CN106349592A - Manufacturing method of polyvinyl chloride cable material - Google Patents

Manufacturing method of polyvinyl chloride cable material Download PDF

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CN106349592A
CN106349592A CN201610717212.0A CN201610717212A CN106349592A CN 106349592 A CN106349592 A CN 106349592A CN 201610717212 A CN201610717212 A CN 201610717212A CN 106349592 A CN106349592 A CN 106349592A
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calcium carbonate
polyvinyl chloride
cable material
carbonate crystal
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付竹兰
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/06Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/13Phenols; Phenolates
    • C08K5/134Phenols containing ester groups
    • C08K5/1345Carboxylic esters of phenolcarboxylic acids
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/52Phosphorus bound to oxygen only
    • C08K5/521Esters of phosphoric acids, e.g. of H3PO4
    • C08K5/523Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/08Oxygen-containing compounds
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    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/08Ingredients agglomerated by treatment with a binding agent
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    • C30CRYSTAL GROWTH
    • C30BSINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
    • C30B29/00Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
    • C30B29/10Inorganic compounds or compositions
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    • C30CRYSTAL GROWTH
    • C30BSINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
    • C30B29/00Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
    • C30B29/60Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape characterised by shape
    • C30B29/62Whiskers or needles
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    • C30CRYSTAL GROWTH
    • C30BSINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
    • C30B7/00Single-crystal growth from solutions using solvents which are liquid at normal temperature, e.g. aqueous solutions
    • C30B7/14Single-crystal growth from solutions using solvents which are liquid at normal temperature, e.g. aqueous solutions the crystallising materials being formed by chemical reactions in the solution
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/443Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29Protection against damage caused by extremes of temperature or by flame
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating

Abstract

The invention provides a manufacturing method of a polyvinyl chloride cable material. The manufacturing method comprises the following steps: (1) mixing magnesium chloride, calcium hydroxide and neodymium chloride; then introducing carbon dioxide; after heating and reacting, carrying out suction filtration, washing with water and drying to obtain calcium carbonate crystal whiskers; (2) carrying out purification treatment on the calcium carbonate crystal whiskers through ammonium chloride to obtain purified calcium carbonate crystal whiskers; (3) compounding the purified calcium carbonate crystal whiskers and zirconium oxychloride to obtain compound calcium carbonate crystal whiskers; (4) carrying out modification treatment on the compound calcium carbonate crystal whiskers through a silane coupling agent and zinc stearate to obtain modified compound calcium carbonate crystal whiskers; (5) weighing raw materials including polyvinyl chloride and the like in parts by weight; (6) mixing and extruding the raw materials and molding to obtain the polyvinyl chloride cable material. The polyvinyl chloride cable material manufactured by the manufacturing method has relatively high impact strength, and also has relatively good heat resistance.

Description

A kind of manufacture method of polyvinyl chloride cable material
Technical field
The present invention relates to a kind of CABLE MATERIALS, more particularly to a kind of manufacture method of polyvinyl chloride cable material.
Background technology
Polrvinyl chloride (pvc) is a kind of polymeric material (or resin), and it is the monomer chloroethene by molecular formula for ch2=chcl Alkene (vcm) multiple stacking forms.In addition to chloride, pvc and polyethylene have identical structure, and chlorine accounts for simple polymerisation tree in pvc The 57% of fat, 3 5% chlorine are derived from the electrolysis of chloral potassium.Pure pvc is granular material, and mechanical hardness is high, extraordinary weather protection Change, the anti-chemical physical performance of waterproof and be electrically insulating material, but pvc is relatively unstable to light and heat, heating and ultraviolet light Result in chlorine to lose in the hydrogen chloride (hcl), this can by plus stabilizer avoid, stabilizer generally by slaine such as lead, Barium, calcium, cadmium or organo-tin compound composition.Pvc has good physics, chemistry, the performance such as electrically, twentieth century three or four because of it The ten's abroad began to the insulant using soft pvc as electric wire, and the development and application of China's PVC cable material start from last century The fifties.The popularization of the raising with pvc resin, plasticizer and commercial auxiliaries production capacity and new varieties and application and development, Cable industry has qualitative leap.
