CN106436478A - Moisture-proof transparent cellophane and preparation method thereof - Google Patents

Moisture-proof transparent cellophane and preparation method thereof Download PDF

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Publication number
CN106436478A
CN106436478A CN201611119212.7A CN201611119212A CN106436478A CN 106436478 A CN106436478 A CN 106436478A CN 201611119212 A CN201611119212 A CN 201611119212A CN 106436478 A CN106436478 A CN 106436478A
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China
Prior art keywords
parts
cellulose
serosity
moisture
pulp
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CN201611119212.7A
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Chinese (zh)
Inventor
夏放军
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Foshan Jihe Technology Co Ltd
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Foshan Jihe Technology Co Ltd
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Priority to CN201611119212.7A priority Critical patent/CN106436478A/en
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/10Packing paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F11/00Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/02Chemical or chemomechanical or chemothermomechanical pulp
    • D21H11/04Kraft or sulfate pulp
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/12Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H15/00Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
    • D21H15/02Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
    • D21H15/10Composite fibres
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/005Microorganisms or enzymes
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03Non-macromolecular organic compounds
    • D21H17/05Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/17Ketenes, e.g. ketene dimers
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/21Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24Polysaccharides
    • D21H17/25Cellulose
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/64Alkaline compounds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/65Acid compounds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/67Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/68Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/71Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes
    • D21H17/74Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes of organic and inorganic material

Abstract

The invention discloses moisture-proof transparent cellophane. The moisture-proof transparent cellophane is prepared from the following raw materials in parts by weight: 100-160 parts of long-fiber kraft wood pulp, 70-90 parts of reed pulp, 40-60 parts of cellulose acetate, 40-60 parts of cellulose nitrate, 40-60 parts of ether cellulose, 20-28 parts of ceramic powder, 21-29 parts of alundum powder, 13-19 parts of alpha-cellulose, 8-12 parts of sodium hydroxide, 10-16 parts of carbon disulfide, 7-11 parts of dilute hydrochloric acid, 13-15 parts of cellulase, 10-18 parts of pectinase, 14-18 parts of polygalactosidase, 13-17 parts of alkyl ketene dimer, 9-13 parts of glycerol and 7-9 parts of ethylene glycol. The moisture-proof transparent cellophane has moisture-proof, waterproof, airtight and heat-sealable performances and the like, and has a good protection effect on commodities; compared with a common plastic film, the moisture-proof transparent cellophane has the advantages of no static electricity, dust prevention, good twisting performance and the like.

Description

A kind of protection against the tide cellophane cover and preparation method thereof
Technical field
The present invention relates to a kind of protection against the tide cellophane cover and preparation method thereof.
Background technology
Protection against the tide be exactly prevent in the air humidity too high, the humidity of air is too high to make mycete Fast-propagation, and mycete is not only Article moldy metamorphism can be made, also can make the various disease of the old man of hypoimmunity, childhood infection simultaneously, the whole world every year because moist, The economic loss causing of going mouldy is up to hundreds billion of dollars.Moistureproof paper has certain moisture protection, its moistureproof rate minimum 15% More than.
However, existing packaging for foodstuff is many to be packed using plastic sheeting, such as various prepared for raw material with polyethylene Thin film is although thin and durable, but when using, plastic sheeting easily produces electrostatic, and then makes the substantial amounts of ash of surface adsorption Dirt, the health usage safety performance of impact plastic sheeting, furthermore, environmental pollution can be caused using plastic sheeting, with for moulding in a large number The degradation speed of material thin film is slow, and because dispersion uses, leads to recovery difficult, once user whips to abandon, plastic sheeting buries In soil, cannot degrade for a long time, soil can be affected, and then pollute environment.
Therefore, in sum, existing plastic sheeting has the performance such as moistureproof, waterproof, airtight, heat sealable, to business Product play good protection effect, but compared with cellophane, it has easily generation electrostatic, not dust-proof, kink property difference etc. and asks Topic.
