CN106433315A - Semitransparent black ink for glass cover plate, and production method thereof - Google Patents

Semitransparent black ink for glass cover plate, and production method thereof Download PDF

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Publication number
CN106433315A
CN106433315A CN201610883821.3A CN201610883821A CN106433315A CN 106433315 A CN106433315 A CN 106433315A CN 201610883821 A CN201610883821 A CN 201610883821A CN 106433315 A CN106433315 A CN 106433315A
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CN
China
Prior art keywords
ink
glass cover
black
defoamer
semitransparent
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610883821.3A
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Chinese (zh)
Inventor
熊金水
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Lansi Technology (Dongguan) Co., Ltd.
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LANSIWANG TECHNOLOGY (SHENZHEN) Co Ltd
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Priority to CN201610883821.3A priority Critical patent/CN106433315A/en
Publication of CN106433315A publication Critical patent/CN106433315A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/50Sympathetic, colour changing or similar inks
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention relates to semitransparent black ink for a glass cover plate, and a production method thereof. The semitransparent black ink comprises the following components by weight ratio: transparent resin, black dye, red ink, a curing agent, a defoamer, a flatting agent and a diluent in the ratio of (50-70):(10-15):(3-5):10:(1-3):(1-3):(5-10). The ink can resist high temperature up to 200 DEG C without color change, can be boiled, has ultrasonic washing, acid and water resistant, solvent-resistant effects and can be scrubbed, the ink has the characteristics of being extremely excellent, good in integration effect, stable in silk screen effect and the like, and has good application prospect.