For example, Publication No. cn102924847b, publication date are 2015.06.03, apply for that artificial hundred million profit resource groups are limited The Chinese patent of company discloses " a kind of thermal reversion crosslinking PVC cable material and preparation method thereof ", and described PVC cable material is by following The raw material of component and parts by weight is made: 100 parts of pvc resin;Stabilizer 2-4 part;Plasticizer 10-40 part;Inorganic filler 10-50 Part;Thermal-reversible cross-linking agent 0.5-5 part;Lubricant 0.5-2 part;Antioxidant 0.2-2 part;Fire retardant 10-30 part;This PVC cable material Preparation method include dispensing, the at a high speed processing step such as blending, extruding pelletization, drying;With respect to prior art, this invention prominent Going out feature is to be blended with pvc using a kind of special cross-linking agent of pvc that thermal reversion can be occurred crosslinked, then by with pvc chain Upper active chlorine reacts and causes cross-linking agent, pvc covalent cross-linking, thus improving the heat stability of pvc cable, thermostability and keeping Original thermoplasticity.But, although this CABLE MATERIALS improves thermostability, its impact strength aspect is still poor.
Content of the invention
The technical problem to be solved in the present invention is to provide a kind of manufacture method of polyvinyl chloride cable material, the polychlorostyrene producing The impact strength of ethylene CABLE MATERIALS is higher, and its thermostability is also preferable simultaneously.
For solving above-mentioned technical problem, the technical scheme is that
A kind of manufacture method of polyvinyl chloride cable material, comprises the following steps:
(1) magnesium chloride solution is added in aqua calcises, stirring under room temperature added Neodymium chloride after 40 minutes, continued to stir Obtain mixed solution after mixing 20 minutes, mixed solution is added in flask, after being heated to 75 DEG C, be passed through carbon dioxide, reaction 2 is little When after be precipitated thing by after product sucking filtration, will precipitate aqueouss to neutrality after be dried under vacuum to constant weight, obtain calcium carbonate crystal whisker;
(2) calcium carbonate crystal whisker is added in ammonium chloride solution, react 8 hours after being heated to 90 DEG C, be filtrated to get after taking-up Filtering residue, filtering residue is washed to after neutrality and is dried under vacuum to constant weight, obtains purification calcium carbonate crystal whisker;
(3) purification calcium carbonate crystal whisker is added in deionized water, stir to forming uniform suspension, after being heated to 65 DEG C It is added dropwise to basic zirconium chloride, controls ph value to be 2, drip stirring reaction 3 hours after finishing, standing is layered after 1 hour, lower sediment thing is taken It is washed to neutrality after going out, be placed in calcining at 500 DEG C in Muffle furnace after vacuum drying and obtain composite calcium carbonate whisker in 3 hours;
(4) silane coupler, zinc octadecanate are added in dehydrated alcohol, obtain modified solution after stirring, will be combined Calcium carbonate crystal whisker adds in deionized water, stirs to forming uniform slip, after being heated to 75 DEG C, modified solution is added slip In, stirring reaction after 1 hour while hot sucking filtration obtain filter cake, filter cake is washed to vacuum drying after neutrality and obtains modified compound carbonic acid Calcium pyroborate;
(5) raw material: 100 parts of Corvic, heat stabilizer 3-4 part, antioxidant 0.4-0.9 are weighed by following weight portion Part, light stabilizer 1-1.5 part, plasticizer 18-23 part, fire retardant 11-16 part, modified composite calcium carbonate whisker 12-18 part;
(6) Corvic, heat stabilizer, plasticizer, fire retardant are added in mixer, mix 20 minutes at 60 DEG C Add other components afterwards, mixing after being heated to 80 DEG C obtains compound in 40 minutes, it is the double of 22:1 that compound is put into draw ratio In screw extruder, 160-190 DEG C, extrusion molding under 50rpm speed conditions, obtain polyvinyl chloride cable material.
Preferably, in step (1) of the present invention, magnesium, calcium, the mol ratio of neodymium are 1.6:1:0.1.
Preferably, in step (2) of the present invention, the concentration of ammonium chloride solution is 2.5mol/l, calcium carbonate crystal whisker and chlorine The solid-to-liquid ratio changing ammonium salt solution is 1:6.
Preferably, in step (3) of the present invention, purification calcium carbonate crystal whisker, the weight of basic zirconium chloride are than for 18:1.
Preferably, in step (4) of the present invention, silane coupler, zinc octadecanate, the weight of dehydrated alcohol are than for 1.4: 1:40, than for 1:11, modified solution, the weight of slip are than for 1:20 for composite calcium carbonate whisker, the weight of deionized water.
Preferably, in step (4) of the present invention, heat stabilizer is rare earth thermal stabilizer.
Preferably, in step (5) of the present invention, antioxidant is antioxidant 1076.
