CN106280786B - A kind of high-powered LED lamp - Google Patents

A kind of high-powered LED lamp Download PDF

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Publication number
CN106280786B
CN106280786B CN201610633907.0A CN201610633907A CN106280786B CN 106280786 B CN106280786 B CN 106280786B CN 201610633907 A CN201610633907 A CN 201610633907A CN 106280786 B CN106280786 B CN 106280786B
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weight
parts
lamp housing
radiator
added
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CN106280786A (en
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郭月强
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TIANCHANG WISDOM ELECTRONICS Co.,Ltd.
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Zhongshan Fenghua Xining Lighting Design Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21VFUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
    • F21V15/00Protecting lighting devices from damage
    • F21V15/02Cages
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21VFUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
    • F21V29/00Protecting lighting devices from thermal damage; Cooling or heating arrangements specially adapted for lighting devices or systems
    • F21V29/50Cooling arrangements
    • F21V29/56Cooling arrangements using liquid coolants
    • F21V29/57Cooling arrangements using liquid coolants characterised by control arrangements
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21VFUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
    • F21V29/00Protecting lighting devices from thermal damage; Cooling or heating arrangements specially adapted for lighting devices or systems
    • F21V29/50Cooling arrangements
    • F21V29/60Cooling arrangements characterised by the use of a forced flow of gas, e.g. air
    • F21V29/67Cooling arrangements characterised by the use of a forced flow of gas, e.g. air characterised by the arrangement of fans
    • F21V29/677Cooling arrangements characterised by the use of a forced flow of gas, e.g. air characterised by the arrangement of fans the fans being used for discharging
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21VFUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
    • F21V29/00Protecting lighting devices from thermal damage; Cooling or heating arrangements specially adapted for lighting devices or systems
    • F21V29/50Cooling arrangements
    • F21V29/70Cooling arrangements characterised by passive heat-dissipating elements, e.g. heat-sinks
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21VFUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
    • F21V29/00Protecting lighting devices from thermal damage; Cooling or heating arrangements specially adapted for lighting devices or systems
    • F21V29/50Cooling arrangements
    • F21V29/70Cooling arrangements characterised by passive heat-dissipating elements, e.g. heat-sinks
    • F21V29/83Cooling arrangements characterised by passive heat-dissipating elements, e.g. heat-sinks the elements having apertures, ducts or channels, e.g. heat radiation holes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
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  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of high-powered LED lamps, it include lamp housing, installation base plate is equipped on lamp housing lower end, groove is equipped in installation base plate, it is equipped with the mounting hole through installation base plate in bottom portion of groove, LED chip component is equipped in mounting hole, the conductive graphite piece of energy closed pockets is equipped at slot opening, it is filled with cooling oil in the cavity that groove and conductive graphite piece surround, radiator is equipped in the inner peripheral wall of lamp housing upper end, exhaust slot is equipped on the lamp housing below radiator, exhaust fan device is equipped in lamp housing upper end, exhaust slot can be closed and be vented the dodge gate that can be opened when fan device work by being hinged in exhaust slot, oil cooling service pipe is equipped in radiator, the both ends of oil cooling service pipe are connected to constitute primary Ioops with cavity, oil pump is equipped on oil cooling service pipe.The object of the invention provides a kind of simple in structure, good heat dissipation effect, the high-powered LED lamp that can effectively prolong the service life.

Description

A kind of high-powered LED lamp
Technical field
The present invention relates to a kind of high-powered LED lamps.
Background technology
High-power and high-luminance white LED light source gradually replaces conventional light source at present, but not due to the high problem of LED junction temperature It can effectively solve, lead to the decline of LED chip luminous efficiency, light decay, aging, shorten the working life, make always high-power LED lamp cannot be applied illumination is high, use environment is severe, the longer field of street lamp lighting of life requirements.
So existing high-powered LED lamp is up for further perfect.
Invention content
Place that purpose of the invention is to overcome the shortcomings in the prior art provides a kind of simple in structure, heat dissipation effect It is good, the high-powered LED lamp that can effectively prolong the service life.
In order to achieve the above object, the present invention uses following scheme:
A kind of high-powered LED lamp includes lamp housing, and installation base plate is equipped on the lamp housing lower end, it is characterised in that:? It is equipped with groove in the installation base plate, the mounting hole through installation base plate is equipped in the bottom portion of groove, in the mounting hole Equipped with LED chip component, the conductive graphite piece of the groove can be closed by being equipped at the slot opening, the groove with lead It is filled with cooling oil in the cavity that hot graphite flake surrounds, radiator is equipped in the inner peripheral wall of the lamp housing upper end, is dissipated described Lamp housing below hot device is equipped with exhaust slot, exhaust fan device is equipped in the lamp housing upper end, in the exhaust slot Exhaust slot can be closed and be vented the dodge gate that can be opened when fan device work by being hinged with, and cooling is equipped in the radiator The both ends of oil pipe, the oil cooling service pipe are connected with cavity to constitute primary Ioops, and oil pump is equipped on the oil cooling service pipe.
