CN106242520A - A kind of wear-resisting water proof building insulating brick - Google Patents
A kind of wear-resisting water proof building insulating brick Download PDFInfo
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- CN106242520A CN106242520A CN201610740501.2A CN201610740501A CN106242520A CN 106242520 A CN106242520 A CN 106242520A CN 201610740501 A CN201610740501 A CN 201610740501A CN 106242520 A CN106242520 A CN 106242520A
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- castor oil
- modified castor
- weight
- wear
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 239000011449 brick Substances 0.000 title claims abstract description 22
- 238000003756 stirring Methods 0.000 claims abstract description 40
- PNEYBMLMFCGWSK-UHFFFAOYSA-N al2o3 Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000004359 castor oil Substances 0.000 claims abstract description 39
- 235000019438 castor oil Nutrition 0.000 claims abstract description 39
- 239000000463 material Substances 0.000 claims abstract description 31
- 239000000843 powder Substances 0.000 claims abstract description 17
- TZCXTZWJZNENPQ-UHFFFAOYSA-L Barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 13
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract description 13
- HWKQNAWCHQMZHK-UHFFFAOYSA-N Trolnitrate Chemical compound [O-][N+](=O)OCCN(CCO[N+]([O-])=O)CCO[N+]([O-])=O HWKQNAWCHQMZHK-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910001884 aluminium oxide Inorganic materials 0.000 claims abstract description 13
- 239000000440 bentonite Substances 0.000 claims abstract description 13
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 13
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 13
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims abstract description 13
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims abstract description 13
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000002425 crystallisation Methods 0.000 claims abstract description 12
- 230000005712 crystallization Effects 0.000 claims abstract description 12
- 239000011022 opal Substances 0.000 claims abstract description 12
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 12
- 239000005011 phenolic resin Substances 0.000 claims abstract description 12
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M Sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims abstract description 11
- 239000012065 filter cake Substances 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 11
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 238000005119 centrifugation Methods 0.000 claims abstract description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 8
- 239000010881 fly ash Substances 0.000 claims abstract description 8
- 238000001816 cooling Methods 0.000 claims abstract description 6
- 238000001291 vacuum drying Methods 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 4
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 241001614291 Anoplistes Species 0.000 claims 1
- LCDFWRDNEPDQBV-UHFFFAOYSA-N formaldehyde;phenol;urea Chemical compound O=C.NC(N)=O.OC1=CC=CC=C1 LCDFWRDNEPDQBV-UHFFFAOYSA-N 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- DGTNSSLYPYDJGL-UHFFFAOYSA-N Phenylisocyanate Chemical compound O=C=NC1=CC=CC=C1 DGTNSSLYPYDJGL-UHFFFAOYSA-N 0.000 abstract 1
- 239000010883 coal ash Substances 0.000 description 5
- 238000009413 insulation Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 125000005250 alkyl acrylate group Chemical group 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 210000001138 Tears Anatomy 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000002209 hydrophobic Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- -1 poly-alkyl acrylic Ester Chemical class 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/135—Combustion residues, e.g. fly ash, incineration waste
- C04B33/1352—Fuel ashes, e.g. fly ash
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/1305—Organic additives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/04—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3215—Barium oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/448—Sulphates or sulphites
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/48—Organic compounds becoming part of a ceramic after heat treatment, e.g. carbonising phenol resins
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Abstract
The invention discloses a kind of wear-resisting water proof building insulating brick, its raw material includes by weight: bentonite 20～40 parts, flyash 5～15 parts, aluminium oxide 2～8 parts, blanc fixe 2～6 parts, calcinated argil 2～8 parts, natural diabase 1～4 parts, phenolic resin 0.5～1.2 parts, polyalkyl acrylate 1～4 parts, carboxymethyl cellulose 2～5 parts, modified castor oil 1～5 parts.Wherein modified castor oil uses following technique to prepare: opal powder body, sodium polyacrylate, water are ground, and adds crystallization TiO2Continuing to grind, add water stirring, centrifugation, filter cake is washed with deionized, and dry, pulverize, and obtains prefabricated material；By weight Oleum Ricini is vacuum dried, removes vacuum, cooling, add di-2-ethylhexylphosphine oxide (4 phenyl isocyanate), prefabricated material under stirring, continue stirring, heat up, continue stirring, be stirred under vacuum state, be down to room temperature and obtain modified castor oil.