Content of the invention
In view of this, it is an object of the present invention to provide a kind of performance such as moistureproof, waterproof, airtight, heat sealable, commodity are risen To good protection effect, compare with common plasticses film, the transparent glass of protection against the tide that it has the advantages that not static electrification, dust-proof, kink property is good Glass paper.
In order to solve above-mentioned technical problem, the technical scheme is that:A kind of protection against the tide cellophane cover, by following weight The raw material of part is made, including long fibre sulfate wood pulp 100-160 part, reed pulp 70-90 part, cellulose acetate 40-60 part, nitrification Cellulose 40-60 part, ethers cellulose 40-60 part, ceramics 20-28 part, schmigel 21-29 part, alpha-cellulose 13-19 part, Sodium hydroxide 8-12 part, Carbon bisulfide 10-16 part, dilute hydrochloric acid 7-11 part, cellulase 13-15 part, pectase 10-18 part, many Poly- galactose thuja acid enzyme 14-18 part, alkyl ketene dimer 13-17 part, glycerol 9-13 part and ethylene glycol 7-9 part.
Further, described protection against the tide cellophane cover is made up of the raw material of following weight portion, including long fibre sulfate wood 160 parts of slurry, 70 parts of reed pulp, 40 parts of cellulose acetate, 40 parts of nitrocellulose, 40 parts of ethers cellulose, 20 parts of ceramics, corundum 21 parts of powder, 13 parts of alpha-cellulose, 8 parts of sodium hydroxide, 10 parts of Carbon bisulfide, 7 parts of dilute hydrochloric acid, 13 parts of cellulase, pectase 10 Part, 14 parts of poly galactose thuja acid enzyme, 13 parts of alkyl ketene dimer, 9 parts of glycerol and 7 parts of ethylene glycol.
Further, described protection against the tide cellophane cover is made up of the raw material of following weight portion, by the raw material of following weight portion Make, fine including 100 parts of long fibre sulfate wood pulp, 90 parts of reed pulp, 60 parts of cellulose acetate, 60 parts of nitrocellulose, ethers 60 parts of dimension element, 28 parts of ceramics, 29 parts of schmigel, 19 parts of alpha-cellulose, 12 parts of sodium hydroxide, 16 parts of Carbon bisulfide, dilute hydrochloric acid 11 parts, 15 parts of cellulase, 18 parts of pectase, 18 parts of poly galactose thuja acid enzyme, 17 parts of alkyl ketene dimer, 13 parts of glycerol With 9 parts of ethylene glycol.
Further, described protection against the tide cellophane cover is made up of the raw material of following weight portion, by the raw material of following weight portion Make, fine including 130 parts of long fibre sulfate wood pulp, 80 parts of reed pulp, 50 parts of cellulose acetate, 50 parts of nitrocellulose, ethers 50 parts of dimension element, 24 parts of ceramics, 25 parts of schmigel, 16 parts of alpha-cellulose, 10 parts of sodium hydroxide, 13 parts of Carbon bisulfide, dilute hydrochloric acid 9 parts, 14 parts of cellulase, 14 parts of pectase, 16 parts of poly galactose thuja acid enzyme, 15 parts of alkyl ketene dimer, 11 parts of glycerol With 8 parts of ethylene glycol.
