CN106422677A - Novel formaldehyde spray type absorption tower - Google Patents

Novel formaldehyde spray type absorption tower Download PDF

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Publication number
CN106422677A
CN106422677A CN201610766954.2A CN201610766954A CN106422677A CN 106422677 A CN106422677 A CN 106422677A CN 201610766954 A CN201610766954 A CN 201610766954A CN 106422677 A CN106422677 A CN 106422677A
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Prior art keywords
formaldehyde
tank body
absorption tower
group
absorption
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李正华
王健
李金良
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Anhui Jinhe Industrial Co Ltd
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Anhui Jinhe Industrial Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/18Absorbing units; Liquid distributors therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1487Removing organic compounds

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)

Abstract

本发明提供一种新型甲醛喷淋式吸收塔,它包括罐体(1),在罐体(1)顶端设有甲醛吸收液输入口(2),在罐体(1)底端设有甲醛吸收液回收口(3),所述的输入口(2)与回收口(3)之间通过循环管道(5)连通,且在循环管道(5)上设有泵体(4);在罐体(1)上的一侧设有甲醛工艺气进口(6);在罐体(1)内还间隔设有一组填料(9),其特征在于:在罐体(1)上的另一侧还设有一组甲醛吸收液进口(7),所述的甲醛吸收液进口(7)通过管道与循环管道(5)相连通。本发明结构简单、便于在现有设备上改造,可以有效提高产量降低消耗。

The invention provides a novel formaldehyde spray absorption tower, which includes a tank body (1), a formaldehyde absorption liquid input port (2) is provided at the top of the tank body (1), and a formaldehyde absorber is provided at the bottom end of the tank body (1). The absorption liquid recovery port (3), the input port (2) and the recovery port (3) are connected through the circulation pipe (5), and the pump body (4) is arranged on the circulation pipe (5); One side of the body (1) is provided with a formaldehyde process gas inlet (6); a group of fillers (9) are arranged at intervals in the tank body (1), and the feature is that: on the other side of the tank body (1) A group of formaldehyde absorbing liquid inlets (7) are also provided, and the formaldehyde absorbing liquid inlets (7) are connected to the circulation pipe (5) through pipes. The invention has a simple structure, is convenient for modification on existing equipment, and can effectively increase output and reduce consumption.

Description

一种新型甲醛喷淋式吸收塔A new formaldehyde spray absorption tower

技术领域:Technical field:

本发明涉及一种甲醛生产设备,具体地说就是一种新型甲醛喷淋式吸收塔。The invention relates to a formaldehyde production equipment, in particular to a novel formaldehyde spray absorption tower.

背景技术:Background technique:

目前甲醛生产工艺较为成熟,甲醛生产的关键过程为氧化、吸收两个工段,控制好这两个工段,那么整个生产过程就能稳定。At present, the formaldehyde production process is relatively mature. The key process of formaldehyde production is oxidation and absorption. If these two processes are well controlled, the entire production process will be stable.

一般情况下,压力是影响气液吸收的重要因素。但是在甲醛生产吸收中,由于甲醛在水中溶解度较大,因此只要吸收温度不高,在常压下也可完成吸收,因此不需要较大的压力。甲醛易溶于水,在实际生产中,甲醛吸收塔是利用水来吸收甲醛生成气的,而吸收塔的吸收效果直接影响了甲醛的含量以及消耗。一般来说,生产甲醛所用的吸收塔采用三段式填料塔结构、使用吸收液循环的方式来吸收甲醛气体,但是在实际操作中,时常由于循环液喷洒不均匀而导致沟流现象导致吸收效率降低,一般来说,填料塔的喷淋密度应控制40m3/m2·h 左右,过小或过大都会导致吸收效率降低、增加不必要的动力消耗,导致甲醛产量不达标且电耗增大。In general, pressure is an important factor affecting gas-liquid absorption. However, in the production and absorption of formaldehyde, since formaldehyde has a high solubility in water, as long as the absorption temperature is not high, the absorption can be completed under normal pressure, so no high pressure is required. Formaldehyde is easily soluble in water. In actual production, the formaldehyde absorption tower uses water to absorb formaldehyde to generate gas, and the absorption effect of the absorption tower directly affects the content and consumption of formaldehyde. Generally speaking, the absorption tower used in the production of formaldehyde adopts a three-stage packed tower structure and uses the absorption liquid circulation method to absorb formaldehyde gas. Generally speaking, the spray density of the packed tower should be controlled around 40m3/m2·h. If it is too small or too large, it will reduce the absorption efficiency and increase unnecessary power consumption, resulting in substandard formaldehyde production and increased power consumption.