Description
Technical field
The present invention relates to insulating brick technical field, particularly relate to a kind of wear-resisting water proof building insulating brick.
Background technology
Insulation material generally refers to the heat conductivity material less than or equal to 0.2, and insulation material is adopted in industry and building
Often can play a multiplier effect with material with good heat preservation technology.Insulation material has that density is little, pliability is high,
The characteristic such as waterproof, can collect waste heat, random good, without cavity, negative blast can be avoided to tear and come off.Heat preserving and insulating material
Being to affect one important influence factor of building energy conservation with goods, the development of building thermal insulation material and application are increasingly by the world
The most attention of various countries.
Insulating brick, as a kind of building thermal insulation material, the novel product of alternative ceramic tile, is primarily adapted for use in toilet, kitchen
Room, television background wall, bedroom, exterior wall etc., have multi-size, can arbitrarily cut, the feature such as tangent plane is neat.But existing guarantor
The hardness of temperature brick is poor with toughness, and wear-resisting, water-fast, acid-proof alkaline does not reaches requirement.
Summary of the invention
The technical problem existed based on background technology, the present invention proposes a kind of wear-resisting water proof building insulating brick, toughness
On the premise of Jun Heng with hardness, anti-wear performance is fabulous, waterproof, acid-proof alkaline is excellent.
The one wear-resisting water proof building insulating brick that the present invention proposes, its raw material includes by weight: bentonite 20～40
Part, flyash 5～15 parts, aluminium oxide 2～8 parts, blanc fixe 2～6 parts, calcinated argil 2～8 parts, natural diabase 1～4 parts,
Phenolic resin 0.5～1.2 parts, polyalkyl acrylate 1～4 parts, carboxymethyl cellulose 2～5 parts, modified castor oil 1～5 parts.
Preferably, modified castor oil uses following technique to prepare: opal powder body, sodium polyacrylate, water is ground, adds
Crystallization TiO2Continuing to grind, add water stirring, centrifugation, filter cake is washed with deionized, and dry, pulverize, and obtains prefabricated material；
By weight Oleum Ricini is vacuum dried, removes vacuum, cooling, under stirring, add di-2-ethylhexylphosphine oxide (4-phenyl Carbimide.
Ester), prefabricated material, continue stirring, heat up, continue stirring, be stirred under vacuum state, be down to room temperature and obtain modified castor oil.
Preferably, modified castor oil use following technique prepare: by weight by 2～6 parts of opal powder body, 0.1～0.2
Part sodium polyacrylate, 30～40 parts of water grind, and add 10～20 parts of crystallization TiO2Continue to grind, add 40～80 parts of water stirrings,
Centrifugation, filter cake is washed with deionized, and dry, pulverize, and obtains prefabricated material；By weight by 8～12 parts of Oleum Ricini vacuum
Be dried, remove vacuum, cooling, add under stirring 4～9 parts of di-2-ethylhexylphosphine oxides (4-phenyl isocyanate), 2～10 parts prefabricated
Material, continues stirring, heats up, and continues stirring, is stirred for, is down to room temperature and obtains modified castor oil under vacuum state.
Preferably, modified castor oil use following technique prepare: by weight by 2～6 parts of opal powder body, 0.1～0.2
Part sodium polyacrylate, 30～40 parts of water grind, and add 10～20 parts of crystallization TiO2Continuing to be ground to particle diameter is 15～35 μm, adds
40～80 parts of water stirrings 30～50min, centrifugation, filter cake is washed with deionized, and dry, pulverize, and obtains prefabricated material；By weight
Amount part is by 8～12 parts of Oleum Ricini vacuum drying 10～30min, and baking temperature is 110～120 DEG C, removes vacuum, be cooled to 60～
70 DEG C, under stirring add 4～9 parts of di-2-ethylhexylphosphine oxides (4-phenyl isocyanate), 2～10 parts of prefabricated material, continue stirring 20～
40min, is warming up to 90～98 DEG C, continues stirring 10～20min, is stirred for 20～40min, is down to room temperature and obtains under vacuum state
Modified castor oil.
