CN106312046A - High-performance 3D printing alloy supplies - Google Patents
High-performance 3D printing alloy supplies Download PDFInfo
- Publication number
- CN106312046A CN106312046A CN201610762208.6A CN201610762208A CN106312046A CN 106312046 A CN106312046 A CN 106312046A CN 201610762208 A CN201610762208 A CN 201610762208A CN 106312046 A CN106312046 A CN 106312046A
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- CN
- China
- Prior art keywords
- parts
- alloy
- high performance
- printing consumables
- calcium carbonate
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/10—Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C49/00—Alloys containing metallic or non-metallic fibres or filaments
Abstract
The invention discloses high-performance 3D printing alloy supplies. The high-performance 3D printing alloy supplies comprise, by weight, 5-10 parts of low-melting-point alloy particles, 7-10 parts of carbon fibers, 1-2 parts of calcium carbonate, 1-2 parts of refractory cellulose, 0.05-0.1 part of magnesium chloride crystals, 1-2 parts of chitosan particles, 1-2 parts of clay particles, and 2-3 parts of glass fibers. The printing alloy supplies provided by the invention are low in manufacturing cost and high in stability, and rapid 3D printing can be achieved conveniently.
Description
Technical field
The present invention relates to 3D printing consumables, particularly relate to a kind of high performance 3D printing consumables alloy material.
Background technology
The 3D printing i.e. one of rapid shaping technique, it is a kind of based on mathematical model file, uses powdered gold
Belong to or plastics etc. can jointing material, by the way of successively printing, carry out the technology of constructed object.3D prints and is typically with numeral
Technologic material printer realizes.Often be used for modeling in the field such as Making mold, industrial design, after be gradually available for one
Directly manufacturing of a little products, has had the parts using this technology to print.This technology sets in jewelry, footwear, industry
Meter, building, engineering and construction, automobile, Aero-Space, dentistry and medical industries, education, GIS-Geographic Information System, civil engineering, rifle
Prop up and other field has been applied.
But, existing 3D printed material does not have low melting point alloy particles component, is not easy to print the alloy of high intensity
The product of material, this problems demand solves.
Summary of the invention
It is an object of the invention to overcome the deficiency of above-mentioned prior art to provide a kind of high performance 3D printing consumables to close
Gold copper-base alloy.
For achieving the above object, the present invention provides a kind of high performance 3D printing consumables alloy material, by weight, including
Following component:
Low melting point alloy particles, 5 to 10 parts;
Carbon fiber, 7 to 10 parts;
Calcium carbonate, 1 to 2 part;
Refractory fibre element, 1 to 2 part;
Magnesium chloride crystal, 0.05 to 0.1 part;
Chitosan particle, 1 part to 2 part;
Clay particle, 1 part to 2 part;
Glass fibre, 2 parts to 3 parts.
Preferably, described low melting point alloy particles includes gallium-base alloy layer, indium-base alloy layer, bismuth-base alloy from outside to inside
Layer, bell metal layer, photosensitive material layer.
Preferably, the particle diameter of described calcium carbonate is 1 micron to 10 microns.
Preferably, a diameter of 1 millimeter to 3 millimeters of the cross section of described refractory fibre element.
Preferably, the particle diameter of described glass fibre is 1 millimeter to 5 millimeters.
Preferably, by weight, including following component:
Low melting point alloy particles, 6 parts;
Carbon fiber, 8 parts;
Calcium carbonate, 1.2 parts;
Refractory fibre element, 1.5 parts;
Magnesium chloride crystal, 0.08 part;
Chitosan particle, 1.3 parts;
Clay particle, 1.4 parts;
Glass fibre, 2.1 parts.
Preferably, by weight, including following component:
Low melting point alloy particles, 9 parts;
Carbon fiber, 7 parts;
Calcium carbonate, 1.2 parts;
Refractory fibre element, 1.5 parts;
Magnesium chloride crystal, 0.08 part;
Chitosan particle, 1.3 parts;
Clay particle, 1.4 parts;
Glass fibre, 2.1 parts;
Also include native gold powder, 0.01 part.
