CN106430969A - Method for improving glossiness of glaze-surface of glazed tile - Google Patents

Method for improving glossiness of glaze-surface of glazed tile Download PDF

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Publication number
CN106430969A
CN106430969A CN201610736820.6A CN201610736820A CN106430969A CN 106430969 A CN106430969 A CN 106430969A CN 201610736820 A CN201610736820 A CN 201610736820A CN 106430969 A CN106430969 A CN 106430969A
Authority
CN
China
Prior art keywords
glaze
light
sodium
adobe
glazed tile
Prior art date
Application number
CN201610736820.6A
Other languages
Chinese (zh)
Inventor
叶德林
洪卫
李辉
黄诗程
谢石长
Original Assignee
佛山市三水新明珠建陶工业有限公司
广东新明珠陶瓷集团有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by 佛山市三水新明珠建陶工业有限公司, 广东新明珠陶瓷集团有限公司 filed Critical 佛山市三水新明珠建陶工业有限公司
Priority to CN201610736820.6A priority Critical patent/CN106430969A/en
Publication of CN106430969A publication Critical patent/CN106430969A/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02Frit compositions, i.e. in a powdered or comminuted form
    • C03C8/10Frit compositions, i.e. in a powdered or comminuted form containing lead
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/89Coating or impregnation for obtaining at least two superposed coatings having different compositions

Abstract

The invention provides a method for improving glossiness of the glaze-surface of a glazed tile. The method comprises the steps that after ground glaze is applied to the glazed tile and surface glaze is sprayed on the glazed tile, and a layer of sodium-containing glossy glaze layer is subjected to roll printing through a roller. The sodium-containing glossy glaze layer is prepared from 100 parts of roller printing ink, 1%-20% of sodium chloride and 1%-70% of glazed base powder, and preferably prepared from 100 parts of roller printing ink, 5% of sodium chloride and 20% of glazed base powder. When the light glazed tile is produced, sometimes the glossiness of the glaze-surface of the light glazed tile is insufficient, or fusion cakes and raw materials of some batches are insufficient in sintering gloss, the problem that the gloss of the glaze-surface is insufficient can be well solved by means of the method, and the effectiveness of treating the fusion cakes or the raw materials which have the gloss problem is particularly obvious.

