precursora, un procedimiento para trimerizar isocianatos, espumas rígidas de poliisocianurato/poliuretano preparadas a partir del mismo y un procedimiento para preparar dichas espumas
JP2012508302A (ja) 2008-11-10 2012-04-05 ダウ グローバル テクノロジーズ エルエルシー イソシアネートの三量化触媒系、前駆体配合物、イソシアネートの三量化方法、それから作製された硬質ポリイソシアヌレート／ポリウレタン発泡体、および該発泡体の作製方法
CN102245665B (zh) 2008-11-10 2013-11-13 陶氏环球技术有限责任公司 一种异氰酸酯三聚催化剂体系，前体制剂，使异氰酸酯三聚的方法，由其制备的硬质多异氰脲酸酯/聚氨酯泡沫体，和制备这种泡沫体的方法
US20110201709A1 (en) 2008-11-10 2011-08-18 Dow Global Technologies Llc Isocyanate trimerisation catalyst system, a precursor formulation, a process for trimerising isocyanates, rigid polyisocyanurate/polyurethane foams made therefrom, and a process for making such foams
US8541478B2 (en) * 2009-05-21 2013-09-24 Huntsman International Llc Rigid polyurethane foam and system and method for making the same

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Publication number Priority date Publication date Assignee Title
GB1498506A (en) * 1975-04-14 1978-01-18 Eurane Europ Polyurethan Flexible cellular polyurethane foam compositions having increased flame retardance
US4256841A (en) * 1978-06-10 1981-03-17 Basf Aktiengesellschaft Manufacture of light-stable polyurethane integral foams
US4568703A (en) * 1984-07-27 1986-02-04 Bp Chemicals Limited Process for the production of polymers containing isocyanurate and or oxazolidone linkages
CN1031383A (zh) * 1987-05-26 1989-03-01 帝国化学工业公司 聚异氰脲酸酯硬质泡沫
US5151216A (en) * 1991-11-12 1992-09-29 Martin Marietta Corporation High temperature ablative foam
CN102203156A (zh) * 2008-10-22 2011-09-28 陶氏环球技术有限责任公司 闭孔刚性聚氨酯泡沫体的制备方法
CN103619904A (zh) * 2011-06-29 2014-03-05 陶氏环球技术有限责任公司 用于改进聚异氰脲酸酯刚性泡沫体的原始强度的多元醇制剂

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BR112016021581B1 (pt) 2021-09-28
BR112016021581A2 (https=) 2017-08-15
EP3126423A1 (en) 2017-02-08
EP3126423B1 (en) 2017-12-20
US11548973B2 (en) 2023-01-10
RU2016143070A (ru) 2018-05-04
CN106459335A (zh) 2017-02-22
CA2941348C (en) 2019-02-05
US20170198082A1 (en) 2017-07-13
CA2941348A1 (en) 2015-10-08
PL3126423T3 (pl) 2018-04-30
RU2707290C2 (ru) 2019-11-26
WO2015150408A1 (en) 2015-10-08
RU2016143070A3 (https=) 2018-10-17

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