CN106256780A - A kind of reinjection treatment method up to standard of the wastewater with high concentration of sulfide of oil gas field - Google Patents
A kind of reinjection treatment method up to standard of the wastewater with high concentration of sulfide of oil gas field Download PDFInfo
- Publication number
- CN106256780A CN106256780A CN201510340481.5A CN201510340481A CN106256780A CN 106256780 A CN106256780 A CN 106256780A CN 201510340481 A CN201510340481 A CN 201510340481A CN 106256780 A CN106256780 A CN 106256780A
- Authority
- CN
- China
- Prior art keywords
- sulfide
- wastewater
- oil gas
- high concentration
- gas field
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002351 wastewater Substances 0.000 title claims abstract description 136
- 238000000034 method Methods 0.000 title claims abstract description 112
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 title claims abstract description 83
- 238000006477 desulfuration reaction Methods 0.000 claims abstract description 100
- 230000023556 desulfurization Effects 0.000 claims abstract description 97
- 239000007789 gas Substances 0.000 claims abstract description 92
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 89
- 238000005516 engineering process Methods 0.000 claims abstract description 57
- 238000004062 sedimentation Methods 0.000 claims abstract description 56
- 230000003311 flocculating effect Effects 0.000 claims abstract description 54
- 239000012528 membrane Substances 0.000 claims abstract description 54
- 230000008569 process Effects 0.000 claims abstract description 46
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 43
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 42
- 239000011593 sulfur Substances 0.000 claims abstract description 42
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 41
- 230000003647 oxidation Effects 0.000 claims abstract description 39
- 230000003197 catalytic effect Effects 0.000 claims abstract description 34
- 239000000126 substance Substances 0.000 claims abstract description 32
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims abstract description 20
- 238000002347 injection Methods 0.000 claims abstract description 5
- 239000007924 injection Substances 0.000 claims abstract description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 24
- 238000005189 flocculation Methods 0.000 claims description 22
- 230000016615 flocculation Effects 0.000 claims description 22
- 230000004907 flux Effects 0.000 claims description 14
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 12
- 239000003054 catalyst Substances 0.000 claims description 12
- 238000001914 filtration Methods 0.000 claims description 12
- 239000007800 oxidant agent Substances 0.000 claims description 12
- 239000002893 slag Substances 0.000 claims description 11
- 239000011790 ferrous sulphate Substances 0.000 claims description 10
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 10
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical group [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 10
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 10
- 230000001590 oxidative effect Effects 0.000 claims description 9
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 229910017604 nitric acid Inorganic materials 0.000 claims description 8
- 229950000845 politef Drugs 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- 239000001117 sulphuric acid Substances 0.000 claims description 8
- 235000011149 sulphuric acid Nutrition 0.000 claims description 8
- 125000000129 anionic group Chemical group 0.000 claims description 6
- 238000006555 catalytic reaction Methods 0.000 claims description 6
- 230000008859 change Effects 0.000 claims description 5
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 238000005987 sulfurization reaction Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical group [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 230000014759 maintenance of location Effects 0.000 claims 1
- 239000010865 sewage Substances 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 238000012423 maintenance Methods 0.000 abstract description 5
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000000725 suspension Substances 0.000 abstract description 3
- 239000003921 oil Substances 0.000 description 69
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 21
- 239000003795 chemical substances by application Substances 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 8
- 238000010992 reflux Methods 0.000 description 7
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- 230000033228 biological regulation Effects 0.000 description 5
- 239000012141 concentrate Substances 0.000 description 5
- 238000001471 micro-filtration Methods 0.000 description 5
- 238000003672 processing method Methods 0.000 description 4
- 238000011953 bioanalysis Methods 0.000 description 3
- -1 has Physical Substances 0.000 description 3
- 239000010842 industrial wastewater Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000003345 natural gas Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical group O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 230000003044 adaptive effect Effects 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 230000003009 desulfurizing effect Effects 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 229920002401 polyacrylamide Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 244000241872 Lycium chinense Species 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000031018 biological processes and functions Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000008398 formation water Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000005374 membrane filtration Methods 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000010815 organic waste Substances 0.000 description 1
- RECVMTHOQWMYFX-UHFFFAOYSA-N oxygen(1+) dihydride Chemical compound [OH2+] RECVMTHOQWMYFX-UHFFFAOYSA-N 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000010734 process oil Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 238000003325 tomography Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Landscapes
- Separation Of Suspended Particles By Flocculating Agents (AREA)
Abstract
The present invention relates to the reinjection treatment method up to standard of the wastewater with high concentration of sulfide of a kind of oil gas field, first, use negative pressure desulfurization technology by the most of hydrogen sulfide stripping out centralized burning in waste water；Secondly, use chemical catalytic oxidation technology by the remaining Oxidation of Hydrogen Sulfide in negative pressure desulfurization water outlet；Afterwards, catalytic oxidation desulfurization water outlet carries out flocculating sedimentation；Finally, flocculating sedimentation water outlet enters organic membrane filter unit and carries out organic membrane filter, and water outlet sulfur content, suspension content and oil content meet oil gas field reinjected water standard.The reinjection treatment method up to standard of the wastewater with high concentration of sulfide of oil gas field of the present invention, use negative pressure desulfurization+chemical catalytic oxidation+flocculating sedimentation+organic membrane filter technology, can effectively remove the sulfide in waste water, solve the problem that sulfur content is too high in oil gas field wastewater with high concentration of sulfide re-injection process, solve that existing treatment technology equipment is huge, complex process, inefficient, environmental suitability is poor, operating cost is high, is difficult to the shortcomings such as maintenance.
Description
Technical field
The present invention relates to field of industrial waste water treatment, the high sulfur-bearing of a kind of oil gas field gives up
The reinjection treatment method up to standard of water.Espespecially utilize negative pressure desulfurization+chemical catalytic oxidation+flocculating sedimentation
The reinjection treatment method up to standard of the wastewater with high concentration of sulfide of+organic membrane filter technical finesse oil gas field.