Description

A kind of method improving glazed tile glaze paint glossiness
Technical field
The invention belongs to ceramic building decoration material field is and in particular to a kind of side improving glazed tile glaze paint glossiness Method.
Background technology
In prior art, the glossiness of glazed tile to be increased, the main method adopting has:A, adjustment cover-coat enamel formula make glass Mutually increase;B, adjustment kiln sintering curve;C, glaze mirror polish, etc. means.But, all there is very big deficiency in the above method.
Method A adjustment cover-coat enamel requires time for, and such as in ceramics produces, cover-coat enamel primary raw material is frit (is raw material through joining Material is blended in 1500 about and is melt into the particle that glass metal flows out water quenching one-tenth), frit accounts for 95% in formula sometimes.In glaze kiln If when find that glossiness is bad, need to return again to Cinker clew furnace adjustment frit formula, normal condition frit all can standby stock 1~3 day Amount.Glaze kiln and Cinker clew furnace are all continuous production, and the process product of formula adjustment process and Cinker clew furnace side of changing itself also can Output transitional product, the transitional product that stock was produced with the later stage all belongs to substandard products.Adjust big production again through formula test, normally melt Block out also needs to test through properties, and the aspect such as bag brick, compression strength, heat endurance is tested, and qualified could put into life Produce.As can be seen here, the method for adjustment cover-coat enamel formula require time for and also the waste that produces greatly, it is difficult to meet normal production Quick needs.
Although method B can to a certain degree solve the problems, such as gloss, kiln is adjusted also to belong to systemic engineering, a glaze kiln can Several glaze lines can be had to enter brick, the product that every glaze line does is different, and some specifications are different, product fancy is different, also bright Light and sub- light multifuel combustion, when a glaze line occur gloss bad when, you adjust kiln and burn till the product that can affect that other glaze lines enter brick. In addition the lagging property of adjustment that kiln burns till, needs the product that even could pass through to burn till after 1 hour 2 hours after 0.5 hour Determine whether to change, and in this period, the not mass change of method guarantee product.
Method C needs to set up a lot of equipment, and operation slightly complicated is relatively costly, and some glazed tiles are not appropriate for throwing Light.
N105000916A discloses glazed tile and the preparation side that a kind of surface of shraff preparation has stone shape gloss Method, emphasis is to the formula composition of biscuit body, bottom, the composition of cover-coat enamel frit, bottom, different performance frit preferred and joining in cover-coat enamel Formula composition than, ground-coat enamel etc. is adjusted and optimizes, so that the shraff more than 50% for the interpolation in body recipe.This article Offer and employ above-mentioned method A, because adjustment cover-coat enamel needs the long period, thus do not only result in and put into production cost greatly, Er Qiezhou Phase is long.
Content of the invention
For solving the shortcoming and defect of prior art, the present invention provides a kind of method improving glazed tile glaze paint glossiness, The method includes the steps of:
1) adobe dispensing ball milling:Choose in order to prepare the adobe raw material of glaze for glazed tile, dispensing feeding ball mill is carried out Ball milling;
2) spraying and powder making is compressing:Described adobe raw material is carried out being spray-dried prepared adobe powder using spray drying tower Material, carries out adobe using described adobe powder and suppresses and be molded, prepared adobe;
3) biscuiting:Biscuit kiln is put in described adobe and burns till biscuit;
4) drench ground-coat enamel:Described biscuit spoons ground-coat enamel;
5) topped with light cover-coat enamel:Topped with light cover-coat enamel on described ground-coat enamel;
6) print has light glaze layer containing sodium:With roller, on the cover coat of biscuit, one layer of roll printing has light glaze layer containing sodium, obtains glaze paint Brick;
7) stamp:There is the surface printing of light glaze layer in glazed tile;
8) glaze firing:Glazed tile after stamp is put into glaze firing in glaze kiln;
9) by the glazed tile edging after glaze firing, it is classified and is packaged into finished product.
Preferably, described have light glaze layer to comprise roller stamp-pad ink, sodium chloride, have light original washing powder containing sodium;By roller stamp-pad ink, chlorination Sodium, there is light original washing powder to be respectively put in dispersion machine, be dispersed into fancy glaze, after mixing, obtain there is light glaze layer glaze containing sodium.
Preferably, the described composition having light glaze layer glaze to comprise following mass percent containing sodium:100 parts of roller stamp-pad ink, outward Plus sodium chloride 0~20%, outward added with light original washing powder 0~70%, it is 0% when additional sodium chloride is different with there being light original washing powder.
Preferably, the described composition having light glaze layer glaze to comprise following mass percent containing sodium:100 parts of roller stamp-pad ink, outward Plus sodium chloride 5%, outward added with light original washing powder 20%.
