CN106365770A - Organic active fertilizer with soil improving effect, and production method thereof - Google Patents

Organic active fertilizer with soil improving effect, and production method thereof Download PDF

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Publication number
CN106365770A
CN106365770A CN201610696807.2A CN201610696807A CN106365770A CN 106365770 A CN106365770 A CN 106365770A CN 201610696807 A CN201610696807 A CN 201610696807A CN 106365770 A CN106365770 A CN 106365770A
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mixing
soil
mud
fertilizer
organic active
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王延梅
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05CNITROGENOUS FERTILISERS
    • C05C3/00Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/60Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants

Abstract

The invention discloses an organic active fertilizer with a soil improving effect, and a production method thereof. The organic fertilizer mainly comprises animal dung, sludge, scorched earth, straws, traditional Chinese medicine meal, vinasse, biogas residues, internal organ powder, sweet potato root tuber, composite vegetable fibers, oil residues, ammonium humate, modified bentonite, dolomite and a compounded functional inoculant. The organic fertilizer prepared through improving the material proportions and a making technology has the advantages of improvement of the decomposition rate of organic matters, improvement of the dispersion of the organic matters in soil, improvement of the output of crops, improvement of the soil conditions and the crop quality, enhancement of the disease resistance of the crops, and effective solving of the problems of low decomposition rate, low utilization rate and agglomeration of organic fertilizers.

Description

A kind of have Organic active fertilizer of soil improvement action and preparation method thereof
Technical field
The present invention relates to technical field of biological fertilizer, specifically refer to a kind of Organic active fertilizer with soil improvement action And preparation method thereof.
Background technology
With the development of China's agricultural, chemical fertilizer, so that nutrient is high, instant effect, can provide nitrogen required for crop, phosphorus, potassium in a large number Deng element, the advantages such as farm output is greatly improved and is widely used.But solely can be caused using inorganic fertilizer for a long time Soil acidification or alkalization, serious is even hardened, so that soil is lost activity, becomes the fatal position in not long crops, such as salt-soda soil.
In order to improve this situation, in recent years, the fertilizer being made by agricultural wastes and other organic substance Material, because it can increase and update the content of organic matter in soil, promotes microbial reproduction, improves physicochemical property and the biology of soil Activity, mitigates hardened and acidifying situation, improves the utilization rate of soil and enjoy high praise.
But although China's organic manure resource enriches, and quantity sustainable growth, but quality is reducing, utilization rate Reducing.Low in order to solve the problems, such as organic fertilizer quality and utilization rate, the present invention is carried out emphatically from formula and preparation technology Improvement, in improved soil, improves fertility and has a positive effect in terms of improving crop quality.
Content of the invention
Present invention solves the technical problem that being to provide a kind of Organic active fertilizer with soil improvement action and its preparation Method, can improved soil, improve fertility and improve crop quality.
The technical scheme is that a kind of Organic active fertilizer with soil improvement action, by weight component meter, bag Include following component: fowl and animal excrement 40-50 part, mud 35-45 part, scorched earth 10-20 part, straw 15-25 part, Chinese medicine coarse powder 5-10 Part, distiller grains 5-10 part, biogas residue 8-15 part, visceral meal 5-8 part, sweet potato root tuber powder 4-6 part, composite plant fiber powder 11-26 part, oil Slag 3-8 part, ammonium humate 3-5 part, modified alta-mud 3-5 part, dolomite 3-5 part, compound function microbial inoculum 0.5-1 part.
Further, in such scheme, the preparation method of described compound function microbial inoculum is: distinguishes in the medium Add bacillus subtilises 15%, bacillus amyloliquefaciens 15%, bacillus megaterium 15%, gel-shaped series bacillus 15%th, enterococcus faecalis 8%, cellulase 10%, proteinase 8 %, saccharomyces cerevisiae 9%, trichoderma aureoviride 5%, culture medium is put into Fermented in fermentation tank, temperature is set in 25-30 DEG C, mixing speed is 200r/min, fermentation time is 24-48 hour, lives Bacterium sum >=1 × 1010Individual, obtain mixed bacteria liquid;By turfy soil, Vermiculitum and Kaolin according to the weight ratio mixing of 6:3:1, use powder Broken machine is pulverized, and stirs, obtains mixture, sprays the water with respect to described mixture weight 5-10% in whipping process, Using dehydrator flash baking after machine-shaping in cylinder, form loose microgranule, obtain adsorbent, to be adsorbed dose of cooling Afterwards, described adsorbent is carried out mixing and absorption with described mixed bacteria liquid according to the weight ratio of 4:1, after adsorbing completely through drying, Pulverize, sieve and make the powder compound function microbial inoculum of 300-400 mesh, bacillus megaterium, gel-shaped series bacillus can Increase the sources of nitrogen in soil, and gel-shaped series bacillus also can produce plant hormone substance and stimulate plant growth, Enterococcus faecalis, cellulase, protease, saccharomyces cerevisiae, trichoderma aureoviride etc. can improve organic resolution ratio in dispensing, and increase has Machine content of material, can play fixed nitrogen, phosphorus decomposing, potassium decomposing on the whole, improve crop yield, improve crop quality, strengthen crop The effect of disease resistance.
Further, in such scheme, described method for preparing modified bentonite is: by bentonite and na2co3Pure Liquid carries out soaking according to the weight ratio of 1:2, stirring reaction, obtains mixed serum, and regulation ph is 7-8, and reaction temperature is 65-75 DEG C, mixing speed is 60-100r/min, described mixed serum is carried out sucking filtration, at 95-105 DEG C after the completion of 1.5-2h reaction Under dried, pulverize after cooling and make 200 mesh particles below, obtain modified alta-mud, compared to calcium-base bentonite, favorably Disperse in soil in organic matter, be difficult to deposit, be easy to pelletize, inhale ammonia and easily store.