Preferably, by weight, including following component:
Low melting point alloy particles, 10 parts;
Carbon fiber, 8 parts;
Calcium carbonate, 1.5 parts;
Refractory fibre element, 1.1 parts;
Magnesium chloride crystal, 0.05 part;
Chitosan particle, 1.3 parts;
Clay particle, 1.4 parts;
Glass fibre, 2.1 parts;
Native gold powder, 0.01 part;
Also include, amino acid crystals, 1.3 parts.
Invention additionally discloses a kind of high performance 3D printing consumables alloy material, comprise the steps:
S901, in reactor, by low melting point alloy particles heating and melting;
S902, puts into calcium carbonate granule in proportion, mixing;
S903, is proportionally added into magnesium chloride crystal, mixing;
S904, is proportionally added into refractory fibre element, mixing;
S905, puts into remaining material, mixing.
The invention has the beneficial effects as follows: the consumptive material of the present invention, low cost of manufacture, and stability are strong, intensity is high, it is simple to quickly
3D prints.The main body of this consumptive material is low-melting alloy, it is simple to melts and implements to print.By low melting point alloy particles is prepared as
Multiple structure, when, after outer melting layer, the most gradually making material system become flowable state, consequently facilitating material conveying.Additionally, by adopting
With carbon fiber, when carbon fibre carbonizing, material system forms cavity, in order to form the structure of similar blister steel, but, with
Time achieve again carburization process, carbon is penetrated into inside alloy, thus gives alloy higher intensity.And refractory fibre
Element, glass fibre, give the toughness that alloy is higher.After carrying out 3D printing with the alloy material of the present invention, the product printed its
Intensity is high, toughness is good, it is simple to Surface Machining processes.
Detailed description of the invention
Embodiment one:
The present invention provides a kind of high performance 3D printing consumables alloy material, by weight, including following component: low melting point
Alloying pellet, 5 to 10 parts;Carbon fiber, 7 to 10 parts;Calcium carbonate, 1 to 2 part;Refractory fibre element, 1 to 2 part;Magnesium chloride crystal,
0.05 to 0.1 part;Chitosan particle, 1 part to 2 part;Clay particle, 1 part to 2 part;Glass fibre, 2 parts to 3 parts.
Embodiment two:
The present invention provides a kind of high performance 3D printing consumables alloy material, by weight, including following component: low melting point
Alloying pellet, 5 to 10 parts;Carbon fiber, 7 to 10 parts;Calcium carbonate, 1 to 2 part;Refractory fibre element, 1 to 2 part;Magnesium chloride crystal,
0.05 to 0.1 part;Chitosan particle, 1 part to 2 part;Clay particle, 1 part to 2 part;Glass fibre, 2 parts to 3 parts.Wherein, described
Low melting point alloy particles includes gallium-base alloy layer, indium-base alloy layer, bismuth-base alloy layer, bell metal layer, photosensitive from outside to inside
Material layer.When preparing low melting point alloy particles, preparation in layer.
Embodiment three:
The present invention provides a kind of high performance 3D printing consumables alloy material, by weight, including following component: low melting point
Alloying pellet, 5 to 10 parts;Carbon fiber, 7 to 10 parts;Calcium carbonate, 1 to 2 part;Refractory fibre element, 1 to 2 part;Magnesium chloride crystal,
0.05 to 0.1 part;Chitosan particle, 1 part to 2 part;Clay particle, 1 part to 2 part;Glass fibre, 2 parts to 3 parts;Wherein, described
The particle diameter of calcium carbonate is 1 micron to 10 microns.A diameter of 1 millimeter to 3 millimeters of the cross section of described refractory fibre element.Preferably
, the particle diameter of described glass fibre is 1 millimeter to 5 millimeters.
Embodiment four:
The present invention provides a kind of high performance 3D printing consumables alloy material, by weight, including following component: low melting point
Alloying pellet, 6 parts;Carbon fiber, 8 parts;Calcium carbonate, 1.2 parts;Refractory fibre element, 1.5 parts;Magnesium chloride crystal, 0.08 part;Shell gathers
Sugar granule, 1.3 parts;Clay particle, 1.4 parts;Glass fibre, 2.1 parts.
