CN106359437A - Weeding composition containing clodinafop-propargyl, flucarbazone-sodium and florasulam - Google Patents
Weeding composition containing clodinafop-propargyl, flucarbazone-sodium and florasulam Download PDFInfo
- Publication number
- CN106359437A CN106359437A CN201610757476.9A CN201610757476A CN106359437A CN 106359437 A CN106359437 A CN 106359437A CN 201610757476 A CN201610757476 A CN 201610757476A CN 106359437 A CN106359437 A CN 106359437A
- Authority
- CN
- China
- Prior art keywords
- flucarbazone
- propargyl
- florasulam
- clodinafop
- herbicidal combinations
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a weeding composition containing clodinafop-propargyl, flucarbazone-sodium and florasulam. The weeding composition is prepared from the following effective ingredients: the clodinafop-propargyl, the flucarbazone-sodium and the florasulam at a weight ratio of (1 to 20) : (1 to 20) : (1 to 20), and the total weight of the effective ingredients accounts for 1-60% of the weight of the weeding composition. After being compounded, the weeding composition has an obvious synergetic effect; the dosage of the effective ingredients in the compound weeding composition is obviously reduced in comparison with that in exclusive use; the pesticide composition is applicable to a 2-3 leaf stage of weeds in a wheat paddock, and uniform spraying is suitable for the pesticide composition.
Description
Technical field
Composition pesticide according to the present invention, is with clodinafop-propargyl, flucarbazone, florasulam as effective ingredient, is used for
Preventing and treating farmland weed, is particularly useful for preventing and kill off wheat paddock annual grassy weeds.
Background technology
Chemical method weeding is agriculturally to control one of Main Means of weeds.In recent years, due to some herbicide kinds
Large area is used alone, and already leads to a lot of weeds and develops immunity to drugs.Meanwhile, grass when weeds occur is mutually complicated, not only 1 year
Raw and perennial weeds mixes life, and draft, liana and shrub have concurrently, uneven, the seed and weeds emerge, and low age, advanced age are miscellaneous
Grass is staggered to be occurred, so when herbicide kind is used alone, all can show defect in a certain respect and limitation.
Clodinafop-propargyl, belongs to fragrant phenoxy phenoxy propionic acid herbicide, and the biosynthesiss that can effectively suppress class ester are the auxiliary quick a hydroxylation of acetyl
Enzyme inhibitor, is degraded to free acid phenyl in soil quickly and pyridine moiety enters soil, can prevent and treat wheat paddock rat-tail and see wheat
The grassy weeds such as ma, Herba avenae fatuae, rye grass, rough stalked blue grass Herba Setariae Viridis.
Flucarbazone, is sulfonylurea internal-suction type efficient wheat field herbicidal, to grass such as wild oat, Herba bromi japonici, amur foxtails
Section weeds and multiple broadleaf weed have obvious preventive effect, can be absorbed by the root of weeds and stem and leaf, by suppressing acetyl in weeds body
The activity of lactic acid synzyme, destroys the normal Physiological and Biochemical Metabolism of weeds and plays activity of weeding, can effectively prevent and kill off wheat paddock big
Part grassy weed, simultaneously also can effective control part broad leaved weed, in Semen Tritici aestivi body can metabolism quickly, to Semen Tritici aestivi, there is pole
Good safety.
Florasulam, is triazolopyrimidine sulfonamides superelevation effective herbicide, is inner-adsorption conduction-type herbicide, Ke Yichuan
It is directed at weeds Herb, thus herbicide thoroughly will not recur.Efficacy stability at low temperature, even still ensure that stable when 2 DEG C
Drug effect, this point is that other herbicides are incomparable.Prevent and kill off broad leaved weed for wheat paddock, florasulam broad weed-killing spectrum,
The most of broad leaved weed of wheatland can be prevented and kill off, including difficult anti-weeds such as Herba Galii Teneri (Rubiaceae), corn gromwells (Boraginaceae), and to wheatland
In the Herba Euphorbiae Helioscopiae (Euphorbiaceae) that is most difficult to prevent and kill off have extraordinary inhibitory action.
During the single use of clodinafop-propargyl, flucarbazone, florasulam, all there are certain defect and limitation.
