CN106345214A - Water-base emergent rapid purifying agent for haze (fine particulate matters) - Google Patents

Water-base emergent rapid purifying agent for haze (fine particulate matters) Download PDF

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Publication number
CN106345214A
CN106345214A CN201610730101.3A CN201610730101A CN106345214A CN 106345214 A CN106345214 A CN 106345214A CN 201610730101 A CN201610730101 A CN 201610730101A CN 106345214 A CN106345214 A CN 106345214A
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haze
water
fine particle
urgent need
purification agent
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周端午
易坚
周恩施
周思贝
袁明俊
肖建如
邓召利
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Hunan Energy Gathering New Mstar Technology Ltd
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Hunan Energy Gathering New Mstar Technology Ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D51/00—Auxiliary pretreatment of gases or vapours to be cleaned
    • B01D51/02—Amassing the particles, e.g. by flocculation
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16—Heavy metals; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/91—Bacteria; Microorganisms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/06—Polluted air

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Environmental Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
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  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention relates to a water-base emergent rapid purifying agent for haze (fine particulate matters). The water-base emergent rapid cleaning agent is used for emergently and rapidly purifying heavy haze (the fine particulate matters are more than or equal to 250 microgram/m<3>) and particularly emergently and rapidly purifying harmful components (organic matters, polyaromatic hydrocarbon, bacteria and viruses) in the haze. The water-base emergent rapid purifying agent is prepared from toxic-free, harmless, easily degradable matters and natural edible matters and is safe and environmentally friendly. The water-base emergent rapid purifying agent has the beneficial effect that the cost of the purifying agent which is used for purifying each 1m<3> heavy-polluted hazed air is only 0.00004 Yuan (RMB). Therefore, the water-base emergent rapid purifying agent can be actually used for rapidly purifying the haze in mist of airplanes, killing harmful microorganisms in the haze, catalyzing and decomposing harmful organic matters in the haze and converting the harmful organic matters into water and CO2.

Description

Water base haze (fine particle) is met an urgent need fast purification agent
Technical field
The fast purification agent the present invention relates to a kind of water base haze (fine particle) is met an urgent need.More specifically to a kind of water base Haze (pm2.5) is met an urgent need fast purification agent, belongs to public health and security fields.
Background technology
Haze is also called fine particle, pm2.5.Fine particle finger ring border in the air equivalent aerodynamic diameter be less than etc. In 2.5 microns of particulate matter.It can be suspended in the air long period, its in atmosphere content concn higher, just represent sky Gas pollution is more serious.Although pm2.5 is the little component of content in earth atmosphere composition, it is to air quality and visibility Etc. there being important impact.Compared with thicker Atmospheric particulates, pm2.5 particle diameter is little, and area is big, and activity is strong, easily subsidiary poisonous, have Evil material (for example, heavy metal, microorganism etc.), and time of staying length in an atmosphere, fed distance are remote, thus to health Bigger with the impact of atmosphere quality.
The chemical composition of pm2.5 includes inorganic constituentss, organic principle, minor metallic element, elemental carbon, biological substance (carefully Bacterium, pathogenic bacteria, mycete etc.) etc..Carbon contg particle in air is made up of the elemental carbon (ec) of organic carbon (oc) and extinction, element Similar to impure graphite, organic carbon is content highest component in pm2.5 to the chemical constitution of carbon.
In air, fine particle mainly has Water-soluble inorganic ions, carbonaceous material and insoluble mineral to constitute, wherein water-soluble Property inorganic ionss and carbonaceous material are mainly derived from the combustion process of all kinds of Fossil fuels and biomass, and gaseous contaminant Conversion.Pm2.5 is by being directly discharged into the primary particle of in the air and the gaseous contaminant of in the air is generated by chemical conversion two Secondary particle composition.The primary particle mainly carbon black (organic carbon) producing that burns by dust particle and by plant and fossil fuel Particle two big class forms.Offspring is mainly by ammonium sulfate and ammonium nitrate (reacting generation by so2 and nox in air and nh3) Composition, the main process that it forms is gaseous contaminant so2 and nox in air by homogeneous or heterogeneous oxidation shape Become acid aerosol, then generate ammonium sulfate (ammonium sulfite) and ammonium nitrate gas with the gas nh3 reaction of meta-alkalescence unique in air Sol particles.Water droplet in air is that these chemical conversion process provide important precondition.So, the water droplet in air Just easily become the secondary pollution important medium that low latitude constantly accumulates below 1000 meters.
