CN106432970A - Sunblock film for window glass and preparation method of sunblock film - Google Patents

Sunblock film for window glass and preparation method of sunblock film Download PDF

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Publication number
CN106432970A
CN106432970A CN201610885290.1A CN201610885290A CN106432970A CN 106432970 A CN106432970 A CN 106432970A CN 201610885290 A CN201610885290 A CN 201610885290A CN 106432970 A CN106432970 A CN 106432970A
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parts
window
film
polyacrylonitrile
benzotriazole
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洪长林
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Anhui Kata Doors & Windows Co Ltd
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Anhui Kata Doors & Windows Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04Homopolymers or copolymers of ethene
    • C08J2423/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a sunblock film for window glass. The sunblock film is prepared from, by weight, 24-28 parts of polyethylene, 37-41 parts of polyvinyl chloride, 6-14 parts of polyvinylidene chloride, 9-12 parts of benzotriazole, 7-12 parts of triazine, 5-8 parts of hindered amine, 13-16 parts of phenyl salicylate, 4-8 parts of silicon carbide fibers, 12-14 parts of polyacrylonitrile-based carbon fibers, 2-3 parts of alison aerogel blankets, 14-18 parts of polyphenylene sulfide, 7-15 parts of cellulose esters, 6-8 parts of polyamides, 7-10 parts of dithiocar-bamate, 11-15 parts of benzoic acid, 4-6 parts of perlite powder, 7-8 parts of silica gel, 12-14 parts of graphene, 1-2 parts of organic antimony, 3-8 parts of potassium stearate and 1-3 parts of methyl 3-aminocrotonate. The sunblock film for the window glass is high in ultraviolet isolating effect, high in structural strength and safe to use.

Description

A kind of sunscreen film of window-glass and preparation method thereof
Technical field
The present invention relates to a kind of sunscreen film of window-glass and preparation method thereof.
Background technology
Window refers to the hole that builds on wall or roof on architectonics, in order to get in light or air.True The original idea at upper window and family refers to window and door respectively, and in Modern Chinese, window then singly refers to window." window " this work " chimney "(" chimney " is character in popular form), Hole is stayed on the wall, inframe is window lattice, can be with printing opacity, it is also possible to smoke, afterwards plus " cave " prefix constitutes phonogram.《Say text》 Say:" say in wall, chimney is said in room.Window, or from cave." window frame is responsible for supporting the main structure of forms, can be timber, metal, pottery Porcelain or plastic material, transparent part is attached on window frame, can be paper, cloth, silk or glass material.
The window of modern window is by window frame, glass and movable part(Hinge, handle, pulley etc.)Three parts constitute.Window frame It is responsible for the main structure of forms is supported, can is timber, metal, pottery or plastic material, transparent part is attached on window frame, permissible It is paper, cloth, silk or glass material.Movable part is likely to parcel mainly based on metal material where staff is touched With adiabators such as plastics.
With the development of Building technology and the raising of human living standard, the construction of window is also increasingly sophisticated higher to meet Thermal technology require.Senior building can be using double-deck even three layers of vacuum Low-E glass, and two pass rubber weather strip, to ensure which Optimal thermal and insulating performance.Rimless unit, also referred to as dome skylight can be made in horizontal skylight.Glass curtain wall can be recognized For being that a kind of special window, i.e. whole building exterior wall all become the window of light-permeable.
The sunscreen film of existing window adopts PET(Polyethylene)Base material, leading use multiple layer metal sputtering technology and vacuum Technology and ion technology and thin film physicses, fine chemical technology so as to high heat-insulating efficiency, high-tension, high elongation, Strong anti acid alkali performance energy.And natural in color is abundant, test result shows:81% solar energy can be intercepted;In outdoor temperature 38-39 When, reduce 3-5 degree than simple glass temperature, more than 30% air-conditioning power consumption is saved, is high-tech and energy-saving safety material.