Background technology
Along with improving constantly, to demand for energy day of socio-economic development and living standards of the people
Big increasingly, exploitation of oil-gas field amount increases year by year.In the exploitation of oil gas field, particularly in gas field
The middle and late stage of exploitation, owing to formation water can invade gas reservoir along tomography and structural fracture, enters shaft bottom,
Making gas reservoir energy loss increase, well head pressure reduces, and band outlet capacity is deteriorated, and causes the gas well underproduction
Or water logging stops production, for maintaining the steady production of natural gas, water drainage-gas recovery technology is carried out in gas field energetically,
The aquifer yield making gas well increases sharply, and a lot of gas wells are forced because extracted waste water cannot process to close
Well, have impact on normal gas production and produces.
Oil gas field extracted waste water to oil gas field produce cause a difficult problem while, caused society
Problem also appears undoubtedly, causes huge pressure, especially mining area of southwest China to natural environment high
The a large amount of extracted waste waters produced in Oil & gas field in sulfur recovery process, this strand of waste water contains a large amount of sulfuration
Hydrogen and sulfide, belong to sulfur-containing waste water.If can not get effectively processing, not only environment can be produced
Raw severe contamination, also can produce heavy corrosion to waterline, there is severe compromise.
For the process of oil gas field extracted waste water, currently mainly have reinjection into reservoir, comprehensive utilization and
Process three kinds of modes of standard discharge.For existing process technique, currently mainly it is by fitting
Re-injection after degree process, can't realize standard discharge.According to the reinjection standard that China is existing, right
For oil gas field wastewater with high concentration of sulfide, main process target is the hydrogen sulfide in removal water, sulfur
Compound and float.
At present, the processing method of sulfur-containing waste water mainly has Physical, chemical method and bioanalysis.Its
In, Physical mainly includes stripping and stripping, and stripping is identical with stripping principle, except for the difference that,
Stripping is to use gas, and stripping is to use steam；Chemical method mainly includes chemical oxidization method and mixes
The solidifying sedimentation method；Bioanalysis mainly includes aerobe method and anaerobic biological process.In three kinds of methods,
Physical is the simplest, chemical method owing to there occurs chemical reaction, medicine when waste water sulfur content is higher
Agent consumption and the quantity of slag are relatively big, are not therefore suitable for processing the waste water that sulfur content is higher；Bioanalysis is
By microorganism, sulfide-oxidation is removed, due to the tolerance limitation of microorganism, process sulfur and contain
Measure during higher waste water inefficient, be not the most also suitable for processing the waste water that sulfur content is higher.
In Practical Project practice, due to the limitation in place, gas field, process gas field wastewater with high concentration of sulfide
Middle hydrogen sulfide and sulfide mainly use stripping process.Stripping is to allow waste water directly connect with gas
Touch, make the volatility poisonous and harmful substance in waste water be diffused into by a certain percentage in gas phase, from
And reach to separate the purpose of pollutant from waste water.In view of site condition is limited, currently mainly adopt
Carrying out stripping with natural gas, thus consume substantial amounts of natural gas, this has been considerably improved the method
The operating cost of desulfurization.Additionally, the method equipment needed thereby volume is big, it is complicated to install maintenance operation,
To gas well local environment bad adaptability, and treatment effeciency has much room for improvement.
Chinese patent 201410444573.3 has related to a kind of employing stripping removal high concentration and has contained
The process technique of sulfur waste water.Wastewater pH is regulated to 3～4 by this patent, carries out stripping afterwards,
Sulfide in stripping residual liquid carries out chemical reaction removal by adding Iron sulfuret..Chinese patent
200710010393.4 processing methods being directed to a kind of sulfur-containing waste water, this patent uses air to expose
Sulfide in waste water after gas removal acid adjustment, its principle is identical with stripping principle.Use air exposes
Gas problematically, hydrogen sulfide is inflammable harmful influence, mix with air and can form explosive mixing
Thing, chance naked light, high heat energy cause combustion explosion.
Chinese patent 200910201614.5 relates to a kind of employing CWO and processes sulfur-bearing
The method of waste water, this patent is by COD 2000～200000mg/L, and sulfur weight content is less than
The industrial wastewater of 70g/L, at reaction temperature 230～300 DEG C, reaction pressure 3～10MPa, liquid
Body air speed 0.5～2.5h-1, gas-liquid raw material standard state lower volume is than the condition being 70～300:1
Under, by using CWO to be removed by the Organic substance in waste water, by complete for the sulfur in waste water
Portion is converted into sulfate ion.The severe reaction conditions of CWO, invest, run and
Maintenance cost is higher, and equipment is huge, higher to site requirements.CWO is main
For removing high COD, being difficult to biodegradable waste water system.
Chinese patent 201110273016.6 relates to the sulfur-containing waste water processing method of a kind of oil gas field,
This patent mainly by adding pH adjusting agent and desulfurizing agent, carries out chemical reaction by waste water
Sulfur remove, desulfurizing agent uses ferrous sulfate, and the quantity of slag produced due to chemical reaction is relatively big, because of
The method of this this patent is applicable to process the highest waste water of sulfur content, this patent clearly define into
Sulfur content≤the 3000mg/L of water.
Chinese patent 201210567540.9 is directed to a kind of chemical oxidization method removing industrial wastewater
Middle sulfide and organic method, this patent uses chlorine as oxidant.This patent is the brightest
Fidelity is determined this patent and is applicable to process COD concentration 2000～20000mg/L, sulfide content
The waste water of 200～2000mg/L.Chinese patent 201210210210.4 is directed to a kind of oil gas field
Sulfur-containing waste water processing method, this patent is also to be removed by the sulfur in waste water by chemical oxidation, de-
Sulfur agent uses persulfate, and uses ferrous sulfate as catalyst.Additionally, Chinese patent
01118462.0 is directed to the sulfur in a kind of chemical oxidization method removing waste water and the method for ammonia, and specially
Profit 201110273016.6 is identical, and the quantity of slag produced due to chemical reaction is relatively big, these patents
All it is applicable to process the waste water that sulfur content is the highest.