Preferably, in step (5) of the present invention, light stabilizer is gw-310.
Preferably, in step (5) of the present invention, plasticizer is triphenyl phosphate.
Preferably, in step (5) of the present invention, fire retardant is tdcpp.
Compared with prior art, the method have the advantages that
1) present invention is first obtained shape by being passed through carbon dioxide after magnesium chloride, calcium hydroxide, Neodymium chloride mixing by carbonatation process The Aragonite Style Calcium Carbonate Whiskers that looks are good, mechanical performance is excellent, wherein, magnesium chloride is chemical additives, and Neodymium chloride then can be effective Improve calcium carbonate crystal whisker consistency, then by calcium carbonate crystal whisker pass through ammonium chloride by magnesium therein carried out effective removal thus Obtain the purification calcium carbonate crystal whisker of high purity more than 96%, then obtained compound to purification calcium carbonate crystal whisker and basic zirconium chloride Doped with the composite calcium carbonate whisker of zr element, the presence of zirconium effectively increases the hot property of calcium carbonate crystal whisker, therefore composite carbon The mechanical performance of sour calcium pyroborate and hot property are all preferable, with polychloroethylene blended after can improve well CABLE MATERIALS shock resistance strong Degree and thermostability.
2) composite calcium carbonate whisker surface is hydrophilic, and polyvinyl chloride surface is then hydrophobicity, phase therefore therebetween Capacitive is not good, and directly blending effect is bad, and therefore composite calcium carbonate whisker is entered by the present invention by silane coupler, zinc octadecanate Row modification, the hydrophilic on composite calcium carbonate whisker surface is become hydrophobicity, thus significantly improving therebetween The compatibility and adhesion, further increase impact strength and the thermostability of CABLE MATERIALS;Additionally, with respect to existing single idol For connection agent or other modifying agent, the silane coupler that the present invention adopts and zinc octadecanate can form Synergistic, to composite carbon The modified effect of sour calcium pyroborate is also more preferable.
Specific embodiment
To describe the present invention, the illustrative examples of the here present invention and explanation below in conjunction with specific embodiment in detail It is used for explaining the present invention, but not as a limitation of the invention.
Embodiment 1
According to following steps manufacture polyvinyl chloride cable material:
(1) will magnesium chloride solution add aqua calcises in, under room temperature stirring 40 minutes after add Neodymium chloride, magnesium, calcium, The mol ratio of neodymium is 1.6:1:0.1, obtains mixed solution after continuing stirring 20 minutes, mixed solution is added in flask, heating It is passed through carbon dioxide to after 75 DEG C, reaction was precipitated thing by after product sucking filtration after 2 hours, will be true after precipitate aqueouss to neutrality Sky is dried to constant weight, obtains calcium carbonate crystal whisker;
(2) calcium carbonate crystal whisker is added in the ammonium chloride solution that concentration is 2.5mol/l, calcium carbonate crystal whisker is molten with ammonium chloride The solid-to-liquid ratio of liquid is 1:6, reacts 8 hours, be filtrated to get filtering residue after taking-up after being heated to 90 DEG C, filtering residue is washed to true after neutrality Sky is dried to constant weight, obtains purification calcium carbonate crystal whisker;
(3) purification calcium carbonate crystal whisker is added in deionized water, stir to forming uniform suspension, after being heated to 65 DEG C It is added dropwise to basic zirconium chloride, purification calcium carbonate crystal whisker, the weight ratio of basic zirconium chloride for 18:1, control ph value to be 2, drip stirring after finishing anti- Answer 3 hours, standing was layered after 1 hour, is washed to neutrality, is placed in Muffle furnace after vacuum drying after lower sediment thing is taken out At 500 DEG C, calcining obtains composite calcium carbonate whisker in 3 hours;
(4) silane coupler, zinc octadecanate are added in dehydrated alcohol, silane coupler, zinc octadecanate, dehydrated alcohol Weight ratio for 1.4:1:40, obtains modified solution after stirring, composite calcium carbonate whisker is added in deionized water, composite carbon Sour calcium pyroborate, the weight of deionized water, than for 1:11, stir to forming uniform slip, after being heated to 75 DEG C by modified solution plus Enter in slip, modified solution, the weight of slip than for 1:20, stirring reaction after 1 hour while hot sucking filtration obtain filter cake, by filter cake water After being washed till neutrality, vacuum drying obtains modified composite calcium carbonate whisker;
(5) raw material: 100 parts of Corvic, 3 parts of rare earth thermal stabilizer, antioxidant 1076 are weighed by following weight portion 0.9 part, 1.4 parts of gw-310,19 parts of triphenyl phosphate, 13 parts of tdcpp, 14 parts of modified composite calcium carbonate whisker;
(6) Corvic, rare earth thermal stabilizer, triphenyl phosphate, tdcpp are added in mixer, mixed at 60 DEG C Add other components after closing 20 minutes, mixing after being heated to 80 DEG C obtains compound in 40 minutes, compound input draw ratio is In the double screw extruder of 22:1,160-190 DEG C, extrusion molding under 50rpm speed conditions, obtain polyvinyl chloride cable material.