A kind of high-powered LED lamp as described above, it is characterised in that the radiator includes radiator body, described Radiator body inner vertical is arranged at intervals with several radiating fins in radiator length direction, and the oil cooling service pipe is through described Radiating fin.
A kind of high-powered LED lamp as described above, it is characterised in that the gap pair between lamp housing upper surface and radiating fin The position answered is equipped with air admission hole.Gas enters from the gap between radiating fin, is discharged from exhaust slot, good cooling results
A kind of high-powered LED lamp as described above, it is characterised in that temp probe is equipped in the groove, in the lamp Controller is equipped in shell, the temp probe, exhaust fan device, oil pump are connected with controller respectively.
A kind of high-powered LED lamp as described above, it is characterised in that the LED chip component includes aluminum substrate, in institute It states and is welded with LED chip on aluminum substrate one end, the aluminum substrate other end is arranged in groove.
A kind of high-powered LED lamp as described above, it is characterised in that exhaust fan device includes to be connected to lamp housing upper end bottom Mounting base on face is equipped with motor in the mounting base, and flabellum is equipped on the motor shaft of the motor.
A kind of high-powered LED lamp as described above, it is characterised in that the radiating fin and conductive graphite piece outer periphery are tight Close connection.
Any a kind of high-powered LED lamp as described above, it is characterised in that in the radiator and oil cooling service pipe Thermal dispersant coatings are respectively equipped on outer wall.
A kind of high-powered LED lamp as described above, it is characterised in that the thermal dispersant coatings include with the following group by weight Point:
In conclusion advantage is the present invention compared with the existing technology:
The light efficiency of high-powered LED lamp can be effectively ensured in the configuration of the present invention is simple, good heat dissipation effect, extend its service life.
Description of the drawings
Fig. 1 is one of the stereoscopic schematic diagram of the present invention;
Fig. 2 is the two of the stereoscopic schematic diagram of the present invention;
Fig. 3 is the diagrammatic cross-section of the present invention;
Fig. 4 is the schematic diagram of oil cooling service pipe of the present invention and radiator assembly.
Specific implementation mode
The invention will be further described with specific implementation mode for explanation below in conjunction with the accompanying drawings:
A kind of high-powered LED lamp as shown in Figures 1 to 4 includes lamp housing 1, and installation base is equipped on 1 lower end of the lamp housing Plate 2 is equipped with groove 3 in the installation base plate 2, the mounting hole through installation base plate 2 is equipped in 3 bottom of the groove, in institute It states and is equipped with LED chip component 5 in mounting hole 4, the conductive graphite piece that can close the groove 3 is equipped in 3 opening of the groove 6, it is filled with cooling oil 7 in the cavity that the groove 3 and conductive graphite piece 6 surround, in 1 upper end inner peripheral wall of the lamp housing Equipped with radiator 8, it is equipped with exhaust slot 9 on the lamp housing 1 below the radiator 8, exhaust is equipped in 1 upper end of the lamp housing Fan device 10, exhaust slot 9 can be closed and be vented when fan device 10 works and can be opened by being hinged in the exhaust slot 9 Dodge gate 11, is equipped with oil cooling service pipe 12 in the radiator 8, and the both ends of the oil cooling service pipe 12 are connected with cavity to structure At primary Ioops, oil pump 13 is equipped on the oil cooling service pipe 12.
The cooling oil in heat and groove 3 generated in 5 course of work of LED chip component in the present invention quickly carries out hot friendship It changes, 3 outside of groove is provided with conductive graphite piece 6, the heat in cooling oil is by conductive graphite piece 6, by being vented fan device 10 effect is discharged into the external world;Cooling oil is under the driving of oil pump 13, and in 12 internal circulation flow of oil cooling service pipe, oil cooling service pipe 12 is set It sets in radiator 8, since the pipeline of oil cooling service pipe 12 is relatively long, the heat in cyclic process in cooling oil can have enough On Time Transmission to radiator 8, in the effect of exhaust fan device 10, the heat that radiator 8 distributes can effectively be discharged into the external world.It dissipates Thermal effect is good, and the light efficiency of LED light can be effectively ensured, and postpones service life.
Heretofore described radiator 8 includes radiator body 81, in 81 inner vertical of the radiator body in scattered Hot device length direction is arranged at intervals with several radiating fins 82, and the oil cooling service pipe 12 runs through the radiating fin 82.In order into One step increases the heat exchanger time of oil cooling service pipe 12 and radiating fin 82 of the present invention, and the oil cooling service pipe 12 is on radiating fin 82 Detour runs through, and the oil cooling service pipe 12 in the radiator 8 of 1 surrounding of lamp housing constitutes primary Ioops.
It is equipped with air admission hole 16 in the present invention on the corresponding position in gap between 1 upper surface of lamp housing and radiating fin 82.Gas Body enters from the gap between radiating fin 82, is discharged from exhaust slot, good cooling results.
Temp probe is equipped in the present invention in the groove 3, controller is equipped in the lamp housing 1, the temperature is visited Head, exhaust fan device 10, oil pump are connected with controller respectively.When temp probe detects cooling in groove 3 during use When oil temperature is more than predetermined value, controller sends out control signal to exhaust fan device 10, oil pump 13, makes exhaust fan device 10, oil 13 work of pump, to ensure the heat dissipation of LED light.