发明内容:Invention content:

本发明就是为了克服现有技术中的不足,提供一种具有结构简单、使用方便、便于在现有设备上直接改造,且能有效提高产量降低消耗的新型甲醛喷淋式吸收塔。The purpose of the present invention is to overcome the deficiencies in the prior art, and provide a new type formaldehyde spray absorption tower with simple structure, convenient use, convenient for direct transformation on existing equipment, and capable of effectively increasing output and reducing consumption.

本发明提供以下技术方案:The invention provides the following technical solutions:

一种新型甲醛喷淋式吸收塔,它包括罐体,在罐体顶端设有甲醛吸收液输入口,在罐体底端设有甲醛吸收液回收口,所述的输入口与回收口之间通过循环管道连通,且在循环管道上设有泵体;在罐体上的一侧设有甲醛工艺气进口;在罐体内还间隔设有一组填料,其特征在于:在罐体上的另一侧还设有一组甲醛吸收液进口,所述的甲醛吸收液进口通过管道与循环管道相连通。A new type formaldehyde spray absorption tower, which includes a tank body, an input port for formaldehyde absorption liquid is provided at the top of the tank body, and a recovery port for formaldehyde absorption liquid is provided at the bottom end of the tank body, between the input port and the recovery port It is communicated through the circulation pipeline, and a pump body is provided on the circulation pipeline; a formaldehyde process gas inlet is provided on one side of the tank body; a group of packing is also arranged at intervals in the tank body, and the characteristic is that: on the other side of the tank body There is also a group of formaldehyde absorbing liquid inlets on the side, and the formaldehyde absorbing liquid inlets are connected with the circulation pipe through pipes.

在上述技术方案的基础上,还可以有以下进一步的技术方案:On the basis of above-mentioned technical scheme, also can have following further technical scheme:

所述的一组甲醛吸收液进口与所述的一组填料相对应,均位于填料底部。The group of formaldehyde absorbing liquid inlets corresponds to the group of fillers, and they are all located at the bottom of the fillers.

在位于罐体内侧的每个甲醛吸收液进口上均连通有一个与罐体横截面相对应的喷淋。Each formaldehyde absorbing liquid inlet located inside the tank body is connected with a spray corresponding to the cross section of the tank body.

在每根管道上均设有流量控制阀门。There are flow control valves on each pipe.

本发明的优点在于:The advantages of the present invention are:

本发明具有结构简单、使用方便、便于在现有设备上改造,且改造费用低廉等优点。特别是喷淋设置在填料下方,由于其喷淋量较为稳定,可以去除部分吸收塔填料,减少吸收塔阻力、增加喷淋密度,增加吸收效果,增加甲醛产量,又降低产品单耗。The invention has the advantages of simple structure, convenient use, convenient modification on existing equipment, low modification cost and the like. In particular, the spraying is set under the filler. Because of its relatively stable spray volume, part of the absorber filler can be removed, the resistance of the absorber can be reduced, the spray density can be increased, the absorption effect can be increased, the formaldehyde output can be increased, and the product unit consumption can be reduced.

附图说明:Description of drawings:

图1是本发明的结构示意图。Fig. 1 is a structural schematic diagram of the present invention.

具体实施方式:detailed description:

如图1所示,一种新型甲醛喷淋式吸收塔,它包括罐体1,在罐体1顶端设有甲醛吸收液输入口2,在罐体1底端设有甲醛吸收液回收口3,在所述的输入口2与回收口3之间通过循环管道5连通,在循环管道5上还设有甲醛吸收液注入口5a,且在循环管道5上设有泵体4。As shown in Figure 1, a new type of formaldehyde spray absorption tower, it includes a tank body 1, a formaldehyde absorption liquid input port 2 is provided at the top of the tank body 1, and a formaldehyde absorption liquid recovery port 3 is provided at the bottom end of the tank body 1 , between the input port 2 and the recovery port 3 are communicated through a circulation pipe 5, and a formaldehyde absorption liquid injection port 5a is also provided on the circulation pipe 5, and a pump body 4 is provided on the circulation pipe 5.

