CN106422150A - Far infrared anion nanometer solution - Google Patents

Far infrared anion nanometer solution Download PDF

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Publication number
CN106422150A
CN106422150A CN201610735137.0A CN201610735137A CN106422150A CN 106422150 A CN106422150 A CN 106422150A CN 201610735137 A CN201610735137 A CN 201610735137A CN 106422150 A CN106422150 A CN 106422150A
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CN
China
Prior art keywords
parts
far infrared
anion
negative ion
powder
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Pending
Application number
CN201610735137.0A
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Chinese (zh)
Inventor
谢洪涛
张小平
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Kunshan Times Environmental Protection Industry Co Ltd
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Kunshan Times Environmental Protection Industry Co Ltd
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Priority to CN201610735137.0A priority Critical patent/CN106422150A/en
Publication of CN106422150A publication Critical patent/CN106422150A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D3/00Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
    • A62D3/10Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by subjecting to electric or wave energy or particle or ionizing radiation
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D2101/00Harmful chemical substances made harmless, or less harmful, by effecting chemical change
    • A62D2101/20Organic substances
    • A62D2101/28Organic substances containing oxygen, sulfur, selenium or tellurium, i.e. chalcogen

Abstract

The invention discloses a far infrared anion nanometer solution. The far infrared anion nanometer solution is composed of the ingredients of, by weight, 100 parts of anion powder, 400 parts to 600 parts of distilled water, 6 parts to 8 parts of sodium polyacrylate, 12 parts to 15 parts of dodecyl polyglucoside, 4 parts to 6 parts of ethylene glycol, 10 parts to 12 parts of ethyleneurea, 4 parts to 6 parts of citric acid, 6 parts to 8 parts of zirconia, 12 parts to 15 parts of dodecyl dimethyl betaine, 15 parts to 18 parts of tert-butyl acetate, and 10 parts to 15 parts of alkoxy type titanate coupling agent. The ingredients are mixed and soaked for 2 days to 3 days, and then placed into a ball mill to be subjected to low-speed ball milling for 2 hours to 3 hours and high-speed ball milling for 40 minutes to 60 minutes, and the far infrared anion nanometer solution is obtained. According to the far infrared anion nanometer solution, a permanent nanoscale anion film is formed on the surface of a pollution source to decompose formaldehyde before formaldehyde escapes into the air, formaldehyde is prevented from causing harm to human bodies, anion release can be triggered only by slight changes of temperature and pressure without light irradiation under any room temperature states to decompose formaldehyde, and because the far infrared anion nanometer solution is colorless and odorless, the surfaces of furniture are not damaged.