Summary of the invention
For defect present in prior art, it is an object of the invention to provide a kind of oil gas field
The reinjection treatment method up to standard of wastewater with high concentration of sulfide, use negative pressure desulfurization+chemical catalytic oxidation+
Flocculating sedimentation+organic membrane filter technology, can effectively remove the sulfide in waste water, solves oil gas
The problem that in the wastewater with high concentration of sulfide re-injection process of field, sulfur content is too high, solves existing treatment technology equipment
Huge, complex process, inefficient, environmental suitability is poor, operating cost is high, be difficult to safeguard
Etc. shortcoming.
For reaching object above, the present invention adopts the technical scheme that:
A kind of reinjection treatment method up to standard of the wastewater with high concentration of sulfide of oil gas field, it is characterised in that: profit
Deposit with hydrogen sulfide form with the sulfide in oil gas field wastewater with high concentration of sulfide waste water in acid condition
Characteristic, first, use negative pressure desulfurization technology the most of hydrogen sulfide stripping in waste water is gone out
Carry out centralized burning；Secondly, use chemical catalytic oxidation technology by the remnants in negative pressure desulfurization water outlet
Oxidation of Hydrogen Sulfide；Afterwards, catalytic oxidation desulfurization water outlet carries out flocculating sedimentation；Finally, flocculation is heavy
Fall water outlet enters organic membrane filter unit and carries out organic membrane filter, and water outlet sulfur content, float contain
Amount and oil content meet oil gas field reinjected water standard.
On the basis of technique scheme, specifically include following steps:
Step 1, wastewater with high concentration of sulfide, after first time pH regulator, enters negative pressure desulfurization unit
Carry out desulfurization；The hydrogen sulfide produced after negative pressure desulfurization is collected and is carried out burning disposal；
Step 2, negative pressure desulfurization water outlet, after second time pH regulator, enters chemical catalysis oxygen
Change unit and carry out treating technology desulfurization；
Step 3, catalytic oxidation desulfurization water outlet, after third time pH regulator, enters flocculation heavy
Fall unit carries out flocculating sedimentation；Outward transport is concentrated to process after flocculating sedimentation slag class is cured；
Step 4, flocculating sedimentation water outlet enters organic membrane filter unit and carries out organic membrane filter, has
Machine film filtration effluent carries out reinjection technology.
On the basis of technique scheme, the main water quality of the wastewater with high concentration of sulfide of described oil gas field
It is characterized as: sulfide 2000～20000mg/L, total dissolved solid 10000～50000
Mg/L, float 500～5000mg/L, oil content 0～100mg/L.
Oil gas field height sulfur-bearing on the basis of technique scheme, after step 1～4 process
Waste water, and water outlet sulfur content < 0.5mg/L, oil content ＜ 5mg/L, float ＜ 1mg/L are full
Foot oil gas field reinjected water standard.
On the basis of technique scheme, described negative pressure desulfurization unit arranges circulating pump and gives up
Water circulates, and reflux ratio is 2～5:1.
On the basis of technique scheme, in step 1, the tune used by pH regulator for the first time
Joint agent is the one in hydrochloric acid, sulphuric acid or nitric acid；
Wastewater with high concentration of sulfide is after first time pH regulator, and pH scope is 4～6.
On the basis of technique scheme, in step 2, the tune used by pH regulator for the second time
Joint agent is the one in hydrochloric acid, sulphuric acid or nitric acid；
Negative pressure desulfurization water outlet is after second time pH regulator, and pH scope is 3～4.
On the basis of technique scheme, in step 3, the tune used by pH regulator for the third time
Joint agent is sodium hydroxide；
Catalytic oxidation desulfurization water outlet is after third time pH regulator, and pH scope is 8～9.
On the basis of technique scheme, in step 1, the waste water of negative pressure desulfurization unit stops
Time is 20～30min；
The inflow temperature of negative pressure desulfurization unit is 35～45 DEG C, runs negative pressure and is
-0.04～-0.07MPa.
On the basis of technique scheme, in step 2, described treating technology desulfurization is
Sulphion catalysis is oxidized to sulfate ion；
The oxidant of described chemical catalytic oxidation unit is hydrogen peroxide, and catalyst is ferrous sulfate；
Oxidizer is 100～300mg/L, and catalyst amount is 40～120mg/L.
On the basis of technique scheme, in step 3, the flocculation aid of flocculating sedimentation unit is
Anion-polyacrylamide, molecular weight 5,000,000～8,000,000；
The flocculation aid consumption of flocculating sedimentation unit is 2-5mg/L；
The flocculating sedimentation time is 10～20min.
On the basis of technique scheme, in step 4, the filtration shape of organic membrane filter unit
Formula is that Ge Er filters；
The membrane material of organic membrane filter unit is politef, membrane aperture 0.1～0.25 μm；
The membrane flux of organic membrane filter unit controls 300～500L/m2·h。
The reinjection treatment method up to standard of the wastewater with high concentration of sulfide of oil gas field of the present invention, uses negative
Pressure-off sulfur+chemical catalytic oxidation+flocculating sedimentation+organic membrane filter technology, can effectively remove waste water
In sulfide, solve the problem that sulfur content is too high in oil gas field wastewater with high concentration of sulfide re-injection process,
Solve that existing treatment technology equipment is huge, complex process, inefficient, environmental suitability is poor,
Operating cost is high, be difficult to the shortcomings such as maintenance.
Accompanying drawing explanation
The present invention has a drawings described below:
The process chart of Fig. 1 present invention.
Detailed description of the invention
Below in conjunction with accompanying drawing, the present invention is described in further detail.
