CN106430432A - Rotational micro electrolytic industrial wastewater treatment device and treatment method - Google Patents

Rotational micro electrolytic industrial wastewater treatment device and treatment method Download PDF

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Publication number
CN106430432A
CN106430432A CN201610809900.XA CN201610809900A CN106430432A CN 106430432 A CN106430432 A CN 106430432A CN 201610809900 A CN201610809900 A CN 201610809900A CN 106430432 A CN106430432 A CN 106430432A
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CN
China
Prior art keywords
filler
filler assembly
reactive tank
waste water
industrial waste
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Pending
Application number
CN201610809900.XA
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Chinese (zh)
Inventor
张国闽
魏伟
胡明
宋祖威
刘龙
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Priority to CN201610809900.XA priority Critical patent/CN106430432A/en
Publication of CN106430432A publication Critical patent/CN106430432A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4672Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • C02F2001/46123Movable electrodes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/06Controlling or monitoring parameters in water treatment pH
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/14Maintenance of water treatment installations

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention discloses a rotational micro electrolytic industrial wastewater treatment device and a treatment method. The rotational micro electrolytic industrial wastewater treatment device comprises an Fe-C packing component, a rotating bracket, a pH meter, a reaction tank, dosing equipment and driving equipment, wherein the driving equipment is in driving connection with a central rotating shaft of the rotating bracket; the rotating bracket is erected on the reaction tank; the Fe-C packing component is uniformly fixed and distributed at a connecting end of the rotating bracket; the pH meter is arranged inside the reaction tank; and the dosing equipment is communicated with the reaction tank. The rotational micro electrolytic industrial wastewater treatment device and the treatment method, which are disclosed by the invention, are free of an air-blowing aeration system, and have the characteristics of being low in investment cost, stable in operation, convenient to maintain, good in economic property and the like.