The present inventor has made intensive studies to the mixture of clodinafop-propargyl, flucarbazone, florasulam, in substantial amounts of interior
On the basis of formulation screening test and field medicine effect test, find that clodinafop-propargyl, flucarbazone, florasulam carry out mixture,
In the range of certain mixed ratio, weeds of wheat is shown with obvious potentiation, after further study, complete this
Bright.
Clodinafop-propargyl, flucarbazone, the mixture of florasulam and application there is no report at present.
Content of the invention
It is an object of the invention in solution prior art, farmland weed is developed immunity to drugs problem and actual prevention effect
Poor, provide a kind of efficiently, low toxicity, quick-acting are good and the lasting period is long, are conducive to the Herbicidal combinations of farmland weed comprehensive control.
It is a further object of the present invention to provide being used for preventing and kill off farmland weed by this Herbicidal combinations, it is particularly useful for preventing and kill off Semen Tritici aestivi
Field annual gramineous weed etc..
Technical solution of the present invention: a kind of Herbicidal combinations containing clodinafop-propargyl and flucarbazone and florasulam, have
Effect composition is clodinafop-propargyl and flucarbazone and florasulam, and clodinafop-propargyl, flucarbazone, the weight of florasulam are than respectively
For 1-20:1-20:1-20, percentage by weight in Herbicidal combinations for the effective ingredient weight summation is 1%-60%, and remaining is
Allow in pesticide to use and acceptable auxiliary element.
The known method of Herbicidal combinations of the present invention is prepared into any one dosage form being suitable for agriculturally using, relatively good
Dosage form be one of wettable powder, suspending agent or water dispersible granules.
Used in Herbicidal combinations of the present invention, auxiliary agent includes solvent, dispersant, stabilizer, emulsifying agent, antifreezing agent, thickening
Agent etc. and other be beneficial to effective ingredient known substance that is stable in the formulation and playing drug effect, be all conventional in pesticidal preparations or
Allow the various composition using, be not particularly limited, concrete composition and consumption pass through simple test according to recipe requirements and determine.
Product described in the invention can be provided in the form of finished product preparation, and that is, in compositionss, each material is blended, group
The composition of compound can also the form of single dose provide, and is directly mixed in tank or bucket using front, dense required for being then diluted to
Degree.The frequency of administration of Herbicidal combinations of the present invention and amount of application change and change with weather condition and crop condition, can pass through
Reach the purpose of preventing and treating using suitable dosage form.
Herbicidal combinations of the present invention are applied to 1 year weeds of preventing and treating, especially wheat paddock annual grassy weeds.
Compared with prior art, the beneficial effects of the present invention is, compounding have obvious potentiation, improves preventing and treating
Effect；Expand preventing and treating spectrum；Two kinds of effective ingredient compound, and reduce Pesticide use amount, thus reduce cost and decrease right
The pollution of environment.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention are more short and sweet, present invention specific examples below
Illustrate, but the present invention is only limitted to absolutely not these examples.Described below is only the preferable embodiment of the present invention, is used only for retouching
State the present invention it is impossible to be interpreted as limiting the scope of the present invention.It should be pointed out that all the spirit and principles in the present invention it
Interior done any modification, equivalent and improvement etc., should be included within the scope of the present invention.Therefore, the present invention
The protection domain of patent should be defined by claims.
Embodiment 1: bioassay test
Test method: using potted plant stem and leaf nebulization (ny/t 1155.4-2006): in high 6cm, the porcelain alms bowl of diameter 9cm
Dress quantitative soil, will be placed in greenhouse after the fine earth of lid 0.5～1cm for 15～20 sowings of examination target weeds seed in porcelain alms bowl
Culture, treats amur foxtail, Herba Galii Teneri length to 2～4 leaf phases, carries out stem and leaf spraying treatment, and every porcelain alms bowl quantitatively sprays 1ml, often processes 4 weights
Multiple, and the process setting without medicament is comparison, tries material and be placed in warm indoor cultivation, the growth feelings of routine observation target weeds after process
Condition, range estimation target damage symptoms and growth inhibited situation after 15d, and claim aerial partss fresh weight, evaluated with target fresh weight inhibition
The toxicity action to target weeds for the medicament.
Estimate target damage symptoms and growth inhibited situation after data survey and statistical analysiss test process 15d, and claim ground
Upper part fresh weight, calculates fresh weight inhibition (%).