Organic substance is the important chemical species in Chinese pm2.5；so4 2-, so3 2-, no3 -, nh4 +, cl-It is East China Topmost chemical species in pm2.5；The high-load of soil dirt is a feature of Chinese pm2.5, on the ground being affected by sand and dust Area and season are more so.
Polycyclic aromatic hydrocarbon (polycyclic aromatic hydrocarbons, abbreviation pahs) is the weight of Atmospheric particulates Want ingredient, be a kind of carcinogenic, teratogenesis, mutagenic material, participate in biological and human body metabolism, have very strong Toxicity.
The composition of haze particulate matter is very complicated, depends primarily on its source.Mainly there are natural source and two kinds of artificial source, but danger That evil is larger is the latter.
Natural source include soil airborne dust (containing oxide mineral and other compositions) sea salt (the second largest source of particulate matter, Its composition is similar with the composition of sea water), plant pollen, spore, antibacterial etc..
Artificial source includes stationary source and mobile source.Stationary source includes various fuel combustion sources, such as generating, metallurgy, oil, change The various industrial process such as, textile printing and dyeing, heat supply, the coal-fired flue dust with combustion gas or fuel emission in gastronomical process.Mobile source master If all kinds of vehicles when in running using fuel to air in discharge tail gas.Between past 50 years, due to Gradually made no public appearances using coal in the family in London and industry, traffic emission becomes the source of the maximum of air pollution. The nitrogen oxides of London in the air 58%, and 68% pm10 contaminant particle both is from motor vehicle exhaust emission.Indoors, two Handss cigarette is the topmost source of particulate matter.
Although fine particle is the little component of content in earth atmosphere composition, research shows, fine particle is to human body The harm of health is bigger, because diameter is less, the position entering respiratory tract is deeper.The particulate matter of 10 μ m diameter is usually deposited at Upper respiratory tract, less than 2 μm of be deep into bronchioless and alveolar.Fine particle enters human body to after alveolar, directly affects lung Ventilatory function, make body easily be in anaerobic condition.
" the global environment prospect 5 " of United Nations Environment Programme's announcement in 2012 points out have 700,000 people to die from because smelly every year The respiratory system disease that oxygen leads to, have nearly 2,000,000 premature death case relevant with Particulate Pollution." NAS Proceeding " (pnas) also delivered research report, claims in report, and the average life of the mankind is because air pollution is likely to shorten 5 years half.
The report that World Health Organization (WHO) issues shows, the premature death number being led to by outdoor air pollution, and average out to is every Its 1000 people, has 35 to 40 ten thousand people to be faced with death every year.Specifically, early in 1997, World Health Organization (WHO) is just expected There are 50,000 Chinese because air pollution and premature death.On the whole, this part report finds, the air pollution of China makes city The life-span of city resident decreases 18 years.
On October 17th, 2013, international cancer research institution of World Health Organization (WHO) issued report, pointed out atmospheric pollution pair first The mankind are carcinogenic, and regard it as universal and main environmental carcinogen.When the concentration of in the air pm2.5 is higher than 10 μ g/m for a long time, just The rising of mortality risk can be brought.Concentration often increases by 10 μ g/m, and total mortality risk rises 4%, the dead wind that heart and lung diseases bring Danger rises 6%, and the mortality risk that pulmonary carcinoma is brought rises 8%.Additionally, the organic pollution such as pm2.5 easily absorbing multiring aromatic hydrocarbon and weight Metal, makes carcinogenic, teratogenesis, mutagenic probability significantly raised.
In addition, pm2.5 can affect into cloud and rainfall, remote-effects climate change.Under the conditions of some, pm2.5 meeting Increase the quantity of the nuclei of condensation, the raindrop making sky aerial increase, it may happen that heavy rain when extreme.
Therefore, concern fine particle present situation and development trend, inquires into and how to pay attention to and take precautions against pm2.5, concerning human health, The important topic of safety and economy coordinated development.
According to the air quality new standard of pm2.5 detection net, 24 hourly average value standard Distribution value are as follows:
Air quality grade 24 hours pm2.5 meansigma methodss standard values
Excellent 0~35μg/m³
Good 35~75μg/m³
Slight pollution 75~115μg/m³
Intermediate pollution 115~150μg/m³
Serious pollution 150~250μg/m³
Severe contamination More than 250 μ g/m and more than
World Health Organization (WHO) (who) 2005 " air quality criteria "
Project Year average Annual average
Criterion value 10μg/m³ 25μg/m³
Transition period target 1 35μg/m³ 75μg/m³
Transition period target 2 25μg/m³ 50μg/m³
Transition period target 3 15μg/m³ 37.5μg/m³
The prevention method of existing reply haze (fine particle) mainly has:
1st, Filtration: include air-conditioning, humidifier, air freshener etc., advantage is substantially to reduce the concentration of pm2.5, and shortcoming is filter Film needs cleaning or changes.
