CN106242520A - A kind of wear-resisting water proof building insulating brick - Google Patents

A kind of wear-resisting water proof building insulating brick Download PDF

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Publication number
CN106242520A
CN106242520A CN201610740501.2A CN201610740501A CN106242520A CN 106242520 A CN106242520 A CN 106242520A CN 201610740501 A CN201610740501 A CN 201610740501A CN 106242520 A CN106242520 A CN 106242520A
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parts
castor oil
modified castor
weight
wear
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CN201610740501.2A
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吴延成
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Bengbu Haotian Huai District New Building Materials Factory
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Bengbu Haotian Huai District New Building Materials Factory
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Priority to CN201610740501.2A priority Critical patent/CN106242520A/en
Publication of CN106242520A publication Critical patent/CN106242520A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/135Combustion residues, e.g. fly ash, incineration waste
    • C04B33/1352Fuel ashes, e.g. fly ash
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/1305Organic additives
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11CFATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/04Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3215Barium oxides or oxide-forming salts thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/44Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
    • C04B2235/448Sulphates or sulphites
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/48Organic compounds becoming part of a ceramic after heat treatment, e.g. carbonising phenol resins
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

Abstract

The invention discloses a kind of wear-resisting water proof building insulating brick, its raw material includes by weight: bentonite 20~40 parts, flyash 5~15 parts, aluminium oxide 2~8 parts, blanc fixe 2~6 parts, calcinated argil 2~8 parts, natural diabase 1~4 parts, phenolic resin 0.5~1.2 parts, polyalkyl acrylate 1~4 parts, carboxymethyl cellulose 2~5 parts, modified castor oil 1~5 parts.Wherein modified castor oil uses following technique to prepare: opal powder body, sodium polyacrylate, water are ground, and adds crystallization TiO2Continuing to grind, add water stirring, centrifugation, filter cake is washed with deionized, and dry, pulverize, and obtains prefabricated material;By weight Oleum Ricini is vacuum dried, removes vacuum, cooling, add di-2-ethylhexylphosphine oxide (4 phenyl isocyanate), prefabricated material under stirring, continue stirring, heat up, continue stirring, be stirred under vacuum state, be down to room temperature and obtain modified castor oil.