Embodiment 2
According to following steps manufacture polyvinyl chloride cable material:
(1) will magnesium chloride solution add aqua calcises in, under room temperature stirring 40 minutes after add Neodymium chloride, magnesium, calcium, The mol ratio of neodymium is 1.6:1:0.1, obtains mixed solution after continuing stirring 20 minutes, mixed solution is added in flask, heating It is passed through carbon dioxide to after 75 DEG C, reaction was precipitated thing by after product sucking filtration after 2 hours, will be true after precipitate aqueouss to neutrality Sky is dried to constant weight, obtains calcium carbonate crystal whisker;
(2) calcium carbonate crystal whisker is added in the ammonium chloride solution that concentration is 2.5mol/l, calcium carbonate crystal whisker is molten with ammonium chloride The solid-to-liquid ratio of liquid is 1:6, reacts 8 hours, be filtrated to get filtering residue after taking-up after being heated to 90 DEG C, filtering residue is washed to true after neutrality Sky is dried to constant weight, obtains purification calcium carbonate crystal whisker;
(3) purification calcium carbonate crystal whisker is added in deionized water, stir to forming uniform suspension, after being heated to 65 DEG C It is added dropwise to basic zirconium chloride, purification calcium carbonate crystal whisker, the weight ratio of basic zirconium chloride for 18:1, control ph value to be 2, drip stirring after finishing anti- Answer 3 hours, standing was layered after 1 hour, is washed to neutrality, is placed in Muffle furnace after vacuum drying after lower sediment thing is taken out At 500 DEG C, calcining obtains composite calcium carbonate whisker in 3 hours;
(4) silane coupler, zinc octadecanate are added in dehydrated alcohol, silane coupler, zinc octadecanate, dehydrated alcohol Weight ratio for 1.4:1:40, obtains modified solution after stirring, composite calcium carbonate whisker is added in deionized water, composite carbon Sour calcium pyroborate, the weight of deionized water, than for 1:11, stir to forming uniform slip, after being heated to 75 DEG C by modified solution plus Enter in slip, modified solution, the weight of slip than for 1:20, stirring reaction after 1 hour while hot sucking filtration obtain filter cake, by filter cake water After being washed till neutrality, vacuum drying obtains modified composite calcium carbonate whisker;
(5) raw material: 100 parts of Corvic, 3.2 parts of rare earth thermal stabilizer, antioxidant are weighed by following weight portion 1076 0.7 parts, 1.2 parts of gw-310,21 parts of triphenyl phosphate, 11 parts of tdcpp, 18 parts of modified composite calcium carbonate whisker;
(6) Corvic, rare earth thermal stabilizer, triphenyl phosphate, tdcpp are added in mixer, mixed at 60 DEG C Add other components after closing 20 minutes, mixing after being heated to 80 DEG C obtains compound in 40 minutes, compound input draw ratio is In the double screw extruder of 22:1,160-190 DEG C, extrusion molding under 50rpm speed conditions, obtain polyvinyl chloride cable material.