Further, in such scheme, described Chinese medicine coarse powder component meter by weight, comprise the following ingredients: benefit Herba Linderniae Crustaceae 0.4-0.7 part, Radix Cacaliae Ainsliaeflorae 0.3-0.7 part, Poria 0.4-0.8 part, Herba urariae macrostachyae 0.3-0.6 part, Folium Perillae 0.3-0.6 part, Cannabis,fructuses 0.3-0.6 part, Fructus Cnidii 0.3-0.7 part, Elephantopus scaber L. 0.3-0.6 part, Pericarpium Granati 0.4-0.8 part, Radix seu Caulis Embeliae Parviflorae 0.4-0.8 Part, Fructus Broussonetiae 0.4-0.7 part, Herba Artemisiae Annuae 0.3-0.6 part, Fructrs Trichosanthis root 0.3-0.6 part, Radix Platycodoniss 0.3-0.6 part, Radix Rehmanniae 0.3-0.6 part; The preparation method of described Chinese medicine coarse powder is: all of above composition is respectively dried, is crushed to 20-40 mesh, remix,;Institute The Chinese medicine ingredients equal nonhazardouss effect stated, in addition to can providing abundant organic matter, distinctive Radix Cacaliae Ainsliaeflorae and Herba urariae macrostachyae also have and kill The specially good effect of worm.
Further, in such scheme, described composite plant fiber powder component meter by weight, is by following component group Become: sawdust 1-3 part, wood flour 1-3 part, bamboo scraps 1-3 part, rice husk 2-5 part, soybean cover 2-4 part, Pericarppium arachidis hypogaeae 2-4 part, bagasse 2-4 Part;The preparation method of described composite plant fiber powder is: gathers with nonionic surfactant after all of above composition is mixed Ethylene glycol, water are soaked with the weight ratio of 1:0.05:3, and soak time is 0.5-1h, dries, is crushed at 40-50 DEG C 30-50 mesh,;The composite plant fiber crossed by nonionic surfactant immersion treatment, while providing organic Also there is anti-cohering and anti-caking effect.
Further, in such scheme, described fowl and animal excrement is pig manure, cattle manure, sheep stool, chicken manure, in duck excrement one Plant or arbitrarily several mixing, in order to avoid in sweat, nutrient loss is serious, and fowl and animal excrement is aqueous before compost Amount should control in 30-50%.
Further, in such scheme, described mud is river, pond sludge or domestic sludge and sewage treatment plant produces One of mud or mixing several, for avoiding its overrun metal content, wherein sludge of sewage treatment plant proportion does not surpass Cross 60%.
Further, in such scheme, described visceral meal is one of chicken, duck, fish internal organs or arbitrarily several Mixing, add 1% pepsin, stir, at 20-40 DEG C be incubated 2-5h, add ethanol, mixing, stand 1-2h, Filtration separation obtains clear liquid, is mixed using the described clear liquid of modified alta-mud absorption, dry, pulverize to 200-300 mesh,;Through The visceral meal of preparation contains abundant aminoacid, has promotion plant growing, opposing and the effect eliminating crops pathogenic bacteria.
Further, in such scheme, described straw length, between 10-20mm, plays ventilation in fermentation and makees With.
A kind of preparation method of the Organic active fertilizer with soil improvement action is:
Step one: be separately added into bacillus subtilises 15%, bacillus amyloliquefaciens 15%, huge spore in the medium Bacillus 15%, gel-shaped series bacillus 15%, enterococcus faecalis 8%, cellulase 10%, proteinase 8 %, saccharomyces cerevisiae 9%, Trichoderma aureoviride 5%, culture medium is put in fermentation tank and is fermented, and temperature is set in 25-30 DEG C, and mixing speed is 200r/ Min, fermentation time is 24-48 hour, total viable count >=1 × 1010Individual, obtain mixed bacteria liquid;By turfy soil, Vermiculitum and Kaolin According to 6:3:1 weight than mixing, with pulverizer pulverize, stir, obtain mixture, spray in whipping process with respect to The water of described mixture weight 5-10%, using dehydrator flash baking after machine-shaping in cylinder, forms loose microgranule, Obtain adsorbent, after to be adsorbed dose of cooling, described adsorbent is carried out mixing suction according to the weight ratio of 4:1 with described mixed bacteria liquid Attached, after adsorbing completely through drying, pulverize, sieve and make the powder compound function microbial inoculum of 300-400 mesh;
Step 2: by bentonite and na2co3Pure liquid carries out soaking according to the weight ratio of 1:2, stirring reaction, obtains mixing slurry Liquid, regulation ph is 7-8, and reaction temperature is 65-75 DEG C, and mixing speed is 60-100r/min, will be described after the completion of 1.5-2h reaction Mixed serum carry out sucking filtration, dried at 95-105 DEG C, after cooling pulverize make 200 mesh particles below, changed Property bentonite;
Step 3: by the fowl and animal excrement of described components by weight percent, mud, scorched earth, straw, Chinese medicine coarse powder, distiller grains, biogas residue, interior Dirty powder, sweet potato root tuber powder, composite plant fiber, the dregs of fat, ammonium humate, modified alta-mud, dolomite, compound function microbial inoculum make Use blender mix homogeneously, using forklift, mixture is put into and in fermenting case, carry out semiclosed compost fermentation, abundant every 2-3 day Stir once, temperature control at 55-65 DEG C, moisture Control in 35-50%, when the c/n of fermented product is maintained at (15-20): 1, ph Representing when between 7.5-8.5 becomes thoroughly decomposed completes;Described fermenting case is the rectangular box thing of 10m × 6m × 2m, and lower section is provided with One long 6m, wide 0.2m, the ventilation slot of deep 0.1m;
Step 4: the fertilizer after becoming thoroughly decomposed is put in roller drier, dries at 40-50 DEG C, sends into biological deodorizing machine In carry out deodorization, size-reduced machine is pulverized, carry out cool drying after granulator granulation, controls moisture below 5%, then by rotary screen Extension set screens out granule in 1-2.5mm for the particle diameter, finally carries out packing, stores and obtain a kind of thering is having of soil improvement action Machine active fertilizer.
Beneficial effects of the present invention are to improve organic resolution ratio, organic dispersibility in soil and make produce Amount, improves soil regime and crop quality, strengthens crop resistance, effectively solves organic fertilizer resolution ratio and utilization rate Low, fertilizer agglomeration problem.