Description

A kind of wear-resisting water proof building insulating brick
Technical field
The present invention relates to insulating brick technical field, particularly relate to a kind of wear-resisting water proof building insulating brick.
Background technology
Insulation material generally refers to the heat conductivity material less than or equal to 0.2, and insulation material is adopted in industry and building Often can play a multiplier effect with material with good heat preservation technology.Insulation material has that density is little, pliability is high, The characteristic such as waterproof, can collect waste heat, random good, without cavity, negative blast can be avoided to tear and come off.Heat preserving and insulating material Being to affect one important influence factor of building energy conservation with goods, the development of building thermal insulation material and application are increasingly by the world The most attention of various countries.
Insulating brick, as a kind of building thermal insulation material, the novel product of alternative ceramic tile, is primarily adapted for use in toilet, kitchen Room, television background wall, bedroom, exterior wall etc., have multi-size, can arbitrarily cut, the feature such as tangent plane is neat.But existing guarantor The hardness of temperature brick is poor with toughness, and wear-resisting, water-fast, acid-proof alkaline does not reaches requirement.
Summary of the invention
The technical problem existed based on background technology, the present invention proposes a kind of wear-resisting water proof building insulating brick, toughness On the premise of Jun Heng with hardness, anti-wear performance is fabulous, waterproof, acid-proof alkaline is excellent.
The one wear-resisting water proof building insulating brick that the present invention proposes, its raw material includes by weight: bentonite 20~40 Part, flyash 5~15 parts, aluminium oxide 2~8 parts, blanc fixe 2~6 parts, calcinated argil 2~8 parts, natural diabase 1~4 parts, Phenolic resin 0.5~1.2 parts, polyalkyl acrylate 1~4 parts, carboxymethyl cellulose 2~5 parts, modified castor oil 1~5 parts.
Preferably, modified castor oil uses following technique to prepare: opal powder body, sodium polyacrylate, water is ground, adds Crystallization TiO2Continuing to grind, add water stirring, centrifugation, filter cake is washed with deionized, and dry, pulverize, and obtains prefabricated material; By weight Oleum Ricini is vacuum dried, removes vacuum, cooling, under stirring, add di-2-ethylhexylphosphine oxide (4-phenyl Carbimide. Ester), prefabricated material, continue stirring, heat up, continue stirring, be stirred under vacuum state, be down to room temperature and obtain modified castor oil.
Preferably, modified castor oil use following technique prepare: by weight by 2~6 parts of opal powder body, 0.1~0.2 Part sodium polyacrylate, 30~40 parts of water grind, and add 10~20 parts of crystallization TiO2Continue to grind, add 40~80 parts of water stirrings, Centrifugation, filter cake is washed with deionized, and dry, pulverize, and obtains prefabricated material;By weight by 8~12 parts of Oleum Ricini vacuum Be dried, remove vacuum, cooling, add under stirring 4~9 parts of di-2-ethylhexylphosphine oxides (4-phenyl isocyanate), 2~10 parts prefabricated Material, continues stirring, heats up, and continues stirring, is stirred for, is down to room temperature and obtains modified castor oil under vacuum state.
Preferably, modified castor oil use following technique prepare: by weight by 2~6 parts of opal powder body, 0.1~0.2 Part sodium polyacrylate, 30~40 parts of water grind, and add 10~20 parts of crystallization TiO2Continuing to be ground to particle diameter is 15~35 μm, adds 40~80 parts of water stirrings 30~50min, centrifugation, filter cake is washed with deionized, and dry, pulverize, and obtains prefabricated material;By weight Amount part is by 8~12 parts of Oleum Ricini vacuum drying 10~30min, and baking temperature is 110~120 DEG C, removes vacuum, be cooled to 60~ 70 DEG C, under stirring add 4~9 parts of di-2-ethylhexylphosphine oxides (4-phenyl isocyanate), 2~10 parts of prefabricated material, continue stirring 20~ 40min, is warming up to 90~98 DEG C, continues stirring 10~20min, is stirred for 20~40min, is down to room temperature and obtains under vacuum state Modified castor oil.
Preferably, phenolic resin, polyalkyl acrylate, carboxymethyl cellulose, the weight ratio of modified castor oil be 0.6~ 1:2~3:3~4:2~4.
Preferably, bentonite, flyash, aluminium oxide, blanc fixe, calcinated argil, natural diabase, modified castor oil Weight ratio is 25~35:8~12:4~6:3~5:4~6:2~3:2~4.
Preferably, its raw material includes by weight: bentonite 25~35 parts, flyash 8~12 parts, aluminium oxide 4~6 parts, Blanc fixe 3~5 parts, calcinated argil 4~6 parts, natural diabase 2~3 parts, phenolic resin 0.6~1 part, poly-alkyl acrylic Ester 2~3 parts, carboxymethyl cellulose 3~4 parts, modified castor oil 2~4 parts.
Preparation technology of the present invention is as follows: by above-mentioned raw materials mix homogeneously, is warming up to 50~80 DEG C, stands 2.5~5h, filter pressing Obtaining adobe, proceed to store stove sintering and obtain wear-resisting water proof building insulating brick, sintering temperature is 750~800 DEG C.