The effect of existing sunscreen film isolation ultraviolet is bad, and structural strength is not high, using dangerous.
Content of the invention
The technical problem to be solved in the present invention is good, the structural strength height that provides a kind of effect of isolation ultraviolet, keeps making Sunscreen film with the window-glass of safety.
For solving the above problems, the present invention is adopted the following technical scheme that:
A kind of sunscreen film of window-glass, is made up of the material of following parts by weight proportioning:Including polyethylene 24-28 part, polychlorostyrene Ethylene 37-41 part, polyvinylidene chloride 6-14 part, benzotriazole 9-12 part, triazine 7-12 part, hindered amine 5-8 part, o-hydroxy Phenyl formate 13-16 part, silicon carbide fibre 4-8 part, polyacrylonitrile-based carbon fibre 12-14 part, aerogel blanket 2-3 part, polyphenylene sulfide Ether 14-18 part, cellulose esters 7-15 part, -8 parts of polyamide 6, dithiocar-bamate 7-10 part, benzoic acid 11-15 part, treasure Pearl rock dust 4-6 part, Silica hydrogel 7-8 part, Graphene 12-14 part, antimony organic 1-2 part, potassium stearate 3-8 part and 3- amino .beta.-methylacrylic acid Methyl ester 1-3 part.
Preferably, being made up of the material of following parts by weight proportioning:Including 24 parts of polyethylene, 37 parts of polrvinyl chloride, gather 6 parts of vinylidene chloride, 9 parts of benzotriazole, 7 parts of triazine, 5 parts of hindered amine, 13 parts of oxybenzoic acid phenyl ester, silicon carbide fibre 4 Part, 12 parts of polyacrylonitrile-based carbon fibre, 2 parts of aerogel blanket, 14 parts of polyphenylene sulfide, 7 parts of cellulose esters, polyamide 6 part, dithio 7 parts of carbaminate, 11 parts of benzoic acid, 4 parts of crushed crude pearlite, 7 parts of Silica hydrogel, 12 parts of Graphene, 1 part of antimony organic, potassium stearate 3 Part and 1 part of METHYL 3 AMINO CROTONATE.
Preferably, being made up of the material of following parts by weight proportioning:Including 26 parts of polyethylene, 39 parts of polrvinyl chloride, gather 10 parts of vinylidene chloride, 10.5 parts of benzotriazole, 9.5 parts of triazine, 6.5 parts of hindered amine, 14.5 parts of oxybenzoic acid phenyl ester, carbon 6 parts of SiClx fiber, 13 parts of polyacrylonitrile-based carbon fibre, 2.5 parts of aerogel blanket, 16 parts of polyphenylene sulfide, 11 parts of cellulose esters, polyamides 7 parts of amine, 8.5 parts of dithiocar-bamate, 13 parts of benzoic acid, 5 parts of crushed crude pearlite, 7.5 parts of Silica hydrogel, 13 parts of Graphene, have 1.5 parts of machine antimony, 5.5 parts of potassium stearate and 2 parts of METHYL 3 AMINO CROTONATE.
Preferably, being made up of the material of following parts by weight proportioning:Including 28 parts of polyethylene, 41 parts of polrvinyl chloride, gather 14 parts of vinylidene chloride, 12 parts of benzotriazole, 12 parts of triazine, 8 parts of hindered amine, 16 parts of oxybenzoic acid phenyl ester, carborundum fibre Dimension 8 parts, 14 parts of polyacrylonitrile-based carbon fibre, 3 parts of aerogel blanket, 18 parts of polyphenylene sulfide, 15 parts of cellulose esters, 8 parts of polyamide, two 10 parts of thiocarbamate, 15 parts of benzoic acid, 6 parts of crushed crude pearlite, 8 parts of Silica hydrogel, 14 parts of Graphene, 2 parts of antimony organic, Hard Fat 8 parts of sour potassium and 3 parts of METHYL 3 AMINO CROTONATE.