The invention solves the problems that another technical problem be that a kind of preparation method of protection against the tide cellophane cover is provided, include below Step:
1) take long fibre sulfate wood pulp 100-160 part and reed pulp 70-90 part to be added in agitator, and start blender With the running of the rotating speed of 55r/min so that long fibre sulfate wood pulp and true qualities sulfate wood pulp mix homogeneously, prepared body paper slurry Liquid, standby;
2) by step 1) the body paper serosity that is obtained poured in Bellmer and bleached, then washed and starched by pressurized screen and vacuum Machine carries out washing and screening, obtains the body paper serosity that concentration is 13~15%, standby;
3) by step 2) be obtained body paper serosity pour in steam stove, then add cellulose acetate 40-60 part, nitrocellulose Plain 40-60 part, ethers cellulose 40-60 part, ceramics 20-28 part and schmigel 21-29 part, by blender with 45r/min Rotating speed stir so that cellulose acetate, nitrocellulose, ethers cellulose, ceramics and schmigel are mixed with body paper serosity Uniformly, then passing through heating makes the temperature of steam stove be increased to 300-380 DEG C so that serosity boils, standby;
4) take alpha-cellulose 13-19 part as raw material, then add sodium hydroxide 8-12 part and carry out alkalizing, squeeze, pulverize Alkali cellulose is obtained etc. process, then adds Carbon bisulfide 10-16 part to make alkali cellulose yellow become cellulose xanthic acid after aging Ester, finally adds dilute hydrochloric acid 7-11 part and makes cellulose xanthate ester dissolving make saffron cellulose viscose, standby;
5) by step 4) the cellulose viscose that is obtained is added to step 3) in the serosity that is obtained, and add cellulase 13-15 part, pectase 10-18 part, poly galactose thuja acid enzyme 14-18 part and alkyl ketene dimer 13-17 part, then pass through Serosity is stirred with the rotating speed of 35r/min by blender with mixed pulp, prepared body paper serosity, and the body paper serosity being obtained is fallen Enter in pressure cooker, and the pressure set of pressure cooker is 50KPa, then paper pulp raw material is heated to 170- in the pressure setting 250 DEG C, so that body paper serosity is reacted with ingredients at high temperature, strengthen the function of body paper serosity, standby;
6) by step 5) the body paper serosity that is obtained is cooled to 20-30 DEG C, and carry out maturation process at this temperature so that former Pulp liquor is obtained cellulose membrane by film balance extrusion, standby;
7) by step 6) cellulose membrane extruded adds glycerol 9-13 part and ethylene glycol in the state of uncolled solidification 7-9 part, carries out plastics processing through glycerol and ethylene glycol to cellulose membrane, is then passed through low temp dryer low with 5-15 DEG C Temperature is dried, and obtains final product.
The technology of the present invention effect major embodiment is in the following areas:By using long fibre sulfate wood pulp and reed pulp as main Material, and add cellulose acetate, nitrocellulose, ethers cellulose, ceramics and schmigel be obtained filler, in conjunction with α- The viscose rayon that cellulose, sodium hydroxide, Carbon bisulfide and dilute hydrochloric acid are obtained, and add cellulase, pectase, poly gala The additives such as glycuronide enzyme, alkyl ketene dimer, glycerol and ethylene glycol, prepared moistureproof cellophane cover has protection against the tide, no Commodity are played good protection effect, are compared with common plasticses film, it has without quiet by the performance such as permeable, airtight, heat sealable The advantages of electric, dust-proof, kink property is good.
Specific embodiment
Embodiment 1
A kind of protection against the tide cellophane cover, is made up of the raw material of following weight portion, is made up of the raw material of following weight portion, including 160 parts of long fibre sulfate wood pulp, 70 parts of reed pulp, 40 parts of cellulose acetate, 40 parts of nitrocellulose, 40 parts of ethers cellulose, 20 parts of ceramics, 21 parts of schmigel, 13 parts of alpha-cellulose, 8 parts of sodium hydroxide, 10 parts of Carbon bisulfide, 7 parts of dilute hydrochloric acid, cellulose 13 parts of enzyme, 10 parts of pectase, 14 parts of poly galactose thuja acid enzyme, 13 parts of alkyl ketene dimer, 9 parts of glycerol and 7 parts of ethylene glycol.