Description

Far infrared negative ion nano liquid
Technical field
The present invention relates to air cleaning coating liquid field, and in particular to a kind of far infrared negative ion nano liquid.
Background technology
With the improvement of people's living standards, indoor decoration is throughout town and country, but the various ornament materials that decoration is used are such as: Plywood, coating, plastic, floor, cement etc. contain volatile harmful substance, the master of room air pollution in various degree Poisonous and harmful molecule is wanted to have formaldehyde, benzene, ammonia etc., indoor pollution has become one of top killer of human health.Therefore, how Within the time short to the greatest extent, comprehensive purifying the air of a room becomes the task of top priority.At present, the measure of purify air has:Anion is sent out Raw device dedusting technology, High-voltage electrostatic purification, active carbon adsorption technology and ozone purification technology etc..Comprehensive air above purifies skill Noxious substance can only typically be stored by art, but can not change, some measures such as anion and High-voltage electrostatic purification technology energy Remove smoke abatement well, but the pollution caused by chemistry, microorganism etc. is difficult to purify.E.g. lived with the catalysis in photocatalyst Gonosome system adopts impregnating slurry, sol-gel technique by TiO2Nanoparticle or thin film are carried in carrier surface and space, shape Become compound nanometer photocatalyst, which is uviol lamp to be fixed on metal gauze to constitute catalytic reactor, though room can be removed well Interior harmful gass, but using relatively limiting to, its function only indoors certain segment space have an effect, also cannot solve rapidly occupying The problem of the harmful gass such as indoor comprehensive elimination formaldehyde, benzene, ammonia.
Content of the invention
It is an object of the invention to provide a kind of far infrared negative ion nano liquid, the far infrared negative ion nano liquid is in pollution Source surface forms one layer of permanent nanoscale anionic film, is decomposed before formaldehyde ' escape ' in the air, it is to avoid harm people Body, irradiates without the need for light, under any room temperature state, as long as the slight variations for having temperature and pressure can trigger anion release, Decomposing formaldehyde, colourless, tasteless, do not destroy furniture surface.
For reaching above-mentioned purpose, the technical solution used in the present invention is:A kind of far infrared negative ion nano liquid, by following heavy The group of amount part is grouped into:
100 parts of anion powder,
400 ~ 600 parts of distilled water,
6 ~ 8 parts of sodium polyacrylate,
12 ~ 15 parts of Dodecyl Polyglucosides,
4 ~ 6 parts of ethylene glycol,
10 ~ 12 parts of 2- imidazolidinone,
4 ~ 6 parts of citric acid,
6 ~ 8 parts of zirconium oxide,
12 ~ 15 parts of empgen BB,
Hydroxyl lactyl-lactic acid closes 15 ~ 18 parts of titanium,
10 ~ 15 parts of Monoalkoxy-titanates coupling agent;
By 100 parts of the anion powder, 400 ~ 600 parts of distilled water, 6 ~ 8 parts of sodium polyacrylate, Dodecyl Polyglucosides 12 ~ 15 Part, 4 ~ 6 parts of ethylene glycol, 10 ~ 12 parts of 2- imidazolidinone, 4 ~ 6 parts of citric acid, 6 ~ 8 parts of zirconium oxide, empgen BB 12 ~ 15 After part, hydroxyl lactyl-lactic acid close 15 ~ 18 parts of titanium and the mixing immersion 2 ~ 3 days of 10 ~ 15 parts of Monoalkoxy-titanates coupling agent, ball milling is put into Low velocity ball milling 2 ~ 3 hours in machine, then high speed ball milling obtains the far infrared negative ion nano liquid for 40 ~ 60 minutes;
The anion powder is obtained by following steps:
Step one, by nano-scale tourmaline powder, nanometer titanium dioxide titanium valve, sodium silicate, butanol and 2- alkyl acetoacetates amino-ethyl Imidazoline is added in autoclave, the nano-scale tourmaline powder and nanometer titanium dioxide titanium valve, sodium silicate, butanol and 2- Alkyl acetoacetates amino ethyl imidazoline mass ratio is 1:3~5:1.5~2:2~4:3 ~ 5, the slurry mixed liquor for preparing is carried out water Thermal response, the nano-scale tourmaline powder is by elbaite, dravite, iron tourmaline according to 10:2 ~4:6 ~ 9 weight portions Ratio is mixed;
Step 2, will filter through the reacted slurry mixed liquor of step one, and successively deionized water and washing with alcohol respectively The slurry mixed liquor that three times obtain after washing;
Step 3, drying:Baking oven in 80 DEG C ~ 150 DEG C drying is placed in again by complete for slurry mixed liquor sucking filtration after washing, finally To anion powder.
The further improved technical scheme of technique scheme is as follows:
1., in such scheme, it is 20h ~ 60h 150 DEG C ~ 250 DEG C, time that in the step one, hydrothermal temperature is.
2., in such scheme, the low velocity of the ball mill is 40 ~ 50 revs/min of balls, and the high speed of the ball mill is 300 ~ 500 revs/min.
3., in such scheme, the elbaite, dravite, the average diameter of iron tourmaline are 30 nanoscales.
Due to the utilization of technique scheme, the present invention has following advantages compared with prior art:
1. far infrared negative ion nano liquid of the present invention, which forms one layer of permanent nanoscale anionic film on polluter surface, in first Aldehyde is decomposed before ' escape ' in the air, it is to avoid harmful to human, is irradiated without the need for light, under any room temperature state, as long as having The slight variations of temperature and pressure can trigger anion and discharge, and decomposing formaldehyde is colourless, tasteless, does not destroy furniture surface;It is based on Specific anion powder embodies interpolation 2- imidazolidinone, Dodecyl Polyglucosides further and is more beneficial for hydroxyl radical free radical energy and nitrogen There is quick chain reaction in the air pollutants such as oxide, formaldehyde, toluene, harmful substance is converted into CO2、H2O or inorganic Salt, non-secondary pollution, after improvement, two weeks can move in, and save and dry in the air the time of blowing;And using by elbaite, dravite, ferrum Tourmaline is according to 10:2 ~4:6 ~ 9 weight ratios mix nano-scale tourmaline powder, can deeply be attached to pollutant table Face, eliminates formaldehyde no dead angle, using on become apparent from effect, more directly, interfacial effect is bigger, has further increased poison The adsorption rate of body, adsorptivity is higher, makes the nano thin-film to be formed more direct with body surface fusion.
2. far infrared negative ion nano liquid of the present invention, which adds zirconium oxide, sodium polyacrylate in formula further, and In conjunction with hydroxyl lactyl-lactic acid close 15 ~ 18 parts of titanium, 10 ~ 15 parts of Monoalkoxy-titanates coupling agent, be conducive to anion powder dispersion with Separate, resistivity is improve, improves environment anion burst size;Secondly, using using the negative of specific components and PROCESS FOR TREATMENT Ion powder body, improves the continuous action time, reaches more than 5 years.
Specific embodiment
Embodiment 1 ~ 4:A kind of far infrared negative ion nano liquid, is grouped into by the group of following weight portion, as shown in table 1:
Table 1
By 100 parts of the anion powder, 400 ~ 600 parts of distilled water, 6 ~ 8 parts of sodium polyacrylate, Dodecyl Polyglucosides 12 ~ 15 Part, 4 ~ 6 parts of ethylene glycol, 10 ~ 12 parts of 2- imidazolidinone, 4 ~ 6 parts of citric acid, 6 ~ 8 parts of zirconium oxide, empgen BB 12 ~ 15 After part, hydroxyl lactyl-lactic acid close 15 ~ 18 parts of titanium and the mixing immersion 2 ~ 3 days of 10 ~ 15 parts of Monoalkoxy-titanates coupling agent, ball milling is put into Low velocity ball milling 2 ~ 3 hours in machine, then high speed ball milling obtains the far infrared negative ion nano liquid for 40 ~ 60 minutes;
The anion powder is obtained by following steps:
Step one, by nano-scale tourmaline powder, nanometer titanium dioxide titanium valve, sodium silicate, butanol and 2- alkyl acetoacetates amino-ethyl Imidazoline is added in autoclave, the nano-scale tourmaline powder and nanometer titanium dioxide titanium valve, sodium silicate, butanol and 2- Alkyl acetoacetates amino ethyl imidazoline mass ratio is 1:3~5:1.5~2:2~4:3 ~ 5, the slurry mixed liquor for preparing is carried out water Thermal response, the nano-scale tourmaline powder is by elbaite, dravite, iron tourmaline according to 10:2 ~4:6 ~ 9 weight portions Ratio is mixed;
Step 2, will filter through the reacted slurry mixed liquor of step one, and successively deionized water and washing with alcohol respectively The slurry mixed liquor that three times obtain after washing;
Step 3, drying:Baking oven in 80 DEG C ~ 150 DEG C drying is placed in again by complete for slurry mixed liquor sucking filtration after washing, finally To anion powder.
It is 25h 160 DEG C, time that in embodiment 1, in step one, hydrothermal temperature is;Hydrothermal temperature in step one in embodiment 2 For 200 DEG C, the time is 30h;It is 25h 220 DEG C, time that in embodiment 3, in step one, hydrothermal temperature is;Step one in embodiment 4 Middle hydrothermal temperature is 180 DEG C, and the time is 40h;It is 42h 200 DEG C, time that in embodiment 5, in step one, hydrothermal temperature is.
The low velocity of above-mentioned ball mill is 40 or 45 revs/min of balls, the high speed of above-mentioned ball mill be 300 or 380 or 500 revs/min of person.
Above-mentioned elbaite, dravite, the average diameter of iron tourmaline are 30 nanoscales.
After the far infrared negative ion nano liquid coating of the preparation of the embodiment of the present invention 1 ~ 3, detect that the data of performance are as follows:
Table 2
During using above-mentioned far infrared negative ion nano liquid, which forms one layer of permanent nanoscale anionic film on polluter surface, Formaldehyde is decomposed before ' escape ' in the air, it is to avoid harmful to human, is irradiated without the need for light, under any room temperature state, as long as The slight variations for having temperature and pressure can trigger anion and discharge, and decomposing formaldehyde is colourless, tasteless, does not destroy furniture surface;Base In specific anion powder embody further add 2- imidazolidinone, Dodecyl Polyglucosides be more beneficial for hydroxyl radical free radical can be with There is quick chain reaction in the air pollutants such as nitrogen oxides, formaldehyde, toluene, harmful substance is converted into CO2、H2O or inorganic Salt, non-secondary pollution, after improvement, two weeks can move in, and save and dry in the air the time of blowing;And using by elbaite, dravite, ferrum Tourmaline is according to 10:2 ~4:6 ~ 9 weight ratios mix nano-scale tourmaline powder, can deeply be attached to pollutant table Face, eliminates formaldehyde no dead angle, using on become apparent from effect, more directly, interfacial effect is bigger, has further increased poison The adsorption rate of body, adsorptivity is higher, makes the nano thin-film to be formed more direct with body surface fusion;Again, which enters in formula One step adds zirconium oxide, sodium polyacrylate, and combine hydroxyl lactyl-lactic acid close 15 ~ 18 parts of titanium, Monoalkoxy-titanates coupling agent 10 ~ 15 parts, be conducive to anion powder dispersion and separate, resistivity is improve, improves environment anion burst size;Again, adopt Using specific components and the anion powder of PROCESS FOR TREATMENT, the continuous action time is improve, reach more than 5 years.
Above-described embodiment technology design only to illustrate the invention and feature, its object is to allow person skilled in the art Scholar will appreciate that present disclosure and implement according to this, can not be limited the scope of the invention with this.All according to the present invention Equivalence changes or modification that spirit is made, should all be included within the scope of the present invention.