2nd, water adsorption method: ultrasound atomizer, indoor cascade, pond, fish jar etc., being capable of hydrophilic in absorption air Pm2.5, shortcoming is to increase humidity, and hydrophobicity pm2.5 can not effectively remove.
3rd, plant absorption method: plant leaf blade has larger surface area, can absorb harmful gass and absorption pm2.5, excellent Point is to produce favourable gas, and shortcoming is that absorption efficiency is low, and some plants can produce harmful gass.
Chinese patent cn201410584779.6 discloses a kind of wet dedusting agent and purifies haze, the method for dust, should Method adopts jfc to dilute 10000 ~ 100000 times of spraying sedimentation hazes.
The method that Chinese patent cn201610076018.9 discloses haze in a kind of suppression air, the method adopts vehicle-mounted Sprayer unit adds water, Sal, glycerol and the spraying of 1 ~ 5% modified acrylic polymer.Fountain height is 30～40ml/m3.
Chinese patent cn201610033589.4(Shanghai Communications University) disclose a kind of haze diluent, the method adopts Polyhydric alcohol is selected from glycerol, propylene glycol or Sorbitol；Thickening agent is selected from xanthan gum or sodium alginate；Alkaline matter (sodium hydroxide, carbon Sour sodium etc.), reducing substanceses (vitamin etc.), plant extract agent (Aloe etc.), preservative or surfactant；
Chinese patent cn201410188841.x discloses a kind of method eliminating atmospheric haze by biocatalyzer, the method Using vegetable and fruit fermentation liquid, carry out spraying using aircraft and eliminate haze.
Chinese patent cn201610015150.9 discloses a kind of " rain making snowfall degraded haze measure ", and the method is adopted Do vehicle by dry ice silver iodide etc. coolant artificial snow-making with aerial incendiary dart big gun antiaircraft gun, reduce haze layer.
Chinese patent cn201510777353.7 discloses a kind of catalyst (v2o5/ (moo3) x (wo3) of preventing and treating haze 1-x and tio2 mixture), including carrier (zeolite), active component and promoter (silver and palladium),
Chinese patent cn201510422921.1(Changzhou University) disclose a kind of method dispersing haze above runway, should Method disperses haze using oil combustion heating.
Chinese patent cn201410185349.7(Nanjing University) disclose shitosan haze sedimentation agent preparation method and Its application, it is 10000-1000000g/mol that the method adopts the scope of molecular weight, and the shitosan for 60 ~ 99% for the deacetylation is molten After acid solution, the mass percentage concentration of acid solution is 0.01 ~ 1% to solution, and mass percentage concentration in acid solution for the shitosan is 0.05 ~ 1%；Mix homogeneously；(2) add small molecule-modified dose, described small molecule-modified dose of mass percent accounts for shell and gathers mixing The 1-20% of liquid, fully dissolves, prepares shitosan haze sedimentation agent.
Chinese patent cn201510184851.0(Guangdong University of Technology) disclose and a kind of new reduce indoor haze Spray and its application, the method is with plant extract (Radix Sophorae Flavescentiss, Aloe, Herba Ephedrae, Radix Stephaniae Tetrandrae, Rhizoma Coptidis and the Huang of nitrogenous alkaloid Stilbene), compounding Polyvinylpyrrolidone, aminopolysaccharide (heparin, chondroitin sulfate, hyaluronic acid), adsorbed by nitrogenous alkaloid, Polyvinylpyrrolidone, aminopolysaccharide, deionized water mixture parcel pellet, effectively reduce the dense of indoor haze Degree.
Above-mentioned patent some do not account for the complexity of haze composition, particularly some of them harmful substance and be harmful to micro- life The impact that the removal of thing or climatic environment (wind-force, humidity etc.) are formed to haze.