Preferably, the described composition having light glaze layer glaze to comprise following mass percent containing sodium:100 parts of roller stamp-pad ink, outward Plus sodium chloride 1~20%.
Preferably, the described composition having light glaze layer glaze to comprise following mass percent containing sodium:100 parts of roller stamp-pad ink, outward Added with light original washing powder 1~70%.
Preferably, the described raw material having light original washing powder include the composition of following mass percent:SiO250~60%, Al2O36~10%, CaO 5~8%, MgO 1~2%, K2O 3~5%, Na2O 0.2~1%, BaO 1~2%, B2O31 ~2%, ZnO 5~7%, PbO 0.5~2%.
Preferably, the described preparation method having a light original washing powder is as follows:Above-mentioned raw material are uniformly mixed by proportioning, warp Cinker clew furnace is melt into glass metal and flows out, cold through water quenching, makes frit granules, then presses the composition of following mass percent:Frit Particle 50~98%, air knife soil 1~5%, water 0.1~40%, sodium tripolyphosphate 0.1~0.5%, dispensing enters ball mill, ball milling After tail over as 0%, go out ball and sieve to be dried into original washing powder.
Preferably, the temperature of described Cinker clew furnace melting is 1450~1550 DEG C.
Preferably, after described dispensing enters ball mill ball milling, fineness is less than or equal to 325 mesh.
Preferably, described stamp can adopt the stamp mode such as silk screen, roller, ink-jet.
Preferably, carving of roller gray scale is pure gray scale 10~60.
Beneficial effect:
(1) present invention brick glaze face top layer introduce have light glaze layer to improve glaze paint gloss containing sodium while, to lower floor's glazed body Affect very little with the overall performance of brick, whole production technology is not required to big adjustment.
(2) this method has simple, fast feature, can greatly save time, cost-effective.
(3) present invention is especially prominent for the benefit processing some low gloss frits or raw material.
Brief description
Fig. 1 is the flow chart of steps of the inventive method.
Specific embodiment
Below in conjunction with the accompanying drawings the specific embodiment of the present invention is described in detail.
Embodiment 1
Specifically, the method improving glazed tile glaze paint glossiness comprises the steps:
1) adobe dispensing ball milling:Choose in order to prepare the adobe raw material of glaze for glazed tile, dispensing feeding ball mill is carried out Ball milling;
2) spraying and powder making is compressing:Described adobe raw material is carried out being spray-dried prepared adobe powder using spray drying tower Material, carries out adobe using described adobe powder and suppresses and be molded, prepared adobe;
3) biscuiting:Biscuit kiln is put in described adobe and burns till biscuit;
4) drench ground-coat enamel:Described biscuit spoons ground-coat enamel;
5) topped with light cover-coat enamel:Topped with light cover-coat enamel on described ground-coat enamel;
6) there is the preparation of light original washing powder:Raw material include SiO250%, Al2O36%, CaO 10%, MgO 2%, K2O 5%, Na2O 0.3%, BaO 1%, B2O31%, ZnO 5%, PbO 1%, above-mentioned raw material are pressed proportioning stirring mixing all Even, through Cinker clew furnace, 1450~1550 DEG C are melt into glass metal outflow, cold through water quenching, make frit granules, then press formula:Frit Particle 98%, air knife soil 1%, water 0.5%, sodium tripolyphosphate 0.5%, dispensing enters ball mill, tails over as 0%, go out ball after ball milling Sieve and be dried into original washing powder.Dispensing enters ball mill, and ball milling to fineness 325 mesh screen residue is 0%, goes out ball and sieve to be dried into original washing powder;
7) there is the preparation of light glaze layer containing sodium:By roller stamp-pad ink 100kg, additional sodium chloride 5%, outward added with 20% point of light original washing powder Do not put in dispersion machine and be dispersed into fancy glaze, after mixing, obtain there is light glaze layer glaze containing sodium;
8) with roller, on the cover coat of biscuit, one layer of roll printing has light glaze layer glaze containing sodium, obtains there is light glaze layer containing sodium;
9) stamp:There is the surface printing of light glaze layer with roller in glazed tile;
10) glaze firing:Glazed tile after stamp is put into glaze firing in glaze kiln;
11) by the glazed tile edging after glaze firing, it is classified and is packaged into finished product.
Embodiment 2
Specifically, the method improving glazed tile glaze paint glossiness comprises the steps:
1) adobe dispensing ball milling:Choose in order to prepare the adobe raw material of glaze for glazed tile, dispensing feeding ball mill is carried out Ball milling;
2) spraying and powder making is compressing:Described adobe raw material is carried out being spray-dried prepared adobe powder using spray drying tower Material, carries out adobe using described adobe powder and suppresses and be molded, prepared adobe;
3) biscuiting:Biscuit kiln is put in described adobe and burns till biscuit;
4) drench ground-coat enamel:Described biscuit spoons ground-coat enamel;
5) topped with light cover-coat enamel:Topped with light cover-coat enamel on described ground-coat enamel;