Description

A kind of semitransparent black color ink for glass cover-plate and preparation method thereof
Technical field
The present invention relates to a kind of ink, more particularly to a kind of translucent black with concealment effect for glass cover-plate Ink and preparation method thereof.
Background technology
In recent years, with smart mobile phone, abundant perfect, various fuselages and the screen one of the electronic product color style such as flat board Body aspect gradually leads trend of the market.But charging indicator light in the market and IR hole all do not reach and are hidden for one completely The effect of body, and the poor and failure that easily cause IR inducing function of infrared penetration effect, the consumer having a strong impact on Property demand.
Content of the invention
The technical problem to be solved in the present invention is:A kind of semitransparent black color ink and its making for glass cover-plate is provided Method, can not only make charging indicator light and IR hole show with screen under available light integrated effect, resistance to ultrasound wave cleaning, Acid and alkali-resistance, solvent resistant and washable, and adhesive force is good, infrared penetration function-stable, silk-screen effect stability.
The technical solution adopted for the present invention to solve the technical problems is, a kind of translucent black oil for glass cover-plate Ink, the weight proportion of each component is, transparent resin:Black dyes:Red ink:Firming agent:Defoamer:Levelling agent:Diluent 50~70:10~15:3~5:10:1~3:1~3:5~10.
The semitransparent black color ink of high concealment effect is a kind of functional ink with special-effect, is printed by reverse side Brush is on transparent material and body color of arranging in pairs or groups reaches the effect of integration, and the semitransparent black color ink with concealment effect is imprinted on glass Function with high IR light penetration on glass, while control visible ray penetration performance that can be stable, hides with higher Effect, infrared light is penetrated to be stablized, and adhesive force is good, can preferably meet the fuselage of the consumer's pursuit individual character integrated with screen Change demand theory.
Preferably, transparent resin:Black dyes:Red ink:Firming agent:Defoamer:Levelling agent:Between diluent Weight proportion is 50:10:3:10:1:1:5.
Transparent resin has the stable feature of the higher and infrared penetration of transparency, and black dyes has stronger hiding effect Fruit and the feature of control infrared penetration rate, defoamer and levelling agent have makes semitransparent black color ink have good outward appearance effect Really, firming agent has makes ink have good adhesion effect.
Additionally, selected material in ink of the present invention is all the material for meeting European Union ROS and FDA standard so that ink More environmentally-friendly.
The present invention also provides a kind of manufacture method of the semitransparent black color ink for glass cover-plate, comprises the steps:
(1) take transparent resin first and black dyes is added, the transparent resin is 10 with the weight proportion of black dyes:1, Machine is stirred 5 minutes;
(2) gone forward side by side according to the corresponding addition shades of colour ink of the expression in the eyes feature of body color toward in the mixed liquor being stirred Row is sufficiently stirred for, and so that color ink is merged with mixed liquor completely, and mixing speed is 600r/min;
(3) add 1% defoamer, 1% levelling agent, 5% diluent carry out according to the quantity of above-mentioned mixed liquor It is sufficiently stirred for;
(4) 10% firming agent is added to stir when printing, mixing speed 600r/min, 10 minutes being stood after stirring, makes Dissipation of air bubbles therein, obtains finished product.
The invention has the beneficial effects as follows, the present invention using transparent resin, red ink, defoamer, levelling agent, firming agent, The components such as diluent, the black dyes being specifically added makes ink have preferable concealment effect and infrared penetration stablizing effect, The ink is resistant to 200 DEG C of high temperature invariant colors, and the cleaning of water boiling resistance, ultrasound wave, soda acid, solvent and washable, with hiding effect Really splendid, one effect is good, silk-screen effect stability the features such as, have a good application prospect.
Specific embodiment
The present invention is further detailed explanation now.Hereinafter description includes various specific details to help the reason Solution, but these details should be understood that simply exemplary.Therefore, it will be understood by those skilled in the art that not In the case of departing from the scope of the present invention and being spiritual, embodiment described here can be made various changes and modifications.In addition, being For the sake of clear and simple and clear, the description to known function and structure is omitted.
A kind of semitransparent black color ink for glass cover-plate, the weight proportion of each component is, transparent resin:Black contaminates Material:Red ink:Firming agent:Defoamer:Levelling agent:Diluent 50~70:10~15:3~5:10:1~3:1~3:5~10. Preferably, transparent resin:Black dyes:Red ink:Firming agent:Defoamer:Levelling agent:Weight proportion between diluent For 50:10:3:10:1:1:5.
This is used for the manufacture method of the semitransparent black color ink of glass cover-plate, comprises the steps:
(1) take 50g transparent resin first and 5g black dyes is added, machine is stirred 5 minutes;
(2) gone forward side by side according to the corresponding addition shades of colour ink of the expression in the eyes feature of body color toward in the mixed liquor being stirred Row is sufficiently stirred for, and so that color ink is merged with mixed liquor completely, and mixing speed is 600r/min;
(3) add 1% defoamer, 1% levelling agent, 5% diluent carry out according to the quantity of above-mentioned mixed liquor It is sufficiently stirred for;
(4) 10% firming agent is added to stir when printing, mixing speed 600r/min, 10 minutes being stood after stirring, makes Dissipation of air bubbles therein, obtains finished product.
During use, it is 75 or 80 that this has the frictioning hardness for using during the semitransparent black color ink silk screen printing of concealment effect The frictioning of (shore);The mesh number of web plate is 350~420 mesh, should reach thin and thick uniformly during printing, and general thickness is 8-12um, root Web plate mesh number is adjusted according to product needed;This ink baking-curing optimum condition is 150 DEG C~200 DEG C, 15~30 points of baking time Clock, can adjust temperature and time according to different product performance requirement.
With reference to embodiment, the invention will be further described.
Embodiment 1:
A kind of semitransparent black color ink for glass cover-plate, is made up of following proportioning raw materials:Transparent resin 1000g is black Color dyestuff 50g, red ink 50g, defoamer 20g, diluent 50g, firming agent 100g, levelling agent 20g.
Embodiment 2:
A kind of semitransparent black color ink for glass cover-plate, is made up of following proportioning raw materials:Transparent resin 1000g is black Color dyestuff 70g, red ink 70g, defoamer 20g, diluent 50g, firming agent 100g, levelling agent 20g.
Embodiment 3:
A kind of semitransparent black color ink for glass cover-plate, is made up of following proportioning raw materials:Transparent resin 1000g is black Color dyestuff 100g, red ink 100g, defoamer 30g, diluent 100g, firming agent 100g, levelling agent 30g.
As follows for ink reliability test data obtained in embodiment 1-3:
Resistance to ultrasonic testing:Using 12~13%NaOH solution, 5~6min of ultrasound at 50~60 DEG C, crosses 50-60 DEG C 2~5min of pure water, dry, test hundred lattice >=4B, ink result of determination obtained in embodiment 1-3 is for qualified.
Hundred lattice are tested:1) with the line of 1mm spacing, go shape is made in test piece;2) with hairbrush, surface irregularities are removed;3) use 600 gummed paper of 3M is taken off 1 time to 180 ° of directions by force after fully sticking together 1-2min;4) each sample must be detected 3 times in different positions More than, detection >=4B is qualified.
Infrared penetration is tested:Tested with infrared penetration instrument, 850nm:> 75%, 550nm:10% ± 5%, Ink result of determination obtained in embodiment 1-3 is qualified.
Ethanol acetone is tested:Wiped in the inked areas to be measured of wiped clean back and forth with the cotton swab for dipping in upper dehydrated alcohol or acetone 3 times are wiped, test section is not stayed without ink then for qualified on wiping vestige and cotton swab, and ink obtained in embodiment 1-3 judges knot Fruit is qualified.
Hot and humid test:1) test piece is placed in proof box;2) make in 2 hours proof box temperature humidity reach 70 DEG C, 90%, kept for 24 hours in 70 DEG C, 90%;3) test piece room temperature is taken out 2 hours;4) after finishing test, product does the survey of hundred lattice Examination.Determinating reference:1) test front/rear outward appearance without exception, no deform, no come off, flawless, no discoloration etc. are abnormal;2) grid exists Gummed paper can not have delamination after taking off by force, will reach 4B ratings above.Ink result of determination obtained in embodiment 1-3 is qualified.
Thermal shock is tested:1) test piece is put in proof box, and temperature dropped to -40 DEG C from+25 DEG C in 2 minutes, at -40 DEG C At a temperature of keep 1 hour;2)+85 DEG C are raised to from -40 DEG C in 2 minutes, (1 circulation 2 in 1 hour is kept at a temperature of 85 DEG C Hour is completed);3) 30 loop tests are completed;4) test piece is taken out in room temperature hour;4) after finishing test, product does hundred lattice Test.Determinating reference:1) test front/rear outward appearance without exception, no deform, no come off, flawless, no discoloration etc. are abnormal;2) grid There can not be delamination after gummed paper is de- by force, 4B ratings above will be reached.Ink result of determination obtained in embodiment 1-3 is qualified.
Brine spray is tested:1) test piece is put into 5%NaCl, it is 20psi that pressure barrel temperature is 47 ± 1 DEG C, air pressure (1.4Kgf/cm2), place 24 hours in testing machine;2) wash;3) moisture is removed;4) room temperature 4 hours;5) examination is finished Testing rear product carries out hundred lattice tests.Determinating reference:1) test front/rear outward appearance without exception, no deform, no come off, flawless, no become Color etc. is abnormal;2) grid can not have delamination after gummed paper is de- by force, will reach 4B ratings above.Obtained in embodiment 1-3, ink is sentenced It is qualified to determine result.
With the above-mentioned desirable embodiment according to the present invention as enlightenment, by above-mentioned description, relevant staff is complete In the range of without departing from this invention technological thought, various change and modification can be carried out entirely.The technology of this invention Property scope is not limited to the content in description, it is necessary to determine its technical scope according to right.