Content of the invention
The fast purification agent it is an object of the invention to provide a kind of water base haze (pm2.5 and fine grained) is met an urgent need, particularly haze In containing oxious component (Organic substance, many aromatic hydrocarbon, antibacterial, virus etc.) emergent fast purification agent.For realizing the present invention:
The water base haze (fine particle) of the present invention meet an urgent need fast purification agent it is characterized in that: include by non-ionic surface active Agent, organo-silicon coupling agent, photocatalyst and doping catalyst, antibacterial biocide, chelating agen, water-absorbing resin, sol-gel film forming Agent, conditioner and water composition.
The water base haze (fine particle) of the present invention meets an urgent need fast purification agent it is characterised in that described non-ionic surface is lived Property agent be alkyl polyglucoside, sucrose fatty acid ester, organosilicon nonionic surfactant, one or more, consumption be 0.05 ~ 5.0%.
The water base haze (fine particle) of the present invention meets an urgent need fast purification agent it is characterised in that described organo-silicon coupling agent For, kh550, kh560, kh570, kh792, dl602, dl171, more than one or their compositionss, its content is 0.01～ 0.5%.
The water base haze (fine particle) of the present invention meets an urgent need fast purification agent it is characterised in that described photocatalyst and mixing Miscellaneous catalyst is: photocatalyst is contaminated for photosensitive dye n719 or metal phthalocyanine contaminates sensitization nano titanium oxide, nano-silica Change titanium；Doping catalyst is zinc phosphate or Copper-cladding Aluminum Bar nano titanium oxide, and photocatalyst and doping catalyst content are 0.01 ~ 0.5%.
The water base haze (fine particle) of the present invention meets an urgent need fast purification agent it is characterised in that described antibacterial biocide is Oligochitosan, its consumption of nano titanium oxide is 0.01 ~ 0.1%.
The water base haze (fine particle) of the present invention meets an urgent need fast purification agent it is characterised in that described chelating agen is silicic acid Sodium, anhydrous sodium metasilicate, metasilicate pentahydrate sodium, non-hydrate sodium metasilicate, sodium gluconate, sodium citrate, oligochitosan, one of which More than, consumption is 0.05%～1.5%.
The water base haze (fine particle) of the present invention meets an urgent need fast purification agent it is characterised in that described water-absorbing resin is to form sediment Powder class modified water absorbent resin, its consumption is 0.1 ~ 5%.
The water base haze (fine particle) of the present invention meets an urgent need fast purification agent it is characterised in that described sol-gel becomes Membrane be shitosan, maltodextrin, modified starch, xanthan gum, Konjac glucomannan (glucomannan), sodium alginate one of which with On, consumption is 0.05 ~ 5%.
The water base haze (fine particle) of the present invention meets an urgent need fast purification agent it is characterised in that described regulator is perfume Essence, its consumption is 0.0 ~ 0.05%.
The water base haze (fine particle) of the present invention meets an urgent need fast purification agent it is characterised in that this cleanser is molten with water Agent.
The fast purification agent it is an object of the invention to provide a kind of water base haze (pm2.5 and fine grained) is met an urgent need, particularly haze In containing oxious component (Organic substance, many aromatic hydrocarbon, antibacterial, virus etc.) emergent fast purification agent.
For realizing the present invention, the present invention is according to specified in air quality new standard: fine particle >=250 μ g/m3 haze Serious pollution air is main application, have studied normal occur haze from different places temperature, different humidity (in the air is aqueous Amount) and with condition dew point haze gathering, settlement factors, different wind condition, the gathering of haze, according to the required grain of sedimentation Footpath, density, time；And the concentration of fast purification agent that the haze (pm2.5 and fine grained) of preparation is met an urgent need, solution density (ratio Again), viscosity, size droplet diameter, (atomizing particle size), sedimentation velocity etc. have carried out screening and optimizing.
When using biphase (liquid and air) compression sprayer, liquid phase pressure is 0.15 ~ 0.25mpa, and gas phase is (empty Gas) pressure when being 0.15 ~ 0.6mpa, can obtain mean diameter (50 ~ 300 μ that haze needed for the present invention is assembled, sedimentation is required M).Then corresponding sedimentation velocity is about 10 ~ 380m/h(or about 0.003 ~ 0.1m/s).Also single-phase (liquid) Direct spraying can be adopted When, press atomization pressure 6 ~ 8mpa, nozzle diameter 0.5 ~ 1.0mm mpa.