Specific embodiment
Embodiment 1:
A kind of Organic active fertilizer with soil improvement action, by weight component meter, including following component: fowl and animal excrement 40 parts, 35 parts of mud, 10 parts of scorched earth, 15 parts of straw, 5 parts of Chinese medicine coarse powder, 5 parts of distiller grains, 8 parts of biogas residue, 5 parts of visceral meal, Rhizoma Dioscoreae esculentae block 4 parts of root powder, 11 parts of composite plant fiber powder, 3 parts of the dregs of fat, 3 parts of ammonium humate, 3 parts of modified alta-mud, 3 parts of dolomite, compound 0.5 part of function microbial inoculum.
Wherein, the preparation method of described compound function microbial inoculum is: is separately added into bacillus subtilises in the medium 15%th, bacillus amyloliquefaciens 15%, bacillus megaterium 15%, gel-shaped series bacillus 15%, enterococcus faecalis 8%, fibre The plain enzyme 10% of dimension, proteinase 8 %, saccharomyces cerevisiae 9%, trichoderma aureoviride 5%, culture medium are put in fermentation tank and are fermented, temperature Degree is set in 25 DEG C, and mixing speed is 200r/min, and fermentation time is 24 hours, total viable count 1 × 1010Individual, obtain mixed vaccine Liquid;By turfy soil, Vermiculitum and Kaolin according to the weight ratio mixing of 6:3:1, pulverized with pulverizer, stir, mixed Thing, sprays the water with respect to described mixture weight 5% in whipping process, fast using dehydrator after machine-shaping in cylinder Speed is dried, and forms loose microgranule, obtains adsorbent, after to be adsorbed dose of cooling, described adsorbent is pressed with described mixed bacteria liquid Weight ratio according to 4:1 carries out mixing and absorption, after adsorbing completely through drying, pulverize, sieve make 300 mesh powder compound Function microbial inoculum, bacillus megaterium, gel-shaped series bacillus can increase the sources of nitrogen in soil, and gel-shaped class spore Bacillus also can produce plant hormone substance stimulates plant growth, enterococcus faecalis, cellulase, protease, saccharomyces cerevisiae, yellowish green Trichoderma spp. etc. can improve in dispensing organic resolution ratio, increases organic matter content, can play on the whole fixed nitrogen, phosphorus decomposing, Potassium decomposing, improve crop yield, improve crop quality, strengthening the effect of crop resistance.
Described method for preparing modified bentonite is: by bentonite and na2co3Pure liquid is soaked according to the weight ratio of 1:2 Bubble, stirring reaction, obtain mixed serum, and adjusting ph is 7, and reaction temperature is 65 DEG C, and mixing speed is 60r/min, reacts 1.5h Afterwards described mixed serum is carried out sucking filtration, dried at 95 DEG C, pulverize, after cooling, the granule making 200 mesh, changed Property bentonite, compared to calcium-base bentonite, be conducive to organic disperse in soil, be difficult to deposit, be easy to pelletize, inhale ammonia and easily store up Deposit.
Described Chinese medicine coarse powder component meter by weight, comprises the following ingredients: 0.4 part of Herba Leonuri, 0.3 part of Radix Cacaliae Ainsliaeflorae, 0.4 part of Poria, 0.3 part of Herba urariae macrostachyae, 0.3 part of Folium Perillae, 0.3 part of cannabis,fructuses, 0.3 part of Fructus Cnidii, 0.3 part of Elephantopus scaber L., Pericarpium Granati 0.4 part, 0.4 part of Radix seu Caulis Embeliae Parviflorae, 0.4 part of Fructus Broussonetiae, 0.3 part of Herba Artemisiae Annuae, 0.3 part of Fructrs Trichosanthis root, 0.3 part of Radix Platycodoniss, 0.3 part of the Radix Rehmanniae;Described The preparation method of Chinese medicine coarse powder is: all of above composition is respectively dried, is crushed to 20 mesh, remix,;Described Chinese medicine The equal nonhazardouss of composition act on, and in addition to can providing abundant organic matter, distinctive Radix Cacaliae Ainsliaeflorae and Herba urariae macrostachyae also have the specially good effect of parasite killing.
Described composite plant fiber powder component meter by weight, comprises the following ingredients: 1 part of sawdust, 1 part of wood flour, bamboo 1 part of bits, 2 parts of rice husk, 2 parts of soybean cover, 2 parts of Pericarppium arachidis hypogaeae, 2 parts of bagasse;The preparation method of described composite plant fiber powder is: will Soaked with the weight ratio of 1:0.05:3 with nonionic surfactant Polyethylene Glycol, water after all of above composition mixing, Soak time is 0.5h, dries, is crushed to 30 mesh at 40 DEG C,;Crossed by nonionic surfactant immersion treatment Composite plant fiber, also has anti-cohering and anti-caking effect while providing organic.
Described fowl and animal excrement is one of pig manure, cattle manure, sheep stool, chicken manure, duck excrement or arbitrarily several mixing, is Seriously, water content before compost for the fowl and animal excrement should control 30% to avoid nutrient loss in sweat.
Described mud is one of mud of river, pond sludge or domestic sludge and sewage treatment plant's generation or mixing is several Kind, for avoiding its overrun metal content, wherein sludge of sewage treatment plant proportion is less than 60%.
Described visceral meal is one of chicken, duck, fish internal organs or arbitrarily several mixing, adds 1% pepsin Enzyme, stirs, and is incubated 2h at 20 DEG C, adds ethanol, mixing, stands 1h, filtration separation obtains clear liquid, using modified alta-mud The described clear liquid of absorption, dry, pulverize to 200 mesh,;Contain abundant aminoacid through the visceral meal of preparation, there is promotion Plant growing, opposing and the effect eliminating crops pathogenic bacteria.
Described straw length is 10mm, plays draught effect in fermentation.
