CN106431304A - Spherical light cassava-residue ceramsite with air purification function and through holes - Google Patents

Spherical light cassava-residue ceramsite with air purification function and through holes Download PDF

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Publication number
CN106431304A
CN106431304A CN201610847332.2A CN201610847332A CN106431304A CN 106431304 A CN106431304 A CN 106431304A CN 201610847332 A CN201610847332 A CN 201610847332A CN 106431304 A CN106431304 A CN 106431304A
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spheroidal
air purification
purification function
manioc waste
lightweight
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Inventor
陈馨
黄庆英
焦文涛
王鲁海
邱茗
王跃皓
许庆华
蒋文兰
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Gansu Huachen Ecological Management Co Ltd
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Gansu Huachen Ecological Management Co Ltd
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Priority to CN201610847332.2A priority Critical patent/CN106431304A/en
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Abstract

The invention discloses spherical light cassava-residue ceramsite with an air purification function and through holes. The technical scheme mainly includes that ingredients for the spherical light cassava-residue ceramsite include attapulgite pottery clay powder with an air purification function, cassava residues, activated argil waste residues, white carbon black, activated aluminum oxide, sodium aluminate, sodium dodecyl sulfate, attapulgite photocatalyst spray liquid capable of being scrubbed and the like; the ingredients are subjected to stirring, extrusion granulation, drying, calcination, heat-insulation treatment, sieving, soaking, drying, sieving and hermetic packaging to obtain the spherical light cassava-residue ceramsite with the air purification function and the through holes. The spherical light cassava-residue ceramsite with the air purification function and the through holes has the advantages of large specific surface area, low stacking density, high moisture absorption, excellent adsorption performance, good lightweight strength and micropore and macropore integration. Besides, the spherical light cassava-residue ceramsite is suitable to be arranged in indoor environments, furniture and cupboards, vehicles, aircrafts, ships or other buildings, pollutants such as formaldehyde, ammonia, benzene and TVOC (total volatile organic compounds) can be adsorbed and degraded by the spherical light cassava-residue ceramsite, and accordingly the purpose of purifying air can be achieved.

Description

Spheroidal has the manioc waste lightweight through hole haydite of air purification function
Technical field
The present invention relates to haydite is and in particular to a kind of spheroidal has the manioc waste lightweight through hole pottery of air purification function Grain.
Background technology
The air purifying preparation supplied in the market has following several types:Absorbent-type air purifying preparation, covering type taste removal Product and Breakdown type taste removal product.Absorbent-type air purifying preparation is using materials such as activated carbon, bamboo charcoal, molecular sieve, mineral The performances such as physical absorption, chemisorbed, catalysis oxidation and reduction remove the purification product of pollutant;Covering type taste removal product is profit Cover the various abnormal flavour of in the air with the fragrance of aromatic hydrocarbon, abnormal flavour is not in fact removed, simply by a lot of air fresheners With a kind of odor type, abnormal flavour is covered;Breakdown type air clearing product is more rare on the market.
Chinese patent Authorization Notice No.:CN 103861421 B, authorized announcement date:On November 18th, 2015, entitled " one Kind of air purifying preparation ", discloses that " a kind of air purifying preparation, its preparing raw material is contained by mass fraction:Diatomite in powder, zeolite powder, Medical stone powder, tourmaline powder, activated carbon powder, sepiolite powder, titanium dioxide powder, and adopt and prepare with the following method:1) by kieselguhr Powder, zeolite powder, medical stone powder, tourmaline powder, activated carbon powder, sepiolite powder, titanium dioxide powder mixing;2) by step 1) gained mix Compound pelletize;3) baking step 2) gained mixture after pelletize.The air purifying preparation specific surface that the present invention is obtained is big and uniform, Good to the adsorption-decomposition function effect of in the air harmful substance, it is for interior, the depollution of environment of the closing space such as in-car and various sky The ideal chose material of gas purifier ".
The weak point of above-mentioned patent is:(1) diatomite in powder, zeolite powder, medical stone powder, tourmaline powder, activated carbon powder and sea Afrodite powder, not through necessary modification, is difficult to really play the effect of its effective purify air.(2) gained mixed powder Adopt granulating disc pelletize after the clear water stirring adding 20-30%, be a kind of circular granular of a diameter of 1.2-1.6mm.Should Mixed powder itself normal moisture content of invention is more than 10%, and the circular granular moisture content after the pelletize that adds water will be greater than 30%, and Drying temperature, in the case of less than 100 DEG C, is difficult to dry circular granular in 3 hours.Kieselguhr, zeolite, Maifanitum, After tourmaline and meerschaum carry out heat treatment process at 250~450 DEG C, its absorption property is relatively good, and this is the technology of this area Personnel know altogether;The circular granular of this invention is dried in the case of less than 100 DEG C, can not effectively improve the work of purify air With, and the comprcssive strength of circular granular also very little, gently one pinched with handss, circular granular will be crumbed as powdered.