Preferably, by weight, including following component:
Low melting point alloy particles, 9 parts;Carbon fiber, 7 parts;Calcium carbonate, 1.2 parts;Refractory fibre element, 1.5 parts;Magnesium chloride is brilliant
Body, 0.08 part;Chitosan particle, 1.3 parts;Clay particle, 1.4 parts;Glass fibre, 2.1 parts;Also include native gold powder, 0.01
Part.
Embodiment five:
The present invention provides a kind of high performance 3D printing consumables alloy material, by weight, including following component: low melting point
Alloying pellet, 10 parts;Carbon fiber, 8 parts;Calcium carbonate, 1.5 parts;Refractory fibre element, 1.1 parts;Magnesium chloride crystal, 0.05 part;Shell gathers
Sugar granule, 1.3 parts;Clay particle, 1.4 parts;Glass fibre, 2.1 parts;Native gold powder, 0.01 part;Also include, amino acid crystals,
1.3 part.
Invention additionally discloses a kind of high performance 3D printing consumables alloy material, comprise the steps: S901, at reactor
In, by low melting point alloy particles heating and melting;S902, puts into calcium carbonate granule in proportion, mixing;S903, is proportionally added into chlorine
Change magnesium crystal, mixing;S904, is proportionally added into refractory fibre element, mixing;S905, puts into remaining material, mixing.
In sum, the consumptive material of the present invention, low cost of manufacture, and stability is strong, it is simple to quickly 3D prints.The master of this consumptive material
Body is low-melting alloy, it is simple to melts and implements to print.By low melting point alloy particles is prepared as multiple structure, when outer layer melts
After change, material system is the most gradually made to become flowable state, consequently facilitating material conveying.Additionally, by using carbon fiber, work as carbon fiber
During carbonization, material system forms cavity, in order to form the structure of similar blister steel, but, achieve again carburizer simultaneously
Skill, penetrates into carbon inside alloy, thus gives alloy higher intensity.And refractory fibre is plain, glass fibre, gives and closing
The toughness that gold is higher.After carrying out 3D printing with the alloy material of the present invention, its intensity of the product printed is high, toughness is good, it is simple to
Surface Machining processes.
Although above it has been shown and described that embodiments of the invention, it is to be understood that above-described embodiment is example
Property, it is impossible to be interpreted as limitation of the present invention, those of ordinary skill in the art is without departing from the principle of the present invention and objective
In the case of above-described embodiment can be changed within the scope of the invention, revise, replace and modification.
Claims (8)
1. a high performance 3D printing consumables alloy material, it is characterised in that by weight, including following component:
Low melting point alloy particles, 5 to 10 parts;
Carbon fiber, 7 to 10 parts;
Calcium carbonate, 1 to 2 part;
Refractory fibre element, 1 to 2 part;
Magnesium chloride crystal, 0.05 to 0.1 part;
Chitosan particle, 1 part to 2 part;
Clay particle, 1 part to 2 part;
Glass fibre, 2 parts to 3 parts.
High performance 3D printing consumables alloy material the most according to claim 1, it is characterised in that described low-melting alloy
Granule includes gallium-base alloy layer, indium-base alloy layer, bismuth-base alloy layer, bell metal layer, photosensitive material layer from outside to inside.
High performance 3D printing consumables alloy material the most according to claim 1, it is characterised in that the grain of described calcium carbonate
Footpath is 1 micron to 10 microns.
High performance 3D printing consumables alloy material the most according to claim 1, it is characterised in that described refractory fibre element
A diameter of 1 millimeter to 3 millimeters of cross section.
High performance 3D printing consumables alloy material the most according to claim 1, it is characterised in that described glass fibre
Particle diameter is 1 millimeter to 5 millimeters.