Embodiment 3
According to following steps manufacture polyvinyl chloride cable material:
(1) will magnesium chloride solution add aqua calcises in, under room temperature stirring 40 minutes after add Neodymium chloride, magnesium, calcium, The mol ratio of neodymium is 1.6:1:0.1, obtains mixed solution after continuing stirring 20 minutes, mixed solution is added in flask, heating It is passed through carbon dioxide to after 75 DEG C, reaction was precipitated thing by after product sucking filtration after 2 hours, will be true after precipitate aqueouss to neutrality Sky is dried to constant weight, obtains calcium carbonate crystal whisker;
(2) calcium carbonate crystal whisker is added in the ammonium chloride solution that concentration is 2.5mol/l, calcium carbonate crystal whisker is molten with ammonium chloride The solid-to-liquid ratio of liquid is 1:6, reacts 8 hours, be filtrated to get filtering residue after taking-up after being heated to 90 DEG C, filtering residue is washed to true after neutrality Sky is dried to constant weight, obtains purification calcium carbonate crystal whisker;
(3) purification calcium carbonate crystal whisker is added in deionized water, stir to forming uniform suspension, after being heated to 65 DEG C It is added dropwise to basic zirconium chloride, purification calcium carbonate crystal whisker, the weight ratio of basic zirconium chloride for 18:1, control ph value to be 2, drip stirring after finishing anti- Answer 3 hours, standing was layered after 1 hour, is washed to neutrality, is placed in Muffle furnace after vacuum drying after lower sediment thing is taken out At 500 DEG C, calcining obtains composite calcium carbonate whisker in 3 hours;
(4) silane coupler, zinc octadecanate are added in dehydrated alcohol, silane coupler, zinc octadecanate, dehydrated alcohol Weight ratio for 1.4:1:40, obtains modified solution after stirring, composite calcium carbonate whisker is added in deionized water, composite carbon Sour calcium pyroborate, the weight of deionized water, than for 1:11, stir to forming uniform slip, after being heated to 75 DEG C by modified solution plus Enter in slip, modified solution, the weight of slip than for 1:20, stirring reaction after 1 hour while hot sucking filtration obtain filter cake, by filter cake water After being washed till neutrality, vacuum drying obtains modified composite calcium carbonate whisker;
(5) raw material: 100 parts of Corvic, 3.4 parts of rare earth thermal stabilizer, antioxidant are weighed by following weight portion 1076 0.5 parts, 1 part of gw-310,23 parts of triphenyl phosphate, 15 parts of tdcpp, 16 parts of modified composite calcium carbonate whisker;
(6) Corvic, rare earth thermal stabilizer, triphenyl phosphate, tdcpp are added in mixer, mixed at 60 DEG C Add other components after closing 20 minutes, mixing after being heated to 80 DEG C obtains compound in 40 minutes, compound input draw ratio is In the double screw extruder of 22:1,160-190 DEG C, extrusion molding under 50rpm speed conditions, obtain polyvinyl chloride cable material.
Embodiment 4
According to following steps manufacture polyvinyl chloride cable material:
(1) will magnesium chloride solution add aqua calcises in, under room temperature stirring 40 minutes after add Neodymium chloride, magnesium, calcium, The mol ratio of neodymium is 1.6:1:0.1, obtains mixed solution after continuing stirring 20 minutes, mixed solution is added in flask, heating It is passed through carbon dioxide to after 75 DEG C, reaction was precipitated thing by after product sucking filtration after 2 hours, will be true after precipitate aqueouss to neutrality Sky is dried to constant weight, obtains calcium carbonate crystal whisker;
(2) calcium carbonate crystal whisker is added in the ammonium chloride solution that concentration is 2.5mol/l, calcium carbonate crystal whisker is molten with ammonium chloride The solid-to-liquid ratio of liquid is 1:6, reacts 8 hours, be filtrated to get filtering residue after taking-up after being heated to 90 DEG C, filtering residue is washed to true after neutrality Sky is dried to constant weight, obtains purification calcium carbonate crystal whisker;
(3) purification calcium carbonate crystal whisker is added in deionized water, stir to forming uniform suspension, after being heated to 65 DEG C It is added dropwise to basic zirconium chloride, purification calcium carbonate crystal whisker, the weight ratio of basic zirconium chloride for 18:1, control ph value to be 2, drip stirring after finishing anti- Answer 3 hours, standing was layered after 1 hour, is washed to neutrality, is placed in Muffle furnace after vacuum drying after lower sediment thing is taken out At 500 DEG C, calcining obtains composite calcium carbonate whisker in 3 hours;
(4) silane coupler, zinc octadecanate are added in dehydrated alcohol, silane coupler, zinc octadecanate, dehydrated alcohol Weight ratio for 1.4:1:40, obtains modified solution after stirring, composite calcium carbonate whisker is added in deionized water, composite carbon Sour calcium pyroborate, the weight of deionized water, than for 1:11, stir to forming uniform slip, after being heated to 75 DEG C by modified solution plus Enter in slip, modified solution, the weight of slip than for 1:20, stirring reaction after 1 hour while hot sucking filtration obtain filter cake, by filter cake water After being washed till neutrality, vacuum drying obtains modified composite calcium carbonate whisker;
(5) raw material: 100 parts of Corvic, 3.8 parts of rare earth thermal stabilizer, antioxidant are weighed by following weight portion 1076 0.6 parts, 1.3 parts of gw-310,20 parts of triphenyl phosphate, 16 parts of tdcpp, 12 parts of modified composite calcium carbonate whisker;
(6) Corvic, rare earth thermal stabilizer, triphenyl phosphate, tdcpp are added in mixer, mixed at 60 DEG C Add other components after closing 20 minutes, mixing after being heated to 80 DEG C obtains compound in 40 minutes, compound input draw ratio is In the double screw extruder of 22:1,160-190 DEG C, extrusion molding under 50rpm speed conditions, obtain polyvinyl chloride cable material.