The spheroidal air purifying preparation of supply, molecular sieve, desiccant or other spherical granules on market, in pelletize It is first powdery dispensing to be processed into the bead that a kind of diameter is less than 0.5 millimeter in journey, then by the vaporific aqueous solution preparing, spray Spill in the bead in on-stream comminutor, then powdery dispensing is trickled down on the surface of moistening bead, through being repeated several times Spray vaporific aqueous solution and trickle down on the surface of moistening bead by powdery dispensing, through the parcel of layer upon layer, bead Volume constantly increase, be finally completed the overall process of pelletize, be prepared into a kind of spherical granules, due to spherical granules internal junction Structure is very closely knit, greatly reduces the effective specific surface area of spherical granules, the proportion of spherical granules and bulk density all than Larger, directly influence the absorption purifying effect of spherical granules.
Content of the invention
The purpose of the present invention is to overcome weak point in prior art, provides a kind of spheroidal to have air purification function Manioc waste lightweight through hole haydite.
Spheroidal has the dispensing of the manioc waste lightweight through hole haydite of air purification function by having air purification function Attapulgite potter's clay powder, manioc waste, active white clay waste slag, white carbon, precipitated calcium carbonate, light magnesium oxide, activated alumina, aluminic acid Sodium, cenosphere, gesso, expanded perlite, sodium lauryl sulphate and washable attapulgite photocatalytic spray liquid composition.
Spheroidal has the production method of the manioc waste lightweight through hole haydite of air purification function:Spheroidal had purification The dispensing of the manioc waste lightweight through hole semi-finished product of air function is stirred, extruder grain, drying, roasting, insulation, sieve Divide, soak, drying, sieving, packing the manioc waste lightweight through hole haydite for spheroidal with air purification function.
The attapulgite potter's clay powder with air purification function is by high viscous Concave-convex clay rod, attapulite constant humidity amendment, sky So mineral adsorption filtering agent, Cacumen Platycladi, aluminium silicate fiber peacekeeping polyacrylamide composition, has preferable caking property, plasticity, touches Degeneration, fire resistance and heat stability, can effectively adsorb the harmful substances such as formaldehyde in air, ammonia and benzene, environmental protection and enhancement People's is healthy, and the present invention is from fineness of the particles≤0.074 millimeter of the attapulgite potter's clay powder with air purification function.
Maninot esculenta crantz., also known as Nan Yang potato, wooden Ipomoea batatas Lam., cassava, is the tuber of euphorbia plant, has meat elongated cylindrical tuber, tuber Meat rich in starch, edible or make thickener, can ground wood potato starch, make bread, tapioca be provided and wash and starch with starch or even wine Smart beverage, manioc waste is a kind of waste residue producing after ethanol, and the present invention selects fineness of the particles≤0.074 millimeter of manioc waste.
Active hargil is a kind of odorless, tasteless, nontoxic white or cream-coloured powder or granule, and the activity after decolouring is white Soil loses activity and becomes active white clay waste slag, some oily factories all by these active white clay waste slags abandon, if cannot and When process, produces after the organic fermentation of lipid in active white clay waste slag and goes mouldy and stench, the not only wasting of resources, pollute environment and Groundwater quality, and fire hazardous, will cause certain loss to society and enterprise;The present invention selects active white clay waste slag Fineness of the particles≤0.149 millimeter.
White carbon is a kind of ultra tiny inorganic porous property material, due to its particle diameter very little, has that specific surface area is big, surface is inhaled Attached power is strong, chemical purity is high, dispersive property is good, superior stability, reinforcing, thickening property, adhesive force and thixotropy etc. are special Performance.
Precipitated calcium carbonate fine particles, surface are rougher, and specific surface area is big, and precipitated calcium carbonate also has and do not settle, easily point Dissipate, the characteristic such as good luster, the present invention selects fineness of the particles≤0.074 millimeter of precipitated calcium carbonate.
Light magnesium oxide is the white loose unformed powder of lightweight, odorless, tasteless, and nontoxic, volume shared by light magnesium oxide is about About the three times of heavy-burned magnesia, there are extremely fireproof heat-insulating property, reinforcing agent, adhesive, the present invention selects light magnesium oxide Fineness of the particles≤0.074 millimeter.