In the present invention, modified castor oil is covalently cross-linked in phenolic resin with urethane, makes the toughness of the present invention with hydrophobic Property fabulous, and modified castor oil formed elastic microsphere be dispersed in bentonite, flyash, aluminium oxide, blanc fixe, calcining pottery In native and natural diabase, reciprocal compatibility is fabulous;In the prefabricated material of modified castor oil of the present invention, opal powder surface is formed Great amount of hydroxy group and all kinds of defects and crystallization TiO2The association reaction degree of the functional group that surface is formed is fabulous, wear-resisting, acid and alkali-resistance Performance is good, simultaneously with polyalkyl acrylate, the good dispersion of carboxymethyl cellulose;Modified castor oil reacts with rest materials, Can be on the premise of ensureing that toughness of the present invention is Jun Heng with hardness, anti-wear performance is fabulous, waterproof, acid-proof alkaline is excellent.
Detailed description of the invention
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
The one wear-resisting water proof building insulating brick that the present invention proposes, its raw material includes by weight: bentonite 20 parts, powder Coal ash 15 parts, aluminium oxide 2 parts, blanc fixe 6 parts, calcinated argil 2 parts, natural diabase 4 parts, 0.5 part of phenolic resin, poly-alkyl Acrylate 4 parts, carboxymethyl cellulose 2 parts, modified castor oil 5 parts.
Embodiment 2
The one wear-resisting water proof building insulating brick that the present invention proposes, its raw material includes by weight: bentonite 40 parts, powder Coal ash 5 parts, aluminium oxide 8 parts, blanc fixe 2 parts, calcinated argil 8 parts, natural diabase 1 part, 1.2 parts of phenolic resin, poly-alkyl Acrylate 1 part, carboxymethyl cellulose 5 parts, modified castor oil 1 part.
Modified castor oil uses following technique to prepare: opal powder body, sodium polyacrylate, water is ground, adds crystallization TiO2Continuing to grind, add water stirring, centrifugation, filter cake is washed with deionized, and dry, pulverize, and obtains prefabricated material;By weight Oleum Ricini is vacuum dried by amount part, removes vacuum, cooling, adds di-2-ethylhexylphosphine oxide (4-phenyl isocyanate), pre-under stirring System material, continues stirring, heats up, and continues stirring, is stirred for, is down to room temperature and obtains modified castor oil under vacuum state.
Embodiment 3
The one wear-resisting water proof building insulating brick that the present invention proposes, its raw material includes by weight: bentonite 25 parts, powder Coal ash 12 parts, aluminium oxide 4 parts, blanc fixe 5 parts, calcinated argil 4 parts, natural diabase 3 parts, 0.6 part of phenolic resin, poly-alkyl Acrylate 3 parts, carboxymethyl cellulose 3 parts, modified castor oil 4 parts.
Modified castor oil uses following technique to prepare: by weight by 2 parts of opal powder body, 0.2 part of sodium polyacrylate, 30 Part water grinds, and adds 20 parts of crystallization TiO2Continuing to be ground to particle diameter is 15 μm, adds 80 parts of water stirring 30min, centrifugation, filter Cake is washed with deionized, and dry, pulverize, and obtains prefabricated material;By weight by 12 parts of Oleum Ricini vacuum drying 10min, it is dried Temperature is 120 DEG C, removes vacuum, is cooled to 60 DEG C, add under stirring 9 parts of di-2-ethylhexylphosphine oxides (4-phenyl isocyanate), 2 parts Prefabricated material, continues stirring 40min, is warming up to 90 DEG C, continues stirring 20min, is stirred for 20min, is down to room temperature under vacuum state Obtain modified castor oil.
Embodiment 4
The one wear-resisting water proof building insulating brick that the present invention proposes, its raw material includes by weight: bentonite 35 parts, powder Coal ash 8 parts, aluminium oxide 6 parts, blanc fixe 3 parts, calcinated argil 6 parts, natural diabase 2 parts, 1 part of phenolic resin, poly-alkyl third Olefin(e) acid ester 2 parts, carboxymethyl cellulose 4 parts, modified castor oil 2 parts.
Modified castor oil uses following technique to prepare: by weight by 6 parts of opal powder body, 0.1 part of sodium polyacrylate, 40 Part water grinds, and adds 10 parts of crystallization TiO2Continuing to be ground to particle diameter is 35 μm, adds 40 parts of water stirring 50min, centrifugation, filter Cake is washed with deionized, and dry, pulverize, and obtains prefabricated material;By weight by 8 parts of Oleum Ricini vacuum drying 30min, it is dried temperature Degree is 110 DEG C, removes vacuum, is cooled to 70 DEG C, add under stirring 4 parts of di-2-ethylhexylphosphine oxides (4-phenyl isocyanate), 10 parts Prefabricated material, continues stirring 20min, is warming up to 98 DEG C, continues stirring 10min, is stirred for 40min, is down to room temperature under vacuum state Obtain modified castor oil.
Embodiment 5
The one wear-resisting water proof building insulating brick that the present invention proposes, its raw material includes by weight: bentonite 30 parts, powder Coal ash 10 parts, aluminium oxide 5 parts, blanc fixe 4 parts, calcinated argil 5 parts, natural diabase 2.3 parts, 0.8 part of phenolic resin, poly-alkane Base acrylate 2.7 parts, carboxymethyl cellulose 3.4 parts, modified castor oil 3 parts.
Modified castor oil uses following technique to prepare: by weight by 4 parts of opal powder body, 0.15 part of sodium polyacrylate, 35 parts of water grind, and add 15 parts of crystallization TiO2Continuing to grind, add 60 parts of water stirrings, centrifugation, filter cake is washed with deionized water Wash, dry, pulverize, obtain prefabricated material;By weight by 10 parts of Oleum Ricini vacuum drying, removing vacuum, cooling, under stirring Add 6 parts of di-2-ethylhexylphosphine oxides (4-phenyl isocyanate), 6 parts of prefabricated material, continue stirring, heat up, continue stirring, under vacuum state again Stirring, is down to room temperature and obtains modified castor oil.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto, Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.