A kind of preparation method of the Organic active fertilizer with soil improvement action is:
Step one: be separately added into bacillus subtilises 15%, bacillus amyloliquefaciens 15%, huge spore in the medium Bacillus 15%, gel-shaped series bacillus 15%, enterococcus faecalis 8%, cellulase 10%, proteinase 8 %, saccharomyces cerevisiae 9%, Trichoderma aureoviride 5%, culture medium is put in fermentation tank and is fermented, and temperature is set in 25 DEG C, and mixing speed is 200r/min, sends out The ferment time is 24 hours, total viable count 1 × 1010Individual, obtain mixed bacteria liquid;By turfy soil, Vermiculitum and Kaolin according to 6:3:1's Weight, than mixing, is pulverized with pulverizer, is stirred, obtain mixture, spray with respect to described mixture in whipping process The water of weight 5%, using dehydrator flash baking after machine-shaping in cylinder, forms loose microgranule, obtains adsorbent, treat After adsorbent cooling, described adsorbent is carried out mixing and absorption with described mixed bacteria liquid according to the weight ratio of 4:1, treats to adsorb completely By drying, pulverize, sieve and make the powder compound function microbial inoculum of 300 mesh;
Step 2: by bentonite and na2co3Pure liquid carries out soaking according to the weight ratio of 1:2, stirring reaction, obtains mixing slurry Liquid, adjusting ph is 7, and reaction temperature is 65 DEG C, and mixing speed is 60r/min, after reaction 2h is taken out described mixed serum Filter, is dried at 95 DEG C, pulverizes and makes 200 mesh particles below, obtain modified alta-mud after cooling;
Step 3: by the fowl and animal excrement of described components by weight percent, mud, scorched earth, straw, Chinese medicine coarse powder, distiller grains, biogas residue, interior Dirty powder, sweet potato root tuber powder, composite plant fiber, the dregs of fat, ammonium humate, modified alta-mud, dolomite, compound function microbial inoculum make Use blender mix homogeneously, using forklift, mixture is put into and in fermenting case, carry out semiclosed compost fermentation, fully turned over every 2 days Stir once, at 55 DEG C, 35%, when the c/n of fermented product is maintained at 15:1, ph represents rotten to moisture Control to temperature control when 7.5 Ripe complete;Described fermenting case is the rectangular box thing of 10m × 6m × 2m, and lower section is provided with a long 6m, wide 0.2m, deep 0.1m Ventilation slot;
Step 4: the fertilizer after becoming thoroughly decomposed is put in roller drier, dries at 40 DEG C, sends in biological deodorizing machine Row deodorization, size-reduced machine is pulverized, carry out cool drying after granulator granulation, controls moisture 5%, then is sieved by cylinder round sifter Go out the granule in 1mm for the particle diameter, finally carry out packing, store and obtain a kind of Organic active fertilizer with soil improvement action.
Embodiment 2:
A kind of Organic active fertilizer with soil improvement action, by weight component meter, including following component: fowl and animal excrement 50 parts, 45 parts of mud, 20 parts of scorched earth, 25 parts of straw, 10 parts of Chinese medicine coarse powder, 10 parts of distiller grains, 15 parts of biogas residue, 8 parts of visceral meal, Rhizoma Dioscoreae esculentae 6 parts of tuber powder, 26 parts of composite plant fiber powder, 8 parts of the dregs of fat, 5 parts of ammonium humate, 5 parts of modified alta-mud, 5 parts of dolomite, compound 1 part of type function microbial inoculum.
Wherein, the preparation method of described compound function microbial inoculum is: is separately added into bacillus subtilises in the medium 15%th, bacillus amyloliquefaciens 15%, bacillus megaterium 15%, gel-shaped series bacillus 15%, enterococcus faecalis 8%, fibre The plain enzyme 10% of dimension, proteinase 8 %, saccharomyces cerevisiae 9%, trichoderma aureoviride 5%, culture medium are put in fermentation tank and are fermented, temperature Degree is set in 30 DEG C, and mixing speed is 200r/min, and fermentation time is 48 hours, total viable count 1.3 × 1010Individual, mixed Bacterium solution;By turfy soil, Vermiculitum and Kaolin according to the weight ratio mixing of 6:3:1, pulverized with pulverizer, stir, mixed Compound, sprays the water with respect to described mixture weight 10%, using drying after machine-shaping in cylinder in whipping process Machine flash baking, forms loose microgranule, obtains adsorbent, after to be adsorbed dose of cooling, by described adsorbent and described mixed vaccine Liquid carries out mixing and absorption according to the weight ratio of 4:1, after adsorbing completely through drying, pulverize, sieve make 400 mesh powder multiple Mould assembly function microbial inoculum, bacillus megaterium, gel-shaped series bacillus can increase the sources of nitrogen in soil, and gel-shaped class Bacillus cereuss also can produce plant hormone substance stimulate plant growth, enterococcus faecalis, cellulase, protease, saccharomyces cerevisiae, Trichoderma aureoviride etc. can improve organic resolution ratio in dispensing, increase organic matter content, can play fixed nitrogen, solution on the whole Phosphorus, potassium decomposing, improve crop yield, improve crop quality, strengthening the effect of crop resistance.
Described method for preparing modified bentonite is: by bentonite and na2co3Pure liquid is soaked according to the weight ratio of 1:2 Bubble, stirring reaction, obtain mixed serum, and adjusting ph is 8, and reaction temperature is 75 DEG C, and mixing speed is 100r/min, after reaction 2h Described mixed serum is carried out sucking filtration, is dried at 105 DEG C, pulverize, after cooling, the granule making 200 mesh, obtain modification Bentonite, compared to calcium-base bentonite, is conducive to organic dispersion in soil, is difficult to deposit, is easy to pelletize, inhale ammonia and easily store up Deposit.
Described Chinese medicine coarse powder component meter by weight, comprises the following ingredients: 0.7 part of Herba Leonuri, 0.7 part of Radix Cacaliae Ainsliaeflorae, 0.8 part of Poria, 0.6 part of Herba urariae macrostachyae, 0.6 part of Folium Perillae, 0.6 part of cannabis,fructuses, 0.7 part of Fructus Cnidii, 0.6 part of Elephantopus scaber L., Pericarpium Granati 0.8 part, 0.8 part of Radix seu Caulis Embeliae Parviflorae, 0.7 part of Fructus Broussonetiae, 0.6 part of Herba Artemisiae Annuae, 0.6 part of Fructrs Trichosanthis root, 0.6 part of Radix Platycodoniss, 0.6 part of the Radix Rehmanniae;Described The preparation method of Chinese medicine coarse powder is: all of above composition is respectively dried, is crushed to 40 mesh, remix,;Described Chinese medicine The equal nonhazardouss of composition act on, and in addition to can providing abundant organic matter, distinctive Radix Cacaliae Ainsliaeflorae and Herba urariae macrostachyae also have the specially good effect of parasite killing.