Activated alumina is the solid material of a kind of porous, high degree of dispersion, has very big surface area, and its micropore surface has Standby characteristic required by catalytic action, such as absorption property, surface activity, excellent heat stability etc., so be widely used as The catalyst of chemical reaction and catalyst carrier, the present invention selects fineness of the particles≤0.074 millimeter of activated alumina.
Sodium aluminate also known as sodium metaaluminate, are a kind of general chemical article, white, odorless, tasteless, in alkaline solid, Easily absorb moisture content and carbon dioxide in atmosphere, the present invention selects fineness of the particles≤0.074 millimeter of sodium aluminate.
Natural dihydrate gypsum is also called Gypsum Fibrosum, through calcining, levigate obtain gesso, Gypsum Fibrosum preparata has more micropore Structure, is allowed to have excellent sound insulation, heat-insulated and fire protecting performance, and the present invention selects fineness of the particles≤0.074 millimeter of gesso.
Cenosphere outward appearance is canescence, is a kind of loose, good fluidity powder body material, cenosphere proportion is little, table Face is smooth, intensity is big, easily disperse, the present invention select the fineness of the particles of cenosphere≤≤ 0.149 millimeter.
Perlite is expanded and becomes a kind of lightweight, multifunctional novel shaped material, have that apparent density is light, heat conductivity is low, The features such as chemical stability is good, the present invention selects fineness of the particles≤0.074 millimeter of expanded perlite.
Sodium lauryl sulphate is white or faint yellow powdery, is dissolved in water, insensitive to alkali and hard water, has decontamination, breast Change and excellent foaming power, be a kind of nontoxic anion surfactant.
Washable attapulgite photocatalytic spray liquid is sprayed on building or decorative material surface, under the irradiation of light, permissible Continual absorption and the pollutant such as degradation of formaldehyde, ammonia, benzene,toluene,xylene, TVOC, and there is extremely strong sterilization, remove Smelly, mould proof, anti-fouling and self-cleaning and the function of purify air.
The technical scheme is that:
1st, spheroidal has the dispensing of the manioc waste lightweight through hole haydite of air purification function by weight percentage by following component Composition:Spheroidal has the manioc waste lightweight through hole semi-finished product 55~95% of air purification function and washable attapulgite light Catalyzed spraying liquid 5~45%.
2nd, spheroidal has the production method of the manioc waste lightweight through hole haydite of air purification function:(1) first will be washable recessed Convex rod photocatalytic spray liquid is put in fermentation vat, then spheroidal is had the manioc waste lightweight through hole haydite half of air purification function Finished product is slowly added in the washable attapulgite photocatalytic spray liquid in fermentation vat, and spheroidal has the Maninot esculenta crantz. of air purification function Micropore inside and outside slag lightweight through hole semi-finished product, constantly sucks washable attapulgite photocatalytic spray liquid, until in saturation State;(2) take out from fermentation vat and be filled the spheroidal of washable attapulgite photocatalytic spray liquid there is the wood of air purification function Potato slag lightweight through hole haydite, is transported in low temperature rotary drying oven and is dried, and drying temperature controls at 150~180 DEG C, dries Dry time control was at 1~3 hour;(3) the spheroidal after oven drying at low temperature had the manioc waste lightweight through hole pottery of air purification function Grain is transported in flat vibrating screen and is sieved, and weeds out broken granule and powder, packs and have purification for spheroidal The finished product of the manioc waste lightweight through hole haydite of air function.
3rd, spheroidal has the dispensing of the manioc waste lightweight through hole semi-finished product of air purification function by weight percentage It is made up of following component:There is the attapulgite potter's clay powder 10~45% of air purification function, manioc waste 5~25%, active hargil Waste residue 2~10%, white carbon 1~8%, precipitated calcium carbonate 1~5%, light magnesium oxide 1~5%, activated alumina 1~5%, Sodium aluminate 0.5~5%, cenosphere 0.5~5%, gesso 0.5~5%, expanded perlite 0.5~5%, dodecyl Sodium sulfate 0.5~5% and water 10~40%.
4th, spheroidal has the production method of the manioc waste lightweight through hole semi-finished product of air purification function:(1) by ball The dispensing that shape has the manioc waste lightweight through hole semi-finished product of air purification function inputs in the stirring mixer having operated, Stirring is mixed into the mixture that spheroidal has the manioc waste lightweight through hole haydite of air purification function;(2) spheroidal is had only The mixture changing the manioc waste lightweight through hole haydite of air function is transported in Squeezinggranulator, and extruder grain has for spheroidal The manioc waste lightweight through hole haydite blank material of air purification function, spheroidal has the manioc waste lightweight through hole of air purification function The macropore at haydite blank material center is through hole;(3) spheroidal had the manioc waste lightweight through hole haydite blank of air purification function Material is transported in swinging drying oven is dried, and drying temperature controls at 200~250 DEG C, and drying time controls little 1~4 When;(4) the manioc waste lightweight through hole haydite blank material spheroidal after drying being had air purification function is transported to swinging roasting Burn kiln roasting, at 900~950 DEG C, roasting time controlled at 1~3 hour the temperature control of combustor;(5) by the circle after roasting The spherical manioc waste lightweight through hole haydite blank material with air purification function, input is incubated, during insulation in rustless steel cylinder storehouse Between control at 24~72 hours;(6) the spheroidal after insulation cooling had the manioc waste lightweight through hole haydite of air purification function Blank material is transported in roller vibrating screen and is sieved, and weeds out broken granule and powder and has purify air work(for spheroidal The manioc waste lightweight through hole semi-finished product of energy.