甲醛吸收液从甲醛吸收液注入口5a进入循环管道5,再从输入口2进入罐体1中,再从罐体1底端的回收口3流回循环管道5,并且在泵体4的作用下,再从输入口2进入罐体1中,从而形成一个循环回路。在泵体4一侧的循环管道5上还设有成品甲醛出口5b。The formaldehyde absorption liquid enters the circulation pipeline 5 from the formaldehyde absorption liquid injection port 5a, enters the tank body 1 from the input port 2, and then flows back to the circulation pipeline 5 from the recovery port 3 at the bottom of the tank body 1, and under the action of the pump body 4 , and then enter the tank 1 from the input port 2, thus forming a circulation loop. A finished formaldehyde outlet 5b is also provided on the circulation pipe 5 on one side of the pump body 4 .

在罐体1上的一侧设有甲醛工艺气进口6。以便甲醛工艺气进入罐体1内进行反应。A formaldehyde process gas inlet 6 is provided on one side of the tank body 1 . So that the formaldehyde process gas enters the tank body 1 for reaction.

在罐体1内还间隔设有一组成段分布的填料9,每段填料9均与罐体1的横截面向对应,且每段填料9之间均间隔有一定距离。In the tank body 1 there is also a set of fillers 9 distributed in sections at intervals, each section of fillers 9 corresponds to the cross-sectional direction of the tank body 1 , and there is a certain distance between each section of fillers 9 .

在罐体1的另一侧还设有一组甲醛吸收液进口7,所述的每个甲醛吸收液进口7均通过管道8与循环管道5相连通,在每根管道8上均设有流量控制阀门8a。On the other side of the tank body 1 is also provided with a group of formaldehyde absorbing liquid inlets 7, each of the formaldehyde absorbing liquid inlets 7 is connected to the circulation pipe 5 through a pipe 8, and each pipe 8 is provided with a flow control Valve 8a.

所述的一组甲醛吸收液进口7与所述的一组填料9相对应,每个甲醛吸收液进口7均位于填料9底部。在位于罐体1内侧的每个甲醛吸收液进口7上均连通有一个与罐体1横截面相对应的不锈钢圆形喷淋10。The group of formaldehyde absorbing liquid inlets 7 corresponds to the group of fillers 9 , and each formaldehyde absorbing liquid inlet 7 is located at the bottom of the filler 9 . A stainless steel circular spray 10 corresponding to the cross section of the tank body 1 is communicated with each formaldehyde absorbing liquid inlet 7 located inside the tank body 1 .

通过流量控制阀门8a可以控制管道8内的甲醛吸收液流量,进而保持喷淋密度维持在40m3/m2·h,从而避免喷淋密度过小或过大造成沟流现象,而且还可以通过控制流量,来控制每段填料9对甲醛吸收液吸收浓度,使其均保持在37%左右。Through the flow control valve 8a, the flow rate of the formaldehyde absorption liquid in the pipeline 8 can be controlled, and the spray density can be maintained at 40m3/m2 h, so as to avoid channeling caused by too small or too large spray density, and can also be controlled by controlling the flow rate. , to control the absorption concentration of the formaldehyde absorption solution for each section of filler 9, so that it is maintained at about 37%.

由于本发明增加了喷淋,通过喷淋又可以将甲醛吸收液均匀的喷洒到喷淋下方的填料上,改变了现有技术中单一的“漫灌式”甲醛吸收液输入方式。使得罐体内的每段填料对甲醛吸收液的吸收更加均匀,所以可适当减少吸收塔填料高度,从而降低了吸收塔阻力,减少系统阻力。同时提高了甲醛生产的稳定流畅,提高了产出,降低了消耗。Due to the addition of spraying in the present invention, the formaldehyde absorbing liquid can be evenly sprayed onto the filler below the spraying through spraying, which changes the single "flooding" formaldehyde absorbing liquid input mode in the prior art. It makes the absorption of the formaldehyde absorption liquid by each section of packing in the tank more uniform, so the height of the packing of the absorption tower can be appropriately reduced, thereby reducing the resistance of the absorption tower and reducing the resistance of the system. At the same time, the stability and smoothness of formaldehyde production are improved, the output is increased, and the consumption is reduced.