6) there is the preparation of light original washing powder:Raw material include SiO250%, Al2O38%, CaO 5%, MgO 2%, K2O 3%, Na2O 0.4%, BaO 1%, B2O31%, ZnO 5%, PbO 1%, above-mentioned raw material are pressed proportioning stirring mixing all Even, through Cinker clew furnace, 1450~1550 DEG C are melt into glass metal outflow, cold through water quenching, make frit granules, then press formula:Frit Particle 90%, air knife soil 5%, water 4.7%, sodium tripolyphosphate 0.3%, dispensing enters ball mill, tails over as 0%, go out ball after ball milling Sieve and be dried into original washing powder.
Dispensing enters ball mill, and ball milling to fineness 325 mesh screen residue is 0%, goes out ball and sieve to be dried into original washing powder;
7) there is the preparation of light glaze layer containing sodium:By roller stamp-pad ink 100kg, it is respectively put in dispersion machine added with light original washing powder 30% outward It is dispersed into fancy glaze, after mixing, obtain there is light glaze layer glaze containing sodium;
8) with roller, on the cover coat of biscuit, one layer of roll printing has light glaze layer glaze containing sodium, obtains there is light glaze layer containing sodium;
9) stamp:There is the surface printing of light glaze layer with roller in glazed tile;
10) glaze firing:Glazed tile after stamp is put into glaze firing in glaze kiln;
11) by the glazed tile edging after glaze firing, it is classified and is packaged into finished product.
Embodiment 3
Specifically, the method improving glazed tile glaze paint glossiness comprises the steps:
1) adobe dispensing ball milling:Choose in order to prepare the adobe raw material of glaze for glazed tile, dispensing feeding ball mill is carried out Ball milling;
2) spraying and powder making is compressing:Described adobe raw material is carried out being spray-dried prepared adobe powder using spray drying tower Material, carries out adobe using described adobe powder and suppresses and be molded, prepared adobe;
3) biscuiting:Biscuit kiln is put in described adobe and burns till biscuit;
4) drench ground-coat enamel:Described biscuit spoons ground-coat enamel;
5) topped with light cover-coat enamel:Topped with light cover-coat enamel on described ground-coat enamel;
6) there is the preparation of light glaze layer containing sodium:By roller stamp-pad ink 100kg, additional sodium chloride 10% is respectively put in dispersion machine and divides Dissipate into fancy glaze, after mixing, obtain there is light glaze layer glaze containing sodium;
7) with roller, on the cover coat of biscuit, one layer of roll printing has light glaze layer glaze containing sodium, obtains there is light glaze layer containing sodium;
8) stamp:There is the surface printing of light glaze layer with roller in glazed tile;
9) glaze firing:Glazed tile after stamp is put into glaze firing in glaze kiln;
10) by the glazed tile edging after glaze firing, it is classified and is packaged into finished product.
Embodiment 4
Specifically, the method improving glazed tile glaze paint glossiness comprises the steps:
1) adobe dispensing ball milling:Choose in order to prepare the adobe raw material of glaze for glazed tile, dispensing feeding ball mill is carried out Ball milling;
2) spraying and powder making is compressing:Described adobe raw material is carried out being spray-dried prepared adobe powder using spray drying tower Material, carries out adobe using described adobe powder and suppresses and be molded, prepared adobe;
3) biscuiting:Biscuit kiln is put in described adobe and burns till biscuit;
4) drench ground-coat enamel:Described biscuit spoons ground-coat enamel;
5) topped with light cover-coat enamel:Topped with light cover-coat enamel on described ground-coat enamel, obtain glazed tile;
6) stamp:There is the surface printing of light glaze layer with roller in glazed tile;
7) glaze firing:Glazed tile after stamp is put into glaze firing in glaze kiln;
8) by the glazed tile edging after glaze firing, it is classified and is packaged into finished product.
The glossiness detection of embodiment glazed tile:Surveyed using glossometer and take 5 on the glazed tile that every group of embodiment produces Place carries out glossiness measurement, takes the mean value of measurement result at 5 to represent the glossiness of every block of glazed tile.Measurement result such as following table institute Show, in table, glossometer reading is bigger, illustrate that the glossiness of glazed tile is better.
The glossiness test of table 1 embodiment glazed tile
Known by table 1, the glaze paint glossiness of the glazed tile that embodiment 1, embodiment 2 and embodiment 3 produce is all preferable, wherein, The glaze paint glossiness of the glazed tile of 1 group of production of embodiment is best.And embodiment 4 has light due to be not added with ratio of the present invention containing sodium Glaze layer, so the glazed tile glaze paint glossiness produced is relatively bad.Above-described embodiment illustrates, is had using the method for the present invention Beneficial to the glazed tile producing high glaze.
The announcement of book and teaching according to the above description, those skilled in the art in the invention can also be to above-mentioned embodiment party Formula is changed and is changed.Therefore, the invention is not limited in specific embodiment disclosed and described above, to invention In the scope of the claims that a little modifications and changes should also be as fall into the present invention.Although additionally, employing in this specification Some specific terms, but these terms are merely for convenience of description, do not constitute any restriction to the present invention.