The production method the 5th, with the attapulgite potter's clay powder of air purification function is:(1) will there is the recessed of air purification function Pulverized in input pulverizer after the dispensing mixing of convex rod potter's clay powder, the compound particles fineness after pulverizing is less than 0.5 millimeter; (2) pulverulent mixture is added and soak in old pond that to carry out soaking old process with water be semi-finished product, soak old time control and exist 7~30 days;(3) semi-finished product are inputted in vacuum-extruder and be squeezed into cylindrical bar, the diameter control of cylindrical bar exists 2~10 millimeters;(4) cylindrical bar is input to cement threshing ground and carries out dry in the sun, the cylindrical bar water content after dry in the sun is little In 15%;(5) pulverizing will be carried out for powder in the cylindrical bar input grinding machine after dry in the sun, the fineness of the particles of powder is little In 0.074 millimeter.
The dispensing with the attapulgite potter's clay powder of air purification function is made up of following component by weight percentage:High viscous recessed Convex rod stone clay 35~60%, attapulite constant humidity amendment 10~35%, natural-minerals adsorptive filter medium 5~20%, Cacumen Platycladi 2 ~15%, alumina silicate fibre 1~5% and polyacrylamide 0.1~3%.
The attapulgite potter's clay powder with air purification function is applied on 2 25th, 2011 using by the present inventor " having the attapulgite potter's clay powder of air purification function ", Chinese patent Authorization Notice No. is:CN 102173743 B, Granted publication Day:On July 25th, 2012.
High viscous Concave-convex clay rod is to be glued using the attapulgite that the processing technique improving viscosity of attapulgite clay produces Soil, from the attapulgite clay of mining area exploitation, needs the weathering through 30~120 days;Modification processing method is:With weight Percentage ratio calculates, and takes the attapulgite clay after weathering 94~98%, is uniformly added into 2~6% sodium carbonate, common input leaching In bubble pond, clear water is added to carry out soaking ageing, soak time is 72~120 hours;Take the attapulgite clay after immersion, input It is stirred in blender, and by the attapulgite clay after stirring, is extruded into thin slice through extruder, its THICKNESS CONTROL is 0.5~2 Millimeter, attapulgite clay thin slice carries out dry in the sun, the attapulgite clay thin slice after dry in the sun, its water content≤15%;Dispensing Calculated in weight percent:Attapulgite clay 94~98% after dry in the sun, High hydrophilous resin 0.5~5% and cellulose 0.5~ 3%, above-mentioned dispensing is stirred, after stirring, in input grinding machine, carries out pulverizing, fineness of the particles≤0.074 millimeter;
Above-mentioned production technology is " to improve viscosity of attapulgite clay using filed in 20 days June in 2005 of the present inventor Processing technique ", Chinese patent Authorization Notice No. is:CN 1317067C, authorized announcement date:On May 23rd, 2007.
The detection method of high viscous Concave-convex clay rod:Take 28.0g attapulgite clay powder sample, add homogenizer In suspension cup, add 372g water, suspension cup is placed on homogenizer, stir under 11000 revs/min of rotating speed 20 minutes, then by the beaker that high-speed stirred sample suspension pours 250mL into, tested using NDJ-1 type rotating cylinder viscometer The viscosity of suspension, tested viscosity value >=2200 mPa s is high viscous Concave-convex clay rod.