The reinjection treatment method up to standard of the wastewater with high concentration of sulfide of oil gas field of the present invention, utilizes oil
Sulfide in gas field wastewater with high concentration of sulfide waste water in acid condition exists with hydrogen sulfide form
Characteristic, first, uses negative pressure desulfurization technology the most of hydrogen sulfide stripping in waste water out to be collected
Middle burning；Secondly, use chemical catalytic oxidation technology by the remaining sulfuration in negative pressure desulfurization water outlet
Hydroxide；Afterwards, catalytic oxidation desulfurization water outlet carries out flocculating sedimentation；Finally, flocculating sedimentation goes out
Water enters organic membrane filter unit and carries out organic membrane filter, finally realizes oil gas field wastewater with high concentration of sulfide
Middle sulfide, float and oil deep removal purpose, water outlet sulfur content, suspension content and
Oil content meets oil gas field reinjected water standard.Specifically include following steps:
Step 1, wastewater with high concentration of sulfide, after first time pH regulator, enters negative pressure desulfurization unit
Carry out desulfurization；The hydrogen sulfide produced after negative pressure desulfurization is collected and is carried out burning disposal；
Step 2, negative pressure desulfurization water outlet, after second time pH regulator, enters chemical catalysis oxygen
Change unit and carry out treating technology desulfurization；
Step 3, catalytic oxidation desulfurization water outlet, after third time pH regulator, enters flocculation heavy
Fall unit carries out flocculating sedimentation；Outward transport is concentrated to process after flocculating sedimentation slag class is cured；
Step 4, flocculating sedimentation water outlet enters organic membrane filter unit and carries out organic membrane filter, has
Machine film filtration effluent carries out reinjection technology.
On the basis of technique scheme, wastewater with high concentration of sulfide described in step 1 be (oil gas field
Wastewater with high concentration of sulfide) main water quality characteristic be: sulfide 2000～20000mg/L, always dissolve
Property solid 10000～50000mg/L, float 500～5000mg/L, oil content 0～100
mg/L。
Oil gas field height sulfur-bearing on the basis of technique scheme, after step 1～4 process
Waste water, and water outlet sulfur content < 0.5mg/L, oil content ＜ 5mg/L, float ＜ 1mg/L are full
Foot oil gas field reinjected water standard.
On the basis of technique scheme, described negative pressure desulfurization unit arranges circulating pump and gives up
Water circulates, and reflux ratio is 2～5:1.
On the basis of technique scheme, in step 1, the tune used by pH regulator for the first time
Joint agent is the one in hydrochloric acid, sulphuric acid or nitric acid；
Wastewater with high concentration of sulfide is after first time pH regulator, and pH scope is 4～6.
On the basis of technique scheme, in step 2, the tune used by pH regulator for the second time
Joint agent is the one in hydrochloric acid, sulphuric acid or nitric acid；
Negative pressure desulfurization water outlet is after second time pH regulator, and pH scope is 3～4.
On the basis of technique scheme, in step 3, the tune used by pH regulator for the third time
Joint agent is sodium hydroxide；
Catalytic oxidation desulfurization water outlet is after third time pH regulator, and pH scope is 8～9.
On the basis of technique scheme, in step 1, the waste water of negative pressure desulfurization unit stops
Time is 20～30min；
The inflow temperature of negative pressure desulfurization unit is 35～45 DEG C, runs negative pressure and is
-0.04～-0.07MPa.
On the basis of technique scheme, in step 2, described treating technology desulfurization is
Sulphion catalysis is oxidized to sulfate ion；
The oxidant of described chemical catalytic oxidation unit is hydrogen peroxide, and catalyst is ferrous sulfate；
Oxidizer is 100～300mg/L, and catalyst amount is 40～120mg/L.
On the basis of technique scheme, in step 3, the flocculation aid of flocculating sedimentation unit is
Anion-polyacrylamide, molecular weight 5,000,000～8,000,000；
The flocculation aid consumption of flocculating sedimentation unit is 2-5mg/L；
The flocculating sedimentation time is 10～20min.
On the basis of technique scheme, in step 4, the filtration shape of organic membrane filter unit
Formula is that Ge Er filters；
The membrane material of organic membrane filter unit is politef, membrane aperture 0.1～0.25 μm；
The membrane flux of organic membrane filter unit controls 300～500L/m2·h。
The present invention is with the essential distinction of prior art: for using stripping in prior art
, complex process, inefficient, ring huge with vaporizing extract process process oil gas field wastewater with high concentration of sulfide equipment
The problem that border bad adaptability, operating cost are high, the present invention uses negative pressure desulfurization+chemical catalysis oxygen
Change technical finesse oil gas field wastewater with high concentration of sulfide.By using this technology, it is achieved that oil gas field height contains
Efficient, quick, the low cost reinjection technology up to standard of sulfur waste water.Compared to the prior art, this
The bright technical equipment related to is simple, operation maintenance is easy, adaptive capacity to environment is strong, desulfuration efficiency
High, skid process can be realized, operating cost is substantially reduced, Technical Economy is good.For oil
Gas field wastewater with high concentration of sulfide, the reinjection technology technology up to standard that the present invention relates to is the most economical, reasonable,
Feasible.It provides the benefit that:
1, the present invention uses negative pressure desulfurization technical finesse oil gas field wastewater with high concentration of sulfide, and stripping,
Stripping Desulfuration technology is compared, and the technical equipment that the present invention relates to is simple, automaticity is high, fortune
Row is safeguarded easily, adaptive capacity to environment is strong, floor space is few, and desulfuration efficiency is high, can realize sled
Dressization process, operating cost are substantially reduced.The negative pressure desulfurization technology that the present invention uses is especially suitable
Wastewater with high concentration of sulfide in place and auxiliary facility imperfection area processes；
2, the negative pressure desulfurization unit of the present invention is by using circulating pump to carry out waste water circulation, accelerates
Hydrogen sulfide in wastewater with high concentration of sulfide overflows, and shortens waste water desulfurization time, improves desulfurized effect；
3, the negative pressure desulfurization unit of the present invention passes through the coupling between negative pressure and wastewater pH,
While reducing waste water desulphurization cost, the hydrogen sulfide eliminated in waste water of maximal efficiency；
4, in the present invention chemical catalytic oxidation unit owing to generating the colloid of iron salt, therefore without
Need to add flocculant, only need to add a small amount of flocculation aid achieves that flocculating sedimentation；
5, the present invention passes through negative pressure desulfurization technology and the efficient coupling of chemical catalytic oxidation technology,
On the basis of using negative pressure desulfurization technology to remove the most of sulphion in waste water, employing again
Learn the catalytic oxidation technologies degree of depth and remove a small amount of sulphion of residual in waste water so that the sulfur in waste water
Ion concentration is preferably minimized, and decreases the simple reagent consumption used needed for chemical oxidation and waste residue
Amount, operating cost is substantially reduced；
6, the present invention utilizes gore film to process the advantage of high suspended matter content waste water, by using
Ge Er organic membrane filter, solves the filtration problem of the high oil gas field waste water of suspension content, gram
Take organic membrane and process the limitation of oil gas field high suspended matter content waste water；
7, the present invention is by using gore film to process the oil gas field waste water of high suspended matter content, keeps away
Exempt to use the high flow rate operational mode of other form membrane filtrations, reduce operating cost, and
Membrane flux is high, and cycle of operation is long；
8, the method for the present invention is used to carry out the reinjection technology up to standard of oil gas field wastewater with high concentration of sulfide,
Effectively overcome existing stripping and the drawback of stripping process desulfurization, solve high suspended matter after desulfurization
The filtration problem of the oil gas field waste water of content.