Synergy evaluation methodology, evaluates herbicide associated form (ny/t1155.7-2006) according to gowing method, and it is public
Formula is as follows:
e0X × y × z/1002
In formula, x is clodinafop-propargyl with certain dosage fresh weight inhibition to target weeds when alone；Y is flucarbazone with certain agent
Fresh weight inhibition to target weeds when measuring alone；Z is that florasulam is pressed down to the fresh weight of target weeds when alone with certain dosage
Rate processed.e0For the theory to target weeds fresh weight inhibition when clodinafop-propargyl, flucarbazone, three kinds of pharmacy mix of florasulam
Value；E is measured value when clodinafop-propargyl, flucarbazone, three kinds of pharmacy mix of florasulam to target weeds fresh weight inhibition.
Evaluation criterion: as e e0During ＞ 10%, it is expressed as potentiation；As 10%≤e e0When≤10%, show as phase
Plus effect；As e e0During ＜ 10%, show as antagonism.Result of the test shows: clodinafop-propargyl, flucarbazone, florasulam are pressed
According to different proportion mixture, notable synergistic effect is all shown to wheat paddock common grassy weed amur foxtail, broad leaved weed Herba Galii Teneri.
Table 1, clodinafop-propargyl, flucarbazone, the florasulam indoor harmacological effect situation to amur foxtail
Table 2, clodinafop-propargyl, flucarbazone, the florasulam indoor harmacological effect situation to Herba Galii Teneri
Embodiment 2:20% clodinafop-propargyl flucarbazone florasulam wettable powder
Mix homogeneously in blender will be entered after above-mentioned formula in proportion coarse pulverization, be obtained 20% after comminution by gas stream
Clodinafop-propargyl flucarbazone florasulam wettable powder.
This embodiment is used for preventing and kill off wheat paddock annual grassy weeds, and 20% clodinafop-propargyl flucarbazone florasulam is wettable
Property powder preparation mu with 40 grams, weeds 2-3 leaf phase spraying treatment, after medicine, 10 days preventive effects are 98.5%；3% clodinafop-propargyl suspending agent is used
Amount 37.5g a.i./ha spraying treatment, after medicine, 10 days preventive effects are 76.2%；15% flucarbazone suspending agent consumption 9g a.i./ha
Spraying treatment, 10 days broad leaved weed preventive effects 77.8% after medicine；20% florasulam suspending agent consumption 4.5g a.i./ha spraying
Process, 10 days broad leaved weed preventive effects 71.6% after medicine.Clodinafop-propargyl, flucarbazone, florasulam can effectively be prevented and kill off little after compounding
Wheatland annual grassy weeds, herbicidal spectrum can be complementary.Because pharmacy control efficacy improves, compound drug effective ingredient consumption reduces, and reduces
Drug cost, delays the generation of disease drug resistance, decreases environmental pollution.
Embodiment 3:15% clodinafop-propargyl flucarbazone florasulam suspending agent
Above-mentioned formula is pulverized in proportion in advance, adds in sand mill and grind, allotment system after high shear mixing
Obtain 20% clodinafop-propargyl flucarbazone florasulam suspending agent.
This embodiment is used for preventing and kill off wheat paddock annual grassy weeds, and 15% clodinafop-propargyl flucarbazone florasulam suspends
Agent formulation mu with 50 grams, weeds 2-3 leaf phase spraying treatment, after medicine, 10 days preventive effects are 96.5%；3% clodinafop-propargyl suspending agent consumption
37.5g a.i./ha spraying treatment, after medicine, 10 days preventive effects are 78.2%；15% flucarbazone suspending agent consumption 9g a.i./ha spray
Mist is processed, 10 days broad leaved weed preventive effects 73.6% after medicine；At 20% florasulam suspending agent consumption 4.5g a.i./ha spraying
Reason, 10 days broad leaved weed preventive effects 80.7% after medicine.Clodinafop-propargyl, flucarbazone, florasulam can effectively prevent and kill off Semen Tritici aestivi after compounding
Field annual grassy weeds, herbicidal spectrum can be complementary.Because pharmacy control efficacy improves, compound drug effective ingredient consumption reduces, and reduces
Drug cost, delays the generation of disease drug resistance, decreases environmental pollution.
Embodiment 4:25% clodinafop-propargyl flucarbazone florasulam water dispersible granules
By above-mentioned formula, dry pulverization process, pelletize, drying, screening preparation are obtained 25% clodinafop-propargyl flucarbazone in proportion
Florasulam water-dispersible granules.