Claims (4)

1. a kind of far infrared negative ion nano liquid, it is characterised in that:It is grouped into by the group of following weight portion:
100 parts of anion powder,
400 ~ 600 parts of distilled water,
6 ~ 8 parts of sodium polyacrylate,
12 ~ 15 parts of Dodecyl Polyglucosides,
4 ~ 6 parts of ethylene glycol,
10 ~ 12 parts of 2- imidazolidinone,
4 ~ 6 parts of citric acid,
6 ~ 8 parts of zirconium oxide,
12 ~ 15 parts of empgen BB,
Hydroxyl lactyl-lactic acid closes 15 ~ 18 parts of titanium,
10 ~ 15 parts of Monoalkoxy-titanates coupling agent;
By 100 parts of the anion powder, 400 ~ 600 parts of distilled water, 6 ~ 8 parts of sodium polyacrylate, Dodecyl Polyglucosides 12 ~ 15 Part, 4 ~ 6 parts of ethylene glycol, 10 ~ 12 parts of 2- imidazolidinone, 4 ~ 6 parts of citric acid, 6 ~ 8 parts of zirconium oxide, empgen BB 12 ~ 15 After part, hydroxyl lactyl-lactic acid close 15 ~ 18 parts of titanium and the mixing immersion 2 ~ 3 days of 10 ~ 15 parts of Monoalkoxy-titanates coupling agent, ball milling is put into Low velocity ball milling 2 ~ 3 hours in machine, then high speed ball milling obtains the far infrared negative ion nano liquid for 40 ~ 60 minutes;
The anion powder is obtained by following steps:
Step one, by nano-scale tourmaline powder, nanometer titanium dioxide titanium valve, sodium silicate, butanol and 2- alkyl acetoacetates amino-ethyl Imidazoline is added in autoclave, the nano-scale tourmaline powder and nanometer titanium dioxide titanium valve, sodium silicate, butanol and 2- Alkyl acetoacetates amino ethyl imidazoline mass ratio is 1:3~5:1.5~2:2~4:3 ~ 5, the slurry mixed liquor for preparing is carried out water Thermal response, the nano-scale tourmaline powder is by elbaite, dravite, iron tourmaline according to 10:2 ~4:6 ~ 9 weight portions Ratio is mixed;
Step 2, will filter through the reacted slurry mixed liquor of step one, and successively deionized water and washing with alcohol respectively The slurry mixed liquor that three times obtain after washing;
Step 3, drying:Baking oven in 80 DEG C ~ 150 DEG C drying is placed in again by complete for slurry mixed liquor sucking filtration after washing, finally To anion powder.
2. far infrared negative ion nano liquid according to claim 1, it is characterised in that:The low velocity of the ball mill is 40 ~ 50 revs/min of balls, the high speed of the ball mill is 300 ~ 500 revs/min.
3. far infrared negative ion nano liquid according to claim 1, it is characterised in that:The elbaite, dravite, The average diameter of iron tourmaline is 30 nanoscales.
4. far infrared negative ion nano liquid according to claim 1, it is characterised in that:In the step one, hydrothermal temperature is 150 DEG C ~ 250 DEG C, the time is 20h ~ 60h.
CN201610735137.0A 2016-08-29 2016-08-29 Far infrared anion nanometer solution Pending CN106422150A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108754777A (en) * 2018-06-28 2018-11-06 安徽鼎鑫纺织品有限公司 A kind of silk, kapok and blend polyester fabric
CN109112823A (en) * 2018-06-28 2019-01-01 安徽鼎鑫纺织品有限公司 A kind of wool blended fabric of terylene

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1310209A (en) * 2001-02-20 2001-08-29 上海硕华高科技产业有限公司 Health building paint intermediate and its preparation
CN1386550A (en) * 2002-07-08 2002-12-25 中国建筑材料科学研究院水泥科学与新型建筑材料研究所 Composition tourmaline powder able to effectively generate negative ions in air and its preparing process
US20100093874A1 (en) * 2007-04-05 2010-04-15 Rhodia Operations Copolymer including betaine units and hydrophobic and/or amphiphilic units, method for preparing same and uses thereof
CN104356793A (en) * 2014-11-14 2015-02-18 三棵树涂料股份有限公司 Multiplex aldehyde-removal internal wall latex paint and preparation method thereof
CN104845481A (en) * 2015-05-20 2015-08-19 上海韬鸿化工科技有限公司 Environment-friendly coating capable of removing formaldehyde

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1310209A (en) * 2001-02-20 2001-08-29 上海硕华高科技产业有限公司 Health building paint intermediate and its preparation
CN1386550A (en) * 2002-07-08 2002-12-25 中国建筑材料科学研究院水泥科学与新型建筑材料研究所 Composition tourmaline powder able to effectively generate negative ions in air and its preparing process
US20100093874A1 (en) * 2007-04-05 2010-04-15 Rhodia Operations Copolymer including betaine units and hydrophobic and/or amphiphilic units, method for preparing same and uses thereof
CN104356793A (en) * 2014-11-14 2015-02-18 三棵树涂料股份有限公司 Multiplex aldehyde-removal internal wall latex paint and preparation method thereof
CN104845481A (en) * 2015-05-20 2015-08-19 上海韬鸿化工科技有限公司 Environment-friendly coating capable of removing formaldehyde

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108754777A (en) * 2018-06-28 2018-11-06 安徽鼎鑫纺织品有限公司 A kind of silk, kapok and blend polyester fabric
CN109112823A (en) * 2018-06-28 2019-01-01 安徽鼎鑫纺织品有限公司 A kind of wool blended fabric of terylene

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Application publication date: 20170222

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