It is below some specific embodiments.
Embodiment 1
The main water quality characteristic of oil gas field wastewater with high concentration of sulfide is: sulfide 2000mg/L, always
Soluble solid 10000mg/L, float 500mg/L, oil content 0mg/L.
Process step is as follows:
First, wastewater with high concentration of sulfide uses sulphuric acid to regulate for the first time the pH to 6 of waste water, laggard
Entering negative pressure desulfurization unit and carry out desulfurization, the operating condition of negative pressure desulfurization is: inflow temperature
35 DEG C, running negative pressure-0.04MPa, hydraulic detention time 20min, the reflux ratio of circulating pump is
5:1；
Secondly, negative pressure desulfurization water outlet uses sulphuric acid second time to regulate the pH to 3 of waste water, afterwards
Entering chemical catalytic oxidation unit and carry out treating technology desulfurization, oxidant is hydrogen peroxide,
Consumption is 100mg/L, and catalyst is ferrous sulfate, and consumption is 40mg/L；
Afterwards, catalytic oxidation desulfurization water outlet uses the pH of sodium hydroxide third time regulation waste water to arrive
8, enter flocculating sedimentation unit afterwards and carry out flocculating sedimentation, flocculation aid is anionic polypropylene
Amide, molecular weight 5,000,000, flocculation aid consumption is 2mg/L, and the flocculating sedimentation time is
10min；
Finally, flocculating sedimentation unit water outlet enters organic membrane filter unit and carries out Ge Er filtration,
Organic film material is politef, and membrane aperture is 0.1 μm, and gore film flux controls 500
L/m2·h.Under this constant flux, in the running of continuous 15 days, the operation of microfiltration
Pressure is risen to the 0.09MPa in later stage by initial 0.04MPa.
Oil gas field wastewater with high concentration of sulfide after above-mentioned steps processes, water outlet sulfur content < 0.5
Mg/L, oil content ＜ 5mg/L, float ＜ 1mg/L, meet oil gas field reinjected water standard.
The hydrogen sulfide produced after negative pressure desulfurization is collected and is carried out burning disposal, and organic membrane filter goes out
Water carries out reinjection technology, concentrates outward transport to process after flocculating sedimentation slag class is cured.
Embodiment 2
The main water quality characteristic of oil gas field wastewater with high concentration of sulfide is: sulfide 5000mg/L, always
Soluble solid 20000mg/L, float 1500mg/L, oil content 30mg/L.
Process step is as follows:
First, wastewater with high concentration of sulfide uses hydrochloric acid to regulate the pH to 4.5 of waste water for the first time, afterwards
Entering negative pressure desulfurization unit and carry out desulfurization, the operating condition of negative pressure desulfurization is: inflow temperature
40 DEG C, running negative pressure-0.05MPa, hydraulic detention time 25min, the reflux ratio of circulating pump is
4:1；
Secondly, negative pressure desulfurization water outlet uses hydrochloric acid second time to regulate the pH to 3.3 of waste water, it
Rear entrance chemical catalytic oxidation unit carries out treating technology desulfurization, and oxidant is dioxygen
Water, consumption is 100mg/L, and catalyst is ferrous sulfate, and consumption is 40mg/L；
Afterwards, catalytic oxidation desulfurization water outlet uses the pH of sodium hydroxide third time regulation waste water to arrive
8.3, enter flocculating sedimentation unit afterwards and carry out flocculating sedimentation, flocculation aid is anionic poly-third
Acrylamide, molecular weight 6,000,000, flocculation aid consumption is 2mg/L, and the flocculating sedimentation time is
10min；
Finally, flocculating sedimentation unit water outlet enters organic membrane filter unit and carries out Ge Er filtration,
Organic film material is politef, and membrane aperture is 0.15 μm, and gore film flux controls
450L/m2·h.Under this constant flux, in the running of continuous 15 days, microfiltration
Operation pressure is risen to the 0.11MPa in later stage by initial 0.04MPa.
Oil gas field wastewater with high concentration of sulfide after above-mentioned steps processes, water outlet sulfur content < 0.5
Mg/L, oil content ＜ 5mg/L, float ＜ 1mg/L, meet oil gas field reinjected water standard.
The hydrogen sulfide produced after negative pressure desulfurization is collected and is carried out burning disposal, and organic membrane filter goes out
Water carries out reinjection technology, concentrates outward transport to process after flocculating sedimentation slag class is cured.
Embodiment 3
The main water quality characteristic of oil gas field wastewater with high concentration of sulfide is: sulfide 10000mg/L, always
Soluble solid 30000mg/L, float 3000mg/L, oil content 50mg/L.