6th, the dispensing of washable attapulgite photocatalytic spray liquid is made up of following component by weight percentage:Recessed after acidifying Convex rod stone clay 4~15%, high viscous Concave-convex clay rod 3~10%, nano titanium oxide 1~5%, white carbon 1~5%, receive Rice Ag-carried antibacterial powder 0.5~5%, nano magnesia 0.5~5%, nano zirconium dioxide 0~5%, nano aluminium oxide 0~5%, Nano zine oxide 0~5%, polyvinyl alcohol 0.5~5%, Polyethylene Glycol 0.1~3%, polydimethylsiloxane 0.1~2% and go Ionized water 50~82%;
The production method of washable attapulgite photocatalytic spray liquid:(1) the dispensing of washable attapulgite photocatalytic spray liquid is inputted Carry out strong stirring, dispersion and emulsifying in the high speed dispersor having operated, be then ground to erasable in input three-roll grinder Wash the semi-finished product of attapulgite photocatalytic spray liquid;(2) the semi-finished product of washable attapulgite photocatalytic spray liquid are inputted colloid mill In, carry out again disperseing, emulsifying, pulverizing, homogenizing, froth breaking and grinding;(3) the washable attapulgite photocatalytic spray liquid after grinding Granularity≤0.01 millimeter of middle solid particle, canned for washable attapulgite photocatalytic spray liquid.
Washable attapulgite photocatalytic spray liquid is using by " washable filed in the applicant on 07 29th, 2016 Attapulgite photocatalytic spray liquid ", Chinese Patent Application No. is:201610612590.2.
Heretofore described PCm is weight percentage.
Having in the attapulgite potter's clay powder of air purification function in the present invention has substantial amounts of micropore and activated carbon, has relatively Caking property well, plasticity, thixotropy, fire resistance and heat stability, can effectively adsorb formaldehyde in air, ammonia and benzene etc. and be harmful to Material.
It is primary raw material using the attapulgite potter's clay powder with air purification function, produce spheroidal and there is purify air work( The manioc waste lightweight through hole haydite of energy, has given full play to the effective efficiency of the attapulgite potter's clay powder with air purification function.
Organic matter in manioc waste, cellulose, hemicellulose and lignin, in roasting process, can improve combustion-gas flow Heat, not only can save energy, also help the manioc waste lightweight through hole haydite hair that spheroidal is had air purification function The inside of blank can be grilled thoroughly completely;Improve the adsorptivity that spheroidal has the manioc waste lightweight through hole haydite of air purification function Can, reduce bulk density and increase the porosity within manioc waste lightweight through hole haydite that spheroidal has air purification function.
In roasting process, the lipid in active white clay waste slag and organic common spheroidal of participating in have active white clay waste slag Have the roasting of the manioc waste lightweight through hole haydite of air purification function, improve the heat of combustion-gas flow, not only can save energy, The inside also helping the manioc waste lightweight through hole haydite that spheroidal has air purification function can be grilled thoroughly completely, increases spheroidal There is the porosity within manioc waste lightweight through hole haydite of air purification function.
White carbon, light magnesium oxide, activated alumina and sodium aluminate can improve the wood that spheroidal has air purification function The absorbability of potato slag lightweight through hole haydite and increase spheroidal have the manioc waste lightweight through hole haydite of air purification function Granule strength.
Spheroidal has in the dispensing of manioc waste lightweight through hole semi-finished product of air purification function and adopts dodecyl Sodium sulfate, is conducive to produce substantial amounts of foam in stirring mixed process, has air purification function to increase spheroidal Micropore within manioc waste lightweight through hole haydite.
Precipitated calcium carbonate, gesso, cenosphere and expanded perlite can reduce spheroidal and have air purification function Manioc waste lightweight through hole haydite bulk density, increase spheroidal and there is the manioc waste lightweight through hole haydite of air purification function Internal porosity.
The spheroidal sucking washable attapulgite photocatalytic spray liquid has the manioc waste lightweight through hole of air purification function Semi-finished product, has the manioc waste lightweight through hole haydite of air purification function, in the irradiation of light after drying for spheroidal Under, spheroidal have air purification function manioc waste lightweight through hole haydite can continual absorption and degradation of formaldehyde, ammonia, The pollutant such as benzene and TVOC, and there is extremely strong sterilization, the function of deodorization, mould proof, anti-fouling and self-cleaning and purify air.
The manioc waste lightweight through hole haydite blank material moisture content that spheroidal after extruder grain has air purification function is big In 30%, it is delivered directly to swinging roaster high temperature roasting, in high-temperature calcination process, the surface of haydite blank material is first opened Beginning sintering curing, and the water vapour of inside is difficult to rapid evaporation out, haydite blank material will produce explosion, nor can be by Grill thoroughly inside haydite blank material.
The manioc waste lightweight through hole haydite blank material that spheroidal is first had air purification function by the present invention is transported to revolution Slowly carry out prebake in formula drying oven, drying temperature controls at 150~250 DEG C, then the spheroidal after drying is had purification The manioc waste lightweight through hole haydite blank material of air function is transported to swinging roasting kiln roasting, and the temperature control of combustor exists 900~950 DEG C it can be ensured that have the manioc waste lightweight through hole haydite hair of air purification function in roasting process by spheroidal Blank is grilled thoroughly, and will not produce explosion.
