CN106312046A - High-performance 3D printing alloy supplies - Google Patents

High-performance 3D printing alloy supplies Download PDF

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Publication number
CN106312046A
CN106312046A CN201610762208.6A CN201610762208A CN106312046A CN 106312046 A CN106312046 A CN 106312046A CN 201610762208 A CN201610762208 A CN 201610762208A CN 106312046 A CN106312046 A CN 106312046A
Authority
CN
China
Prior art keywords
parts
alloy
high performance
printing consumables
calcium carbonate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610762208.6A
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Chinese (zh)
Inventor
段月强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Aosibo Medical Instrument And Equipment Co Ltd
Original Assignee
Anhui Aosibo Medical Instrument And Equipment Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Aosibo Medical Instrument And Equipment Co Ltd filed Critical Anhui Aosibo Medical Instrument And Equipment Co Ltd
Priority to CN201610762208.6A priority Critical patent/CN106312046A/en
Publication of CN106312046A publication Critical patent/CN106312046A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/10Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00Materials specially adapted for additive manufacturing
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C49/00Alloys containing metallic or non-metallic fibres or filaments

Abstract

The invention discloses high-performance 3D printing alloy supplies. The high-performance 3D printing alloy supplies comprise, by weight, 5-10 parts of low-melting-point alloy particles, 7-10 parts of carbon fibers, 1-2 parts of calcium carbonate, 1-2 parts of refractory cellulose, 0.05-0.1 part of magnesium chloride crystals, 1-2 parts of chitosan particles, 1-2 parts of clay particles, and 2-3 parts of glass fibers. The printing alloy supplies provided by the invention are low in manufacturing cost and high in stability, and rapid 3D printing can be achieved conveniently.