A kind of preparation method of the sunscreen film of window-glass, comprises the following steps:
1)By polyethylene 24-28 part, polrvinyl chloride 37-41 part, polyvinylidene chloride 6-14 part, benzotriazole 9-12 part, triazine 7-12 part, hindered amine 5-8 part, oxybenzoic acid phenyl ester 13-16 part, silicon carbide fibre 4-8 part, polyacrylonitrile-based carbon fibre 12-14 part is put in reactor, standby;
2)Regulating step 1)The temperature of middle reactor is 44-55 DEG C, and mixing speed is 1100-1200r/min, the response time to be 25-30 minute, standby;
3)By aerogel blanket 2-3 part, polyphenylene sulfide 14-18 part, cellulose esters 7-15 part, -8 parts of polyamide 6, dithiocarbamates first Hydrochlorate 7-10 part, benzoic acid 11-15 part, crushed crude pearlite 4-6 part, Silica hydrogel 7-8 part, Graphene 12-14 part, antimony organic 1-2 part, Potassium stearate 3-8 part and METHYL 3 AMINO CROTONATE 1-3 part are put in grinder, standby;
4)Regulating step 3)In grinder rotating speed be 9000-9500r/min, grind 16-20 minute, standby;
5)By step 2)Gained raw material and step 4)Gained raw material is put in extruder, and keeping temperature is extruded for 260-300 DEG C In sheet material, then thin film of the thickness for 1.5mm is obtained through biaxial tension.
Beneficial effects of the present invention are:The polyethylene of interpolation, polrvinyl chloride, polyvinylidene chloride, benzotriazole, triazine, The effect of hindered amine and oxybenzoic acid phenyl ester isolation ultraviolet is good, can reach sun-screening function;The silicon carbide fibre of interpolation, Graphene, polyacrylonitrile-based carbon fibre, aerogel blanket structural strength height, keep using safety;The antimony organic of interpolation, potassium stearate Keep film performance stable with METHYL 3 AMINO CROTONATE, long service life.
Specific embodiment
Embodiment 1
A kind of sunscreen film of window-glass, is made up of the material of following parts by weight proportioning:Including 24 parts of polyethylene, polrvinyl chloride 37 parts, 6 parts of polyvinylidene chloride, 9 parts of benzotriazole, 7 parts of triazine, 5 parts of hindered amine, 13 parts of oxybenzoic acid phenyl ester, carbonization 4 parts of silica fibre, 12 parts of polyacrylonitrile-based carbon fibre, 2 parts of aerogel blanket, 14 parts of polyphenylene sulfide, 7 parts of cellulose esters, polyamide 6 Part, 7 parts of dithiocar-bamate, 11 parts of benzoic acid, 4 parts of crushed crude pearlite, 7 parts of Silica hydrogel, 12 parts of Graphene, 1 part of antimony organic, 3 parts of potassium stearate and 1 part of METHYL 3 AMINO CROTONATE.
A kind of preparation method of the sunscreen film of window-glass, comprises the following steps:
1)By 24 parts of polyethylene, 37 parts of polrvinyl chloride, 6 parts of polyvinylidene chloride, 9 parts of benzotriazole, 7 parts of triazine, hindered amine 5 Part, 13 parts of oxybenzoic acid phenyl ester, 4 parts of silicon carbide fibre, 12 parts of polyacrylonitrile-based carbon fibre are put in reactor, standby With;
2)Regulating step 1)The temperature of middle reactor is 44-55 DEG C, and mixing speed is 1100-1200r/min, the response time to be 25-30 minute, standby;
3)By 2 parts of aerogel blanket, 14 parts of polyphenylene sulfide, 7 parts of cellulose esters, polyamide 6 part, 7 parts of dithiocar-bamate, benzene 11 parts of formic acid, 4 parts of crushed crude pearlite, 7 parts of Silica hydrogel, 12 parts of Graphene, 1 part of antimony organic, 3 parts and 3- amino .beta.-methylacrylic acids of potassium stearate 1 part of methyl ester is put in grinder, standby;
4)Regulating step 3)In grinder rotating speed be 9000-9500r/min, grind 16-20 minute, standby;
5)By step 2)Gained raw material and step 4)Gained raw material is put in extruder, and keeping temperature is extruded for 260-300 DEG C In sheet material, then thin film of the thickness for 1.5mm is obtained through biaxial tension.