Process step is as follows:
First, wastewater with high concentration of sulfide uses nitric acid to regulate for the first time the pH to 5 of waste water, laggard
Entering negative pressure desulfurization unit and carry out desulfurization, the operating condition of negative pressure desulfurization is: inflow temperature
45 DEG C, running negative pressure-0.06MPa, hydraulic detention time 30min, the reflux ratio of circulating pump is
3:1；
Secondly, negative pressure desulfurization water outlet uses nitric acid second time to regulate the pH to 3.5 of waste water, it
Rear entrance chemical catalytic oxidation unit carries out treating technology desulfurization, and oxidant is dioxygen
Water, consumption is 200mg/L, and catalyst is ferrous sulfate, and consumption is 80mg/L；
Afterwards, catalytic oxidation desulfurization water outlet uses the pH of sodium hydroxide third time regulation waste water to arrive
8.5, enter flocculating sedimentation unit afterwards and carry out flocculating sedimentation, flocculation aid is anionic poly-third
Acrylamide, molecular weight 7,000,000, flocculation aid consumption is 3mg/L, and the flocculating sedimentation time is
20min；
Finally, flocculating sedimentation unit water outlet enters organic membrane filter unit and carries out Ge Er filtration,
Organic film material is politef, and membrane aperture is 0.2 μm, and gore film flux controls 400
L/m2·h.Under this constant flux, in the running of continuous 15 days, the operation of microfiltration
Pressure is risen to the 0.12MPa in later stage by initial 0.05MPa.
Oil gas field wastewater with high concentration of sulfide after above-mentioned steps processes, water outlet sulfur content < 0.5
Mg/L, oil content ＜ 5mg/L, float ＜ 1mg/L, meet oil gas field reinjected water standard.
The hydrogen sulfide produced after negative pressure desulfurization is collected and is carried out burning disposal, and organic membrane filter goes out
Water carries out reinjection technology, concentrates outward transport to process after flocculating sedimentation slag class is cured.
Embodiment 4
The main water quality characteristic of oil gas field wastewater with high concentration of sulfide is: sulfide 20000mg/L, always
Soluble solid 50000mg/L, float 5000mg/L, oil content 80mg/L.
Process step is as follows:
First, wastewater with high concentration of sulfide uses hydrochloric acid to regulate the pH to 5.5 of waste water for the first time, afterwards
Entering negative pressure desulfurization unit and carry out desulfurization, the operating condition of negative pressure desulfurization is: inflow temperature
45 DEG C, running negative pressure-0.07MPa, hydraulic detention time 30min, the reflux ratio of circulating pump is
2:1；
Secondly, negative pressure desulfurization water outlet uses hydrochloric acid second time to regulate the pH to 4 of waste water, afterwards
Entering chemical catalytic oxidation unit and carry out treating technology desulfurization, oxidant is hydrogen peroxide,
Consumption is 300mg/L, and catalyst is ferrous sulfate, and consumption is 120mg/L；
Afterwards, catalytic oxidation desulfurization water outlet uses the pH of sodium hydroxide third time regulation waste water to arrive
9, enter flocculating sedimentation unit afterwards and carry out flocculating sedimentation, flocculation aid is anionic polypropylene
Amide, molecular weight 8,000,000, flocculation aid consumption is 5mg/L, and the flocculating sedimentation time is
20min；
Finally, flocculating sedimentation unit water outlet enters organic membrane filter unit and carries out Ge Er filtration,
Organic film material is politef, and membrane aperture is 0.2 μm, and gore film flux controls 350
L/m2·h.Under this constant flux, in the running of continuous 15 days, the operation of microfiltration
Pressure is risen to the 0.12MPa in later stage by initial 0.04MPa.
Oil gas field wastewater with high concentration of sulfide after above-mentioned steps processes, water outlet sulfur content < 0.5
Mg/L, oil content ＜ 5mg/L, float ＜ 1mg/L, meet oil gas field reinjected water standard.
The hydrogen sulfide produced after negative pressure desulfurization is collected and is carried out burning disposal, and organic membrane filter goes out
Water carries out reinjection technology, concentrates outward transport to process after flocculating sedimentation slag class is cured.
Embodiment 5
The main water quality characteristic of oil gas field wastewater with high concentration of sulfide is: sulfide 20000mg/L, always
Soluble solid 50000mg/L, float 5000mg/L, oil content 100mg/L.
Process step is as follows:
First, wastewater with high concentration of sulfide uses hydrochloric acid to regulate for the first time the pH to 4 of waste water, laggard
Entering negative pressure desulfurization unit and carry out desulfurization, the operating condition of negative pressure desulfurization is: inflow temperature
45 DEG C, running negative pressure-0.07MPa, hydraulic detention time 30min, the reflux ratio of circulating pump is
3:1；
Secondly, negative pressure desulfurization water outlet uses hydrochloric acid second time to regulate the pH to 4 of waste water, afterwards
Entering chemical catalytic oxidation unit and carry out treating technology desulfurization, oxidant is hydrogen peroxide,
Consumption is 200mg/L, and catalyst is ferrous sulfate, and consumption is 80mg/L；
Afterwards, catalytic oxidation desulfurization water outlet uses the pH of sodium hydroxide third time regulation waste water to arrive
8.6, enter flocculating sedimentation unit afterwards and carry out flocculating sedimentation, flocculation aid is anionic poly-third
Acrylamide, molecular weight 8,000,000, flocculation aid consumption is 5mg/L, and the flocculating sedimentation time is
20min；
Finally, flocculating sedimentation unit water outlet enters organic membrane filter unit and carries out Ge Er filtration,
Organic film material is politef, and membrane aperture is 0.25 μm, and gore film flux controls
300L/m2·h.Under this constant flux, in the running of continuous 15 days, microfiltration
Operation pressure is risen to the 0.11MPa in later stage by initial 0.03MPa.
Oil gas field wastewater with high concentration of sulfide after above-mentioned steps processes, water outlet sulfur content < 0.5
Mg/L, oil content ＜ 5mg/L, float ＜ 1mg/L, meet oil gas field reinjected water standard.