LED chip component 5 of the present invention includes aluminum substrate 51, and LED core is welded on 51 one end of the aluminum substrate Piece 52,51 other end of the aluminum substrate are arranged in groove 3.
It includes the mounting base 101 being connected on the bottom surface of lamp housing upper end that the present invention, which is vented fan device 10, in the mounting base 101 are equipped with motor 102, and flabellum 103 is equipped on the motor shaft of the motor 102.
Radiating fin 82 of the present invention is closely connect with 6 outer periphery of conductive graphite piece.
The present invention is respectively equipped with thermal dispersant coatings on 12 outer wall of the radiator 8 and oil cooling service pipe.
The composition of the thermal dispersant coatings of the present invention is further described below by way of specific embodiment:
Embodiment 1
Thermal dispersant coatings of the present invention include following components by weight:
Thermal dispersant coatings of the present invention are prepared by the following method, and are included the following steps:
A, by water-based acrylic resin, polycarbonate waterborne polyurethane, the organic siliconresin comprising modified Nano particle, Ludox and water are mixed evenly;
B, heat filling, auxiliary agent are added in the state of stirring, stirs evenly, resulting dispersion system;
C, the dispersion in step B is added in paint grinder mill and is ground to 30-50 μm, ultrasonic disperse is uniform.
Wherein the polycarbonate waterborne polyurethane is prepared by the following method:
The polycarbonate glycol of 1000 parts by weight is added in the container of belt stirrer, is warming up to 90 DEG C, vacuum distillation 0.5 Hour, 70 DEG C are cooled to, 280 parts by weight 2,4- toluene di-isocyanate(TDI)s are added, vacuum dehydration 0.5 hour is passed through nitrogen, adds 400 parts by weight enter isophorone diisocyanate, are reacted 2 hours at 80 DEG C, and the acetone of 75 parts by weight is added, is cooled to 30 DEG C, The triethylamine neutralization reaction of 85 parts by weight 15 minutes is added, 25 parts by weight N- methyl pyrrole network alkanones are added, react 0.5 at 50 DEG C Hour, 80 parts by weight butanone and 145 parts by weight 1,4- butanediols is added, reacts 1 hour, be added 1000 parts by weight of deionized water and 95 parts by weight trifluoroacetic acids are dispersed with stirring uniformly, you can.
The wherein described organic siliconresin comprising modified Nano particle is prepared by the following method:
A, 50 parts by weight of methyltriethoxysilane are taken, are added in 650- parts of water, the Catalyzed by Formic Acid of 0.05 parts by weight is added Agent hydrolyzes 1 hour at 0 DEG C, is warming up to 70 DEG C of progress polymerisations, is evaporated under reduced pressure after reaction, obtains organosilicon Resin;
B, by organic siliconresin, the 1- Trifluoromethyl-1s in step A, 3 butadiene, 10 parts by weight, titanate catalyst 0.2 Parts by weight and 12 parts by weight of ethyl acetate are uniformly mixed, and under the protection of argon gas, are heated to 110 DEG C of dehydration condensations 1 hour, Obtain modified organic silicone resin;
C, the modified organic silicone resin in step B is warming up to 80 DEG C, 3 parts of silester is added and react 1 hour, reaction knot Cool down after beam, vacuum distillation removes solvent to get the organic siliconresin of modified Nano particle is included.
Heretofore described heat filling by weight percentage by 0.02% carbon nanotube, 10% Nickel Aluminium Alloy Powder, 2% silver powder, 20% gallium nitride and 67.98% aluminium nitride composition.The wherein described carbon nanotube is handled by following methods: Carbon nanotube is added to appropriate, the dense H of volume ratio 3: 12SO4With dense HNO3Nitration mixture in, cleaning is to neutrality after 80 DEG C of acidification 2h And it is dried in vacuo.
The auxiliary agent is high 270 polyether silicone of wetting agent enlightening.
Embodiment 2
Thermal dispersant coatings of the present invention include following components by weight:
Thermal dispersant coatings of the present invention are prepared by the following method, and are included the following steps:
A, by water-based acrylic resin, polycarbonate waterborne polyurethane, the organic siliconresin comprising modified Nano particle, Ludox and water are mixed evenly;
B, heat filling, auxiliary agent are added in the state of stirring, stirs evenly, resulting dispersion system;
C, the dispersion in step B is added in paint grinder mill and is ground to 30-50 μm, ultrasonic disperse is uniform.
Wherein the polycarbonate waterborne polyurethane is prepared by the following method:
The polycarbonate glycol of 1000 parts by weight is added in the container of belt stirrer, is warming up to 90 DEG C, vacuum distillation 0.5 Hour, 70 DEG C are cooled to, 280 parts by weight 2,4- toluene di-isocyanate(TDI)s are added, vacuum dehydration 0.5 hour is passed through nitrogen, adds 400 parts by weight enter isophorone diisocyanate, are reacted 2 hours at 80 DEG C, and the acetone of 75 parts by weight is added, is cooled to 30 DEG C, The triethylamine neutralization reaction of 85 parts by weight 15 minutes is added, 25 parts by weight N- methyl pyrrole network alkanones are added, react 0.5 at 50 DEG C Hour, 80 parts by weight butanone and 145 parts by weight 1,4- butanediols is added, reacts 1 hour, be added 1000 parts by weight of deionized water and 95 parts by weight trifluoroacetic acids are dispersed with stirring uniformly, you can.