This embodiment is used for preventing and kill off wheat paddock annual grassy weeds, 25% clodinafop-propargyl flucarbazone florasulam moisture
Scattered property granule preparation mu with 30 grams, weeds 2-3 leaf phase spraying treatment, after medicine, 10 days preventive effects are 97.3%；3% clodinafop-propargyl suspending agent
Consumption 37.5g a.i./ha spraying treatment, after medicine, 10 days preventive effects are 78.2%；15% flucarbazone suspending agent consumption 9g a.i./
Ha spraying treatment, 10 days broad leaved weed preventive effects 78.9% after medicine；20% florasulam suspending agent consumption 4.5g a.i./ha spray
Mist is processed, 10 days broad leaved weed preventive effects 87.8% after medicine.Clodinafop-propargyl, flucarbazone, florasulam can effectively be prevented and kill off after compounding
Wheat paddock annual grassy weeds, herbicidal spectrum can be complementary.Because pharmacy control efficacy improves, compound drug effective ingredient consumption reduces, fall
Low drug cost, delays the generation of disease drug resistance, decreases environmental pollution.
Claims (6)
1. a kind of Herbicidal combinations containing clodinafop-propargyl and flucarbazone and florasulam it is characterised in that: effective ingredient
For clodinafop-propargyl and flucarbazone and florasulam, clodinafop-propargyl, flucarbazone, the weight of florasulam are than respectively 1-
20:1-20:1-20.
2. a kind of Herbicidal combinations containing clodinafop-propargyl and flucarbazone and florasulam according to claim 1,
It is characterized in that: clodinafop-propargyl, flucarbazone, the weight of florasulam are than respectively 20:5:2.
3. a kind of Herbicidal combinations containing clodinafop-propargyl and flucarbazone and florasulam according to claim 1,
It is characterized in that: percentage by weight in Herbicidal combinations for the effective ingredient weight summation is 1%-60%.
4. a kind of Herbicidal combinations containing clodinafop-propargyl and flucarbazone and florasulam according to claim 1,
It is characterized in that: also contain pesticidal preparations auxiliary element in described Herbicidal combinations, so that herbicidal composition makes suitable agriculture
The dosage form using in industry.
5. a kind of weeding containing clodinafop-propargyl and flucarbazone and florasulam according to any one of claim 1-4
Compositionss it is characterised in that: its dosage form is one of suspending agent, wettable powder or water dispersible granules.
6. a kind of Herbicidal combinations containing clodinafop-propargyl and flucarbazone and florasulam described in any one of claim 1-4
In the purposes preventing and kill off wheat paddock annual grassy weeds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610757476.9A CN106359437A (en) | 2016-08-29 | 2016-08-29 | Weeding composition containing clodinafop-propargyl, flucarbazone-sodium and florasulam |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610757476.9A CN106359437A (en) | 2016-08-29 | 2016-08-29 | Weeding composition containing clodinafop-propargyl, flucarbazone-sodium and florasulam |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106359437A true CN106359437A (en) | 2017-02-01 |
Family
ID=57900746
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610757476.9A Pending CN106359437A (en) | 2016-08-29 | 2016-08-29 | Weeding composition containing clodinafop-propargyl, flucarbazone-sodium and florasulam |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106359437A (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1449247A (en) * | 2000-06-30 | 2003-10-15 | 拜尔农作物科学股份公司 | Aryl sulfonyl amino carbonyl triazole based selective herbicides |
| CN101926341A (en) * | 2010-09-13 | 2010-12-29 | 尹小根 | Weeding composition containing florasulam and clodinafop-propargyl |
| CN102428945A (en) * | 2012-01-16 | 2012-05-02 | 河北博嘉农业有限公司 | Flucarbazone-Na compounded herbicide |
| CN103210947A (en) * | 2013-05-10 | 2013-07-24 | 步康明 | Wheatfield weed killer composition containing flucarbazone-sodium |
| CN103651491A (en) * | 2013-12-19 | 2014-03-26 | 海利尔药业集团股份有限公司 | Weeding composition containing florasulam and flucarbazone |