Description

A kind of rotary light electrolysis industrial waste water disposal device and processing method
Technical field
The present invention relates to the technical field of sewage disposal, is particularly suited for Industrial Wastewater Treatment.
Background technology
Micro electrolysis tech be at present process high concentrated organic wastewater a kind of ideal technology, it be in cold situation Under, producing 1.2V potential difference using the micro-electrolysis material being filled in waste water itself carries out electrolysis process to waste water, to reach drop The purpose of solution organic pollution.Microelectrolysis processing waste water has just caused the concern of domestic and international environmental protection researcher since the birth, and Substantial amounts of research is carried out, has achieved a lot of patents and practical technique achievement.Recent years, microelectrolysis processing industrial wastewater develops Very rapid, be used for printing and dyeing, electroplated, the industrial wastewater such as petrochemical industry, pharmacy, gas washing, printed circuit board (PCB) are produced and Process engineering containing arsenic, fluoride waste, have received good economic benefit and environment protecting.Decolouring of the weak electrolysis mechanism to waste water There are the effect of good process, and the treatment of wastes with processes of wastes against one another, operating cost is low, therefore in China by with good prospects for commercial application.
Fe-C micro electrolysis are to utilize Principles of Metal Erosion, form the good process processed by galvanic element to waste water, also known as Internal electrolysis, Filtration with Iron Filings etc..Ferrum is become the iron ion (Fe of bivalence by corrosion2+) enter solution, the Fe of nascent state2+With Atom H has very high chemism, can change the structure of many Organic substances and characteristic in waste water, occurs Organic substance disconnected Chain, open loop etc. are acted on.Under acid aerobic condition, course of reaction produces hydroxide ion, and water outlet pH value is raised, and by Fe2+Oxygen The Fe that metaplasia becomes3+Gradually hydrolysis generates the big Fe (OH) of the degree of polymerization3Colloid flocculant, can effectively adsorb, condense in water Pollutant, form more stable flocculate (being also iron cement) and remove, so as to strengthen the clean-up effect to waste water.
Light electrolysis equipment is all fixed bed both at home and abroad at present, is characterized in simple structure, pushes away good fluidity, but exists many real Use sex chromosome mosaicism:One is that ferrum carbon filler is easily passivated, and inefficient, response speed is unhappy;Two is that bed body is easily hardened, causes short-circuit and dead Area;Three is that iron filings supplement high labor intensive.
For the shortcoming of traditional fixed bed, the present invention takes a series of technical measures such as rotary method, effectively overcomes Above fixed bed shortcoming, with certain realistic meaning.
Content of the invention
Goal of the invention:In order to overcome the deficiencies in the prior art, the present invention provides a kind of rotary light electrolysis industry Wastewater treatment equipment and processing method are without the need for blast aeration system, low, stable, easy to maintenance, economical with investment cost The features such as property is high.
Technical scheme:For achieving the above object, technical scheme is as follows:
A kind of rotary light electrolysis industrial waste water disposal device, including Fe-C filler assembly, runing rest, pH meter, reaction Groove, medicine machine and driving equipment, the central rotating shaft drive connection of the driving equipment and runing rest, the runing rest frame It is located on reactive tank, the Fe-C filler assembly is uniformly distributed and is fixed on the connection end of runing rest;The pH meter is arranged on In reactive tank, the medicine machine is connected with reactive tank.
Further, the runing rest includes support frame structure, fixed component and rotating shaft, and support frame as described above structure includes Some are uniformly distributed the support column being connected in rotating shaft, and the fixed component is annular frame, with equally distributed support column It is fixedly connected.
Further, the top of two neighboring support column is provided with Fe-C filler assembly.
Further, the top vertical welding of the support column arranges rustless steel connecting plate, the rustless steel connecting plate left side Right both sides are symmetrical arranged some screws, and the screw of the left and right sides is connected respectively the Fe-C filler assembly of both sides.
Further, the Fe-C filler assembly includes filler assembly and Fe-C filling ball, the Fe-C filling ball filling Be arranged on inside filler assembly, filling rate be 70~90% between.
Further, described filler component is trapezoidal prism structure for section, and prism is hexahedro for having several apertures Porous plate, porous panel aperture be less than Fe-C filler bulb diameter.
Further, notch is left at described filler component two ends, and the porous plate at described filler component two ends is for living Dynamic porous plate, the active multi-hole plate can be inserted in notch or be extracted.
A kind of rotary light electrolysis process for treating industrial waste water, specific as follows:
In one rotation period, first, Fe-C filler assembly is immersed in reactive tank, due to each side of Fe-C filler assembly Face has loose structure, and sewage is entered in Fe-C filler assembly quickly, and carries out micro-electrolysis reaction in Fe-C filler ball surface;
With the carrying out for rotating, Fe-C filler assembly leaves the water surface and gets into the air, Fe-C filler ball surface occur solid, Liquid, gas three-phase chemical reaction;
In rotation process, phase mutual friction and exchange position between Fe-C filling ball, are detained and absorption is in Fe-C filler ball surface Water and Fe-C filler assembly carry water and constantly drop to the water surface from Fe-C filler assembly, realize oxygenation in falling process;
Subsequently Fe-C filler assembly is reentered in reactive tank sewage, repeats said process;
According to pH value in reactive tank, dosing of the medicine machine to reactive tank can be controlled by pH meter, maintain in reactive tank PH is less than 6.