The wherein described organic siliconresin comprising modified Nano particle is prepared by the following method:
A, 80 parts by weight of methyltriethoxysilane are taken, are added in 950 parts of water, the Catalyzed by Formic Acid agent of 0.4 parts by weight is added, It hydrolyzes 5 hours at 5 DEG C, is warming up to 90 DEG C of progress polymerisations, is evaporated under reduced pressure after reaction, obtains organosilicon tree Fat;
B, by organic siliconresin, the 1- Trifluoromethyl-1s in step A, 3 butadiene, 20 parts by weight, titanate catalyst 0.8 Parts by weight and 22 parts by weight of ethyl acetate are uniformly mixed, and under the protection of argon gas, are heated to 120 DEG C of dehydration condensations 3 hours, Obtain modified organic silicone resin;
C, the modified organic silicone resin in step B is warming up to 90 DEG C, 12 parts of silester is added and react 2 hours, reaction After cool down, vacuum distillation removes solvent to get including the organic siliconresin of modified Nano particle.
Heretofore described heat filling by weight percentage by 0.2% carbon nanotube, 30% Nickel Aluminium Alloy Powder, 1.8% silver powder, 20% gallium nitride and 48% aluminium nitride composition.The wherein described carbon nanotube is handled by following methods: Carbon nanotube is added to appropriate, the dense H of volume ratio 3: 12SO4With dense HNO3Nitration mixture in, cleaning is to neutrality after 80 DEG C of acidification 2h And it is dried in vacuo.
Auxiliary agent described in wherein 4 parts by weight includes 0.2 parts by weight wetting agent, 1 parts per weight dispersing agent, 2.8 parts by weight film forming Auxiliary agent.The wetting agent is high 270 polyether silicone of enlightening, and the dispersant is BYK-190 dispersants, and the coalescents are Lauryl Alcohol ester.
Embodiment 3
Thermal dispersant coatings of the present invention include following components by weight:
Thermal dispersant coatings of the present invention are prepared by the following method, and are included the following steps:
A, by water-based acrylic resin, polycarbonate waterborne polyurethane, the organic siliconresin comprising modified Nano particle, Ludox and water are mixed evenly;
B, heat filling, auxiliary agent are added in the state of stirring, stirs evenly, resulting dispersion system;
C, the dispersion in step B is added in paint grinder mill and is ground to 30-50 μm, ultrasonic disperse is uniform.
Wherein the polycarbonate waterborne polyurethane is prepared by the following method:
The polycarbonate glycol of 1000 parts by weight is added in the container of belt stirrer, is warming up to 90 DEG C, vacuum distillation 0.5 Hour, 70 DEG C are cooled to, 280 parts by weight 2,4- toluene di-isocyanate(TDI)s are added, vacuum dehydration 0.5 hour is passed through nitrogen, adds 400 parts by weight enter isophorone diisocyanate, are reacted 2 hours at 80 DEG C, and the acetone of 75 parts by weight is added, is cooled to 30 DEG C, The triethylamine neutralization reaction of 85 parts by weight 15 minutes is added, 25 parts by weight N- methyl pyrrole network alkanones are added, react 0.5 at 50 DEG C Hour, 80 parts by weight butanone and 145 parts by weight 1,4- butanediols is added, reacts 1 hour, be added 1000 parts by weight of deionized water and 95 parts by weight trifluoroacetic acids are dispersed with stirring uniformly, you can.
The wherein described organic siliconresin comprising modified Nano particle is prepared by the following method:
A, 65 parts by weight of methyltriethoxysilane are taken, are added in 800 parts of water, the Catalyzed by Formic Acid agent of 0.2 parts by weight is added, It is hydrolyzed 2 hours at 2 DEG C, is warming up to 80 DEG C of progress polymerisations, is evaporated under reduced pressure after reaction, obtains organosilicon tree Fat;
B, by organic siliconresin, the 1- Trifluoromethyl-1s in step A, 3 butadiene, 15 parts by weight, titanate catalyst 0.5 Parts by weight and 16 parts by weight of ethyl acetate are uniformly mixed, and under the protection of argon gas, are heated to 115 DEG C of dehydration condensations 2 hours, Obtain modified organic silicone resin;
C, the modified organic silicone resin in step B is warming up to 85 DEG C, 5 parts of silester is added and react 1.5 hours, reaction After cool down, vacuum distillation removes solvent to get including the organic siliconresin of modified Nano particle.
Heretofore described heat filling by weight percentage by 0.1% carbon nanotube, 20% Nickel Aluminium Alloy Powder, 1% silver powder, 15% gallium nitride and 63.9% aluminium nitride composition.The wherein described carbon nanotube is handled by following methods: Carbon nanotube is added to appropriate, the dense H of volume ratio 3: 12SO4With dense HNO3Nitration mixture in, cleaning is to neutrality after 80 DEG C of acidification 2h And it is dried in vacuo.