Spheroidal after roasting has in the manioc waste lightweight through hole haydite blank material of air purification function in temperature still Up to more than 700 DEG C, the spheroidal after roasting had the manioc waste lightweight through hole haydite blank material input of air purification function It is incubated in rustless steel cylinder storehouse, it is possible to use the waste heat of itself, the manioc waste continuing spheroidal is had air purification function is light Matter through hole haydite blank material uniformly heats, and not only can ensure that the manioc waste lightweight through hole pottery that spheroidal has air purification function Grill thoroughly completely moreover it is possible to play the effect of uniformly dispersing heat inside grain blank material, to improve spheroidal, there is air purification function Manioc waste lightweight through hole haydite blank material inherent quality.
Spheroidal has a manioc waste lightweight through hole haydite blank material surface of air purification function and inside have substantial amounts of micro- Hole, is a kind of open pore, open pore not only each other insertion also communicate with the external world, spheroidal has the manioc waste of air purification function The macropore at lightweight through hole haydite blank material center is a kind of through hole, is conducive in roasting process, can haydite internal completely Grill thoroughly, and effective ratio area, intensity and the reduction bulk density of haydite can be increased.
The manioc waste lightweight through hole haydite that spheroidal has air purification function has that specific surface area is big, bulk density is low, The feature that hydroscopicity is high, absorption property is superior, appearance and modeling free from extraneous odour attractive in appearance, lightweight intensity are good, micropore and macropore are integrated, circle The spherical manioc waste lightweight through hole haydite with air purification function does not have dust in the dry state, can adsorb in the air big The pollutant such as the formaldehyde of amount, ammonia, benzene and TVOC, are immersed in all the year round in water and also will not produce disintegrate.
The spheroidal sucking washable attapulgite photocatalytic spray liquid has the manioc waste lightweight through hole of air purification function Haydite, be absorption on the basis of degraded, improve comprehensively spheroidal have air purification function manioc waste lightweight lead to Hole haydite absorption and the ability of purify air.
The manioc waste lightweight through hole haydite that spheroidal has air purification function uses through long, and absorption is a certain amount of Pollutant after, manioc waste photocatalyst degradation capability begins to decline, and can present saturation, using 90~100 DEG C of hot water, The spheroidal that will already be at saturation has the manioc waste lightweight through hole haydite of air purification function and carries out backwash, cleaning Stick to spheroidal and there is manioc waste photo-catalyst film or microgranule inside and outside the manioc waste lightweight through hole haydite of air purification function, After cleaning up, the new washable attapulgite photocatalytic spray liquid prepared sprays or is dipped into spheroidal and has purify air Inside and outside the manioc waste lightweight through hole haydite of function, and dried or dried, performance spheroidal can be continued there is purify air The effect of the manioc waste lightweight through hole haydite purify air of function.
The microgranule waste residue washing down can be used for planting bracketplant, Aloe, Folium Sansevieriae Trifasclatae, pocket Cortex cocois radiciss, Caulis Hederae Sinensiies and Epipremnum aureum (Linde et Andre) (Bunting.) In green plantss, the interior thing that stays not decomposed of microgranule waste residue slowly will be adsorbed by green plantss such as bracketplant, Aloe, Folium Sansevieriae Trifasclataes Decompose, new pollution will not be produced.
Spheroidal have air purification function manioc waste lightweight through hole haydite be applied to placement indoors, furniture cabinet, Vehicle, aircraft, ship, subway, tunnel, highway baffle, military installations, ornament materials, public place or other building In thing, carry out absorption and the pollutant such as degradation of formaldehyde, ammonia, benzene, TVOC, to reach the purpose of long-time purify air.
Brief description
Fig. 1 is the manioc waste lightweight through hole haydite schematic diagram that spheroidal has air purification function, and Fig. 2 is that spheroidal has The manioc waste lightweight through hole haydite A-A profile of air purification function.
As shown in the figure:1 is the manioc waste lightweight through hole haydite that spheroidal has air purification function, and 2 is that spheroidal has The through hole of the manioc waste lightweight through hole haydite of air purification function.
Specific embodiment
With reference to embodiment, the invention will be further described:
1st, spheroidal has the dispensing of the manioc waste lightweight through hole haydite 1 of air purification function by weight percentage by following component Composition:Spheroidal has manioc waste lightweight through hole haydite 1 semi-finished product 88% of air purification function and washable attapulgite light touches Matchmaker's spray coating liquor 12%.