Beneficial effect:(1) in rotary micro-electrolysis device rotation process, in each Fe-C filler assembly, filling ball is continuous Alternately with more new position, phase mutual friction between filling ball so that filling ball surface passivated membrane and particle are constantly updated, it is ensured that useless Water is fully contacted with Fe-C filler, improves treatment effect.(2) Fe-C filler assembly is connected with rotation light electrolysis main body using nut Connect, each Fe-C filler assembly two ends is that active multi-hole plate, whole Fe-C filler assembly is readily disassembled, and supplements and change filler appearance Easily, easy to maintenance;(3) Fe-C filler assembly rotate to liquid level with upper bit when, there is Fe- on each Fe-C filler assembly surface C filler (solid phase), electrolyte solution (sewage, liquid phase) and the reaction of air (oxygen, gas phase) three-phase electrochemical, remove pollutant; (4) sewage can be carried from reactive tank to above reactive tank in Fe-C filler assembly rotary course, sewage falls because of action of gravity Aeration is obtained during dropping down onto the water surface, the effect with oxygenation;At the same time, constantly stir in Fe-C filler assembly rotary course Sewage in reactive tank, the dual function with stirring with electrochemical reaction.
Description of the drawings
Accompanying drawing 1 is shown that the device front view in the present invention;
Accompanying drawing 2 is shown that the device side view in the present invention;
Accompanying drawing 3 is shown that the Fe-C filler assembly in the present invention installs details enlarged drawing;
Accompanying drawing 4 is shown that the Fe-C filler assembly three-view diagram in the present invention and details enlarged drawing.
Specific embodiment
Below in conjunction with the accompanying drawings the present invention is further described.
As accompanying drawing 1,2,3 and 4, a kind of rotary light electrolysis industrial waste water disposal device, including Fe-C filler assembly 1, rotation Turn support, pH meter 4, reactive tank 5, medicine machine and driving equipment, the driving equipment is driven with the central rotating shaft of runing rest Connection, the runing rest is erected on reactive tank 5, and the Fe-C filler assembly 1 is uniformly distributed the company for being fixed on runing rest Connect on end;The pH meter is arranged in reactive tank 5, and the medicine machine is connected with reactive tank 5.
The runing rest includes support frame structure, fixed component 3 and rotating shaft 11, and support frame as described above structure includes some The support column 2 being connected in rotating shaft 12 is uniformly distributed, the fixed component 3 is annular frame, solid with equally distributed support column 2 Fixed connection.The top of two neighboring support column 2 is provided with Fe-C filler assembly 1.The top vertical welding of the support column 2 is arranged Rustless steel connecting plate, the rustless steel connecting plate left and right sides is symmetrical arranged some screws, and the screw of the left and right sides is corresponded to respectively It is connected with the Fe-C filler assembly 1 of both sides.The Fe-C filler assembly 1 includes filler assembly and Fe-C filling ball, the Fe-C Filling ball is filled with inside filler assembly, filling rate be 70~90% between.Corrosion-resistant plastic selected by described filler component, Described filler component is trapezoidal prism structure for section, the hexahedro porous plate for having several apertures of prism, porous plate hole Footpath is less than Fe-C filler bulb diameter.Notch, and the porous plate at described filler component two ends are left in described filler component two ends For active multi-hole plate 12, the active multi-hole plate 12 can be inserted in notch or be extracted.
Medicine machine includes dosing pump 7 and dosing tank 6, and the dosing tank 6 is connected with reactive tank 5 by dosing pump 7, described PH meter 4 carries controller, and the signal output part of the controller of pH meter 4 is connected with the signal input part of dosing pump 7, and moment control is anti- The pH value in groove 5 is answered less than 6.Meanwhile, motor 10 can control rotating shaft 11 according to inflow and oxidation effect with frequency conversion function Velocity of rotation.
Driving equipment includes motor 10 and drive mechanism 9, and the motor 10 is driven even with rotating shaft 11 by drive mechanism 9 Connect;And ensure to keep good sealing property between rotating shaft 11 and reactive tank 5 by black box 8.
A kind of rotary light electrolysis process for treating industrial waste water, specific as follows:
In one rotation period, first, Fe-C filler assembly 1 is immersed in reactive tank 5, as Fe-C filler assembly 1 is each Individual side has loose structure, and sewage is entered in Fe-C filler assembly 1 quickly, and it is anti-to carry out light electrolysis in Fe-C filler ball surface Should;
With the carrying out for rotating, Fe-C filler assembly 1 leaves the water surface and gets into the air, and occurs in Fe-C filler ball surface Solid, liquid, gas three-phase chemical reaction;
In rotation process, phase mutual friction and exchange position between Fe-C filling ball, are detained and absorption is in Fe-C filler ball surface Water and Fe-C filler assembly 1 carry water and constantly drop to the water surface from Fe-C filler assembly 1, realize oxygenation in falling process;
Subsequently Fe-C filler assembly 1 is reentered in reactive tank sewage, repeats said process;
According to pH value in reactive tank 5, dosing of the medicine machine to reactive tank 5 can be controlled by pH meter 4, maintain reactive tank 5 In pH be less than 6.
For ensureing the carrying out of Fe-C light electrolysis, in reactive tank 5, pH should be less than 6, can control adding for dosing pump 7 by pH meter 4 Dose.During light electrolysis are carried out, in Fe-C filling ball, Fe is constantly separated out, and filling ball constantly reduces, therefore, operation a period of time Afterwards, Fe-C filling ball in Fe-C filler assembly 1 need to be changed.During replacing, by Fe-C filler assembly 1 and rotary light electrolysis The nut that main body is fixed is turned on, and is proposed Fe-C filler assembly 1, is extracted the active multi-hole plate at 1 two ends of Fe-C filler assembly, you can enter Row Fe-C filling ball is changed and is added, and reinstalling rear Fe-C filler assembly 1 can be continuing with.
A kind of rotary light electrolysis process for treating industrial waste water in the present invention is applicable to Industrial Wastewater Treatment, especially The high concentration indegradable industrial effluent such as dyeing waste water.The present invention can improve the biodegradability of industrial wastewater without the need for blast aeration, Fe-C filler no blocks and is passivated risk, supplements and change filler easily, easy to maintenance.
The above is only the preferred embodiment of the present invention, it should be pointed out that:Ordinary skill people for the art For member, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications also should It is considered as protection scope of the present invention.