When air themperature is 25 DEG C, humidity is 40%, and wind-force is 3 ~ 4 grades, in the air fine particle (pm2.5) >=250 μ g/ M3(serious pollution) when, water base haze (fine particle) is met an urgent need fast purification agent example 1, during 10 times of dilution, is atomized mean diameter For 10 ~ 60 μm, cleanser usage amount be 30 ~ 50g/m3(with the conditions of close to or up moisture mathematic interpolation needed for dew point, and Consider Engineering Error a small amount of moisture vaporization loss), its haze assemble index is 2 ~ 30min, and being gathered into mean diameter is 50 ~ 300 μ M, over time can form bigger granule.
Wherein photocatalyst and doping photocatalyst decomposable asymmetric choice net harmful components, shitosan, oligochitosan, nano titanium oxide can Suppression and killing antibacterial, virus.Embedded sodium silicate, oligochitosan, shitosan, the nano titanium oxide of water-absorbing resin form and reunite Thing, in the granule reunited, by sodium silicate, oligochitosan, shitosan, the haze of water-absorbing resin seizure and harmful components, nanometer two Titanium oxide and visible light nano titanium dioxide (sensitizing dyestuff contaminate nano titanium oxide and titania-doped) synergism, carries High de-agglomeration performance.And oligochitosan, shitosan will wherein harmful microorganism (antibacterial, virus) be killed.
With the photocatalyst as representative for the nano titanium oxide (tio2), under ultraviolet irradiation, can be at normal temperatures and pressures Make multiple harmful odor gas resolve into harmless tasteless substance, and photocatalyst material itself do not consume during the course of the reaction, So being a kind of preferable gas purification material.
The photocatalytic effect of nanometer tio2 quasiconductor, in material internal by absorbing photo-excited electron, produces electron-hole Right, i.e. photo-generated carrier, move to rapidly material surface, active material surface adsorbed oxygen and moisture, produce active hydrogen-oxygen freely Base (oh) and ultra-oxygen anion free radical (o2 -), thus being converted into a kind of active substance with safe chemistry energy, play Degraded environmental contaminants and the effect of bacteriostasis and sterilization.
In many applications, the size and shape of titanium dioxide nanoparticle is often the key factor determining final performance. The size of particle is less, and specific surface area is bigger, and efficiency of light absorption is also higher, and therefore activity is strengthened.Test confirms: crystal grain chi Very little be reduced to 17 nm from 30 nm, the activity of optically catalytic TiO 2 degradation of phenol improves nearly 30%.
The present invention adopts the titanium dioxide of 5 ~ 30nm.
tio2Although non-toxic inexpensive, chemistry and biologically inert, photolytic activity, good light stability, there is the valence band current potential of corrigendum Relatively negative conduction band current potential.But tio2Wider (the e of forbidden bandg=3.2ev), 387.5nm can only be less than by sunlight medium wavelength interval Light excited, and this interval luminous energy only accounts for the 1 ~ 2% about of solar energy.Low-gap semiconductor material, because they are subject to By photoetch and may to environment produce secondary pollution although can by excited by visible light, but not be preferable environmental photocatlytsis material Material.Substantial amounts of test proves: can improve 40% through the photocatalytic activity of the nano titania titanium dioxide of doping treatment More than.
The present invention adopts zinc phosphate or Copper-cladding Aluminum Bar nano titanium oxide.
Nano titanium oxide is due to forbidden band wider (eg=3.2ev), poor to the spectral response of visible ray, and is directly utilizing Solar energy carries out photocatalysis environmental pollution improvement aspect and is very limited.The photocatalyst being applied to environmental photocatlytsis is mainly Semi-conducting material, such as tio2, zno, fe2o3, cds etc..When quasiconductor is subject to optical illumination, energy is equal to or more than valence band and conduction band Between can slot photon, excite valence-band electrons transit to conduction band formed a free electron ecb -, and stay next sky in valence band Cave hvb +Form an electron hole pair.It is in the valence band hole (h of excited statevb +) and conduction band electron (ecb -) Oxidation, Its:
Liquid-solid phase environmental photocatlytsis: the final product co of the purification light-catalyzed reaction of organic sewage2、h2O, mineral acid etc. are to environment Harmless.
Gas-solid phase environmental photocatlytsis: conductor photocatalysis utilize oxygen and the minor amount of water of in the air, generate oh free radical contour Active oxidizer.It is applied to the improvement of atmospheric pollution (harmful gass etc. in acid rain, haze, vehicle exhaust), eliminating in the air h2s、nh3、so2、co、nox、hcho、ch3The harmful gass aspect such as sh achieves good effect.Its light-catalyzed reaction mechanism is led to Often can be described as:
Organic pollution+oh (or o2 -) —→ co2+ h2O+inorganic molecules
The present invention adopts sensitizing dyestuff n719 or metal phthalocyanine to contaminate nano titanium oxide, is catalyzed under natural light with improving Reaction efficiency.