Claims (3)

1. a kind of semitransparent black color ink for glass cover-plate, it is characterised in that the weight proportion of each component is, transparent tree Fat:Black dyes:Red ink:Firming agent:Defoamer:Levelling agent:Diluent 50~70:10~15:3~5:10:1~3:1 ~3:5~10.
2. the semitransparent black color ink of glass cover-plate is used for as claimed in claim 1, it is characterised in that transparent resin:Black Dyestuff:Red ink:Firming agent:Defoamer:Levelling agent:Weight proportion between diluent is 50:10:3:10:1:1:5.
3. a kind of manufacture method of the semitransparent black color ink for glass cover-plate, it is characterised in that comprise the steps:
(1) take transparent resin first and black dyes is added, the transparent resin is 10 with the weight proportion of black dyes:1, machine Stirring 5 minutes;
(2) according to the corresponding addition shades of colour ink of the expression in the eyes feature of body color and filled toward in the mixed liquor being stirred Divide stirring, so that color ink is merged with mixed liquor completely, mixing speed is 600r/min;
(3) add 1% defoamer, 1% levelling agent, 5% diluent carry out fully according to the quantity of above-mentioned mixed liquor Stirring;
(4) 10% firming agent is added to stir when printing, mixing speed 600r/min, 10 minutes are stood after stirring so as in Dissipation of air bubbles, obtain finished product.
CN201610883821.3A 2016-10-09 2016-10-09 Semitransparent black ink for glass cover plate, and production method thereof Pending CN106433315A (en)