2nd, spheroidal has the production method of the manioc waste lightweight through hole haydite 1 of air purification function:(1) first will be washable Attapulgite photocatalytic spray liquid is put in fermentation vat, then spheroidal has the manioc waste lightweight through hole haydite 1 of air purification function Semi-finished product are slowly added in the washable attapulgite photocatalytic spray liquid in fermentation vat, and spheroidal has the wood of air purification function Micropore inside and outside potato slag lightweight through hole haydite 1 semi-finished product, constantly sucks washable attapulgite photocatalytic spray liquid, until in full And state;(2) take out from fermentation vat and be filled the spheroidal of washable attapulgite photocatalytic spray liquid there is air purification function Manioc waste lightweight through hole haydite 1, is transported in low temperature rotary drying oven and is dried, drying temperature controls 160~180 DEG C, drying time controlled at 2 hours;(3) the spheroidal after oven drying at low temperature had the manioc waste lightweight through hole of air purification function Haydite 1 is transported in flat vibrating screen and is sieved, and weeds out broken granule and powder, packs and have only for spheroidal Change the finished product of the manioc waste lightweight through hole haydite 1 of air function.
3rd, spheroidal has the dispensing of manioc waste lightweight through hole haydite 1 semi-finished product of air purification function by weight percentage It is made up of following component:Have the attapulgite potter's clay powder 38% of air purification function, manioc waste 12%, active white clay waste slag 4%, White carbon 3%, precipitated calcium carbonate 2%, light magnesium oxide 2%, activated alumina 2%, sodium aluminate 2%, cenosphere 1%, ripe Gypsum Fibrosum powder 1%, expanded perlite 1%, sodium lauryl sulphate 2% and water 30%.
4th, spheroidal has the production method of manioc waste lightweight through hole haydite 1 semi-finished product of air purification function:(1) will justify The stirring mixer that the dispensing input of spherical manioc waste lightweight through hole haydite 1 semi-finished product with air purification function has operated In, stirring is mixed into the mixture that spheroidal has the manioc waste lightweight through hole haydite 1 of air purification function;(2) spheroidal is had The mixture having the manioc waste lightweight through hole haydite 1 of air purification function is transported in Squeezinggranulator, and extruder grain is ball Shape has manioc waste lightweight through hole haydite 1 blank material of air purification function, and spheroidal has the manioc waste of air purification function The macropore at lightweight through hole haydite 1 blank material center is through hole 2;(3) manioc waste lightweight spheroidal being had air purification function is led to Hole haydite 1 blank material is transported in swinging drying oven is dried, and drying temperature controls at 220~240 DEG C, drying time control System was at 2 hours;(4) manioc waste lightweight through hole haydite 1 blank material spheroidal after drying being had air purification function is transported to Swinging roasting kiln roasting, at 900~920 DEG C, roasting time controlled at 1 hour the temperature control of combustor;(5) by roasting Spheroidal afterwards has manioc waste lightweight through hole haydite 1 blank material of air purification function, and input is incubated in rustless steel cylinder storehouse, Temperature retention time controlled at 48 hours;(6) the spheroidal after insulation cooling had the manioc waste lightweight through hole pottery of air purification function Grain 1 blank material is transported in roller vibrating screen is sieved, and weeds out broken granule and powder and has purification sky for spheroidal Manioc waste lightweight through hole haydite 1 semi-finished product of airway dysfunction.

Claims (3)

1. a kind of spheroidal has the manioc waste lightweight through hole haydite of air purification function it is characterised in that spheroidal has only The dispensing changing the manioc waste lightweight through hole haydite of air function is made up of following component by weight percentage:Spheroidal has purification The manioc waste lightweight through hole semi-finished product 55~95% of air function and washable attapulgite photocatalytic spray liquid 5~45%;
Described spheroidal have the dispensing of the manioc waste lightweight through hole semi-finished product of air purification function by weight percentage by Following component forms:There is the attapulgite potter's clay powder 10~45% of air purification function, manioc waste 5~25%, active hargil give up Slag 2~10%, white carbon 1~8%, precipitated calcium carbonate 1~5%, light magnesium oxide 1~5%, activated alumina 1~5%, aluminum Sour sodium 0.5~5%, cenosphere 0.5~5%, gesso 0.5~5%, expanded perlite 0.5~5%, dodecyl sulfur Sour sodium 0.5~5% and water 10~40%;