A kind of preparation method of protection against the tide cellophane cover, comprises the following steps:
1) take 160 parts of long fibre sulfate wood pulp and 70 parts of reed pulp to be added in agitator, and start blender with 55r/ The rotating speed running of min so that long fibre sulfate wood pulp and true qualities sulfate wood pulp mix homogeneously, prepared body paper serosity, standby;
2) by step 1) the body paper serosity that is obtained poured in Bellmer and bleached, then washed and starched by pressurized screen and vacuum Machine carries out washing and screening, obtains the body paper serosity that concentration is 13%, standby;
3) by step 2) be obtained body paper serosity pour in steam stove, then add 40 parts of cellulose acetate, nitrocellulose 40 parts, 40 parts of ethers cellulose, 20 parts of ceramics and 21 parts of schmigel, stirred with the rotating speed of 45r/min by blender so that Cellulose acetate, nitrocellulose, ethers cellulose, ceramics and schmigel are mixed homogeneously with body paper serosity, then pass through to add Heat makes the temperature of steam stove be increased to 300 DEG C so that serosity boils, standby;
4) take 13 parts of alpha-cellulose as raw material, then add 8 parts of sodium hydroxide and carry out alkalizing, the process such as squeeze, pulverize Prepared alkali cellulose, then add 10 parts of Carbon bisulfide to make alkali cellulose yellow become cellulose xanthate ester after aging, finally add Plus 7 parts of dilute hydrochloric acid makes cellulose xanthate ester dissolving make saffron cellulose viscose, standby;
5) by step 4) the cellulose viscose that is obtained is added to step 3) in the serosity that is obtained, and add cellulase 13 Part, 10 parts of pectase, 14 parts of poly galactose thuja acid enzyme and 13 parts of alkyl ketene dimer, then pass through blender by serosity with Mixed pulp is stirred with the rotating speed of 35r/min, prepared body paper serosity, and the body paper serosity being obtained is poured in pressure cooker, and The pressure set of pressure cooker is 50KPa, then paper pulp raw material is heated in the pressure setting 170 DEG C so that body paper is starched Liquid is reacted with ingredients at high temperature, strengthens the function of body paper serosity, standby;
6) by step 5) the body paper serosity that is obtained is cooled to 20 DEG C, and carry out maturation process at this temperature so that body paper Serosity is obtained cellulose membrane by film balance extrusion, standby;
7) by step 6) cellulose membrane extruded adds 9 parts of glycerol and 7 parts of ethylene glycol in the state of uncolled solidification, Through glycerol and ethylene glycol, plastics processing is carried out to cellulose membrane, be then passed through low temp dryer and dried with 5 DEG C of low temperature Dry, obtain final product.
Embodiment 2
A kind of protection against the tide cellophane cover, be made up of the raw material of following weight portion, including 100 parts of long fibre sulfate wood pulp, 90 parts of reed pulp, 60 parts of cellulose acetate, 60 parts of nitrocellulose, 60 parts of ethers cellulose, 28 parts of ceramics, 29 parts of schmigel, 19 parts of alpha-cellulose, 12 parts of sodium hydroxide, 16 parts of Carbon bisulfide, 11 parts of dilute hydrochloric acid, 15 parts of cellulase, 18 parts of pectase, many 18 parts of poly- galactose thuja acid enzyme, 17 parts of alkyl ketene dimer, 13 parts of glycerol and 9 parts of ethylene glycol.