Claims (8)

1. a kind of rotary light electrolysis industrial waste water disposal device, it is characterised in that:Including Fe-C filler assembly (1), rotation Frame, pH meter (4), reactive tank (5), medicine machine and driving equipment, the driving equipment is driven with the central rotating shaft of runing rest Connection, the runing rest is erected on reactive tank (5), and Fe-C filler assembly (1) is uniformly distributed and is fixed on runing rest Connection end on;The pH meter is arranged in reactive tank (5), and the medicine machine is connected with reactive tank (5).
2. a kind of rotary light electrolysis industrial waste water disposal device according to claim 1, it is characterised in that:The rotation Support includes support frame structure, fixed component (3) and rotating shaft (11), and support frame as described above structure includes that some are uniformly distributed connection Support column (2) in rotating shaft (12), described fixed component (3) are to fix even annular frame, with equally distributed support column (2) Connect.
3. a kind of rotary light electrolysis industrial waste water disposal device according to claim 1 and 2, it is characterised in that:Adjacent The top of two support columns (2) is provided with Fe-C filler assembly (1).
4. a kind of rotary light electrolysis industrial waste water disposal device according to claim 3, it is characterised in that:The support The top vertical welding of post (2) arranges rustless steel connecting plate, and the rustless steel connecting plate left and right sides is symmetrical arranged some screws, The screw of the left and right sides is connected respectively the Fe-C filler assembly (1) of both sides.
5. a kind of rotary light electrolysis industrial waste water disposal device according to claim 1, it is characterised in that:The Fe-C Filler assembly (1) includes filler assembly and Fe-C filling ball, and the Fe-C filling ball is filled with inside filler assembly, filling Rate be 70~90% between.
6. a kind of rotary light electrolysis industrial waste water disposal device according to claim 5, it is characterised in that:Described filler Component is trapezoidal prism structure for section, the hexahedro porous plate for having several apertures of prism, and porous panel aperture is less than Fe- C filler bulb diameter.
7. a kind of rotary light electrolysis industrial waste water disposal device according to claim 6, it is characterised in that:Described filler Notch is left at component two ends, and the porous plate at described filler component two ends is active multi-hole plate (12), the activity porous Plate (12) can be inserted in notch or be extracted.
8. a kind of rotary light electrolysis process for treating industrial waste water, it is characterised in that:
In one rotation period, first, Fe-C filler assembly (1) is immersed in reactive tank (5), due to Fe-C filler assembly (1) Each side has loose structure, and sewage is entered in Fe-C filler assembly (1) quickly, and carries out micro- electricity in Fe-C filler ball surface Solution reaction;
With the carrying out for rotating, Fe-C filler assembly (1) leaves the water surface and gets into the air, Fe-C filler ball surface occur solid, Liquid, gas three-phase chemical reaction;
In rotation process, phase mutual friction and exchange position between Fe-C filling ball, be detained and absorption Fe-C filler ball surface water with And Fe-C filler assembly (1) carries water and constantly drops to the water surface from Fe-C filler assembly (1), realizes oxygenation in falling process;
Subsequently Fe-C filler assembly (1) is reentered in reactive tank sewage, repeats said process;
According to the interior pH value of reactive tank (5), dosing of the medicine machine to reactive tank (5) can be controlled by pH meter (4), maintain reactive tank (5) pH in is less than 6.
CN201610809900.XA 2016-09-08 2016-09-08 Rotational micro electrolytic industrial wastewater treatment device and treatment method Pending CN106430432A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109264833A (en) * 2018-11-30 2019-01-25 广州握胜环保科技有限公司 A kind of device making iron-carbon micro-electrolytic material automatic regeneration
CN111777239A (en) * 2020-07-30 2020-10-16 浙江华强环境科技有限公司 Printing and dyeing wastewater treatment system and method
CN112093857A (en) * 2020-08-03 2020-12-18 优德太湖水务(苏州)有限公司 Micro-electrolysis hardening prevention method
CN116282724A (en) * 2023-03-30 2023-06-23 临涣水务股份有限公司 Industrial wastewater recycling device for desalted water process

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109264833A (en) * 2018-11-30 2019-01-25 广州握胜环保科技有限公司 A kind of device making iron-carbon micro-electrolytic material automatic regeneration
CN111777239A (en) * 2020-07-30 2020-10-16 浙江华强环境科技有限公司 Printing and dyeing wastewater treatment system and method
CN112093857A (en) * 2020-08-03 2020-12-18 优德太湖水务(苏州)有限公司 Micro-electrolysis hardening prevention method
CN116282724A (en) * 2023-03-30 2023-06-23 临涣水务股份有限公司 Industrial wastewater recycling device for desalted water process

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