Described composite plant fiber powder component meter by weight, comprises the following ingredients: 3 parts of sawdust, 3 parts of wood flour, bamboo 3 parts of bits, 5 parts of rice husk, 4 parts of soybean cover, 4 parts of Pericarppium arachidis hypogaeae, 4 parts of bagasse;The preparation method of described composite plant fiber powder is: will Soaked with the weight ratio of 1:0.05:3 with nonionic surfactant Polyethylene Glycol, water after all of above composition mixing, Soak time is 1h, dries, is crushed to 50 mesh at 50 DEG C,;By answering that nonionic surfactant immersion treatment is crossed Close Plant fiber, also there is while providing organic anti-cohering and anti-caking effect.
Described fowl and animal excrement is one of pig manure, cattle manure, sheep stool, chicken manure, duck excrement or arbitrarily several mixing, is Seriously, water content before compost for the fowl and animal excrement should control 50% to avoid nutrient loss in sweat.
Described mud is one of mud of river, pond sludge or domestic sludge and sewage treatment plant's generation or mixing is several Kind, for avoiding its overrun metal content, wherein sludge of sewage treatment plant proportion is less than 60%.
Described visceral meal is one of chicken, duck, fish internal organs or arbitrarily several mixing, adds 1% pepsin Enzyme, stirs, and is incubated 5h at 40 DEG C, adds ethanol, mixing, stands 2h, filtration separation obtains clear liquid, using modified alta-mud The described clear liquid of absorption, dry, pulverize to 300 mesh,;Contain abundant aminoacid through the visceral meal of preparation, there is promotion Plant growing, opposing and the effect eliminating crops pathogenic bacteria.
Described straw length is 20mm, plays draught effect in fermentation.
A kind of preparation method of the Organic active fertilizer with soil improvement action is:
Step one: be separately added into bacillus subtilises 15%, bacillus amyloliquefaciens 15%, huge spore in the medium Bacillus 15%, gel-shaped series bacillus 15%, enterococcus faecalis 8%, cellulase 10%, proteinase 8 %, saccharomyces cerevisiae 9%, Trichoderma aureoviride 5%, culture medium is put in fermentation tank and is fermented, and temperature is set in 30 DEG C, and mixing speed is 200r/min, sends out The ferment time is 48 hours, total viable count 1.3 × 1010Individual, obtain mixed bacteria liquid;By turfy soil, Vermiculitum and Kaolin according to 6:3:1 Weight than mixing, with pulverizer pulverize, stir, obtain mixture, spray in whipping process with respect to described mixing The water of thing weight 10%, using dehydrator flash baking after machine-shaping in cylinder, forms loose microgranule, is adsorbed Agent, after to be adsorbed dose of cooling, described adsorbent is carried out mixing and absorption with described mixed bacteria liquid according to the weight ratio of 4:1, has treated Through drying after full absorption, pulverize, sieve and make the powder compound function microbial inoculum of 400 mesh;
Step 2: by bentonite and na2co3Pure liquid carries out soaking according to the weight ratio of 1:2, stirring reaction, obtains mixing slurry Liquid, adjusting ph is 8, and reaction temperature is 75 DEG C, and mixing speed is 100r/min, after reaction 2h is taken out described mixed serum Filter, is dried at 105 DEG C, pulverizes and makes 200 mesh particles below, obtain modified alta-mud after cooling;
Step 3: by the fowl and animal excrement of described components by weight percent, mud, scorched earth, straw, Chinese medicine coarse powder, distiller grains, biogas residue, interior Dirty powder, sweet potato root tuber powder, composite plant fiber, the dregs of fat, ammonium humate, modified alta-mud, dolomite, compound function microbial inoculum make Use blender mix homogeneously, using forklift, mixture is put into and in fermenting case, carry out semiclosed compost fermentation, fully turned over every 3 days Stir once, at 65 DEG C, 50%, when the c/n of fermented product is maintained at 20:1, ph represents rotten to moisture Control to temperature control when 8.5 Ripe complete;Described fermenting case is the rectangular box thing of 10m × 6m × 2m, and lower section is provided with a long 6m, wide 0.2m, deep 0.1m Ventilation slot;
Step 4: the fertilizer after becoming thoroughly decomposed is put in roller drier, dries at 50 DEG C, sends in biological deodorizing machine Row deodorization, size-reduced machine is pulverized, carry out cool drying after granulator granulation, controls moisture 5%, then is sieved by cylinder round sifter Go out the granule that particle diameter is 2.5mm, finally carry out packing, store and obtain a kind of Organic active fertilizer with soil improvement action.
Embodiment 3:
A kind of Organic active fertilizer with soil improvement action, by weight component meter, including following component: fowl and animal excrement 45 parts, 40 parts of mud, 15 parts of scorched earth, 20 parts of straw, 8 parts of Chinese medicine coarse powder, 8 parts of distiller grains, 12 parts of biogas residue, 6 parts of visceral meal, Rhizoma Dioscoreae esculentae block 5 parts of root powder, 19 parts of composite plant fiber powder, 5 parts of the dregs of fat, 4 parts of ammonium humate, 4 parts of modified alta-mud, 4 parts of dolomite, compound 0.7 part of function microbial inoculum.