Hydroscopic high-molecular resin, is net high-polymer nontoxic polymer, to human body nonirritant, no side reaction, has extremely strong Water absorbing properties.High hydrophilous resin is the macromole that a class contains hydrophilic group and cross-linked structure.Divide by raw material, have starch-series (graft, carboxy methylation etc.), cellulose-based (carboxy methylation, graft etc.), synthetic polymer system (polyacrylic, poly- second Enol system, polyoxyethylene system etc.) several big class.Food industry water absorbing agent, the antistaling agent of fruits and vegetables.Super absorbent polymer can As adsorbent for heavy metal and oil absorption material etc..
The present invention adopts starch-series and cellulose-based water-absorbing resin.As hydrophilic absorbent, reunion functional component.
Oligochitosan is that the unique of discovery in current nature can strengthen the mankind, animal, plant part in alkalescence, positively charged Pest resistance, have broad-spectrum antibacterial as nontoxic, non-harmful material.
Oligochitosan has obvious moisturizing, activates body cell, and bacteriostasis and sterilization acts on.And can antistatic, suppression dust.Shell The function of oligosaccharide is closely related with the degree of polymerization (dp) of oligochitosan.
The present invention adopts shitosan and its deacetylation >=90%, oligochitosan below 2000 for the molecular weight.For reduces cost Shitosan has been selected to use cooperatively with it.
Sol-gel film former of the present invention, wherein:
Xanthan gum is a kind of monospore polysaccharide being produced by the fermentation of false xanthomonas, due to its macromole special construction and colloid Characteristic, and there are several functions, extensively can apply as emulsifying agent, stabilizer, gelling thickener, wetting agent, film forming agent etc. In all fields of national economy.
Xanthan gum is soluble in hot water or cold water, solution neutral, resistance and freeze and defrosting, insoluble in ethanol.Chance moisture dissipates, emulsifying Become stable hydrophilic thick gel.Collect thickening, suspension, emulsifying, be stable at one, best performance biogum more.Xanthan Glue has the general performance of long chain macromolecule, but it contains more functional group than general macromolecule, can show under given conditions Show special performance.Its conformation in aqueous is various, not under the conditions of show different characteristics.Xanthan gum pseudoplastic behavior is non- Often project, this pseudoplastic behavior is extremely effective to stable suspension, emulsion.Its to heat, to soda acid, to salt, enzyme digestion reaction steady Qualitative.
Amorphophalluses Araeceae herbaceos perennial, has long kind in Southwestern China portion area and central and west regions Plant history.The main component of Rhizoma amorphophalli is glucomannan, is the food of a kind of low calorie, low-protein, high dietary-fiber, and Rich in needed by human body ten several aminoacid and trace element, can be prevented colon cancer with toxin expelling vivotoxin and rubbish.There is water Multiple physicochemical properties such as molten, thickening, stable, suspension, gel, film forming, bonding.
Maltodextrin is also referred to as water solublity dextrin or enzyme process dextrin.It is to make raw material with each kind of starch, through the low journey of enzyme method technique Degree controls hydrolysis, purification, and drying forms.Maltodextrin is placed in water, sinks quickly, falls in the bottom, and can be gradually past On return, gradually dissolve, its dissolubility is slightly below Saccharum Sinensis Roxb. simultaneously, but aquation power be stronger.After absorption moisture, keep the energy of moisture Power is stronger.It is inserts and the thickening agent of varieties of food items.
The beneficial effects of the present invention is: the present invention adopts nontoxic, nuisanceless, degradable material, and edible natural thing Matter, safe and environment-friendly.Harmful components in haze capable of being fast degraded, suppression, killing harmful microorganism.
Beneficial effects of the present invention also reside in: often purify the air of 1m3 haze serious pollution, the cost of its cleanser is only 0.04 li.Thus, the air-spraying fast purification haze in big region can be actually used in, kill harmful microorganism, catalysis in haze Decompose harmful organic substance in haze, be converted into harmless water and endanger less co2.
Specific embodiment
, by embodiment come further description objects and advantages of the present invention, described is only exemplary for the present invention And illustrative, rather than the restriction of the claims in the present invention.