Claims (4)

1. a kind of novel methylene spray absorption tower, it includes tank body(1), in tank body(1)Top is provided with formaldehyde absorbent input Mouthful(2), in tank body(1)Bottom is provided with formaldehyde absorbent recovery port(3), described input port(2)With recovery port(3)Between pass through Circulating line(5)Connection, and in circulating line(5)It is provided with the pump housing(4);In tank body(1)On side be provided with formaldehyde process gas Import(6);In tank body(1)Inside also it is interval with one group of filler(9)It is characterised in that:In tank body(1)On opposite side be additionally provided with One group of formaldehyde absorbent import(7), described formaldehyde absorbent import(7)By pipeline(8)With circulating line(5)It is connected.
2. a kind of novel methylene spray absorption tower according to claim 1 it is characterised in that:One group of described formaldehyde Absorbing liquid import(7)With one group of described filler(9)Corresponding, it is respectively positioned on filler(9)Bottom.
3. a kind of novel methylene spray absorption tower according to claim 1 it is characterised in that:Positioned at tank body(1) Each formaldehyde absorbent import of inner side(7)On be all communicated with one and tank body(1)The corresponding spray in cross section(10).
4. a kind of novel methylene spray absorption tower according to claim 1 it is characterised in that:In every pipeline(8) On be equipped with flow control valve(8a).
CN201610766954.2A 2016-08-31 2016-08-31 Novel formaldehyde spray type absorption tower Pending CN106422677A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116789232A (en) * 2023-05-30 2023-09-22 常州大学 Integrated device for synchronously treating sulfur-containing wastewater and formaldehyde by electrochemical method and process thereof

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CN103949133A (en) * 2014-05-20 2014-07-30 江苏司能润滑科技有限公司 Waste gas treatment device and method for lubricating oil production line
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CN204522690U (en) * 2015-02-13 2015-08-05 山东迪赛机电有限公司 Tail gas cooling, purifying spray column
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CN105457459A (en) * 2015-12-25 2016-04-06 广东浚丰华科技有限公司 Organic waste gas purification device and method aiming at hardware production workshop
CN105617846A (en) * 2016-03-17 2016-06-01 北京汉清节能技术有限公司 Low concentration formaldehyde waste gas oxidation treatment process and special equipment
CN206152580U (en) * 2016-08-31 2017-05-10 安徽金禾实业股份有限公司 Novel formaldehyde fountain absorption tower

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102198361A (en) * 2011-05-19 2011-09-28 蒋超 Hydrogen chloride tail gas recovery equipment
CN103949133A (en) * 2014-05-20 2014-07-30 江苏司能润滑科技有限公司 Waste gas treatment device and method for lubricating oil production line
CN204159189U (en) * 2014-09-16 2015-02-18 江苏凯茂石化科技有限公司 Absorption tower device in a kind of silver-colored method high-concentration formaldehyde device
CN204522690U (en) * 2015-02-13 2015-08-05 山东迪赛机电有限公司 Tail gas cooling, purifying spray column
CN204563881U (en) * 2015-03-24 2015-08-19 江苏凯茂石化科技有限公司 A kind of high-concentration formaldehyde absorption tower
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CN206152580U (en) * 2016-08-31 2017-05-10 安徽金禾实业股份有限公司 Novel formaldehyde fountain absorption tower

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116789232A (en) * 2023-05-30 2023-09-22 常州大学 Integrated device for synchronously treating sulfur-containing wastewater and formaldehyde by electrochemical method and process thereof
CN116789232B (en) * 2023-05-30 2025-08-22 常州大学 An integrated device and process for simultaneously treating sulfur-containing wastewater and formaldehyde using an electrochemical method

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Application publication date: 20170222