A kind of preparation method of protection against the tide cellophane cover, comprises the following steps:
1) take 100 parts of long fibre sulfate wood pulp and 90 parts of reed pulp to be added in agitator, and start blender with 55r/ The rotating speed running of min so that long fibre sulfate wood pulp and true qualities sulfate wood pulp mix homogeneously, prepared body paper serosity, standby;
2) by step 1) the body paper serosity that is obtained poured in Bellmer and bleached, then washed and starched by pressurized screen and vacuum Machine carries out washing and screening, obtains the body paper serosity that concentration is 15%, standby;
3) by step 2) be obtained body paper serosity pour in steam stove, then add 60 parts of cellulose acetate, nitrocellulose 60 parts, 60 parts of ethers cellulose, 28 parts of ceramics and 29 parts of schmigel, stirred with the rotating speed of 45r/min by blender so that Cellulose acetate, nitrocellulose, ethers cellulose, ceramics and schmigel are mixed homogeneously with body paper serosity, then pass through to add Heat makes the temperature of steam stove be increased to 380 DEG C so that serosity boils, standby;
4) take 19 parts of alpha-cellulose as raw material, then add 12 parts of sodium hydroxide and carry out alkalizing, squeeze, pulverize and waited Journey is obtained alkali cellulose, then adds 16 parts of Carbon bisulfide to make alkali cellulose yellow become cellulose xanthate ester, finally after aging Adding 11 parts of dilute hydrochloric acid makes cellulose xanthate ester dissolving make saffron cellulose viscose, standby;
5) by step 4) the cellulose viscose that is obtained is added to step 3) in the serosity that is obtained, and add cellulase 15 Part, 18 parts of pectase, 18 parts of poly galactose thuja acid enzyme and 17 parts of alkyl ketene dimer, then pass through blender by serosity with Mixed pulp is stirred with the rotating speed of 35r/min, prepared body paper serosity, and the body paper serosity being obtained is poured in pressure cooker, and The pressure set of pressure cooker is 50KPa, then paper pulp raw material is heated in the pressure setting 250 DEG C so that body paper is starched Liquid is reacted with ingredients at high temperature, strengthens the function of body paper serosity, standby;
6) by step 5) the body paper serosity that is obtained is cooled to 30 DEG C, and carry out maturation process at this temperature so that body paper Serosity is obtained cellulose membrane by film balance extrusion, standby;
7) by step 6) cellulose membrane extruded adds 13 parts of glycerol and ethylene glycol 9 in the state of uncolled solidification Part, through glycerol and ethylene glycol, plastics processing is carried out to cellulose membrane, be then passed through low temp dryer and entered with 15 DEG C of low temperature Row is dried, and obtains final product.
Embodiment 3
A kind of protection against the tide cellophane cover, be made up of the raw material of following weight portion, including 130 parts of long fibre sulfate wood pulp, 80 parts of reed pulp, 50 parts of cellulose acetate, 50 parts of nitrocellulose, 50 parts of ethers cellulose, 24 parts of ceramics, 25 parts of schmigel, 16 parts of alpha-cellulose, 10 parts of sodium hydroxide, 13 parts of Carbon bisulfide, 9 parts of dilute hydrochloric acid, 14 parts of cellulase, 14 parts of pectase, many 16 parts of poly- galactose thuja acid enzyme, 15 parts of alkyl ketene dimer, 11 parts of glycerol and 8 parts of ethylene glycol.
A kind of preparation method of protection against the tide cellophane cover, comprises the following steps:
1) take 130 parts of long fibre sulfate wood pulp and 80 parts of reed pulp to be added in agitator, and start blender with 55r/ The rotating speed running of min so that long fibre sulfate wood pulp and true qualities sulfate wood pulp mix homogeneously, prepared body paper serosity, standby;
2) by step 1) the body paper serosity that is obtained poured in Bellmer and bleached, then washed and starched by pressurized screen and vacuum Machine carries out washing and screening, obtains the body paper serosity that concentration is 14%, standby;
3) by step 2) be obtained body paper serosity pour in steam stove, then add 50 parts of cellulose acetate, nitrocellulose 50 parts, 50 parts of ethers cellulose, 24 parts of ceramics and 25 parts of schmigel, stirred with the rotating speed of 45r/min by blender so that Cellulose acetate, nitrocellulose, ethers cellulose, ceramics and schmigel are mixed homogeneously with body paper serosity, then pass through to add Heat makes the temperature of steam stove be increased to 340 DEG C so that serosity boils, standby;