Description

A kind of high performance 3D printing consumables alloy material
Technical field
The present invention relates to 3D printing consumables, particularly relate to a kind of high performance 3D printing consumables alloy material.
Background technology
The 3D printing i.e. one of rapid shaping technique, it is a kind of based on mathematical model file, uses powdered gold Belong to or plastics etc. can jointing material, by the way of successively printing, carry out the technology of constructed object.3D prints and is typically with numeral Technologic material printer realizes.Often be used for modeling in the field such as Making mold, industrial design, after be gradually available for one Directly manufacturing of a little products, has had the parts using this technology to print.This technology sets in jewelry, footwear, industry Meter, building, engineering and construction, automobile, Aero-Space, dentistry and medical industries, education, GIS-Geographic Information System, civil engineering, rifle Prop up and other field has been applied.
But, existing 3D printed material does not have low melting point alloy particles component, is not easy to print the alloy of high intensity The product of material, this problems demand solves.
Summary of the invention
It is an object of the invention to overcome the deficiency of above-mentioned prior art to provide a kind of high performance 3D printing consumables to close Gold copper-base alloy.
For achieving the above object, the present invention provides a kind of high performance 3D printing consumables alloy material, by weight, including Following component:
Low melting point alloy particles, 5 to 10 parts;
Carbon fiber, 7 to 10 parts;
Calcium carbonate, 1 to 2 part;
Refractory fibre element, 1 to 2 part;
Magnesium chloride crystal, 0.05 to 0.1 part;
Chitosan particle, 1 part to 2 part;
Clay particle, 1 part to 2 part;
Glass fibre, 2 parts to 3 parts.
Preferably, described low melting point alloy particles includes gallium-base alloy layer, indium-base alloy layer, bismuth-base alloy from outside to inside Layer, bell metal layer, photosensitive material layer.
Preferably, the particle diameter of described calcium carbonate is 1 micron to 10 microns.
Preferably, a diameter of 1 millimeter to 3 millimeters of the cross section of described refractory fibre element.
Preferably, the particle diameter of described glass fibre is 1 millimeter to 5 millimeters.
Preferably, by weight, including following component:
Low melting point alloy particles, 6 parts;
Carbon fiber, 8 parts;
Calcium carbonate, 1.2 parts;
Refractory fibre element, 1.5 parts;
Magnesium chloride crystal, 0.08 part;
Chitosan particle, 1.3 parts;
Clay particle, 1.4 parts;
Glass fibre, 2.1 parts.
Preferably, by weight, including following component:
Low melting point alloy particles, 9 parts;
Carbon fiber, 7 parts;
Calcium carbonate, 1.2 parts;
Refractory fibre element, 1.5 parts;
Magnesium chloride crystal, 0.08 part;
Chitosan particle, 1.3 parts;
Clay particle, 1.4 parts;
Glass fibre, 2.1 parts;
Also include native gold powder, 0.01 part.
Preferably, by weight, including following component:
Low melting point alloy particles, 10 parts;
Carbon fiber, 8 parts;
Calcium carbonate, 1.5 parts;
Refractory fibre element, 1.1 parts;
Magnesium chloride crystal, 0.05 part;
Chitosan particle, 1.3 parts;
Clay particle, 1.4 parts;
Glass fibre, 2.1 parts;
Native gold powder, 0.01 part;
Also include, amino acid crystals, 1.3 parts.
Invention additionally discloses a kind of high performance 3D printing consumables alloy material, comprise the steps:
S901, in reactor, by low melting point alloy particles heating and melting;
S902, puts into calcium carbonate granule in proportion, mixing;
S903, is proportionally added into magnesium chloride crystal, mixing;
S904, is proportionally added into refractory fibre element, mixing;
S905, puts into remaining material, mixing.
The invention has the beneficial effects as follows: the consumptive material of the present invention, low cost of manufacture, and stability are strong, intensity is high, it is simple to quickly 3D prints.The main body of this consumptive material is low-melting alloy, it is simple to melts and implements to print.By low melting point alloy particles is prepared as Multiple structure, when, after outer melting layer, the most gradually making material system become flowable state, consequently facilitating material conveying.Additionally, by adopting With carbon fiber, when carbon fibre carbonizing, material system forms cavity, in order to form the structure of similar blister steel, but, with Time achieve again carburization process, carbon is penetrated into inside alloy, thus gives alloy higher intensity.And refractory fibre Element, glass fibre, give the toughness that alloy is higher.After carrying out 3D printing with the alloy material of the present invention, the product printed its Intensity is high, toughness is good, it is simple to Surface Machining processes.
Detailed description of the invention
Embodiment one:
The present invention provides a kind of high performance 3D printing consumables alloy material, by weight, including following component: low melting point Alloying pellet, 5 to 10 parts;Carbon fiber, 7 to 10 parts;Calcium carbonate, 1 to 2 part;Refractory fibre element, 1 to 2 part;Magnesium chloride crystal, 0.05 to 0.1 part;Chitosan particle, 1 part to 2 part;Clay particle, 1 part to 2 part;Glass fibre, 2 parts to 3 parts.
Embodiment two:
The present invention provides a kind of high performance 3D printing consumables alloy material, by weight, including following component: low melting point Alloying pellet, 5 to 10 parts;Carbon fiber, 7 to 10 parts;Calcium carbonate, 1 to 2 part;Refractory fibre element, 1 to 2 part;Magnesium chloride crystal, 0.05 to 0.1 part;Chitosan particle, 1 part to 2 part;Clay particle, 1 part to 2 part;Glass fibre, 2 parts to 3 parts.Wherein, described Low melting point alloy particles includes gallium-base alloy layer, indium-base alloy layer, bismuth-base alloy layer, bell metal layer, photosensitive from outside to inside Material layer.When preparing low melting point alloy particles, preparation in layer.
Embodiment three:
The present invention provides a kind of high performance 3D printing consumables alloy material, by weight, including following component: low melting point Alloying pellet, 5 to 10 parts;Carbon fiber, 7 to 10 parts;Calcium carbonate, 1 to 2 part;Refractory fibre element, 1 to 2 part;Magnesium chloride crystal, 0.05 to 0.1 part;Chitosan particle, 1 part to 2 part;Clay particle, 1 part to 2 part;Glass fibre, 2 parts to 3 parts;Wherein, described The particle diameter of calcium carbonate is 1 micron to 10 microns.A diameter of 1 millimeter to 3 millimeters of the cross section of described refractory fibre element.Preferably , the particle diameter of described glass fibre is 1 millimeter to 5 millimeters.
Embodiment four:
The present invention provides a kind of high performance 3D printing consumables alloy material, by weight, including following component: low melting point Alloying pellet, 6 parts;Carbon fiber, 8 parts;Calcium carbonate, 1.2 parts;Refractory fibre element, 1.5 parts;Magnesium chloride crystal, 0.08 part;Shell gathers Sugar granule, 1.3 parts;Clay particle, 1.4 parts;Glass fibre, 2.1 parts.
Preferably, by weight, including following component:
Low melting point alloy particles, 9 parts;Carbon fiber, 7 parts;Calcium carbonate, 1.2 parts;Refractory fibre element, 1.5 parts;Magnesium chloride is brilliant Body, 0.08 part;Chitosan particle, 1.3 parts;Clay particle, 1.4 parts;Glass fibre, 2.1 parts;Also include native gold powder, 0.01 Part.
Embodiment five:
The present invention provides a kind of high performance 3D printing consumables alloy material, by weight, including following component: low melting point Alloying pellet, 10 parts;Carbon fiber, 8 parts;Calcium carbonate, 1.5 parts;Refractory fibre element, 1.1 parts;Magnesium chloride crystal, 0.05 part;Shell gathers Sugar granule, 1.3 parts;Clay particle, 1.4 parts;Glass fibre, 2.1 parts;Native gold powder, 0.01 part;Also include, amino acid crystals, 1.3 part.
Invention additionally discloses a kind of high performance 3D printing consumables alloy material, comprise the steps: S901, at reactor In, by low melting point alloy particles heating and melting;S902, puts into calcium carbonate granule in proportion, mixing;S903, is proportionally added into chlorine Change magnesium crystal, mixing;S904, is proportionally added into refractory fibre element, mixing;S905, puts into remaining material, mixing.
In sum, the consumptive material of the present invention, low cost of manufacture, and stability is strong, it is simple to quickly 3D prints.The master of this consumptive material Body is low-melting alloy, it is simple to melts and implements to print.By low melting point alloy particles is prepared as multiple structure, when outer layer melts After change, material system is the most gradually made to become flowable state, consequently facilitating material conveying.Additionally, by using carbon fiber, work as carbon fiber During carbonization, material system forms cavity, in order to form the structure of similar blister steel, but, achieve again carburizer simultaneously Skill, penetrates into carbon inside alloy, thus gives alloy higher intensity.And refractory fibre is plain, glass fibre, gives and closing The toughness that gold is higher.After carrying out 3D printing with the alloy material of the present invention, its intensity of the product printed is high, toughness is good, it is simple to Surface Machining processes.
Although above it has been shown and described that embodiments of the invention, it is to be understood that above-described embodiment is example Property, it is impossible to be interpreted as limitation of the present invention, those of ordinary skill in the art is without departing from the principle of the present invention and objective In the case of above-described embodiment can be changed within the scope of the invention, revise, replace and modification.