Embodiment 2
A kind of sunscreen film of window-glass, is made up of the material of following parts by weight proportioning:Including 26 parts of polyethylene, polrvinyl chloride 39 parts, 10 parts of polyvinylidene chloride, 10.5 parts of benzotriazole, 9.5 parts of triazine, 6.5 parts of hindered amine, oxybenzoic acid phenyl ester 14.5 parts, 6 parts of silicon carbide fibre, 13 parts of polyacrylonitrile-based carbon fibre, 2.5 parts of aerogel blanket, 16 parts of polyphenylene sulfide, cellulose esters 11 parts, 7 parts of polyamide, 8.5 parts of dithiocar-bamate, 13 parts of benzoic acid, 5 parts of crushed crude pearlite, 7.5 parts of Silica hydrogel, graphite 13 parts of alkene, 1.5 parts of antimony organic, 5.5 parts of potassium stearate and 2 parts of METHYL 3 AMINO CROTONATE.
A kind of preparation method of the sunscreen film of window-glass, comprises the following steps:
1)By 26 parts of polyethylene, 39 parts of polrvinyl chloride, 10 parts of polyvinylidene chloride, 10.5 parts of benzotriazole, 9.5 parts of triazine, receive 6.5 parts of amine of resistance, 14.5 parts of oxybenzoic acid phenyl ester, 6 parts of silicon carbide fibre, 13 parts of polyacrylonitrile-based carbon fibre put into reaction In kettle, standby;
2)Regulating step 1)The temperature of middle reactor is 44-55 DEG C, and mixing speed is 1100-1200r/min, the response time to be 25-30 minute, standby;
3)By 2.5 parts of aerogel blanket, 16 parts of polyphenylene sulfide, 11 parts of cellulose esters, 7 parts of polyamide, dithiocar-bamate 8.5 Part, 13 parts of benzoic acid, 5 parts of crushed crude pearlite, 7.5 parts of Silica hydrogel, 13 parts of Graphene, 1.5 parts of antimony organic, 5.5 parts of potassium stearate and 2 parts of METHYL 3 AMINO CROTONATE is put in grinder, standby;
4)Regulating step 3)In grinder rotating speed be 9000-9500r/min, grind 16-20 minute, standby;
5)By step 2)Gained raw material and step 4)Gained raw material is put in extruder, and keeping temperature is extruded for 260-300 DEG C In sheet material, then thin film of the thickness for 1.5mm is obtained through biaxial tension.
Embodiment 3
A kind of sunscreen film of window-glass, is made up of the material of following parts by weight proportioning:Including 28 parts of polyethylene, polrvinyl chloride 41 parts, 14 parts of polyvinylidene chloride, 12 parts of benzotriazole, 12 parts of triazine, 8 parts of hindered amine, 16 parts of oxybenzoic acid phenyl ester, carbon 8 parts of SiClx fiber, 14 parts of polyacrylonitrile-based carbon fibre, 3 parts of aerogel blanket, 18 parts of polyphenylene sulfide, 15 parts of cellulose esters, polyamide 8 parts, 10 parts of dithiocar-bamate, 15 parts of benzoic acid, 6 parts of crushed crude pearlite, 8 parts of Silica hydrogel, 14 parts of Graphene, antimony organic 2 Part, 8 parts of potassium stearate and 3 parts of METHYL 3 AMINO CROTONATE.