Wherein, the preparation method of described compound function microbial inoculum is: is separately added into bacillus subtilises in the medium 15%th, bacillus amyloliquefaciens 15%, bacillus megaterium 15%, gel-shaped series bacillus 15%, enterococcus faecalis 8%, fibre The plain enzyme 10% of dimension, proteinase 8 %, saccharomyces cerevisiae 9%, trichoderma aureoviride 5%, culture medium are put in fermentation tank and are fermented, temperature Degree is set in 27 DEG C, and mixing speed is 200r/min, and fermentation time is 36 hours, total viable count 1.2 × 1010Individual, mixed Bacterium solution;By turfy soil, Vermiculitum and Kaolin according to the weight ratio mixing of 6:3:1, pulverized with pulverizer, stir, mixed Compound, sprays the water with respect to described mixture weight 8%, using dehydrator after machine-shaping in cylinder in whipping process Flash baking, forms loose microgranule, obtains adsorbent, after to be adsorbed dose of cooling, by described adsorbent and described mixed bacteria liquid Weight ratio according to 4:1 carries out mixing and absorption, after adsorbing completely through drying, pulverize, sieve make 350 mesh powder be combined Type function microbial inoculum, bacillus megaterium, gel-shaped series bacillus can increase the sources of nitrogen in soil, and gel-shaped class bud Spore bacillus also can produce plant hormone substance stimulates plant growth, enterococcus faecalis, cellulase, protease, saccharomyces cerevisiae, Huang Green trichoderma etc. can improve organic resolution ratio in dispensing, increase organic matter content, can play fixed nitrogen, solution on the whole Phosphorus, potassium decomposing, improve crop yield, improve crop quality, strengthening the effect of crop resistance.
Described method for preparing modified bentonite is: by bentonite and na2co3Pure liquid is soaked according to the weight ratio of 1:2 Bubble, stirring reaction, obtain mixed serum, and adjusting ph is 7.5, and reaction temperature is 70 DEG C, and mixing speed is 80r/min, reaction After 105min, described mixed serum is carried out sucking filtration, is dried at 100 DEG C, pulverize, after cooling, the granule making 200 mesh, Obtain modified alta-mud, compared to calcium-base bentonite, be conducive to organic dispersion in soil, be difficult to deposit, be easy to pelletize, inhale Ammonia easily stores.
Described Chinese medicine coarse powder component meter by weight, comprises the following ingredients: 0.5 part of Herba Leonuri, 0.6 part of Radix Cacaliae Ainsliaeflorae, 0.6 part of Poria, 0.5 part of Herba urariae macrostachyae, 0.5 part of Folium Perillae, 0.5 part of cannabis,fructuses, 0.6 part of Fructus Cnidii, 0.4 part of Elephantopus scaber L., Pericarpium Granati 0.7 part, 0.7 part of Radix seu Caulis Embeliae Parviflorae, 0.6 part of Fructus Broussonetiae, 0.4 part of Herba Artemisiae Annuae, 0.4 part of Fructrs Trichosanthis root, 0.5 part of Radix Platycodoniss, 0.5 part of the Radix Rehmanniae;Described The preparation method of Chinese medicine coarse powder is: all of above composition is respectively dried, is crushed to 30 mesh, remix,;Described Chinese medicine The equal nonhazardouss of composition act on, and in addition to can providing abundant organic matter, distinctive Radix Cacaliae Ainsliaeflorae and Herba urariae macrostachyae also have the specially good effect of parasite killing.
Described composite plant fiber powder component meter by weight, comprises the following ingredients: 2 parts of sawdust, 2 parts of wood flour, bamboo 2 parts of bits, 4 parts of rice husk, 3 parts of soybean cover, 3 parts of Pericarppium arachidis hypogaeae, 3 parts of bagasse;The preparation method of described composite plant fiber powder is: will Soaked with the weight ratio of 1:0.05:3 with nonionic surfactant Polyethylene Glycol, water after all of above composition mixing, Soak time is 45min, dries, is crushed to 40 mesh at 45 DEG C,;Crossed by nonionic surfactant immersion treatment Composite plant fiber, also has anti-cohering and anti-caking effect while providing organic.
Described fowl and animal excrement is one of pig manure, cattle manure, sheep stool, chicken manure, duck excrement or arbitrarily several mixing, is Seriously, water content before compost for the fowl and animal excrement should control 40% to avoid nutrient loss in sweat.
Described mud is one of mud of river, pond sludge or domestic sludge and sewage treatment plant's generation or mixing is several Kind, for avoiding its overrun metal content, wherein sludge of sewage treatment plant proportion is less than 60%.
Described visceral meal is one of chicken, duck, fish internal organs or arbitrarily several mixing, adds 1% pepsin Enzyme, stirs, and is incubated 3h at 30 DEG C, adds ethanol, mixing, stands 1.5h, filtration separation obtains clear liquid, using bentone The described clear liquid of soil absorption, dry, pulverize to 250 mesh,;Contain abundant aminoacid through the visceral meal of preparation, there is rush Enter plant growing, opposing and the effect eliminating crops pathogenic bacteria.
Described straw length is 15mm, plays draught effect in fermentation.
