CN106396470A - Normal temperature early strength agent for 3D printing house slurry - Google Patents
Normal temperature early strength agent for 3D printing house slurry Download PDFInfo
- Publication number
- CN106396470A CN106396470A CN201610769129.8A CN201610769129A CN106396470A CN 106396470 A CN106396470 A CN 106396470A CN 201610769129 A CN201610769129 A CN 201610769129A CN 106396470 A CN106396470 A CN 106396470A
- Authority
- CN
- China
- Prior art keywords
- parts
- early strength
- strength agent
- temperature early
- printing house
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000010146 3D printing Methods 0.000 title claims abstract description 41
- 239000002002 slurry Substances 0.000 title abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 41
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L Calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims abstract description 18
- OYHQOLUKZRVURQ-IXWMQOLASA-N Linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 claims abstract description 18
- 239000000654 additive Substances 0.000 claims abstract description 18
- 230000000996 additive Effects 0.000 claims abstract description 18
- 239000000945 filler Substances 0.000 claims abstract description 11
- IYJYQHRNMMNLRH-UHFFFAOYSA-N Sodium aluminate Chemical compound [Na+].O=[Al-]=O IYJYQHRNMMNLRH-UHFFFAOYSA-N 0.000 claims abstract description 9
- 235000020778 linoleic acid Nutrition 0.000 claims abstract description 9
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 9
- 229910001388 sodium aluminate Inorganic materials 0.000 claims abstract description 9
- PMZURENOXWZQFD-UHFFFAOYSA-L na2so4 Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 4
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 25
- 239000000203 mixture Substances 0.000 claims description 18
- 239000012467 final product Substances 0.000 claims description 10
- 229920001592 potato starch Polymers 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- ARUVKPQLZAKDPS-UHFFFAOYSA-L Copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 8
- GUBGYTABKSRVRQ-PICCSMPSSA-N D-Maltose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 claims description 8
- 229910000366 copper(II) sulfate Inorganic materials 0.000 claims description 8
- 239000010802 sludge Substances 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 6
- 235000002595 Solanum tuberosum Nutrition 0.000 claims description 5
- 240000001016 Solanum tuberosum Species 0.000 claims description 5
- 229920001817 Agar Polymers 0.000 claims description 3
- 239000008272 agar Substances 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229920005610 lignin Polymers 0.000 claims description 3
- 229920005615 natural polymer Polymers 0.000 claims description 3
- 239000002689 soil Substances 0.000 claims description 3
- 241000609240 Ambelania acida Species 0.000 claims description 2
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 2
- -1 Pulvis Talci Substances 0.000 claims description 2
- 239000010905 bagasse Substances 0.000 claims description 2
- 239000006229 carbon black Substances 0.000 claims description 2
- 239000004917 carbon fiber Substances 0.000 claims description 2
- 235000013312 flour Nutrition 0.000 claims description 2
- 239000010439 graphite Substances 0.000 claims description 2
- 229910002804 graphite Inorganic materials 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 239000002861 polymer material Substances 0.000 claims 1
- 239000002994 raw material Substances 0.000 abstract description 16
- 238000009833 condensation Methods 0.000 abstract description 2
- 230000005494 condensation Effects 0.000 abstract description 2
- 239000002585 base Substances 0.000 description 13
- 239000004035 construction material Substances 0.000 description 13
- 239000004568 cement Substances 0.000 description 12
- 238000002156 mixing Methods 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000004567 concrete Substances 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 6
- PZZYQPZGQPZBDN-UHFFFAOYSA-N Aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 5
- 239000005995 Aluminium silicate Substances 0.000 description 5
- 235000012211 aluminium silicate Nutrition 0.000 description 5
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- WEEGYLXZBRQIMU-UHFFFAOYSA-N 1,8-cineole Chemical compound C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000010276 construction Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- 229940109501 Eucalyptol Drugs 0.000 description 2
- 239000011398 Portland cement Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 229960005233 cineole Drugs 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 229920002748 Basalt fiber Polymers 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N Silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229940006477 nitrate ion Drugs 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 231100000957 no side effect Toxicity 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/10—Accelerators; Activators
- C04B2103/12—Set accelerators
Abstract
The invention discloses a normal temperature early strength agent for 3D printing house slurry. The normal temperature early strength agent is prepared from the following component raw materials in parts by weight: 50 to 100 parts of anhydrous sodium sulfate, 1 to 7 parts of sodium aluminate, 10 to 20 parts of calcium sulfate, 5 to 10 parts of linoleic acid, 5 to 7 parts of 3-[(2,4-dichloro) phenyl]-2-acrylic acid, 10 to 20 parts of a filler and 1 to 3 parts of an additive. The normal temperature early strength agent is specially used for a 3D printing house, and can promote quick condensation and hardening of the 3D printing house slurry; furthermore, after the slurry is condensed, the intensity is higher than that of the conventional early strength agent; furthermore, all the raw materials of the early strength agent are low in cost, and the early strength agent is relatively wide in application range.