A kind of preparation method of the sunscreen film of window-glass, comprises the following steps:
1)By 28 parts of polyethylene, 41 parts of polrvinyl chloride, 14 parts of polyvinylidene chloride, 12 parts of benzotriazole, 12 parts of triazine, hindered amine 8 parts, 16 parts of oxybenzoic acid phenyl ester, 8 parts of silicon carbide fibre, 14 parts of polyacrylonitrile-based carbon fibre put in reactor, standby With;
2)Regulating step 1)The temperature of middle reactor is 44-55 DEG C, and mixing speed is 1100-1200r/min, the response time to be 25-30 minute, standby;
3)By 3 parts of aerogel blanket, 18 parts of polyphenylene sulfide, 15 parts of cellulose esters, 8 parts of polyamide, 10 parts of dithiocar-bamate, 15 parts of benzoic acid, 6 parts of crushed crude pearlite, 8 parts of Silica hydrogel, 14 parts of Graphene, 2 parts of antimony organic, 8 parts and 3- amino Fructus Crotonis of potassium stearate 3 parts of sour methyl ester is put in grinder, standby;
4)Regulating step 3)In grinder rotating speed be 9000-9500r/min, grind 16-20 minute, standby;
5)By step 2)Gained raw material and step 4)Gained raw material is put in extruder, and keeping temperature is extruded for 260-300 DEG C In sheet material, then thin film of the thickness for 1.5mm is obtained through biaxial tension.
Beneficial effects of the present invention are:The polyethylene of interpolation, polrvinyl chloride, polyvinylidene chloride, benzotriazole, triazine, The effect of hindered amine and oxybenzoic acid phenyl ester isolation ultraviolet is good, can reach sun-screening function;The silicon carbide fibre of interpolation, Graphene, polyacrylonitrile-based carbon fibre, aerogel blanket structural strength height, keep using safety;The antimony organic of interpolation, potassium stearate Keep film performance stable with METHYL 3 AMINO CROTONATE, long service life.
The above, the only specific embodiment of the present invention, but protection scope of the present invention is not limited thereto, and any Without the change or replacement that creative work is expected, should all be included within the scope of the present invention.

Claims (5)

1. a kind of sunscreen film of window-glass, it is characterised in that:It is made up of the material of following parts by weight proportioning:Including polyethylene 24-28 part, polrvinyl chloride 37-41 part, polyvinylidene chloride 6-14 part, benzotriazole 9-12 part, triazine 7-12 part, hindered amine 5- 8 parts, oxybenzoic acid phenyl ester 13-16 part, silicon carbide fibre 4-8 part, polyacrylonitrile-based carbon fibre 12-14 part, aerogel blanket 2-3 part, polyphenylene sulfide 14-18 part, cellulose esters 7-15 part, -8 parts of polyamide 6, dithiocar-bamate 7-10 part, benzene first Sour 11-15 part, crushed crude pearlite 4-6 part, Silica hydrogel 7-8 part, Graphene 12-14 part, antimony organic 1-2 part, potassium stearate 3-8 part and METHYL 3 AMINO CROTONATE 1-3 part.
2. the sunscreen film of window-glass as claimed in claim 1, it is characterised in that:Material system by following parts by weight proportioning Become:Including 24 parts of polyethylene, 37 parts of polrvinyl chloride, 6 parts of polyvinylidene chloride, 9 parts of benzotriazole, 7 parts of triazine, 5 parts of hindered amine, 13 parts of oxybenzoic acid phenyl ester, 4 parts of silicon carbide fibre, 12 parts of polyacrylonitrile-based carbon fibre, 2 parts of aerogel blanket, polyphenylene sulfide 14 parts, 7 parts of cellulose esters, polyamide 6 part, 7 parts of dithiocar-bamate, 11 parts of benzoic acid, 4 parts of crushed crude pearlite, Silica hydrogel 7 Part, 12 parts of Graphene, 1 part of antimony organic, 3 parts of potassium stearate and 1 part of METHYL 3 AMINO CROTONATE.