The hydrogen sulfide produced after negative pressure desulfurization is collected and is carried out burning disposal, and organic membrane filter goes out
Water carries out reinjection technology, concentrates outward transport to process after flocculating sedimentation slag class is cured.
The foregoing is only the preferable possible embodiments of the present invention, not thereby limit to the present invention's
The scope of the claims, therefore the equivalence change that every utilization description of the invention and accompanying drawing content are made, all
It is contained in protection scope of the present invention.
The content not being described in detail in this specification belongs to known in professional and technical personnel in the field
Prior art.
Claims (12)
1. the reinjection treatment method up to standard of the wastewater with high concentration of sulfide of an oil gas field, it is characterised in that:
Utilize the sulfide in oil gas field wastewater with high concentration of sulfide waste water in acid condition with hydrogen sulfide form
The characteristic existed, first, uses negative pressure desulfurization technology by the most of hydrogen sulfide stripping in waste water
Out centralized burning；Secondly, residual by negative pressure desulfurization water outlet of chemical catalytic oxidation technology is used
Remaining Oxidation of Hydrogen Sulfide；Afterwards, catalytic oxidation desulfurization water outlet carries out flocculating sedimentation；Finally, flocculation
Sedimentation water outlet enters organic membrane filter unit and carries out organic membrane filter, water outlet sulfur content, float
Content and oil content meet oil gas field reinjected water standard.
2. the reinjection technology side up to standard of the wastewater with high concentration of sulfide of oil gas field as claimed in claim 1
Method, it is characterised in that specifically include following steps:
Step 1, wastewater with high concentration of sulfide, after first time pH regulator, enters negative pressure desulfurization unit
Carry out desulfurization；The hydrogen sulfide produced after negative pressure desulfurization is collected and is carried out burning disposal；
Step 2, negative pressure desulfurization water outlet, after second time pH regulator, enters chemical catalysis oxygen
Change unit and carry out treating technology desulfurization；
Step 3, catalytic oxidation desulfurization water outlet, after third time pH regulator, enters flocculation heavy
Fall unit carries out flocculating sedimentation；Outward transport is concentrated to process after flocculating sedimentation slag class is cured；
Step 4, flocculating sedimentation water outlet enters organic membrane filter unit and carries out organic membrane filter, has
Machine film filtration effluent carries out reinjection technology.
3. the reinjection technology side up to standard of the wastewater with high concentration of sulfide of oil gas field as claimed in claim 2
Method, it is characterised in that: the main water quality characteristic of the wastewater with high concentration of sulfide of described oil gas field is: sulfuration
Thing 2000～20000mg/L, total dissolved solid 10000～50000mg/L, float
500～5000mg/L, oil content 0～100mg/L.
4. the reinjection technology side up to standard of the wastewater with high concentration of sulfide of oil gas field as claimed in claim 2
Method, it is characterised in that: the oil gas field wastewater with high concentration of sulfide after step 1～4 process, water outlet sulfur
< 0.5mg/L, oil content ＜ 5mg/L, float ＜ 1mg/L meet oil gas field re-injection to content
Water quality standard.
5. the reinjection technology side up to standard of the wastewater with high concentration of sulfide of oil gas field as claimed in claim 2
Method, it is characterised in that: described negative pressure desulfurization unit arranges circulating pump and carries out waste water circulation, backflow
Ratio is 2～5:1.
6. the reinjection technology side up to standard of the wastewater with high concentration of sulfide of oil gas field as claimed in claim 2
Method, it is characterised in that: in step 1, for the first time the regulator used by pH regulator be hydrochloric acid,
One in sulphuric acid or nitric acid；
Wastewater with high concentration of sulfide is after first time pH regulator, and pH scope is 4～6.
7. the reinjection technology side up to standard of the wastewater with high concentration of sulfide of oil gas field as claimed in claim 2
Method, it is characterised in that: in step 2, for the second time the regulator used by pH regulator be hydrochloric acid,
One in sulphuric acid or nitric acid；
Negative pressure desulfurization water outlet is after second time pH regulator, and pH scope is 3～4.
8. the reinjection technology side up to standard of the wastewater with high concentration of sulfide of oil gas field as claimed in claim 2
Method, it is characterised in that: in step 3, the regulator used by pH regulator is hydroxide for the third time
Sodium；
Catalytic oxidation desulfurization water outlet is after third time pH regulator, and pH scope is 8～9.
9. the reinjection technology side up to standard of the wastewater with high concentration of sulfide of oil gas field as claimed in claim 2
Method, it is characterised in that: in step 1, the retention time of sewage of negative pressure desulfurization unit is
20～30min；
The inflow temperature of negative pressure desulfurization unit is 35～45 DEG C, runs negative pressure and is
-0.04～-0.07MPa.
10. the reinjection technology side up to standard of the wastewater with high concentration of sulfide of oil gas field as claimed in claim 2
Method, it is characterised in that: in step 2, described treating technology desulfurization is to be catalyzed by sulphion
It is oxidized to sulfate ion；
The oxidant of described chemical catalytic oxidation unit is hydrogen peroxide, and catalyst is ferrous sulfate；
Oxidizer is 100～300mg/L, and catalyst amount is 40～120mg/L.
The reinjection technology side up to standard of the wastewater with high concentration of sulfide of 11. oil gas fields as claimed in claim 2
Method, it is characterised in that: in step 3, the flocculation aid of flocculating sedimentation unit is anionic poly-third
Acrylamide, molecular weight 5,000,000～8,000,000；
The flocculation aid consumption of flocculating sedimentation unit is 2-5mg/L；
The flocculating sedimentation time is 10～20min.