A kind of preparation method of the Organic active fertilizer with soil improvement action is:
Step one: be separately added into bacillus subtilises 15%, bacillus amyloliquefaciens 15%, huge spore in the medium Bacillus 15%, gel-shaped series bacillus 15%, enterococcus faecalis 8%, cellulase 10%, proteinase 8 %, saccharomyces cerevisiae 9%, Trichoderma aureoviride 5%, culture medium is put in fermentation tank and is fermented, and temperature is set in 27 DEG C, and mixing speed is 200r/min, sends out The ferment time is 36 hours, total viable count >=1.2 × 1010Individual, obtain mixed bacteria liquid;By turfy soil, Vermiculitum and Kaolin according to 6: The weight of 3:1, than mixing, is pulverized with pulverizer, is stirred, obtain mixture, sprays mixed with respect to described in whipping process The water of polymer weight 8%, using dehydrator flash baking after machine-shaping in cylinder, forms loose microgranule, is adsorbed Agent, after to be adsorbed dose of cooling, described adsorbent is carried out mixing and absorption with described mixed bacteria liquid according to the weight ratio of 4:1, has treated Through drying after full absorption, pulverize, sieve and make the powder compound function microbial inoculum of 350 mesh;
Step 2: by bentonite and na2co3Pure liquid carries out soaking according to the weight ratio of 1:2, stirring reaction, obtains mixing slurry Liquid, adjusting ph is 7.5, and reaction temperature is 70 DEG C, and mixing speed is 80r/min, by described mixed serum after reaction 105min Carry out sucking filtration, dried at 100 DEG C, pulverize, after cooling, the granule making 200 mesh, obtain modified alta-mud;
Step 3: by the fowl and animal excrement of described components by weight percent, mud, scorched earth, straw, Chinese medicine coarse powder, distiller grains, biogas residue, interior Dirty powder, sweet potato root tuber powder, composite plant fiber, the dregs of fat, ammonium humate, modified alta-mud, dolomite, compound function microbial inoculum make Use blender mix homogeneously, using forklift, mixture is put into and in fermenting case, carry out semiclosed compost fermentation, every 2.5 days fully Stir once, at 60 DEG C, 45%, when the c/n of fermented product is maintained at 18:1, ph represents rotten to moisture Control to temperature control when 7 Ripe complete;Described fermenting case is the rectangular box thing of 10m × 6m × 2m, and lower section is provided with a long 6m, wide 0.2m, deep 0.1m Ventilation slot;
Step 4: the fertilizer after becoming thoroughly decomposed is put in roller drier, dries at 45 DEG C, sends in biological deodorizing machine Row deodorization, carries out cool drying after size-reduced machine pulverizing, granulator granulation, controls moisture below 5%, then by cylinder round sifter Screen out the granule that particle diameter is 2mm, finally carry out packing, store that to obtain a kind of organic active with soil improvement action fertile Material.
Test example:
A kind of application of the Organic active fertilizer with soil improvement action: this experiment adopts stochastic averagina distribution method, with 5 Mu winter wheat is subjects, and one is divided into totally five groups of original group, matched group, experimental group 1, experimental group 2 and experimental group 3.Wherein, First gather soil sample before the fertilizer applying the present invention and determine soil physical and chemical property, be labeled as original group, market routine fertilizer is right According to group, embodiments of the invention 1, embodiment 2, embodiment 3 are respectively experimental group 1, experimental group 2, experimental group 3, and amount of application is 50kg/ mu.Above-mentioned group, except the fertilizer applied is different, the management all same in later stage.
Testing result:
The contrast to wheat yield for table 1 different disposal
Original group Matched group Experimental group 1 Experimental group 2 Experimental group 3
Average product (kg/ mu) 298.35 335.46 381.38 383.71 388.30
Volume increase (%) 12.44 27.83 28.61 30.02
The impact to soil physical and chemical property for table 2 different disposal
Original group Matched group Experimental group 1 Experimental group 2 Experimental group 3
ph 8.81 8.50 7.75 7.68 7.56
The content of organic matter (%) 1.35 1.89 2.57 2.61 2.69
As seen from Table 1, the fertilizer prepared by enforcement various embodiments of the present invention, the average product respectively 27.83% of Semen Tritici aestivi, 28.61%th, 30.02%, compared to original group and matched group conventional fertilizer, three experimental grouies all have to Semen Tritici aestivi average product Significantly improve, wherein good with experimental group 3 (embodiment 3) effect.
As seen from Table 2, the fertilizer prepared by various embodiments of the present invention, compared to original group and matched group, soil are implemented Ph value is all reduced in the range of neutral soil, and the content of organic matter in soil also has significant increase, wherein to test Group 3 (embodiment 3) effect is the best.
In sum, the organic fertilizer being produced according to inventive formulation, utilization rate is high, diffusibility is good, range is wide, no It is easy to run off, no any pollution, environment-friendly high-efficiency, easily stores, improving crop yield, improved soil situation, improving crop quality, increasing Plus crop disease-resistant insect pest aspect has remarkable result.
Although the present invention is described and illustrated with reference to its specific embodiments, it will be appreciated by those skilled in the art that Without departing from the spirit and scope of the present invention it can be variously modified, change and replace.Therefore, the present invention It is intended to only be limited by the scope of following claims and these claim should be explained in rational degree as broadly as possible.

Claims (9)

1. a kind of Organic active fertilizer with soil improvement action is it is characterised in that component meter by weight, including following become Point: fowl and animal excrement 40-50 part, mud 35-45 part, scorched earth 10-20 part, straw 15-25 part, Chinese medicine coarse powder 5-10 part, distiller grains 5- 10 parts, biogas residue 8-15 part, visceral meal 5-8 part, sweet potato root tuber powder 4-6 part, composite plant fiber powder 11-26 part, dregs of fat 3-8 part, Ammonium humate 3-5 part, modified alta-mud 3-5 part, dolomite 3-5 part, compound function microbial inoculum 0.5-1 part.
2. a kind of Organic active fertilizer with soil improvement action according to claim 1 is it is characterised in that described The preparation method of compound function microbial inoculum is: is separately added into bacillus subtilises 15%, bacillus amyloliquefaciens in the medium 15%th, bacillus megaterium 15%, gel-shaped series bacillus 15%, enterococcus faecalis 8%, cellulase 10%, protease 8%th, saccharomyces cerevisiae 9%, trichoderma aureoviride 5%, culture medium are put in fermentation tank and are fermented, temperature is set in 25-30 DEG C, stir Mixing speed is 200r/min, and fermentation time is 24-48 hour, total viable count >=1 × 1010Individual, obtain mixed bacteria liquid;By turf Soil, Vermiculitum and Kaolin, according to the weight ratio mixing of 6:3:1, are pulverized with pulverizer, are stirred, obtain mixture, in stirring During spray water with respect to described mixture weight 5-10%, quickly dried using dehydrator after machine-shaping in cylinder Dry, form loose microgranule, obtain adsorbent, after to be adsorbed dose of cooling, by described adsorbent with described mixed bacteria liquid according to 4:1 Weight ratio carry out mixing and absorption, after adsorbing completely through drying, pulverize, sieve make 300-400 mesh powder compound Function microbial inoculum.