Spheroidal has the production method of the manioc waste lightweight through hole semi-finished product of air purification function:(1) spheroidal is had In the stirring mixer that the dispensing input of the manioc waste lightweight through hole semi-finished product of air purification function has operated, stirring is mixed It is combined into the mixture that spheroidal has the manioc waste lightweight through hole haydite of air purification function;(2) spheroidal had purify air The mixture of the manioc waste lightweight through hole haydite of function is transported in Squeezinggranulator, and it is empty that extruder grain has purification for spheroidal The manioc waste lightweight through hole haydite blank material of airway dysfunction, spheroidal has the manioc waste lightweight through hole haydite hair of air purification function The macropore at blank center is through hole;(3) spheroidal had the manioc waste lightweight through hole haydite blank material conveying of air purification function Dried in swinging drying oven, drying temperature controls at 200~250 DEG C, and drying time controlled at 1~4 hour;(4) will The manioc waste lightweight through hole haydite blank material that spheroidal after drying has air purification function is transported in swinging roaster Roasting, at 900~950 DEG C, roasting time controlled at 1~3 hour the temperature control of combustor;(5) the spheroidal after roasting is had There is the manioc waste lightweight through hole haydite blank material of air purification function, input is incubated in rustless steel cylinder storehouse, and temperature retention time controls At 24~72 hours;(6) the spheroidal after insulation cooling had the manioc waste lightweight through hole haydite blank material of air purification function It is transported in roller vibrating screen and is sieved, weed out the wood that broken granule and powder have air purification function for spheroidal Potato slag lightweight through hole semi-finished product;
The dispensing of described washable attapulgite photocatalytic spray liquid is made up of following component by weight percentage:Concavo-convex after acidifying Excellent stone clay 4~15%, high viscous Concave-convex clay rod 3~10%, nano titanium oxide 1~5%, white carbon 1~5%, nanometer Ag-carried antibacterial powder 0.5~5%, nano magnesia 0.5~5%, nano zirconium dioxide 0~5%, nano aluminium oxide 0~5%, receive Rice zinc oxide 0~5%, polyvinyl alcohol 0.5~5%, Polyethylene Glycol 0.1~3%, polydimethylsiloxane 0.1~2% and go from Sub- water 50~82%;
The production method of washable attapulgite photocatalytic spray liquid:(1) the dispensing of washable attapulgite photocatalytic spray liquid is inputted Carry out strong stirring, dispersion and emulsifying in the high speed dispersor having operated, be then ground to erasable in input three-roll grinder Wash the semi-finished product of attapulgite photocatalytic spray liquid;(2) the semi-finished product of washable attapulgite photocatalytic spray liquid are inputted colloid mill In, carry out again disperseing, emulsifying, pulverizing, homogenizing, froth breaking and grinding;(3) the washable attapulgite photocatalytic spray liquid after grinding Granularity≤0.01 millimeter of middle solid particle, canned for washable attapulgite photocatalytic spray liquid.
2. spheroidal according to claim 1 has the manioc waste lightweight through hole haydite of air purification function, and its feature exists In, there is fineness of the particles≤0.074 millimeter of the attapulgite potter's clay powder of air purification function, the fineness of the particles of manioc waste≤ 0.074 millimeter, fineness of the particles≤0.149 millimeter of active white clay waste slag, fineness of the particles≤0.074 millimeter of precipitated calcium carbonate, Fineness of the particles≤0.074 millimeter of light magnesium oxide, fineness of the particles≤0.074 millimeter of activated alumina, the granule of sodium aluminate Fineness≤0.074 millimeter, fineness of the particles≤0.149 millimeter of cenosphere, fineness of the particles≤0.074 millimeter of gesso, Fineness of the particles≤0.074 millimeter of expanded perlite.
3. spheroidal according to claim 1 has the manioc waste lightweight through hole haydite of air purification function, and its feature exists In spheroidal has the production method of the manioc waste lightweight through hole haydite of air purification function:(1) first by washable attapulgite light Catalyzed spraying liquid is put in fermentation vat, then the manioc waste lightweight through hole semi-finished product that spheroidal is had air purification function is delayed In the slow washable attapulgite photocatalytic spray liquid adding in fermentation vat, spheroidal has the manioc waste lightweight of air purification function Micropore inside and outside through hole semi-finished product, constantly sucks washable attapulgite photocatalytic spray liquid, until in saturation;⑵ From fermentation vat take out be filled washable attapulgite photocatalytic spray liquid spheroidal have air purification function manioc waste light Matter through hole haydite, is transported in low temperature rotary drying oven and is dried, and drying temperature controls at 150~180 DEG C, drying time Control at 1~3 hour;(3) the spheroidal after oven drying at low temperature had the manioc waste lightweight through hole haydite conveying of air purification function Sieved in flat vibrating screen, weeded out broken granule and powder, pack, for spheroidal, there is purify air work( The finished product of the manioc waste lightweight through hole haydite of energy.
CN201610847332.2A 2016-09-24 2016-09-24 Spherical light cassava-residue ceramsite with air purification function and through holes Pending CN106431304A (en)

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WD01 Invention patent application deemed withdrawn after publication