Claims (10)

1. a kind of method improving glazed tile glaze paint glossiness is it is characterised in that the method includes the steps of:
1) adobe dispensing ball milling:Choose in order to prepare the adobe raw material of glaze for glazed tile, dispensing feeding ball mill is carried out ball milling;
2) spraying and powder making is compressing:Described adobe raw material is carried out being spray-dried prepared adobe powder using spray drying tower, Carry out adobe using described adobe powder to suppress and be molded, prepared adobe;
3) biscuiting:Biscuit kiln is put in described adobe and burns till biscuit;
4) drench ground-coat enamel:Described biscuit spoons ground-coat enamel;
5) topped with light cover-coat enamel:Topped with light cover-coat enamel on described ground-coat enamel;
6) print has light glaze layer containing sodium:With roller, on the cover coat of biscuit, one layer of roll printing has light glaze layer glaze containing sodium, obtains containing sodium There is light glaze layer;
7) stamp:There is the surface printing of light glaze layer in glazed tile;
8) glaze firing:Glazed tile after stamp is put into glaze firing in glaze kiln;
9) by the glazed tile edging after glaze firing, it is classified and is packaged into finished product.
2. method according to claim 1 is it is characterised in that described have light glaze layer glaze to comprise roller stamp-pad ink, chlorine containing sodium Change sodium, have light original washing powder;By roller stamp-pad ink, sodium chloride, there is light original washing powder to be respectively put in dispersion machine, be dispersed into fancy glaze, after mixing There is light glaze layer glaze to containing sodium.
3. method according to claim 2 is it is characterised in that described has light glaze layer to comprise following mass percent containing sodium Composition:100 parts of roller stamp-pad ink, additional sodium chloride 0~20%, outward added with light original washing powder 0~70%, additional sodium chloride and have light It is 0% when original washing powder is different.
4. method according to claim 3 is it is characterised in that described has light glaze layer to comprise following mass percent containing sodium Composition:100 parts of roller stamp-pad ink, additional sodium chloride 5%, outward added with light original washing powder 20%.
5. method according to claim 3 is it is characterised in that described has light glaze layer to comprise following mass percent containing sodium Composition:100 parts of roller stamp-pad ink, additional sodium chloride 1~20%.
6. method according to claim 3 is it is characterised in that described has light glaze layer to comprise following mass percent containing sodium Composition:100 parts of roller stamp-pad ink, outward added with light original washing powder 1~70%.
7. the method according to claim 2-4 or 6 any one is it is characterised in that the described raw material having light original washing powder include The composition of following mass percent:SiO250~60%, Al2O36~10%, CaO 5~8%, MgO 1~2%, K2O 3~ 5%, Na2O 0.2~1%, BaO 1~2%, B2O31~2%, ZnO 5~7%, PbO 0.5~2%.
8. method according to claim 7 is it is characterised in that the described preparation method having a light original washing powder is as follows:Will by right Ask the raw material described in 7 to be uniformly mixed by proportioning, be melt into glass metal through Cinker clew furnace and flow out, cold through water quenching, make frit Particle, then presses the formula of following mass percent:Frit granules 50~98%, air knife soil 1~5%, water 0.1~40%, three Polyphosphate sodium 0.1~0.5%, dispensing enters ball mill, tails over as 0% after ball milling, goes out ball and sieve to be dried into original washing powder.
9. method according to claim 8 is it is characterised in that the temperature of described Cinker clew furnace melting is 1450~1550 DEG C.
10. method according to claim 8 it is characterised in that after described dispensing enters ball mill ball milling fineness be less than Or it is equal to 325 mesh.
CN201610736820.6A 2016-08-26 2016-08-26 Method for improving glossiness of glaze-surface of glazed tile CN106430969A (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107324656A (en) * 2017-08-18 2017-11-07 佛山市石湾裕龙陶瓷有限公司 A kind of ceramic tile with antifouling glaze

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102951932A (en) * 2012-12-06 2013-03-06 广东金牌陶瓷有限公司 Ceramic chip and manufacturing method thereof
CN103086750A (en) * 2013-01-09 2013-05-08 佛山市三水新明珠建陶工业有限公司 Method for manufacturing glazed interior wall bricks with two glazed effects
CN105016787A (en) * 2015-07-10 2015-11-04 广东宏海陶瓷实业发展有限公司 Matte background and glossy pattern glazed tile manufactured by using polished slag and preparation method of matte background and glossy pattern glazed tile

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102951932A (en) * 2012-12-06 2013-03-06 广东金牌陶瓷有限公司 Ceramic chip and manufacturing method thereof
CN103086750A (en) * 2013-01-09 2013-05-08 佛山市三水新明珠建陶工业有限公司 Method for manufacturing glazed interior wall bricks with two glazed effects
CN105016787A (en) * 2015-07-10 2015-11-04 广东宏海陶瓷实业发展有限公司 Matte background and glossy pattern glazed tile manufactured by using polished slag and preparation method of matte background and glossy pattern glazed tile

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107324656A (en) * 2017-08-18 2017-11-07 佛山市石湾裕龙陶瓷有限公司 A kind of ceramic tile with antifouling glaze
CN107324656B (en) * 2017-08-18 2020-04-07 佛山市石湾裕龙陶瓷有限公司 Ceramic tile with antifouling glaze

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