3. a kind of Organic active fertilizer with soil improvement action according to claim 1 is it is characterised in that described Method for preparing modified bentonite is: by bentonite with na2co3 pure liquid carry out soaking according to the weight ratio of 1:2, stirring reaction, Obtain mixed serum, regulation ph is 7-8, reaction temperature is 65-75 DEG C, mixing speed is 60-100r/min, 1.5-2h has reacted After one-tenth, described mixed serum is carried out sucking filtration, is dried at 95-105 DEG C, after cooling pulverize make below 200 mesh Grain, obtains modified alta-mud.
4. a kind of Organic active fertilizer with soil improvement action according to claim 1 is it is characterised in that described Chinese medicine coarse powder component meter by weight, comprises the following ingredients: Herba Leonuri 0.4-0.7 part, Radix Cacaliae Ainsliaeflorae 0.3-0.7 part, Poria 0.4-0.8 part, Herba urariae macrostachyae 0.3-0.6 part, Folium Perillae 0.3-0.6 part, cannabis,fructuses 0.3-0.6 part, Fructus Cnidii 0.3-0.7 part, Radix Gentianae 0.3-0.6 part, Pericarpium Granati 0.4-0.8 part, Radix seu Caulis Embeliae Parviflorae 0.4-0.8 part, Fructus Broussonetiae 0.4-0.7 part, Herba Artemisiae Annuae 0.3-0.6 part, Fructrs Trichosanthis root 0.3-0.6 part, Radix Platycodoniss 0.3-0.6 part, Radix Rehmanniae 0.3-0.6 part;The preparation method of described Chinese medicine coarse powder is: by above institute There is composition to be respectively dried, be crushed to 20-40 mesh, remix,.
5. a kind of Organic active fertilizer with soil improvement action according to claim 1 is it is characterised in that described Composite plant fiber powder component meter by weight, comprises the following ingredients: sawdust 1-3 part, wood flour 1-3 part, bamboo scraps 1-3 part, rice Shell 2-5 part, soybean cover 2-4 part, Pericarppium arachidis hypogaeae 2-4 part, bagasse 2-4 part;The preparation method of described composite plant fiber powder is: will Soaked with the weight ratio of 1:0.05:3 with nonionic surfactant Polyethylene Glycol, water after all of above composition mixing, Soak time is 0.5-1h, dries, is crushed to 30-50 mesh at 40-50 DEG C,.
6. a kind of Organic active fertilizer with soil improvement action according to claim 1 is it is characterised in that described Fowl and animal excrement is one of pig manure, cattle manure, sheep stool, chicken manure, duck excrement or arbitrarily several mixing, and water content is 20-50%.
7. a kind of Organic active fertilizer with soil improvement action according to claim 1 is it is characterised in that described Mud is one of mud of river, pond sludge or domestic sludge and sewage treatment plant's generation or mixing is several, wherein at sewage Reason factory mud proportion is less than 60%.
8. a kind of Organic active fertilizer with soil improvement action according to claim 1 is it is characterised in that described Straw length is between 10-20mm.
9. a kind of Organic active fertilizer with soil improvement action according to claim 1-8 any one and its preparation Method is it is characterised in that comprise the steps of
Step one: be separately added into bacillus subtilises 15%, bacillus amyloliquefaciens 15%, bacillus megaterium in the medium 15%th, gel-shaped series bacillus 15%, enterococcus faecalis 8%, cellulase 10%, proteinase 8 %, saccharomyces cerevisiae 9%, yellowish green Trichoderma spp. 5%, culture medium is put in fermentation tank and is fermented, and temperature is set in 25-30 DEG C, and mixing speed is 200r/min, sends out The ferment time is 24-48 hour, total viable count >=1 × 1010Individual, obtain mixed bacteria liquid;By turfy soil, Vermiculitum and Kaolin according to 6: The weight of 3:1, than mixing, is pulverized with pulverizer, is stirred, obtain mixture, sprays mixed with respect to described in whipping process The water of polymer weight 5-10%, using dehydrator flash baking after machine-shaping in cylinder, forms loose microgranule, is inhaled Attached dose, after to be adsorbed dose of cooling, described adsorbent is carried out mixing and absorption with described mixed bacteria liquid according to the weight ratio of 4:1, treats Through drying after adsorbing completely, pulverize, sieve and make the powder compound function microbial inoculum of 300-400 mesh;
Step 2: by bentonite and na2co3Pure liquid carries out soaking according to the weight ratio of 1:2, stirring reaction, obtains mixed serum, Regulation ph is 7-8, and reaction temperature is 65-75 DEG C, and mixing speed is 60-100r/min, will be described after the completion of 1.5-2h reaction Mixed serum carries out sucking filtration, is dried at 95-105 DEG C, pulverizes and makes 200 mesh particles below, obtain modification after cooling Bentonite;
Step 3: by the fowl and animal excrement of described components by weight percent, mud, scorched earth, straw, Chinese medicine coarse powder, distiller grains, biogas residue, visceral meal, Sweet potato root tuber powder, composite plant fiber, the dregs of fat, ammonium humate, modified alta-mud, dolomite, compound function microbial inoculum use and stir Mix machine mix homogeneously, using forklift, mixture is put into and in fermenting case, carry out semiclosed compost fermentation, fully stir every 2-3 day Once, temperature control is at 55-65 DEG C, moisture Control in 35-50%, when the c/n of fermented product is maintained at (15-20): 1, ph 7.5-8.5 between when represent to become thoroughly decomposed and complete;Described fermenting case is the rectangular box thing of 10m × 6m × 2m, and lower section is provided with one Individual long 6m, wide 0.2m, the ventilation slot of deep 0.1m;
Step 4: the fertilizer after becoming thoroughly decomposed is put in roller drier, dries at 40-50 DEG C, sends in biological deodorizing machine Row deodorization, carries out cool drying after size-reduced machine pulverizing, granulator granulation, controls moisture below 5%, then by cylinder round sifter Screen out granule in 1-2.5mm for the particle diameter, finally carry out packing, store and obtain a kind of organic work with soil improvement action Property fertilizer.
CN201610696807.2A 2016-08-19 2016-08-19 Organic active fertilizer with soil improving effect, and production method thereof Pending CN106365770A (en)

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CN106946619A (en) * 2017-05-02 2017-07-14 王丽雯 A kind of composite fertilizer and preparation method thereof
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Application publication date: 20170201