Description
Technical field
The present invention relates to a kind of room temperature early strength agent, particularly to a kind of 3D printing house slip room temperature early strength agent.
Background technology
3D printing technique, be a kind of based on mathematical model file, material can be bonded with powdery metal or plastics etc.
Material, carrys out the technology of constructed object by way of successively printing.Now, 3D printing technique has started to attempt building for house
Make.Compared with traditional architectural technology, the advantage of 3D printing Building technology is embodied in：Speed is soon fast 10 than traditional architectural technology
More than times；The complicated variation building that traditional approach is difficult to build can be produced, and without using template, reduce and be built into
This；It is not required to the builder of substantial amounts, reduce the security risk in construction；And decrease waste by-product, Ke Yiyou
The utilization construction material of effect, greatly reduces cement demand, can reduce building waste simultaneously, have the spy of low-carbon (LC), green, environmental protection
Point.
Due to building itself, building is in printing manufacture process and after the completion of manufacturing, to material therefor
Workability, mechanical property, feature, durability and economy etc. have specific requirement, and for present circumstances, cement mixes
Solidifying soil is still the first-selection manufacturing building, but due to printing the form of construction work built using no template, extrude and be superimposed molding,
The performance of construction material is put forward higher requirement, traditional cement concrete is not suitable as 3D printing construction material.
Although early strength agent produces and applicating history is longer, with people to chloride ion, sulfate ion, nitrate ion
With the intensification to concrete performance and the awareness of long-time stability potential hazard such as alkali metal ion, and large dosage slag
Powder or the exploitation of flyash concrete, also need to do substantial amounts of work in terms of early strength agent.3D printing construction material is typically adopted now
It is base material with cement, prepare a kind of cement base composite construction materials of suitable 3D printing, apply to 3D printing house technology.3D beats
Print construction material is different from the concrete of entity construction timber, and its material is more fine and smooth, seriality is more preferably it is adaptable to entity is built
The early strength agent of the concrete used by material is not suitable for the construction material used by 3D printing house, therefore, needs badly a kind of suitable now
Early strength agent for 3D printing house slip.
The information being disclosed in this background section is merely intended to increase the understanding of the general background to the present invention, and should not
Recognize when being considered or imply in any form that this information structure has been the prior art well known to persons skilled in the art.
Content of the invention
It is an object of the invention to provide a kind of room temperature early strength agent is it is intended to be used for 3D printing house slip purposes, the present invention
Early strength agent is environmentally friendly, during use, human body is had no side effect, and can promote the cement based used in the process of 3D printing house
Quick-hardening after construction material condensation.
For achieving the above object, the technical scheme that the present invention provides is as follows：
A kind of 3D printing house slip room temperature early strength agent, according to ratio of weight and number, comprises following components raw material：Anhydrous sulfur
50～100 parts of sour sodium, 1～7 part of sodium aluminate, 10～20 parts of calcium sulfate, 5～10 parts of linoleic acid, 3- [(2,4- dichloro) phenyl] -2-
5～7 parts of acrylic acid, 10～20 parts of filler and 1～3 part of additive.
Wherein, described filler is that Kaolin, kieselguhr, Pulvis Talci, graphite, white carbon black, mica powder, silica flour or carbon are fine
One of dimension.
Wherein, described additive is made up of pond sludge, malt sugar, anhydrous cupric sulfate and natural macromolecular material.
Wherein, described additive is according to ratio of weight and number, by 10～30 parts of pond sludge, 10～16 parts of malt sugar, anhydrous slufuric acid
5～9 parts of copper and 11～18 parts of compositions of natural macromolecular material.
Wherein, described natural macromolecular material is one of agar, lignin, bagasse or potato starch.
Wherein, described potato starch is 70～80 DEG C of drying 5～10min of fresh potato, breaks into powder, obtains final product.
3D printing house of the present invention slip room temperature early strength agent volume is the 1.5～4.5% of base material, and base material is 3D printing
The construction material concrete base building base material in house.