Auxiliary agent described in wherein 2 parts by weight includes 0.2 parts by weight wetting agent, 0.3 parts per weight dispersing agent, 1 parts by weight film forming Auxiliary agent, 0.1 parts by weight antifoaming agent, 0.4 parts by weight rheological agent.The wetting agent is high 270 polyether silicone of enlightening, the dispersion Agent is BYK-190 dispersants, and the coalescents are Lauryl Alcohol ester, and the antifoaming agent is BYK-014 antifoaming agent, the rheology Agent is high 450 levelling agent of enlightening.
Embodiment 4
Thermal dispersant coatings of the present invention include following components by weight:
Thermal dispersant coatings of the present invention are prepared by the following method, and are included the following steps:
A, by water-based acrylic resin, polycarbonate waterborne polyurethane, the organic siliconresin comprising modified Nano particle, Ludox and water are mixed evenly;
B, heat filling, auxiliary agent are added in the state of stirring, stirs evenly, resulting dispersion system;
C, the dispersion in step B is added in paint grinder mill and is ground to 30-50 μm, ultrasonic disperse is uniform.
Wherein the polycarbonate waterborne polyurethane is prepared by the following method:
The polycarbonate glycol of 1000 parts by weight is added in the container of belt stirrer, is warming up to 90 DEG C, vacuum distillation 0.5 Hour, 70 DEG C are cooled to, 280 parts by weight 2,4- toluene di-isocyanate(TDI)s are added, vacuum dehydration 0.5 hour is passed through nitrogen, adds 400 parts by weight enter isophorone diisocyanate, are reacted 2 hours at 80 DEG C, and the acetone of 75 parts by weight is added, is cooled to 30 DEG C, The triethylamine neutralization reaction of 85 parts by weight 15 minutes is added, 25 parts by weight N- methyl pyrrole network alkanones are added, react 0.5 at 50 DEG C Hour, 80 parts by weight butanone and 145 parts by weight 1,4- butanediols is added, reacts 1 hour, be added 1000 parts by weight of deionized water and 95 parts by weight trifluoroacetic acids are dispersed with stirring uniformly, you can.
The wherein described organic siliconresin comprising modified Nano particle is prepared by the following method:
A, 50 parts by weight of methyltriethoxysilane are taken, are added in 950 parts of water, the Catalyzed by Formic Acid of 0.05 parts by weight is added Agent hydrolyzes 1 hour at 0 DEG C, is warming up to 90 DEG C of progress polymerisations, is evaporated under reduced pressure after reaction, obtains organosilicon Resin;
B, by organic siliconresin, the 1- Trifluoromethyl-1s in step A, 3 butadiene, 10 parts by weight, titanate catalyst 0.2 Parts by weight and 15 parts by weight of ethyl acetate are uniformly mixed, and under the protection of argon gas, are heated to 110 DEG C of dehydration condensations 1 hour, Obtain modified organic silicone resin;
C, the modified organic silicone resin in step B is warming up to 80 DEG C, 3 parts of silester is added and react 1 hour, reaction knot Cool down after beam, vacuum distillation removes solvent to get the organic siliconresin of modified Nano particle is included.
Heretofore described heat filling by weight percentage by 0.05% carbon nanotube, 30% Nickel Aluminium Alloy Powder, 0.55% silver powder, 10% gallium nitride and 59.4% aluminium nitride composition.The wherein described carbon nanotube is by following methods Reason:Carbon nanotube is added to appropriate, the dense H of volume ratio 3: 12SO4With dense HNO3Nitration mixture in, 80 DEG C acidification 2h after clean to Neutrality is simultaneously dried in vacuo.
Auxiliary agent described in wherein 0.2 parts by weight is 0.05 wetting agent, 0.15 coalescents.The wetting agent is that enlightening is high 270 polyether silicones, the coalescents are Lauryl Alcohol ester.
Embodiment 5
Thermal dispersant coatings of the present invention include following components by weight:
Thermal dispersant coatings of the present invention are prepared by the following method, and are included the following steps:
A, by water-based acrylic resin, polycarbonate waterborne polyurethane, the organic siliconresin comprising modified Nano particle, Ludox and water are mixed evenly;
B, heat filling, auxiliary agent are added in the state of stirring, stirs evenly, resulting dispersion system;
C, the dispersion in step B is added in paint grinder mill and is ground to 30-50 μm, ultrasonic disperse is uniform.
Wherein the polycarbonate waterborne polyurethane is prepared by the following method:
The polycarbonate glycol of 1000 parts by weight is added in the container of belt stirrer, is warming up to 90 DEG C, vacuum distillation 0.5 Hour, 70 DEG C are cooled to, 280 parts by weight 2,4- toluene di-isocyanate(TDI)s are added, vacuum dehydration 0.5 hour is passed through nitrogen, adds 400 parts by weight enter isophorone diisocyanate, are reacted 2 hours at 80 DEG C, and the acetone of 75 parts by weight is added, is cooled to 30 DEG C, The triethylamine neutralization reaction of 85 parts by weight 15 minutes is added, 25 parts by weight N- methyl pyrrole network alkanones are added, react 0.5 at 50 DEG C Hour, 80 parts by weight butanone and 145 parts by weight 1,4- butanediols is added, reacts 1 hour, be added 1000 parts by weight of deionized water and 95 parts by weight trifluoroacetic acids are dispersed with stirring uniformly, you can.