The reinjection technology side up to standard of the wastewater with high concentration of sulfide of 12. oil gas fields as claimed in claim 2
Method, it is characterised in that: in step 4, the filtered version of organic membrane filter unit is that Ge Er filters；
The membrane material of organic membrane filter unit is politef, membrane aperture 0.1～0.25 μm；
The membrane flux of organic membrane filter unit controls 300～500L/m2·h。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510340481.5A CN106256780A (en) | 2015-06-18 | 2015-06-18 | A kind of reinjection treatment method up to standard of the wastewater with high concentration of sulfide of oil gas field |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510340481.5A CN106256780A (en) | 2015-06-18 | 2015-06-18 | A kind of reinjection treatment method up to standard of the wastewater with high concentration of sulfide of oil gas field |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106256780A true CN106256780A (en) | 2016-12-28 |
Family
ID=57713321
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510340481.5A Pending CN106256780A (en) | 2015-06-18 | 2015-06-18 | A kind of reinjection treatment method up to standard of the wastewater with high concentration of sulfide of oil gas field |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106256780A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109824165A (en) * | 2017-11-23 | 2019-05-31 | 上海江柘环境工程技术有限公司 | A kind of sulfur-containing waste water treatment process |
| CN112062340A (en) * | 2020-09-08 | 2020-12-11 | 江苏众志新禹环境科技有限公司 | Method for treating sulfur-containing wastewater |
| RU2741546C1 (en) * | 2020-03-13 | 2021-01-26 | Альфия Гариповна Ахмадуллина | Method of oxidising sodium sulphide |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010115233A1 (en) * | 2009-04-07 | 2010-10-14 | Dewatering Filtration Technology Services Pty Ltd | Process and system for producing potable water |
| CN102701487A (en) * | 2012-06-25 | 2012-10-03 | 杨德敏 | Method for treating sulfur-containing wastewater of oil and gas field |
| CN103880202A (en) * | 2012-12-12 | 2014-06-25 | 王炜 | Rejection processing technology for gas production wastewater in sulfur acid containing gas field |
| CN203807199U (en) * | 2014-01-26 | 2014-09-03 | 山东洁通环保设备有限公司 | Device for removing hydrogen sulfide by vacuum membrane method |
| CN203976507U (en) * | 2014-06-24 | 2014-12-03 | 杭州松源机械制造有限公司 | The water treatment system that reverse osmosis is degassed |
-
2015
- 2015-06-18 CN CN201510340481.5A patent/CN106256780A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010115233A1 (en) * | 2009-04-07 | 2010-10-14 | Dewatering Filtration Technology Services Pty Ltd | Process and system for producing potable water |
| CN102701487A (en) * | 2012-06-25 | 2012-10-03 | 杨德敏 | Method for treating sulfur-containing wastewater of oil and gas field |
| CN103880202A (en) * | 2012-12-12 | 2014-06-25 | 王炜 | Rejection processing technology for gas production wastewater in sulfur acid containing gas field |
| CN203807199U (en) * | 2014-01-26 | 2014-09-03 | 山东洁通环保设备有限公司 | Device for removing hydrogen sulfide by vacuum membrane method |
| CN203976507U (en) * | 2014-06-24 | 2014-12-03 | 杭州松源机械制造有限公司 | The water treatment system that reverse osmosis is degassed |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109824165A (en) * | 2017-11-23 | 2019-05-31 | 上海江柘环境工程技术有限公司 | A kind of sulfur-containing waste water treatment process |
| RU2741546C1 (en) * | 2020-03-13 | 2021-01-26 | Альфия Гариповна Ахмадуллина | Method of oxidising sodium sulphide |
| CN112062340A (en) * | 2020-09-08 | 2020-12-11 | 江苏众志新禹环境科技有限公司 | Method for treating sulfur-containing wastewater |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102295359B (en) | Treatment method for deep-well polysulfide slurry drilling waste water | |
| CN101898854B (en) | A method and device for treating wastewater produced from high-sulfur and low-permeability oil reservoirs | |
| CN107746160A (en) | It is a kind of to be used for the processing of low temperature distillation waste water and reuse method in coal | |
| CN113024032B (en) | A short-range nitrification and denitrification coupled with anammox-MBR-sulfur autotrophic denitrification and denitrification process and system | |
| CN104291528B (en) | Anammox/part denitrification process advanced treatment Super matrix waste water plant and method | |
| CN108101310B (en) | Device and method for treating desulfurization and denitrification wastewater of thermal power plant | |
| CN102344223A (en) | Treatment or recycling method and purpose for coal gasification and coal carbonization waste water | |
| CN203530059U (en) | Treatment system of waste drilling mud filtrate | |
| CN102690018A (en) | Method for treating and recycling coal tar processing wastewater | |
| CN106698733A (en) | Deep desulfurization method for high-sulfur-containing wastewater of oil and gas field | |
| CN102583895A (en) | High-ammonia-nitrogen wastewater treatment method | |
| CN102730897A (en) | Technology for treating and recovering sewage obtained by crushed coal pressure gasification | |
| CN103626353A (en) | Method for processing city household garbage leachate | |
| CN104276657B (en) | ANAMMOX-PD synchronous processing height nitrogen waste water and municipal effluent apparatus and method | |
| CN106256780A (en) | A kind of reinjection treatment method up to standard of the wastewater with high concentration of sulfide of oil gas field | |
| CN112441701B (en) | Shale gas flowback fluid efficient treatment, reuse and zero emission method and system | |
| CN110124488A (en) | One kind is administered for VOCs in biochemical treatment and tail gas recycles technique | |
| CN204174039U (en) | Sequence batch (absorption aerating filter | |
| CN107055940B (en) | Advanced treatment process of high ammonia nitrogen wastewater based on short-cut nitrification and denitrification | |
| CN103626323A (en) | Technology and special-purpose device for deep-treatment on pharmacy and papermaking waste water | |
| CN209456248U (en) | Electroless Plating Wastewater Treatment and Reuse System | |
| CN107285505A (en) | A kind of oil gas field wastewater with high concentration of sulfide reduces standard discharge method | |
| CN209178182U (en) | One kind can recombinate garbage leachate treatment device | |
| CN107285503A (en) | Oil gas field wastewater with high concentration of sulfide reduces standard discharge method | |
| CN106256778A (en) | A kind of process for deep desulphurization of oil gas field wastewater with high concentration of sulfide |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161228 |