| CN105360151A (en) * | 2015-07-22 | 2016-03-02 | 南京华洲药业有限公司 | Weeding composition containing clodinafop-propargyl and flucarbazone-sodium and application of weeding composition |
| CN105532704A (en) * | 2015-12-07 | 2016-05-04 | 安徽美兰农业发展股份有限公司 | Dispersible oil suspension of composite herbicide composed of flucarbazone-sodium and clodinafop-propargyl and preparation method thereof |
| CN107660554A (en) * | 2016-07-27 | 2018-02-06 | 海利尔药业集团股份有限公司 | A kind of Herbicidal combinations containing florasulam |
-
2016
- 2016-08-29 CN CN201610757476.9A patent/CN106359437A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1449247A (en) * | 2000-06-30 | 2003-10-15 | 拜尔农作物科学股份公司 | Aryl sulfonyl amino carbonyl triazole based selective herbicides |
| CN101926341A (en) * | 2010-09-13 | 2010-12-29 | 尹小根 | Weeding composition containing florasulam and clodinafop-propargyl |
| CN102428945A (en) * | 2012-01-16 | 2012-05-02 | 河北博嘉农业有限公司 | Flucarbazone-Na compounded herbicide |
| CN103210947A (en) * | 2013-05-10 | 2013-07-24 | 步康明 | Wheatfield weed killer composition containing flucarbazone-sodium |
| CN103651491A (en) * | 2013-12-19 | 2014-03-26 | 海利尔药业集团股份有限公司 | Weeding composition containing florasulam and flucarbazone |
| CN105360151A (en) * | 2015-07-22 | 2016-03-02 | 南京华洲药业有限公司 | Weeding composition containing clodinafop-propargyl and flucarbazone-sodium and application of weeding composition |
| CN105532704A (en) * | 2015-12-07 | 2016-05-04 | 安徽美兰农业发展股份有限公司 | Dispersible oil suspension of composite herbicide composed of flucarbazone-sodium and clodinafop-propargyl and preparation method thereof |
| CN107660554A (en) * | 2016-07-27 | 2018-02-06 | 海利尔药业集团股份有限公司 | A kind of Herbicidal combinations containing florasulam |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103766372A (en) | Weeding composition containing flucarbazone sodium and saflufenacil | |
| CN102265861B (en) | Mixed herbicide containing bentazone, cyhalofop-butyl and propanil and application thereof | |
| CN105191970A (en) | Pesticide composition containing thiencarbazone-methyl, clodinafop-propargyl and flucarbazone-sodium | |
| CN106577715A (en) | Pesticide composition containing benzene oxazole fluridon, nicosulfuron and fluroxypyr | |
| CN104106576B (en) | A kind of containing metazachlor with the Herbicidal combinations of metribuzin | |
| CN103688991A (en) | Weeding composition containing glufosinate-ammonium and atrazine | |
| CN103688970A (en) | Herbicidal composition containing foramsulfuron and fluroxypyr | |
| CN102273468A (en) | Pesticide composition containing high-efficiency haloxyfop and cloransulammethyl | |
| CN105076200A (en) | Weeding composition containing glyphosate and florasulam | |
| CN105284856A (en) | Weeding combination containing halauxifen-methyl and thiencarbazone-methyl | |
| CN113331188B (en) | Weeding composition and application thereof | |
| CN103503899A (en) | Pesticide composition containing pyribenzoxim and halosulfuron-methyl | |
| CN107114397A (en) | A kind of herbicidal composition containing anilofos, cyhalofop-butyl He metamifop | |
| CN106305749A (en) | Herbicide for controlling weeds in zoysia japonica | |
| CN106359437A (en) | Weeding composition containing clodinafop-propargyl, flucarbazone-sodium and florasulam | |
| CN106665615A (en) | Weeding composition containing penoxsulam, bispyribac-sodium and butachlor | |
| CN106465722A (en) | Herbicidal combinations containing clodinafop-propargyl and pinoxaden and flucarbazone | |
| CN104351215A (en) | Herbicide for potato field | |
| CN104396985A (en) | Sorghum field herbicide | |
| CN103461344A (en) | Wheat filed weeding combination | |
| CN103766373A (en) | Weeding composition containing flucarbazone and bentazone | |
| CN103766374A (en) | Weeding composition containing flucarbazone sodium and tralkoxydim | |
| CN103210934B (en) | Weeding composite | |
| CN104542665A (en) | Phytocidal composition containing mesosulfuron, carfentrazone and fluroxypyr | |
| CN109832296A (en) | A kind of herbicidal composition containing anilofos, cyhalofop-butyl and pyraclonil |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170201 |
|
| RJ01 | Rejection of invention patent application after publication |