Claims (7)

1. a wear-resisting water proof building insulating brick, it is characterised in that its raw material includes by weight: bentonite 20~40 parts, Flyash 5~15 parts, aluminium oxide 2~8 parts, blanc fixe 2~6 parts, calcinated argil 2~8 parts, natural diabase 1~4 parts, phenol Urea formaldehyde 0.5~1.2 parts, polyalkyl acrylate 1~4 parts, carboxymethyl cellulose 2~5 parts, modified castor oil 1~5 parts.
The most wear-resisting water proof building insulating brick, it is characterised in that modified castor oil uses following technique Preparation: opal powder body, sodium polyacrylate, water are ground, adds crystallization TiO2Continue to grind, add water and stir, centrifugation, Filter cake is washed with deionized, and dry, pulverize, and obtains prefabricated material;By weight Oleum Ricini is vacuum dried, removes vacuum, cold But, add di-2-ethylhexylphosphine oxide (4-phenyl isocyanate), prefabricated material under stirring, continue stirring, heat up, continue stirring, vacuum It is stirred under state, is down to room temperature and obtains modified castor oil.
Wear-resisting water proof building insulating brick the most according to claim 1 or claim 2, it is characterised in that modified castor oil uses as follows Prepared by technique: 2~6 parts of opal powder body, 0.1~0.2 part of sodium polyacrylate, 30~40 parts of water are ground by weight, add 10~20 parts of crystallization TiO2Continuing to grind, add 40~80 parts of water stirrings, centrifugation, filter cake is washed with deionized, and is dried, Pulverize, obtain prefabricated material;By weight by 8~12 parts of Oleum Ricini vacuum drying, remove vacuum, cooling, under stirring, add 4 ~9 parts of di-2-ethylhexylphosphine oxides (4-phenyl isocyanate), 2~10 parts of prefabricated material, continue stirring, heat up, continue stirring, under vacuum state It is stirred for, is down to room temperature and obtains modified castor oil.
4. according to water proof building insulating brick wear-resisting described in any one of claim 1-3, it is characterised in that modified castor oil uses Prepared by following technique: 2~6 parts of opal powder body, 0.1~0.2 part of sodium polyacrylate, 30~40 parts of water are ground by weight, Add 10~20 parts of crystallization TiO2Continuing to be ground to particle diameter is 15~35 μm, adds 40~80 parts of water stirrings 30~50min, centrifugal Separating, filter cake is washed with deionized, and dry, pulverize, and obtains prefabricated material;By weight by 8~12 parts of Oleum Ricini vacuum drying 10~30min, baking temperature is 110~120 DEG C, removes vacuum, is cooled to 60~70 DEG C, adds 4~9 parts of Asias under stirring Methyl double (4-phenyl isocyanate), 2~10 parts of prefabricated material, continue stirring 20~40min, be warming up to 90~98 DEG C, continue to stir Mix and under 10~20min, vacuum state, be stirred for 20~40min, be down to room temperature and obtain modified castor oil.
5. according to water proof building insulating brick wear-resisting described in any one of claim 1-4, it is characterised in that phenolic resin, poly-alkane Base acrylate, carboxymethyl cellulose, the weight ratio of modified castor oil are 0.6~1:2~3:3~4:2~4.
6. according to water proof building insulating brick wear-resisting described in any one of claim 1-4, it is characterised in that bentonite, flyash, Aluminium oxide, blanc fixe, calcinated argil, natural diabase, the weight ratio of modified castor oil be 25~35:8~12:4~6:3~ 5:4~6:2~3:2~4.
7. according to water proof building insulating brick wear-resisting described in any one of claim 1-4, it is characterised in that its raw material is by weight Including: bentonite 25~35 parts, flyash 8~12 parts, aluminium oxide 4~6 parts, blanc fixe 3~5 parts, calcinated argil 4~6 parts, Natural diabase 2~3 parts, phenolic resin 0.6~1 part, polyalkyl acrylate 2~3 parts, carboxymethyl cellulose 3~4 parts, change Property Oleum Ricini 2~4 parts.
CN201610740501.2A 2016-08-26 2016-08-26 A kind of wear-resisting water proof building insulating brick Withdrawn CN106242520A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106336213A (en) * 2016-08-29 2017-01-18 天长市中德电子有限公司 MnZn soft magnetic ferrite material with high magnetic conductivity

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101100531A (en) * 2007-07-10 2008-01-09 伍强贤 Hydrophilic natural macromolecule modified by polyurethane micro-sphere and preparation method thereof
CN102993785A (en) * 2012-11-13 2013-03-27 王丕轩 Preparation method for TiO2/opal composite powder material
CN105731976A (en) * 2016-01-20 2016-07-06 广西丛欣实业有限公司 Insulating brick and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101100531A (en) * 2007-07-10 2008-01-09 伍强贤 Hydrophilic natural macromolecule modified by polyurethane micro-sphere and preparation method thereof
CN102993785A (en) * 2012-11-13 2013-03-27 王丕轩 Preparation method for TiO2/opal composite powder material
CN105731976A (en) * 2016-01-20 2016-07-06 广西丛欣实业有限公司 Insulating brick and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106336213A (en) * 2016-08-29 2017-01-18 天长市中德电子有限公司 MnZn soft magnetic ferrite material with high magnetic conductivity

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