Embodiment 5
According to following steps manufacture polyvinyl chloride cable material:
(1) will magnesium chloride solution add aqua calcises in, under room temperature stirring 40 minutes after add Neodymium chloride, magnesium, calcium, The mol ratio of neodymium is 1.6:1:0.1, obtains mixed solution after continuing stirring 20 minutes, mixed solution is added in flask, heating It is passed through carbon dioxide to after 75 DEG C, reaction was precipitated thing by after product sucking filtration after 2 hours, will be true after precipitate aqueouss to neutrality Sky is dried to constant weight, obtains calcium carbonate crystal whisker;
(2) calcium carbonate crystal whisker is added in the ammonium chloride solution that concentration is 2.5mol/l, calcium carbonate crystal whisker is molten with ammonium chloride The solid-to-liquid ratio of liquid is 1:6, reacts 8 hours, be filtrated to get filtering residue after taking-up after being heated to 90 DEG C, filtering residue is washed to true after neutrality Sky is dried to constant weight, obtains purification calcium carbonate crystal whisker;
(3) purification calcium carbonate crystal whisker is added in deionized water, stir to forming uniform suspension, after being heated to 65 DEG C It is added dropwise to basic zirconium chloride, purification calcium carbonate crystal whisker, the weight ratio of basic zirconium chloride for 18:1, control ph value to be 2, drip stirring after finishing anti- Answer 3 hours, standing was layered after 1 hour, is washed to neutrality, is placed in Muffle furnace after vacuum drying after lower sediment thing is taken out At 500 DEG C, calcining obtains composite calcium carbonate whisker in 3 hours;
(4) silane coupler, zinc octadecanate are added in dehydrated alcohol, silane coupler, zinc octadecanate, dehydrated alcohol Weight ratio for 1.4:1:40, obtains modified solution after stirring, composite calcium carbonate whisker is added in deionized water, composite carbon Sour calcium pyroborate, the weight of deionized water, than for 1:11, stir to forming uniform slip, after being heated to 75 DEG C by modified solution plus Enter in slip, modified solution, the weight of slip than for 1:20, stirring reaction after 1 hour while hot sucking filtration obtain filter cake, by filter cake water After being washed till neutrality, vacuum drying obtains modified composite calcium carbonate whisker;
(5) raw material: 100 parts of Corvic, 3.6 parts of rare earth thermal stabilizer, antioxidant are weighed by following weight portion 1076 0.8 parts, 1.5 parts of gw-310,18 parts of triphenyl phosphate, 12 parts of tdcpp, 15 parts of modified composite calcium carbonate whisker;
(6) Corvic, rare earth thermal stabilizer, triphenyl phosphate, tdcpp are added in mixer, mixed at 60 DEG C Add other components after closing 20 minutes, mixing after being heated to 80 DEG C obtains compound in 40 minutes, compound input draw ratio is In the double screw extruder of 22:1,160-190 DEG C, extrusion molding under 50rpm speed conditions, obtain polyvinyl chloride cable material.