Claims (8)

1. a high performance 3D printing consumables alloy material, it is characterised in that by weight, including following component:
Low melting point alloy particles, 5 to 10 parts;
Carbon fiber, 7 to 10 parts;
Calcium carbonate, 1 to 2 part;
Refractory fibre element, 1 to 2 part;
Magnesium chloride crystal, 0.05 to 0.1 part;
Chitosan particle, 1 part to 2 part;
Clay particle, 1 part to 2 part;
Glass fibre, 2 parts to 3 parts.
High performance 3D printing consumables alloy material the most according to claim 1, it is characterised in that described low-melting alloy Granule includes gallium-base alloy layer, indium-base alloy layer, bismuth-base alloy layer, bell metal layer, photosensitive material layer from outside to inside.
High performance 3D printing consumables alloy material the most according to claim 1, it is characterised in that the grain of described calcium carbonate Footpath is 1 micron to 10 microns.
High performance 3D printing consumables alloy material the most according to claim 1, it is characterised in that described refractory fibre element A diameter of 1 millimeter to 3 millimeters of cross section.
High performance 3D printing consumables alloy material the most according to claim 1, it is characterised in that described glass fibre Particle diameter is 1 millimeter to 5 millimeters.
High performance 3D printing consumables alloy material the most according to claim 1, it is characterised in that by weight, including Following component:
Low melting point alloy particles, 6 parts;
Carbon fiber, 8 parts;
Calcium carbonate, 1.2 parts;
Refractory fibre element, 1.5 parts;
Magnesium chloride crystal, 0.08 part;
Chitosan particle, 1.3 parts;
Clay particle, 1.4 parts;
Glass fibre, 2.1 parts.
High performance 3D printing consumables alloy material the most according to claim 1, it is characterised in that by weight, including Following component:
Low melting point alloy particles, 9 parts;
Carbon fiber, 7 parts;
Calcium carbonate, 1.2 parts;
Refractory fibre element, 1.5 parts;
Magnesium chloride crystal, 0.08 part;
Chitosan particle, 1.3 parts;
Clay particle, 1.4 parts;
Glass fibre, 2.1 parts;
Also include native gold powder, 0.01 part.
High performance 3D printing consumables alloy material the most according to claim 1, it is characterised in that by weight, including Following component:
Low melting point alloy particles, 10 parts;
Carbon fiber, 8 parts;
Calcium carbonate, 1.5 parts;
Refractory fibre element, 1.1 parts;
Magnesium chloride crystal, 0.05 part;
Chitosan particle, 1.3 parts;
Clay particle, 1.4 parts;
Glass fibre, 2.1 parts;
Native gold powder, 0.01 part;
Also include, amino acid crystals, 1.3 parts.
CN201610762208.6A 2016-08-29 2016-08-29 High-performance 3D printing alloy supplies Pending CN106312046A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610762208.6A CN106312046A (en) 2016-08-29 2016-08-29 High-performance 3D printing alloy supplies

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610762208.6A CN106312046A (en) 2016-08-29 2016-08-29 High-performance 3D printing alloy supplies

Publications (1)

Publication Number Publication Date
CN106312046A true CN106312046A (en) 2017-01-11

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Application Number Title Priority Date Filing Date
CN201610762208.6A Pending CN106312046A (en) 2016-08-29 2016-08-29 High-performance 3D printing alloy supplies

Country Status (1)

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CN (1) CN106312046A (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1326828A (en) * 2001-05-15 2001-12-19 北京北方恒利科技发展有限公司 Low melting point powder material for laser sintering fast forming precisely casting wax mold
US20020012607A1 (en) * 2000-05-24 2002-01-31 Corbin Stephen F. Variable melting point solders and brazes
CN104672757A (en) * 2015-03-02 2015-06-03 苏州容坤半导体科技有限公司 3D printing wire rod with axial thermal shrinkage rate smaller than 0.5%, preparation technological method and manufacture device
CN104744000A (en) * 2015-03-07 2015-07-01 南京工业大学 Gypsum material for 3D printing and preparation method thereof
CN104889397A (en) * 2014-03-03 2015-09-09 中国科学院理化技术研究所 Low-melting-point metal wire for 3D printing and manufacturing method thereof
CN105598441A (en) * 2015-12-23 2016-05-25 成都新柯力化工科技有限公司 Composite material for 3D printing engine cylinder cover and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020012607A1 (en) * 2000-05-24 2002-01-31 Corbin Stephen F. Variable melting point solders and brazes
CN1326828A (en) * 2001-05-15 2001-12-19 北京北方恒利科技发展有限公司 Low melting point powder material for laser sintering fast forming precisely casting wax mold
CN104889397A (en) * 2014-03-03 2015-09-09 中国科学院理化技术研究所 Low-melting-point metal wire for 3D printing and manufacturing method thereof
CN104672757A (en) * 2015-03-02 2015-06-03 苏州容坤半导体科技有限公司 3D printing wire rod with axial thermal shrinkage rate smaller than 0.5%, preparation technological method and manufacture device
CN104744000A (en) * 2015-03-07 2015-07-01 南京工业大学 Gypsum material for 3D printing and preparation method thereof
CN105598441A (en) * 2015-12-23 2016-05-25 成都新柯力化工科技有限公司 Composite material for 3D printing engine cylinder cover and preparation method thereof

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