4) take 16 parts of alpha-cellulose as raw material, then add 10 parts of sodium hydroxide and carry out alkalizing, squeeze, pulverize and waited Journey is obtained alkali cellulose, then adds 13 parts of Carbon bisulfide to make alkali cellulose yellow become cellulose xanthate ester, finally after aging Adding 9 parts of dilute hydrochloric acid makes cellulose xanthate ester dissolving make saffron cellulose viscose, standby;
5) by step 4) the cellulose viscose that is obtained is added to step 3) in the serosity that is obtained, and add cellulase 14 Part, 14 parts of pectase, 16 parts of poly galactose thuja acid enzyme and 15 parts of alkyl ketene dimer, then pass through blender by serosity with Mixed pulp is stirred with the rotating speed of 35r/min, prepared body paper serosity, and the body paper serosity being obtained is poured in pressure cooker, and The pressure set of pressure cooker is 50KPa, then paper pulp raw material is heated in the pressure setting 210 DEG C so that body paper is starched Liquid is reacted with ingredients at high temperature, strengthens the function of body paper serosity, standby;
6) by step 5) the body paper serosity that is obtained is cooled to 25 DEG C, and carry out maturation process at this temperature so that body paper Serosity is obtained cellulose membrane by film balance extrusion, standby;
7) by step 6) cellulose membrane extruded adds 11 parts of glycerol and ethylene glycol 8 in the state of uncolled solidification Part, through glycerol and ethylene glycol, plastics processing is carried out to cellulose membrane, be then passed through low temp dryer and entered with 10 DEG C of low temperature Row is dried, and obtains final product.
Experimental example
Following table is the technical specification of cellophane:
Above table is the technical requirements of cellophane, according to the data of upper table, by the moistureproof cellophane cover of the present invention Contrasted with other cellophanes, and record data.
Experimental products:Moistureproof cellophane cover using common cellophane, special cellophane and the application compares, And record concrete numerical value, as shown in the table:
In conjunction with upper table, contrast the moistureproof cellophane cover of common cellophane, special cellophane and the application, only originally The moistureproof cellophane cover all technical of invention reaches the standard of high-class product, therefore, compares common cellophane, special Cellophane, the moistureproof cellophane cover of the present invention more can project the performance such as moistureproof, waterproof, airtight, heat sealable, and commodity are risen To good protection effect.
The technology of the present invention effect major embodiment is in the following areas:By using long fibre sulfate wood pulp and reed pulp as main Material, and add cellulose acetate, nitrocellulose, ethers cellulose, ceramics and schmigel be obtained filler, in conjunction with α- The viscose rayon that cellulose, sodium hydroxide, Carbon bisulfide and dilute hydrochloric acid are obtained, and add cellulase, pectase, poly gala The additives such as glycuronide enzyme, alkyl ketene dimer, glycerol and ethylene glycol, prepared moistureproof cellophane cover has protection against the tide, no Commodity are played good protection effect, are compared with common plasticses film, it has without quiet by the performance such as permeable, airtight, heat sealable The advantages of electric, dust-proof, kink property is good.
Certainly, the representative instance of the above simply present invention, in addition, the present invention can also have other multiple be embodied as The technical scheme that mode, all employing equivalents or equivalent transformation are formed, all falls within the scope of protection of present invention.

Claims (4)

1. a kind of protection against the tide cellophane cover it is characterised in that:It is made up of the raw material of following weight portion, including long fibre sulfate wood Slurry 100-160 part, reed pulp 70-90 part, cellulose acetate 40-60 part, nitrocellulose 40-60 part, ethers cellulose 40-60 Part, ceramics 20-28 part, schmigel 21-29 part, alpha-cellulose 13-19 part, sodium hydroxide 8-12 part, Carbon bisulfide 10-16 Part, dilute hydrochloric acid 7-11 part, cellulase 13-15 part, pectase 10-18 part, poly galactose thuja acid enzyme 14-18 part, alkyl alkene Ketone dimer 13-17 part, glycerol 9-13 part and ethylene glycol 7-9 part.