Embodiment 6
According to following steps manufacture polyvinyl chloride cable material:
(1) will magnesium chloride solution add aqua calcises in, under room temperature stirring 40 minutes after add Neodymium chloride, magnesium, calcium, The mol ratio of neodymium is 1.6:1:0.1, obtains mixed solution after continuing stirring 20 minutes, mixed solution is added in flask, heating It is passed through carbon dioxide to after 75 DEG C, reaction was precipitated thing by after product sucking filtration after 2 hours, will be true after precipitate aqueouss to neutrality Sky is dried to constant weight, obtains calcium carbonate crystal whisker;
(2) calcium carbonate crystal whisker is added in the ammonium chloride solution that concentration is 2.5mol/l, calcium carbonate crystal whisker is molten with ammonium chloride The solid-to-liquid ratio of liquid is 1:6, reacts 8 hours, be filtrated to get filtering residue after taking-up after being heated to 90 DEG C, filtering residue is washed to true after neutrality Sky is dried to constant weight, obtains purification calcium carbonate crystal whisker;
(3) purification calcium carbonate crystal whisker is added in deionized water, stir to forming uniform suspension, after being heated to 65 DEG C It is added dropwise to basic zirconium chloride, purification calcium carbonate crystal whisker, the weight ratio of basic zirconium chloride for 18:1, control ph value to be 2, drip stirring after finishing anti- Answer 3 hours, standing was layered after 1 hour, is washed to neutrality, is placed in Muffle furnace after vacuum drying after lower sediment thing is taken out At 500 DEG C, calcining obtains composite calcium carbonate whisker in 3 hours;
(4) silane coupler, zinc octadecanate are added in dehydrated alcohol, silane coupler, zinc octadecanate, dehydrated alcohol Weight ratio for 1.4:1:40, obtains modified solution after stirring, composite calcium carbonate whisker is added in deionized water, composite carbon Sour calcium pyroborate, the weight of deionized water, than for 1:11, stir to forming uniform slip, after being heated to 75 DEG C by modified solution plus Enter in slip, modified solution, the weight of slip than for 1:20, stirring reaction after 1 hour while hot sucking filtration obtain filter cake, by filter cake water After being washed till neutrality, vacuum drying obtains modified composite calcium carbonate whisker;
(5) raw material: 100 parts of Corvic, 4 parts of rare earth thermal stabilizer, antioxidant 1076 are weighed by following weight portion 0.4 part, 1.1 parts of gw-310,22 parts of triphenyl phosphate, 14 parts of tdcpp, 17 parts of modified composite calcium carbonate whisker;
(6) Corvic, rare earth thermal stabilizer, triphenyl phosphate, tdcpp are added in mixer, mixed at 60 DEG C Add other components after closing 20 minutes, mixing after being heated to 80 DEG C obtains compound in 40 minutes, compound input draw ratio is In the double screw extruder of 22:1,160-190 DEG C, extrusion molding under 50rpm speed conditions, obtain polyvinyl chloride cable material.
The polyvinyl chloride cable material that embodiment 1-6 is obtained and the impact strength of comparative example and thermostability are carried out respectively Test, comparative example is the Chinese patent of Publication No. cn102924847b.Impact strength is with reference to gb/t 1843-2008 standard With the test of Charpy Impact experimental machine, then reference gb/t 1633-2000 standard tests each electricity with the heat-resisting instrument of dimension card to thermostability aspect The vicat softening temperature of cable material, this temperature value is higher to represent that thermostability is better.
Test result see table:
As can be seen from the above table, the impact strength of the polyvinyl chloride cable material that embodiment of the present invention 1-6 is obtained is substantially high In comparative example, and vicat softening temperature is slightly less than comparative example, represents that thermostability is preferable.
Above-described embodiment only principle of the illustrative present invention and its effect, not for the restriction present invention.Any ripe The personage knowing this technology all can carry out modifications and changes without prejudice under the spirit and the scope of the present invention to above-described embodiment.Cause This, those of ordinary skill in the art is complete with institute under technological thought without departing from disclosed spirit such as All equivalent modifications becoming or change, must be covered by the claim of the present invention.