Compared with prior art, the present invention has the advantages that：
Room temperature early strength agent of the present invention is exclusively used in 3D printing house, quick-hardening after 3D printing house slip can be made to condense, and
Such slurry condense after strength development than conventional early strength agent faster；The each cost of material of further early strength agent of the present invention is low, is suitable for
Property is wider.
Specific embodiment
It is described in detail with reference to specific embodiment, it is to be understood that protection scope of the present invention is not subject to specifically
The restriction of embodiment.
Embodiment 1
A kind of 3D printing house slip room temperature early strength agent, in units of kg, weighs required each component raw material：Anhydrous sulfur
Sour sodium 100kg, sodium aluminate 7kg, calcium sulfate 20kg, linoleic acid 10kg, 3- [(2,4- dichloro) phenyl] -2- acrylic acid 7kg, filling
Agent carbon fiber 20kg and additive 3kg；Wherein, additive is by pond sludge 30kg, malt sugar 16kg, anhydrous cupric sulfate 9kg and natural height
Molecular material lignin 18kg mixing composition.Weigh the mixing of gained each component raw material by above-mentioned, stir, obtain final product.
Embodiment 2
A kind of 3D printing house slip room temperature early strength agent, in units of kg, weighs required each component raw material：Anhydrous sulfur
Sour sodium 50kg, sodium aluminate 1kg, calcium sulfate 10kg, linoleic acid 5kg, 3- [(2,4- dichloro) phenyl] -2- acrylic acid 5kg, filler
Kieselguhr 10kg and additive 1kg；Wherein, additive is by pond sludge 10kg, malt sugar 10kg, anhydrous cupric sulfate 5kg and natural polymer
Sub- material agar 11kg mixing composition.Weigh the mixing of gained each component raw material by above-mentioned, stir, obtain final product.
Embodiment 3
A kind of 3D printing house slip room temperature early strength agent, in units of kg, weighs required each component raw material：Anhydrous sulfur
Sour sodium 75kg, sodium aluminate 4kg, calcium sulfate 15kg, linoleic acid 7kg, 3- [(2,4- dichloro) phenyl] -2- acrylic acid 6kg, filler
Kaolin 15kg and additive 2kg；Wherein, additive is by pond sludge 20kg, malt sugar 13kg, anhydrous cupric sulfate 7kg and natural polymer
Sub- Material Potato starch 15kg mixing composition；Wherein, potato starch is 80 DEG C of drying 7min of fresh potato, breaks into powder
End, obtains final product.Weigh the mixing of gained each component raw material by above-mentioned, stir, obtain final product.
Embodiment 4
A kind of 3D printing house slip room temperature early strength agent, in units of kg, weighs required each component raw material：Anhydrous sulfur
Sour sodium 75kg, sodium aluminate 4kg, calcium sulfate 15kg, linoleic acid 7kg, 3- [(2,4- dichloro) phenyl] -2- acrylic acid 6kg, filler
Kaolin 15kg, additive 2kg, cineole 0.5kg；Wherein, additive is by pond sludge 20kg, malt sugar 13kg, anhydrous cupric sulfate 7kg
Mix composition with natural macromolecular material potato starch 15kg；Wherein, potato starch is 80 DEG C of drying of fresh potato
7min, breaks into powder, obtains final product.Weigh the mixing of gained each component raw material by above-mentioned, stir, obtain final product.
Embodiment 5
A kind of room temperature early strength agent, in units of kg, weighs required each component raw material：Anhydrous sodium sulfate 75kg, sodium aluminate
4kg, calcium sulfate 15kg, linoleic acid 7kg, filler Kaolin 15kg and additive 2kg；Wherein, additive is by pond sludge 20kg, sugar
Dilute 13kg, anhydrous cupric sulfate 7kg and natural macromolecular material potato starch 15kg mixing composition；Wherein, potato starch is
80 DEG C of drying 7min of fresh potato, break into powder, obtain final product.Weigh the mixing of gained each component raw material by above-mentioned, stir, that is,
?.
Embodiment 6
A kind of room temperature early strength agent, in units of kg, weighs required each component raw material：Anhydrous sodium sulfate 75kg, sodium aluminate
4kg, calcium sulfate 15kg, linoleic acid 7kg, 3- [(2,4- dichloro) phenyl] -2- acrylic acid 6kg and filler Kaolin 15kg.Will
The above-mentioned each component raw material of gained that weighs mixes, and stirs, obtains final product.
Detection
The preparation of the cement base composite construction materials base material of common 3D printing
In units of kg, weigh required each component raw material：Portland cement 100kg, slag micropowder 60kg, starch
Ether 0.5kg, basalt fibre 0.3kg, powder filler 80kg, modulus of fineness is 2.5 middle sand 200kg, rubble (particle diameter≤
10mm)300kg；Standby 6 parts, standby.