High performance 3D printing consumables alloy material the most according to claim 1, it is characterised in that by weight, including
Following component:
Low melting point alloy particles, 6 parts;
Carbon fiber, 8 parts;
Calcium carbonate, 1.2 parts;
Refractory fibre element, 1.5 parts;
Magnesium chloride crystal, 0.08 part;
Chitosan particle, 1.3 parts;
Clay particle, 1.4 parts;
Glass fibre, 2.1 parts.
High performance 3D printing consumables alloy material the most according to claim 1, it is characterised in that by weight, including
Following component:
Low melting point alloy particles, 9 parts;
Carbon fiber, 7 parts;
Calcium carbonate, 1.2 parts;
Refractory fibre element, 1.5 parts;
Magnesium chloride crystal, 0.08 part;
Chitosan particle, 1.3 parts;
Clay particle, 1.4 parts;
Glass fibre, 2.1 parts;
Also include native gold powder, 0.01 part.
High performance 3D printing consumables alloy material the most according to claim 1, it is characterised in that by weight, including
Following component:
Low melting point alloy particles, 10 parts;
Carbon fiber, 8 parts;
Calcium carbonate, 1.5 parts;
Refractory fibre element, 1.1 parts;
Magnesium chloride crystal, 0.05 part;
Chitosan particle, 1.3 parts;
Clay particle, 1.4 parts;
Glass fibre, 2.1 parts;
Native gold powder, 0.01 part;
Also include, amino acid crystals, 1.3 parts.
Priority Applications (1)
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CN201610762208.6A CN106312046A (en) | 2016-08-29 | 2016-08-29 | High-performance 3D printing alloy supplies |
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CN201610762208.6A CN106312046A (en) | 2016-08-29 | 2016-08-29 | High-performance 3D printing alloy supplies |
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Citations (6)
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CN1326828A (en) * | 2001-05-15 | 2001-12-19 | 北京北方恒利科技发展有限公司 | Low melting point powder material for laser sintering fast forming precisely casting wax mold |
US20020012607A1 (en) * | 2000-05-24 | 2002-01-31 | Corbin Stephen F. | Variable melting point solders and brazes |
CN104672757A (en) * | 2015-03-02 | 2015-06-03 | 苏州容坤半导体科技有限公司 | 3D printing wire rod with axial thermal shrinkage rate smaller than 0.5%, preparation technological method and manufacture device |
CN104744000A (en) * | 2015-03-07 | 2015-07-01 | 南京工业大学 | Gypsum material for 3D printing and preparation method thereof |
CN104889397A (en) * | 2014-03-03 | 2015-09-09 | 中国科学院理化技术研究所 | Low-melting-point metal wire for 3D printing and manufacturing method thereof |
CN105598441A (en) * | 2015-12-23 | 2016-05-25 | 成都新柯力化工科技有限公司 | Composite material for 3D printing engine cylinder cover and preparation method thereof |
-
2016
- 2016-08-29 CN CN201610762208.6A patent/CN106312046A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20020012607A1 (en) * | 2000-05-24 | 2002-01-31 | Corbin Stephen F. | Variable melting point solders and brazes |
CN1326828A (en) * | 2001-05-15 | 2001-12-19 | 北京北方恒利科技发展有限公司 | Low melting point powder material for laser sintering fast forming precisely casting wax mold |
CN104889397A (en) * | 2014-03-03 | 2015-09-09 | 中国科学院理化技术研究所 | Low-melting-point metal wire for 3D printing and manufacturing method thereof |
CN104672757A (en) * | 2015-03-02 | 2015-06-03 | 苏州容坤半导体科技有限公司 | 3D printing wire rod with axial thermal shrinkage rate smaller than 0.5%, preparation technological method and manufacture device |
CN104744000A (en) * | 2015-03-07 | 2015-07-01 | 南京工业大学 | Gypsum material for 3D printing and preparation method thereof |
CN105598441A (en) * | 2015-12-23 | 2016-05-25 | 成都新柯力化工科技有限公司 | Composite material for 3D printing engine cylinder cover and preparation method thereof |
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Application publication date: 20170111 |
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