The wherein described organic siliconresin comprising modified Nano particle is prepared by the following method:
A, 60 parts by weight of methyltriethoxysilane are taken, are added in 700 parts of water, the Catalyzed by Formic Acid agent of 0.1 parts by weight is added, It is hydrolyzed 2 hours at 1 DEG C, is warming up to 75 DEG C of progress polymerisations, is evaporated under reduced pressure after reaction, obtains organosilicon tree Fat;
B, by organic siliconresin, the 1- Trifluoromethyl-1s in step A, 3 butadiene, 18 parts by weight, titanate catalyst 0.3 Parts by weight and 14 parts by weight of ethyl acetate are uniformly mixed, and under the protection of argon gas, are heated to 115 DEG C of dehydration condensations 2 hours, Obtain modified organic silicone resin;
C, the modified organic silicone resin in step B is warming up to 85 DEG C, 6 parts of silester is added and react 1.5 hours, reaction After cool down, vacuum distillation removes solvent to get including the organic siliconresin of modified Nano particle.
Heretofore described heat filling by weight percentage by 0.15% carbon nanotube, 30% Nickel Aluminium Alloy Powder, 0.5% silver powder, 5% gallium nitride and 64.35% aluminium nitride composition.The wherein described carbon nanotube is by following methods Reason:Carbon nanotube is added to appropriate, the dense H of volume ratio 3: 12SO4With dense HNO3Nitration mixture in, 80 DEG C acidification 2h after clean to Neutrality is simultaneously dried in vacuo.
Auxiliary agent described in wherein 4 parts by weight be include 0.1 parts by weight wetting agent, 0.2 parts per weight dispersing agent, 2 parts by weight at Film auxiliary agent, 0.3 parts by weight antifoaming agent and 1.4 parts by weight rheological agents.The wetting agent is high 270 polyether silicone of enlightening, described Dispersant is BYK-190 dispersants, and the coalescents are Lauryl Alcohol ester, and the antifoaming agent is BYK-014 antifoaming agent, described Rheological agent is high 450 levelling agent of enlightening.
The anticorrosive packing is trbasic zinc phosphate.
Embodiment 6
Thermal dispersant coatings of the present invention include following components by weight:
Thermal dispersant coatings of the present invention are prepared by the following method, and are included the following steps:
A, by water-based acrylic resin, polycarbonate waterborne polyurethane, the organic siliconresin comprising modified Nano particle, Ludox and water are mixed evenly;
B, heat filling, auxiliary agent are added in the state of stirring, stirs evenly, resulting dispersion system;
C, the dispersion in step B is added in paint grinder mill and is ground to 30-50 μm, ultrasonic disperse is uniform.
Wherein the polycarbonate waterborne polyurethane is prepared by the following method:
The polycarbonate glycol of 1000 parts by weight is added in the container of belt stirrer, is warming up to 90 DEG C, vacuum distillation 0.5 Hour, 70 DEG C are cooled to, 280 parts by weight 2,4- toluene di-isocyanate(TDI)s are added, vacuum dehydration 0.5 hour is passed through nitrogen, adds 400 parts by weight enter isophorone diisocyanate, are reacted 2 hours at 80 DEG C, and the acetone of 75 parts by weight is added, is cooled to 30 DEG C, The triethylamine neutralization reaction of 85 parts by weight 15 minutes is added, 25 parts by weight N- methyl pyrrole network alkanones are added, react 0.5 at 50 DEG C Hour, 80 parts by weight butanone and 145 parts by weight 1,4- butanediols is added, reacts 1 hour, be added 1000 parts by weight of deionized water and 95 parts by weight trifluoroacetic acids are dispersed with stirring uniformly, you can.
The wherein described organic siliconresin comprising modified Nano particle is prepared by the following method:
A, 70 parts by weight of methyltriethoxysilane are taken, are added in 800 parts of water, the Catalyzed by Formic Acid agent of 0.3 parts by weight is added, It is hydrolyzed 3 hours at 3 DEG C, is warming up to 80 DEG C of progress polymerisations, is evaporated under reduced pressure after reaction, obtains organosilicon tree Fat;
B, by organic siliconresin, the 1- Trifluoromethyl-1s in step A, 3 butadiene, 13 parts by weight, titanate catalyst 0.4 Parts by weight and 20 parts by weight of ethyl acetate are uniformly mixed, and under the protection of argon gas, are heated to 110 DEG C of dehydration condensations 1 hour, Obtain modified organic silicone resin;
C, the modified organic silicone resin in step B is warming up to 80 DEG C, 3 parts of silester is added and react 1 hour, reaction knot Cool down after beam, vacuum distillation removes solvent to get the organic siliconresin of modified Nano particle is included.