By embodiment 1～embodiment 6 gained room temperature early strength agent, according to the 3D printing cementitious binder matter of above-mentioned preparation gained
The 3.5% of amount percent, that is, add the room temperature early strength agent of 26kg, the compound cement-base building with above-mentioned standby 3D printing respectively
Material base material mixes, i.e. embodiment 1 gained room temperature early strength agent 26kg, and the cement based of standby 3D printing above-mentioned with 1 part is multiple
Build jointly and build material mixing, embodiment 2 gained room temperature early strength agent 26kg, it is combined with the cement based of another above-mentioned standby 3D printing
Construction material mixes, such；By the mixture of gained room temperature early strength agent and the cement base composite construction materials of 3D printing in standard
Carry out maintenance basis under curing condition《Normal concrete mechanical property test standard》GB/T50081-2002 and《Mortar, mixed
Solidifying soil waterproofing agent》JC474-1999 test specification, detect the comprcssive strength of mixture 0.5h, 1.5h, 3.0h and 12h anti-
Compressive Strength, and 12h age Portland cement mixture quality water suction dose rate.(note：Because of 3D printing compound cement-base building
Material is similar with cement composition, and the method that temporary is applied to common silicic acid muddy water mud detects its each item data)
The test of quality water suction dose rate：By the room temperature early strength agent of 12h age and the cement base composite construction materials of 3D printing
Mixture put in baking oven, at 80 DEG C dry 6h, weigh test specimen quality after drying and write down, under field conditions (factors) that test specimen is cold
But to room temperature, it is then placed in water, test specimen in each 50mm of the upper and lower size of the water surface and keeps water surface elevation constant, with wringing out after 6h
Rag dry surface of test piece, weigh the quality of test specimen after saturation water suction, the test specimen quality that saturation is absorbed water deducts dry test specimen
Quality is quality water suction dose rate.
In above-described embodiment, the data obtained is as shown in data in table 1.
From data in table 1,3D printing house of the present invention slip room temperature early strength agent intensity enhancing in use
Substantially, and its intensity is significantly larger than national building trade mark.From embodiment 5, embodiment 6,3- in inventive formulation
[(2,4- dichloro) phenyl] -2- acrylic acid and additive of the present invention affect larger on properties of product, lack both compositions, its
Intensity in certain time does not much reach the purpose achieved by the present invention；Further by the number shown in embodiment 4
According to as can be seen that in inventive formulation add cineole more can optimize inventive formulation so that products obtained therefrom properties more
Excellent.
The description of the aforementioned specific illustrative embodiment to the present invention illustrate that and illustration purpose.These descriptions
It is not wishing to limit the invention to disclosed precise forms, and it will be apparent that according to above-mentioned teaching, can much be changed
And change.The purpose of selecting and describing the exemplary embodiment is that explaining that the certain principles of the present invention and its reality should
With so that those skilled in the art be capable of and utilize the present invention various different exemplary and
Various different selections and change.The scope of the present invention is intended to be limited by claims and its equivalents.
Claims (6)
1. a kind of 3D printing house slip with room temperature early strength agent it is characterised in that according to ratio of weight and number, comprising following components former
Material：50～100 parts of anhydrous sodium sulfate, 1～7 part of sodium aluminate, 10～20 parts of calcium sulfate, 5～10 parts of linoleic acid, 3- [(2,4- bis-
Chlorine) phenyl] 5～7 parts of -2- acrylic acid, 10～20 parts of filler and 1～3 part of additive.
2. according to claim 1 3D printing house slip with room temperature early strength agent it is characterised in that：Described filler is height
One of ridge soil, kieselguhr, Pulvis Talci, graphite, white carbon black, mica powder, silica flour or carbon fiber.
3. according to claim 1 3D printing house slip with room temperature early strength agent it is characterised in that：Described additive is by the pool
Mud, malt sugar, anhydrous cupric sulfate and natural macromolecular material composition.
4. according to claim 1 3D printing house slip with room temperature early strength agent it is characterised in that：Described additive according to
Ratio of weight and number, by 10～30 parts of pond sludge, 10～16 parts of malt sugar, 5～9 parts of anhydrous cupric sulfate and natural macromolecular material 11～18
Part composition.
5. according to claim 4 3D printing house slip with room temperature early strength agent it is characterised in that：Described natural polymer
Material is one of agar, lignin, bagasse or potato starch.