3. the sunscreen film of window-glass as claimed in claim 2, it is characterised in that:Material system by following parts by weight proportioning Become:Including 26 parts of polyethylene, 39 parts of polrvinyl chloride, 10 parts of polyvinylidene chloride, 10.5 parts of benzotriazole, 9.5 parts of triazine, it is obstructed 6.5 parts of amine, 14.5 parts of oxybenzoic acid phenyl ester, 6 parts of silicon carbide fibre, 13 parts of polyacrylonitrile-based carbon fibre, aerogel blanket 2.5 Part, 16 parts of polyphenylene sulfide, 11 parts of cellulose esters, 7 parts of polyamide, 8.5 parts of dithiocar-bamate, 13 parts of benzoic acid, Margarita 5 parts of rock dust, 7.5 parts of Silica hydrogel, 13 parts of Graphene, 1.5 parts of antimony organic, 5.5 parts of potassium stearate and METHYL 3 AMINO CROTONATE 2 Part.
4. the sunscreen film of window-glass as claimed in claim 3, it is characterised in that:Material system by following parts by weight proportioning Become:Including 28 parts of polyethylene, 41 parts of polrvinyl chloride, 14 parts of polyvinylidene chloride, 12 parts of benzotriazole, 12 parts of triazine, hindered amine 8 Part, 16 parts of oxybenzoic acid phenyl ester, 8 parts of silicon carbide fibre, 14 parts of polyacrylonitrile-based carbon fibre, 3 parts of aerogel blanket, polyphenylene sulfide 18 parts of ether, 15 parts of cellulose esters, 8 parts of polyamide, 10 parts of dithiocar-bamate, 15 parts of benzoic acid, 6 parts of crushed crude pearlite, silicon 8 parts of gel, 14 parts of Graphene, 2 parts of antimony organic, 8 parts of potassium stearate and 3 parts of METHYL 3 AMINO CROTONATE.
5. a kind of preparation method of the sunscreen film of window-glass, it is characterised in that:Comprise the following steps:
1)By polyethylene 24-28 part, polrvinyl chloride 37-41 part, polyvinylidene chloride 6-14 part, benzotriazole 9-12 part, triazine 7-12 part, hindered amine 5-8 part, oxybenzoic acid phenyl ester 13-16 part, silicon carbide fibre 4-8 part, polyacrylonitrile-based carbon fibre 12-14 part is put in reactor, standby;
2)Regulating step 1)The temperature of middle reactor is 44-55 DEG C, and mixing speed is 1100-1200r/min, the response time to be 25-30 minute, standby;
3)By aerogel blanket 2-3 part, polyphenylene sulfide 14-18 part, cellulose esters 7-15 part, -8 parts of polyamide 6, dithiocarbamates first Hydrochlorate 7-10 part, benzoic acid 11-15 part, crushed crude pearlite 4-6 part, Silica hydrogel 7-8 part, Graphene 12-14 part, antimony organic 1-2 part, Potassium stearate 3-8 part and METHYL 3 AMINO CROTONATE 1-3 part are put in grinder, standby;
4)Regulating step 3)In grinder rotating speed be 9000-9500r/min, grind 16-20 minute, standby;
5)By step 2)Gained raw material and step 4)Gained raw material is put in extruder, and keeping temperature is extruded for 260-300 DEG C In sheet material, then thin film of the thickness for 1.5mm is obtained through biaxial tension.
CN201610885290.1A 2016-10-11 2016-10-11 Sunblock film for window glass and preparation method of sunblock film Pending CN106432970A (en)

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Cited By (2)

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CN107134099A (en) * 2017-07-17 2017-09-05 苏州信宏天科技有限公司 A kind of intelligent domestic intelligent anti-theft system and its operation method
CN108976461A (en) * 2018-07-03 2018-12-11 阜南县猛发工艺品有限公司 A kind of scratch resistant anti-cutting flexible protective film of high intensity

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Application publication date: 20170222