Heretofore described heat filling by weight percentage by 0.2% carbon nanotube, 25% Nickel Aluminium Alloy Powder, 1% silver powder, 16% gallium nitride and 57.8% aluminium nitride composition.The wherein described carbon nanotube is handled by following methods: Carbon nanotube is added to appropriate, the dense H of volume ratio 3: 12SO4With dense HNO3Nitration mixture in, cleaning is to neutrality after 80 DEG C of acidification 2h And it is dried in vacuo.
Auxiliary agent described in wherein 0.2 parts by weight is 0.1 parts by weight wetting agent, 0.1 parts per weight dispersing agent.The wetting agent For high 270 polyether silicone of enlightening, the dispersant is BYK-190 dispersants.
The anticorrosive packing is the mixture of trbasic zinc phosphate, modified zinc phosphate.
Embodiment 7
Thermal dispersant coatings of the present invention include following components by weight:
Thermal dispersant coatings of the present invention are prepared by the following method, and are included the following steps:
A, by water-based acrylic resin, polycarbonate waterborne polyurethane, the organic siliconresin comprising modified Nano particle, Ludox and water are mixed evenly;
B, heat filling, auxiliary agent are added in the state of stirring, stirs evenly, resulting dispersion system;
C, the dispersion in step B is added in paint grinder mill and is ground to 30-50 μm, ultrasonic disperse is uniform.
Wherein the polycarbonate waterborne polyurethane is prepared by the following method:
The polycarbonate glycol of 1000 parts by weight is added in the container of belt stirrer, is warming up to 90 DEG C, vacuum distillation 0.5 Hour, 70 DEG C are cooled to, 280 parts by weight 2,4- toluene di-isocyanate(TDI)s are added, vacuum dehydration 0.5 hour is passed through nitrogen, adds 400 parts by weight enter isophorone diisocyanate, are reacted 2 hours at 80 DEG C, and the acetone of 75 parts by weight is added, is cooled to 30 DEG C, The triethylamine neutralization reaction of 85 parts by weight 15 minutes is added, 25 parts by weight N- methyl pyrrole network alkanones are added, react 0.5 at 50 DEG C Hour, 80 parts by weight butanone and 145 parts by weight 1,4- butanediols is added, reacts 1 hour, be added 1000 parts by weight of deionized water and 95 parts by weight trifluoroacetic acids are dispersed with stirring uniformly, you can.
The wherein described organic siliconresin comprising modified Nano particle is prepared by the following method:
A, 60 parts by weight of methyltriethoxysilane are taken, are added in 750 parts of water, the Catalyzed by Formic Acid agent of 0.2 parts by weight is added, It is hydrolyzed 3 hours at 2 DEG C, is warming up to 75 DEG C of progress polymerisations, is evaporated under reduced pressure after reaction, obtains organosilicon tree Fat;
B, by organic siliconresin, the 1- Trifluoromethyl-1s in step A, 3 butadiene, 13 parts by weight, titanate catalyst 0.3 Parts by weight and 18 parts by weight of ethyl acetate are uniformly mixed, and under the protection of argon gas, are heated to 120 DEG C of dehydration condensations 3 hours, Obtain modified organic silicone resin;
C, the modified organic silicone resin in step B is warming up to 90 DEG C, 12 parts of silester is added and react 2 hours, reaction After cool down, vacuum distillation removes solvent to get including the organic siliconresin of modified Nano particle.
Heretofore described heat filling by weight percentage by 0.02% carbon nanotube, 28% Nickel Aluminium Alloy Powder, 0.8% silver powder, 15% gallium nitride and 56.18% aluminium nitride composition.The wherein described carbon nanotube is by following methods Reason:Carbon nanotube is added to appropriate, the dense H of volume ratio 3: 12SO4With dense HNO3Nitration mixture in, 80 DEG C acidification 2h after clean to Neutrality is simultaneously dried in vacuo.
Auxiliary agent described in wherein 2 parts by weight is 0.2 parts by weight wetting agent, 0.1 parts per weight dispersing agent, 1 parts by weight film forming help Agent, 0.2 parts by weight antifoaming agent and 0.5 parts by weight rheological agent.The wetting agent is high 270 polyether silicone of enlightening, the dispersion Agent is BYK-190 dispersants, and the coalescents are Lauryl Alcohol ester, and the antifoaming agent is BYK-014 antifoaming agent, the rheology Agent is high 450 levelling agent of enlightening.
Anticorrosive packing described in wherein 6 parts by weight includes 2 parts by weight of phosphoric acid zinc, 1 part by weight modified trbasic zinc phosphate and 3 parts by weight molybdenums The mixture of sour zinc.