Embodiment 1
Weigh 200g deionized water, add 0.3g alkyl polyglucoside (agp-1000), 0.2g sucrose fatty acid ester, 0.1g organosilicon table Face activating agent, after being uniformly mixed, adds 0.05g organo-silicon coupling agent kh550 and 0.05gdl602,0.1g while stirring 20nm titanium dioxide, 0.1g sodium gluconate, 0.2g sodium citrate, 0.1g deacetylation >=90% oligochitosan and 1g maltodextrin, 0.1g metasilicate pentahydrate sodium, 0.5g essence, continue to be stirred until homogeneous obtained solution a.
Weigh 200g deionized water, add 0.5g water-absorbing resin, stir 20 ~ 40 minutes, after stirring, pour into molten Liquid a, and mend and add water to 1000g, continues stirring 30min, is prepared into haze (fine particle) and meets an urgent need fast purification agent.
The emergent fast purification agent settling test of the water base haze (fine particle) of the present invention:
Haze settling test case: self-control has the haze sedimentation examination of the 2m3 (1m × 1m × 2m) of 8 0.1 × 1.6m glass vision panel Tryoff.
Haze generates test: through experimental determination, the medicated cigarette of the 0.75g tobacco shred that burns completely, produces pm2.5 smog about 4.5 ~ 4.8%(0.034 for tobacco shred weight ~ 0.036g), produce pm10 smog be about tobacco shred weight 10 ~ 10.5%(0.075 ~ 0.079g).According to said determination result, in haze settling test case, put into the tobacco shred that 0.035g is burning, be placed on haze Settling test case smoke inlet, after spontaneous firing is complete, through the detection of hand-held air detection instrument, after recording first, second and third burning In case, pm2.5 is respectively as follows: 452 μ g/m3,526 μ g/m3 and 487 μ g/m3.
Settling test: by above-mentioned water base haze (fine particle) meet an urgent need fast purification agent embodiment 1, respectively dilution 10 times, 50th, 100 times, using the nozzle of nozzle diameter 0.5mm, 6mpa press atomization.Spraying dosage 30 ~ 50ml/m3.Through the inspection of hand-held air Survey instrument detection, pm2.5 content is as follows in the case that 15min, 30min, 45min record respectively:
Dilution 10 times test: spraying 15min after for 59 μ g/m3, spraying 30min after for 27 μ g/m3, spraying 45min after be 17 μ g/ m3.
50 times of tests of dilution: for after 67 μ g/m3, spraying 30min for after 32 μ g/m3, spraying 45min being after spraying 15min 19μg/m3.
100 times of tests of dilution: for after 86 μ g/m3, spraying 30min for after 53 μ g/m3, spraying 45min being after spraying 15min 32μg/m3.
Embodiment 2
Weigh 500g deionized water, add 30g alkyl polyglucoside (agp-1000), 10g sucrose fatty acid ester, 10g organosilyl surface Activating agent, after being uniformly mixed, adds 3g organo-silicon coupling agent kh560 and 2g kh570,5g 5nm titanium dioxide while stirring Titanium, 1g sodium gluconate, 1g sodium citrate, 2g deacetylation >=90% oligochitosan and 7g carboxymethyl cellulose, 2g five water metasilicic acid Sodium, 0.5g essence, continue to be stirred until homogeneous obtained solution a.
Weigh 200g deionized water, add 3.5g water-absorbing resin, stir 20 ~ 40 minutes, after stirring, pour into molten Liquid a, and mend and add water to 1000g, continues stirring 30min, is prepared into haze (fine particle) and meets an urgent need fast purification agent.
The emergent fast purification agent sedimentation of the water base haze (fine particle) of the present invention dilutes 500 times, 1000 times respectively, haze With embodiment 1, result of the test is shown in Table 2 to settling test.
Embodiment 3
Weigh 500g deionized water, add 20g sucrose fatty acid ester, 1g organic silicon surfactant, after being uniformly mixed, side Stirring side add 5g organo-silicon coupling agent kh560 and, 2g 30nm zinc phosphate is titania-doped, 10g sodium gluconate, 10g lemon Lemon acid sodium, 1g shitosan, 1g deacetylation >=90% oligochitosan, 5g metasilicate pentahydrate sodium, 5g maltodextrin, 1g xanthan gum, continue It is stirred until homogeneous obtained solution a.
Weigh 200g deionized water, add 5g water-absorbing resin, stir 20 ~ 40 minutes, after stirring, pour solution into A, and mend and add water to 1000g, continues stirring 30min, is prepared into water base haze (fine particle) and meets an urgent need fast purification agent.
Embodiment 4,5,6
It is shown in Table 1, haze settling test the results are shown in Table 2.