Claims (10)

1. a kind of manufacture method of polyvinyl chloride cable material is it is characterised in that comprise the following steps:
(1) magnesium chloride solution is added in aqua calcises, stirring under room temperature added Neodymium chloride after 40 minutes, continued stirring 20 Obtain mixed solution after minute, mixed solution is added in flask, after being heated to 75 DEG C, be passed through carbon dioxide, after reacting 2 hours It is precipitated thing by after product sucking filtration, be dried under vacuum to constant weight by after precipitate aqueouss to neutrality, obtain calcium carbonate crystal whisker;
(2) calcium carbonate crystal whisker is added in ammonium chloride solution, reacts 8 hours after being heated to 90 DEG C, after taking-up, be filtrated to get filtering residue, Filtering residue is washed to after neutrality and is dried under vacuum to constant weight, obtain purification calcium carbonate crystal whisker;
(3) purification calcium carbonate crystal whisker is added in deionized water, stir to forming uniform suspension, Deca after being heated to 65 DEG C Enter basic zirconium chloride, control ph value to be 2, drip stirring reaction 3 hours after finishing, standing was layered after 1 hour, after lower sediment thing is taken out It is washed to neutrality, be placed in calcining at 500 DEG C in Muffle furnace after vacuum drying and obtain composite calcium carbonate whisker in 3 hours;
(4) silane coupler, zinc octadecanate are added in dehydrated alcohol, obtain modified solution after stirring, by compound carbonic acid Calcium pyroborate adds in deionized water, stirs to forming uniform slip, adds modified solution in slip, stir after being heated to 75 DEG C After mixing reaction 1 hour, sucking filtration obtains filter cake while hot, and filter cake is washed to vacuum drying after neutrality, and to obtain modified composite calcium carbonate brilliant Palpus;
(5) weigh raw material: 100 parts of Corvic by following weight portion, heat stabilizer 3-4 part, antioxidant 0.4-0.9 part, Light stabilizer 1-1.5 part, plasticizer 18-23 part, fire retardant 11-16 part, modified composite calcium carbonate whisker 12-18 part;
(6) Corvic, heat stabilizer, plasticizer, fire retardant are added in mixer, mixing at 60 DEG C added after 20 minutes Enter other components, mixing after being heated to 80 DEG C obtains compound in 40 minutes, compound is put into the twin screw that draw ratio is 22:1 In extruder, 160-190 DEG C, extrusion molding under 50rpm speed conditions, obtain polyvinyl chloride cable material.
2. a kind of polyvinyl chloride cable material according to claim 1 manufacture method it is characterised in that: described step (1) In, magnesium, calcium, the mol ratio of neodymium are 1.6:1:0.1.
3. a kind of polyvinyl chloride cable material according to claim 2 manufacture method it is characterised in that: described step (2) In, the concentration of ammonium chloride solution is 2.5mol/l, and calcium carbonate crystal whisker is 1:6 with the solid-to-liquid ratio of ammonium chloride solution.
4. a kind of polyvinyl chloride cable material according to claim 3 manufacture method it is characterised in that: described step (3) In, purification calcium carbonate crystal whisker, the weight of basic zirconium chloride are than for 18:1.
5. a kind of polyvinyl chloride cable material according to claim 4 manufacture method it is characterised in that: described step (4) In, silane coupler, zinc octadecanate, the weight of dehydrated alcohol are than for 1.4:1:40, composite calcium carbonate whisker, the weight of deionized water , than being 1:11, modified solution, the weight ratio of slip are for 1:20 for amount.
6. a kind of polyvinyl chloride cable material according to claim 5 manufacture method it is characterised in that: described step (4) In, heat stabilizer is rare earth thermal stabilizer.
7. a kind of polyvinyl chloride cable material according to claim 6 manufacture method it is characterised in that: described step (5) In, antioxidant is antioxidant 1076.
8. a kind of polyvinyl chloride cable material according to claim 7 manufacture method it is characterised in that: described step (5) In, light stabilizer is gw-310.
9. a kind of polyvinyl chloride cable material according to claim 8 manufacture method it is characterised in that: described step (5) In, plasticizer is triphenyl phosphate.
10. a kind of polyvinyl chloride cable material according to claim 9 manufacture method it is characterised in that: described step (5) In, fire retardant is tdcpp.
CN201610717212.0A 2016-08-24 2016-08-24 Manufacturing method of polyvinyl chloride cable material Pending CN106349592A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112679876A (en) * 2020-11-27 2021-04-20 杭州龙源电力有限公司 Environment-friendly wear-resistant non-crosslinked polyvinyl chloride material and cable

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102924847A (en) * 2012-11-08 2013-02-13 亿利资源集团有限公司 Heat reversible crosslinking polyvinyl chloride (PVC) cable material and preparation method thereof
CN102964725A (en) * 2012-12-04 2013-03-13 青岛鑫万通塑业发展有限公司 Economic and environment-friendly polymer-based cable bridge
CN103275427A (en) * 2013-06-18 2013-09-04 张宇 PVC cable material and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102924847A (en) * 2012-11-08 2013-02-13 亿利资源集团有限公司 Heat reversible crosslinking polyvinyl chloride (PVC) cable material and preparation method thereof
CN102964725A (en) * 2012-12-04 2013-03-13 青岛鑫万通塑业发展有限公司 Economic and environment-friendly polymer-based cable bridge
CN103275427A (en) * 2013-06-18 2013-09-04 张宇 PVC cable material and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112679876A (en) * 2020-11-27 2021-04-20 杭州龙源电力有限公司 Environment-friendly wear-resistant non-crosslinked polyvinyl chloride material and cable

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Application publication date: 20170125