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Application Number Priority Date Filing Date Title
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107603332A (en) * 2017-09-30 2018-01-19 厦门理工学院 High temperature resistant ink, contain high temperature resistant ink coated glass and preparation method thereof
CN108706886A (en) * 2018-06-01 2018-10-26 江西联创电子有限公司 The spraying method of 3D glass cover-plates
CN109128513A (en) * 2018-08-27 2019-01-04 蓝思科技(长沙)有限公司 A kind of processing method of blind hole
CN109762394A (en) * 2018-11-30 2019-05-17 东莞市晶博光电有限公司 A kind of light white ink and its preparation process and its application method
CN111204145A (en) * 2019-12-27 2020-05-29 黄石瑞视光电技术股份有限公司 Color ink discoloration inhibition method for FPC binding position of touch screen
CN112824106A (en) * 2019-11-21 2021-05-21 重庆神华薄膜太阳能科技有限公司 Manufacturing method of light-transmitting colored glaze glass and light-transmitting colored glaze glass

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101760073A (en) * 2010-01-29 2010-06-30 蓝思科技(湖南)有限公司 Colored translucent printing ink
CN102952428A (en) * 2011-08-21 2013-03-06 比亚迪股份有限公司 Printing ink composition, method for forming near-infrared light antireflection layer on substrate surface, and near-infrared light antireflection material
CN104830145A (en) * 2015-05-22 2015-08-12 苏州安洁科技股份有限公司 Special diluting agent for IR printing ink and IR printing ink
CN104877433A (en) * 2015-06-23 2015-09-02 苏州安洁科技股份有限公司 Infrared light-transmitting printing ink
WO2016052641A1 (en) * 2014-09-30 2016-04-07 大日本印刷株式会社 Infrared-light-transmitting ink of dark color, and infrared-light-transmitting sheet obtained using same

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101760073A (en) * 2010-01-29 2010-06-30 蓝思科技(湖南)有限公司 Colored translucent printing ink
CN102952428A (en) * 2011-08-21 2013-03-06 比亚迪股份有限公司 Printing ink composition, method for forming near-infrared light antireflection layer on substrate surface, and near-infrared light antireflection material
WO2016052641A1 (en) * 2014-09-30 2016-04-07 大日本印刷株式会社 Infrared-light-transmitting ink of dark color, and infrared-light-transmitting sheet obtained using same
CN104830145A (en) * 2015-05-22 2015-08-12 苏州安洁科技股份有限公司 Special diluting agent for IR printing ink and IR printing ink
CN104877433A (en) * 2015-06-23 2015-09-02 苏州安洁科技股份有限公司 Infrared light-transmitting printing ink

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107603332A (en) * 2017-09-30 2018-01-19 厦门理工学院 High temperature resistant ink, contain high temperature resistant ink coated glass and preparation method thereof
CN108706886A (en) * 2018-06-01 2018-10-26 江西联创电子有限公司 The spraying method of 3D glass cover-plates
CN109128513A (en) * 2018-08-27 2019-01-04 蓝思科技(长沙)有限公司 A kind of processing method of blind hole
CN109762394A (en) * 2018-11-30 2019-05-17 东莞市晶博光电有限公司 A kind of light white ink and its preparation process and its application method
CN112824106A (en) * 2019-11-21 2021-05-21 重庆神华薄膜太阳能科技有限公司 Manufacturing method of light-transmitting colored glaze glass and light-transmitting colored glaze glass
CN111204145A (en) * 2019-12-27 2020-05-29 黄石瑞视光电技术股份有限公司 Color ink discoloration inhibition method for FPC binding position of touch screen

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Effective date of registration: 20181219

Address after: 523000 No. 2 Kaohsiung Road, Songshan Lake High-tech Industrial Development Zone, Dongguan City, Guangdong Province

Applicant after: Lansi Technology (Dongguan) Co., Ltd.

Address before: 518000 Gongming Office, Guangming New District, Shenzhen City, Guangdong Province

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Application publication date: 20170222

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