6. according to claim 5 3D printing house slip with room temperature early strength agent it is characterised in that：Described potato starch
For 70～80 DEG C of drying 5～10min of fresh potato, break into powder, obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610769129.8A CN106396470A (en) | 2016-08-30 | 2016-08-30 | Normal temperature early strength agent for 3D printing house slurry |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610769129.8A CN106396470A (en) | 2016-08-30 | 2016-08-30 | Normal temperature early strength agent for 3D printing house slurry |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106396470A true CN106396470A (en) | 2017-02-15 |
Family
ID=58004079
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610769129.8A Pending CN106396470A (en) | 2016-08-30 | 2016-08-30 | Normal temperature early strength agent for 3D printing house slurry |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106396470A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107540260A (en) * | 2017-08-25 | 2018-01-05 | 陈值英 | A kind of well cementation low heat cement early strength agent and the cement for including it |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101200354A (en) * | 2007-11-30 | 2008-06-18 | 苏州二建建筑集团有限公司 | Concrete super instant coagulant |
| CN104710128A (en) * | 2015-03-11 | 2015-06-17 | 东南大学 | Super early strength accelerator for portland cement concrete |
| CN105417986A (en) * | 2015-12-18 | 2016-03-23 | 卓达新材料科技集团威海股份有限公司 | Early-strength waterproof agent for ordinary Portland cement |
-
2016
- 2016-08-30 CN CN201610769129.8A patent/CN106396470A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101200354A (en) * | 2007-11-30 | 2008-06-18 | 苏州二建建筑集团有限公司 | Concrete super instant coagulant |
| CN104710128A (en) * | 2015-03-11 | 2015-06-17 | 东南大学 | Super early strength accelerator for portland cement concrete |
| CN105417986A (en) * | 2015-12-18 | 2016-03-23 | 卓达新材料科技集团威海股份有限公司 | Early-strength waterproof agent for ordinary Portland cement |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107540260A (en) * | 2017-08-25 | 2018-01-05 | 陈值英 | A kind of well cementation low heat cement early strength agent and the cement for including it |
| CN107540260B (en) * | 2017-08-25 | 2020-05-05 | 辽宁利诺尔科技有限公司 | Low-temperature cement early strength agent for well cementation and cement containing low-temperature cement early strength agent |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106977153B (en) | Using the shield synchronous grouting serous fluid and its construction method of the preparation of shield discarded slurry | |
| CN108911603B (en) | Large-volume concrete and preparation and construction process thereof | |
| CN108530001A (en) | A kind of white wall facing mortar prepared by carbide slag | |
| CN100345791C (en) | Heat insulating glue powder material for wall and its prepn and usage | |
| CN103642296B (en) | Novel radiation-proof putty powder | |
| CN101182139A (en) | Masonry cement having higher strength and water retention | |
| CN109020456A (en) | A kind of Machine-made Sand dry-mixed mortar and preparation method thereof | |
| CN108069690B (en) | Environment-friendly joint mixture and preparation method thereof | |
| CN104761229A (en) | Self-compacting concrete prepared from industrial solid wastes and preparation method thereof | |
| CN101614051A (en) | Water-tolerant gypsum hollow building block and production method thereof | |
| CN105819760B (en) | A kind of ground polymers terrace base material | |
| CN105294012A (en) | Anti-cracking-shedding and strong-adhesion dry mixing plastering mortar | |
| CN107032669A (en) | A kind of 3D printing construction material | |
| CN105236893B (en) | One kind mixes ultralight pearlite heat-insulation plate of iron tailings and preparation method thereof | |
| CN102491721A (en) | Ardealite road base course material and preparation method thereof | |
| CN105461272A (en) | Dry-mixed waterproof mortar and preparation technology thereof | |
| CN106316318A (en) | Self-leveling wear-resistant floor and preparation method thereof | |
| CN107793103A (en) | Heat insulation concrete base mortar and its production method | |
| CN104129962B (en) | A kind of post-stressed hole path pressure grouting agent and preparation method thereof | |
| CN103693924A (en) | Bayer-process red mud doped dry-mixed plastering mortar and use method thereof | |
| CN107827417A (en) | High strength cement capital construction mortar and its production method | |
| CN107746233A (en) | A kind of mortar for building and its production method | |
| CN106396470A (en) | Normal temperature early strength agent for 3D printing house slurry | |
| CN110357501A (en) | A kind of concrete waste material concrete and preparation method thereof | |
| CN106396467A (en) | Coagulation-accelerating early strength agent for 3D printing house slurry |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170215 |
|
| RJ01 | Rejection of invention patent application after publication |