The heat dissipation performance of thermal dispersant coatings of the present invention is further verified by following tests:
8 pieces of aluminum substrates are taken to mark respectively, plate 1, plate 2, plate 3, plate 4, plate 5, plate 6, plate 7, plate 8;Wherein plate 1 is not coated with heat-radiation coating Layer, the surfaces plate 2-8 apply the thermal dispersant coatings in 1-7 of the embodiment of the present invention, are detected to its performance after solidification successively respectively;By plate 1 is positioned over to plate 8 in heating plate, be sequentially adjusted in temperature 50 C, 80 DEG C, 100 DEG C, 150 DEG C, 200 DEG C, 250 DEG C, 300 DEG C, every time After temperature adjustment, balance is further continued for being heated to next temperature for 60 minutes, records temperature using temperature measurer, the results are shown in Table 1, room temperature 25 ℃。
Table 1
Initial temperature DEG C 50 80 100 150 200 250 300
Plate 1 balances after sixty minutes 38 65 78 121 155 198 243
Plate 2 balances after sixty minutes 26 50 58 83 110 160 201
Plate 3 balances after sixty minutes 22 48 56 80 105 149 190
Plate 4 balances after sixty minutes 23 45 55 81 103 148 188
Plate 5 balances after sixty minutes 20 41 48 76 98 130 175
Plate 6 balances after sixty minutes 21 42 49 77 99 132 176
Plate 7 balances after sixty minutes 23 49 52 80 100 135 185
Plate 8 balances after sixty minutes 24 47 54 81 103 141 188
It can clearly show that the aluminium base plate temperature for being coated with thermal dispersant coatings of the present invention is far below from table 1 and be not coated with thermal dispersant coatings Aluminum substrate, illustrate thermal dispersant coatings of the present invention have good heat dissipation effect.
Thermal dispersant coatings of the present invention combine, proportioning is reasonable, good heat dissipation effect;Heat dissipation filler in thermal dispersant coatings formula of the present invention Composition and ratio is reasonable, the effective heat dissipation area for increasing the film layer to be formed, to make the heat dissipation effect of thermal dispersant coatings of the present invention It is obviously improved.
The basic principles and main features and advantages of the present invention of the present invention have been shown and described above.The skill of the industry Art personnel it should be appreciated that the present invention is not limited to the above embodiments, the above embodiments and description only describe The principle of the present invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these Changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and Its equivalent thereof.

Claims (6)

1. a kind of high-powered LED lamp includes lamp housing(1), in the lamp housing(1)Lower end is equipped with installation base plate(2), feature It is:In the installation base plate(2)It is interior to be equipped with groove(3), in the groove(3)Bottom, which is equipped with, runs through installation base plate(2)Peace Fill hole(4), in the mounting hole(4)It is interior to be equipped with LED chip component(5), in the groove(3)Opening be equipped with can close described in Groove(3)Conductive graphite piece(6), in the groove(3)With conductive graphite piece(6)It is filled with cooling oil in the cavity surrounded (7), in the lamp housing(1)Upper end inner peripheral wall is equipped with radiator(8), in the radiator(8)The lamp housing of lower section(1)On set There is exhaust slot(9), in the lamp housing(1)Exhaust fan device is equipped in upper end(10), in the exhaust slot(9)Inside it is hinged with Exhaust slot can be closed(9)And exhaust fan device(10)The dodge gate that can be opened when work(11), in the radiator(8)It is interior Equipped with oil cooling service pipe(12), the oil cooling service pipe(12)Both ends be connected with cavity to constitute primary Ioops, in the cooling Oil pipe(12)It is equipped with oil pump(13), in the groove(3)It is interior to be equipped with temp probe, in the lamp housing(1)It is interior to be equipped with control Device, the temp probe, exhaust fan device(10), oil pump be connected respectively with controller, in the radiator(8)And cooling oil Pipe(12)Thermal dispersant coatings are respectively equipped on outer wall;
The thermal dispersant coatings include following components by weight:
Water-based acrylic resin 10-35
Polycarbonate waterborne polyurethane 5-10
Include the organic siliconresin 8-12 of modified Nano particle
Ludox 3-10
Heat filling 10-25
Water 25-50
Auxiliary agent 0.2-4.
2. a kind of high-powered LED lamp according to claim 1, it is characterised in that the radiator(8)It include radiator Ontology(81), in the radiator body(81)Inner vertical is arranged at intervals with several radiating fins in radiator length direction (82), the oil cooling service pipe(12)Through the radiating fin(82).
3. a kind of high-powered LED lamp according to claim 2, it is characterised in that in lamp housing(1)Upper surface and radiating fin (82)Between the corresponding position in gap be equipped with air admission hole(16).
4. a kind of high-powered LED lamp according to claim 1, it is characterised in that the LED chip component(5)Include aluminium Substrate(51), in the aluminum substrate(51)LED chip is welded on one end(52), the aluminum substrate(51)The other end is arranged recessed Slot(3)It is interior.
5. a kind of high-powered LED lamp according to claim 1, it is characterised in that exhaust fan device(10)Include to be connected to Mounting base on the bottom surface of lamp housing upper end(101), in the mounting base(101)It is equipped with motor(102), in the motor(102) Motor shaft be equipped with flabellum(103).
6. a kind of high-powered LED lamp according to claim 2, it is characterised in that the radiating fin(82)With conductive graphite Piece(6)Outer periphery closely connects.
CN201610633907.0A 2016-08-03 2016-08-03 A kind of high-powered LED lamp Active CN106280786B (en)

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CN202484956U (en) * 2012-02-07 2012-10-10 江苏洪昌科技股份有限公司 Heat tube heat radiator for large-power LED (Light-Emitting Diode) automobile headlamp
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