Table 1 embodiment 1 ~ 6 formula table
Table 2 embodiment 1 ~ 6 settling test table
As known from Table 2: the invention has benefit that: spray can be directly installed in aerosol apparatus and be used for removing in the air suspension Granule dust, reduction haze；Also indoor environment can be made with for reducing indoor smog thus haze in clean room to reach " environment Air quality index technical stipulation " hj633-2012 I and II, realizing in the air pm2.5 content is excellent or good index.

Claims (10)

1. water base haze (fine particle) meet an urgent need fast purification agent it is characterized in that: include by nonionic surfactant, organic Silicone couplet, photocatalyst and doping catalyst, antibacterial biocide, chelating agen, water-absorbing resin, sol-gel film former, conditioner With water composition.
2. water base haze (fine particle) according to claim 1 meets an urgent need fast purification agent it is characterised in that described light Catalyst is photosensitive dye n719 nano titanium oxide, metal phthalocyanine contaminates sensitization nano titanium oxide, nano titanium oxide One of, described doping catalyst is zinc phosphate or copper and nanometer titanium dioxide compound.
3. water base haze (fine particle) according to claim 2 meets an urgent need fast purification agent it is characterised in that described light is urged Agent and doping catalyst total content are 0.01 ~ 0.5%.
4. water base haze (fine particle) according to claim 1 meets an urgent need fast purification agent it is characterised in that described is molten Glue-gel film former be shitosan, maltodextrin, modified starch, xanthan gum, Konjac glucomannan (glucomannan), sodium alginate its Middle a kind of and more than.
5. water base haze (fine particle) according to claim 4 meets an urgent need fast purification agent it is characterised in that described is molten Glue-gel film former, consumption is 0.05 ~ 5%.
6. fast purification agent is met an urgent need it is characterised in that institute according to the arbitrary described water base haze (fine particle) of claim 1 to 5 The antibacterial biocide stated at least selects oligochitosan, one of nano titanium oxide, and its consumption is 0.01 ~ 0.1%.
7. fast purification agent is met an urgent need it is characterised in that institute according to the arbitrary described water base haze (fine particle) of claim 1 to 5 The water-absorbing resin stated is starch based modified water absorbent resin, and its consumption is 0.1 ~ 5%.
8. fast purification agent is met an urgent need it is characterised in that institute according to claim to 5 arbitrary described water base hazes (fine particle) The nonionic surfactant stated be alkyl polyglucoside, sucrose fatty acid ester, organosilicon nonionic surfactant, one of which with On, consumption is 0.05 ~ 5.0%.
9. fast purification agent is met an urgent need it is characterised in that institute according to the arbitrary described water base haze (fine particle) of claim 1 to 5 The organo-silicon coupling agent stated is, kh550, kh560, kh570, kh792, dl602, dl171, more than one or their combination Thing, its content is 0.01～0.5%.
10. according to the arbitrary described water base haze (fine particle) of claim 1 to 5 meet an urgent need fast purification agent it is characterised in that Described chelating agen is sodium silicate, anhydrous sodium metasilicate, metasilicate pentahydrate sodium, non-hydrate sodium metasilicate, sodium gluconate, citric acid One or more of sodium, shitosan.
CN201610730101.3A 2016-08-26 2016-08-26 Water-base emergent rapid purifying agent for haze (fine particulate matters) Pending CN106345214A (en)

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CN107626171A (en) * 2017-09-21 2018-01-26 武兴战 A kind of gluey high-activity biological film for eliminating film micro area haze and preparation method thereof
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CN107875773A (en) * 2017-12-11 2018-04-06 中国工程物理研究院化工材料研究所 One kind enhancing absorption PM2.5 particulate elecrtonegativity activated waters and preparation method thereof
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CN111359340A (en) * 2020-03-19 2020-07-03 江苏瑞丰科技实业有限公司 Efficient aerosol removing spray
CN111408221A (en) * 2020-03-30 2020-07-14 广西精典化工新材料有限公司 Anti-haze agent and preparation method thereof
CN111632334A (en) * 2020-06-17 2020-09-08 成都市图腾环保科技有限公司 Disinfectant, and preparation method and application thereof
KR20240143493A (en) * 2023-03-24 2024-10-02 김재영 Absorbent for capturing carbon dioxide and method for preparing the same
KR102888518B1 (en) * 2023-03-24 2025-11-20 김재영 Absorbent for capturing carbon dioxide and method for preparing the same

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