2. as claimed in claim 1 a kind of protection against the tide cellophane cover it is characterised in that:It is made up of the raw material of following weight portion, Including 160 parts of long fibre sulfate wood pulp, 70 parts of reed pulp, 40 parts of cellulose acetate, 40 parts of nitrocellulose, ethers cellulose 40 Part, 20 parts of ceramics, 21 parts of schmigel, 13 parts of alpha-cellulose, 8 parts of sodium hydroxide, 10 parts of Carbon bisulfide, 7 parts of dilute hydrochloric acid, fibre Plain 13 parts of the enzyme of dimension, 10 parts of pectase, 14 parts of poly galactose thuja acid enzyme, 13 parts of alkyl ketene dimer, 9 parts of glycerol and ethylene glycol 7 parts.
3. as claimed in claim 1 a kind of protection against the tide cellophane cover it is characterised in that:It is made up of the raw material of following weight portion, Including 100 parts of long fibre sulfate wood pulp, 90 parts of reed pulp, 60 parts of cellulose acetate, 60 parts of nitrocellulose, ethers cellulose 60 Part, 28 parts of ceramics, 29 parts of schmigel, 19 parts of alpha-cellulose, 12 parts of sodium hydroxide, 16 parts of Carbon bisulfide, 11 parts of dilute hydrochloric acid, 15 parts of cellulase, 18 parts of pectase, 18 parts of poly galactose thuja acid enzyme, 17 parts of alkyl ketene dimer, 13 parts of glycerol and second 9 parts of glycol.
4. as claimed in claim 1 a kind of protection against the tide cellophane cover it is characterised in that:It is made up of the raw material of following weight portion, Including 130 parts of long fibre sulfate wood pulp, 80 parts of reed pulp, 50 parts of cellulose acetate, 50 parts of nitrocellulose, ethers cellulose 50 Part, 24 parts of ceramics, 25 parts of schmigel, 16 parts of alpha-cellulose, 10 parts of sodium hydroxide, 13 parts of Carbon bisulfide, 9 parts of dilute hydrochloric acid, fibre Plain 14 parts of the enzyme of dimension, 14 parts of pectase, 16 parts of poly galactose thuja acid enzyme, 15 parts of alkyl ketene dimer, 11 parts of glycerol and second two 8 parts of alcohol.
CN201611119212.7A 2016-12-08 2016-12-08 Moisture-proof transparent cellophane and preparation method thereof Pending CN106436478A (en)

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CN107287987A (en) * 2017-08-01 2017-10-24 合肥利裕泰玻璃制品有限公司 A kind of mould proof glassine paper of waterproof and preparation method thereof
CN107746584A (en) * 2017-10-16 2018-03-02 王金华 A kind of preparation method of waterproof glass paper

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CN105297539A (en) * 2015-09-11 2016-02-03 句容市兴武包装有限公司 Method for preparing high-strength waterproof wrapping paper
CN105350377A (en) * 2015-11-05 2016-02-24 义乌市义南纸业有限公司 Bacteriostatic tissue wrapping paper and preparation method thereof

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WO1994003676A1 (en) * 1992-07-31 1994-02-17 Minnesota Mining And Manufacturing Company Archival aperture card
CN1765770A (en) * 2005-09-06 2006-05-03 天津大学 Degradation controllable cellulose base microbe carrier stuffing for water disposal and its preparation method
CN105297539A (en) * 2015-09-11 2016-02-03 句容市兴武包装有限公司 Method for preparing high-strength waterproof wrapping paper
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Publication number Priority date Publication date Assignee Title
CN107287987A (en) * 2017-08-01 2017-10-24 合肥利裕泰玻璃制品有限公司 A kind of mould proof glassine paper of waterproof and preparation method thereof
CN107746584A (en) * 2017-10-16 2018-03-02 王金华 A kind of preparation method of waterproof glass paper
CN107746584B (en) * 2017-10-16 2020-05-19 南京汉尔斯生物科技有限公司 Preparation method of waterproof cellophane

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