Preferably, phenolic resin, polyalkyl acrylate, carboxymethyl cellulose, the weight ratio of modified castor oil be 0.6～
1:2～3:3～4:2～4.
Preferably, bentonite, flyash, aluminium oxide, blanc fixe, calcinated argil, natural diabase, modified castor oil
Weight ratio is 25～35:8～12:4～6:3～5:4～6:2～3:2～4.
Preferably, its raw material includes by weight: bentonite 25～35 parts, flyash 8～12 parts, aluminium oxide 4～6 parts,
Blanc fixe 3～5 parts, calcinated argil 4～6 parts, natural diabase 2～3 parts, phenolic resin 0.6～1 part, poly-alkyl acrylic
Ester 2～3 parts, carboxymethyl cellulose 3～4 parts, modified castor oil 2～4 parts.
Preparation technology of the present invention is as follows: by above-mentioned raw materials mix homogeneously, is warming up to 50～80 DEG C, stands 2.5～5h, filter pressing
Obtaining adobe, proceed to store stove sintering and obtain wear-resisting water proof building insulating brick, sintering temperature is 750～800 DEG C.
In the present invention, modified castor oil is covalently cross-linked in phenolic resin with urethane, makes the toughness of the present invention with hydrophobic
Property fabulous, and modified castor oil formed elastic microsphere be dispersed in bentonite, flyash, aluminium oxide, blanc fixe, calcining pottery
In native and natural diabase, reciprocal compatibility is fabulous；In the prefabricated material of modified castor oil of the present invention, opal powder surface is formed
Great amount of hydroxy group and all kinds of defects and crystallization TiO2The association reaction degree of the functional group that surface is formed is fabulous, wear-resisting, acid and alkali-resistance
Performance is good, simultaneously with polyalkyl acrylate, the good dispersion of carboxymethyl cellulose；Modified castor oil reacts with rest materials,
Can be on the premise of ensureing that toughness of the present invention is Jun Heng with hardness, anti-wear performance is fabulous, waterproof, acid-proof alkaline is excellent.
Detailed description of the invention
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
The one wear-resisting water proof building insulating brick that the present invention proposes, its raw material includes by weight: bentonite 20 parts, powder
Coal ash 15 parts, aluminium oxide 2 parts, blanc fixe 6 parts, calcinated argil 2 parts, natural diabase 4 parts, 0.5 part of phenolic resin, poly-alkyl
Acrylate 4 parts, carboxymethyl cellulose 2 parts, modified castor oil 5 parts.
Embodiment 2
The one wear-resisting water proof building insulating brick that the present invention proposes, its raw material includes by weight: bentonite 40 parts, powder
Coal ash 5 parts, aluminium oxide 8 parts, blanc fixe 2 parts, calcinated argil 8 parts, natural diabase 1 part, 1.2 parts of phenolic resin, poly-alkyl
Acrylate 1 part, carboxymethyl cellulose 5 parts, modified castor oil 1 part.
Modified castor oil uses following technique to prepare: opal powder body, sodium polyacrylate, water is ground, adds crystallization
TiO2Continuing to grind, add water stirring, centrifugation, filter cake is washed with deionized, and dry, pulverize, and obtains prefabricated material；By weight
Oleum Ricini is vacuum dried by amount part, removes vacuum, cooling, adds di-2-ethylhexylphosphine oxide (4-phenyl isocyanate), pre-under stirring
System material, continues stirring, heats up, and continues stirring, is stirred for, is down to room temperature and obtains modified castor oil under vacuum state.
Embodiment 3
The one wear-resisting water proof building insulating brick that the present invention proposes, its raw material includes by weight: bentonite 25 parts, powder
Coal ash 12 parts, aluminium oxide 4 parts, blanc fixe 5 parts, calcinated argil 4 parts, natural diabase 3 parts, 0.6 part of phenolic resin, poly-alkyl
Acrylate 3 parts, carboxymethyl cellulose 3 parts, modified castor oil 4 parts.
Modified castor oil uses following technique to prepare: by weight by 2 parts of opal powder body, 0.2 part of sodium polyacrylate, 30
Part water grinds, and adds 20 parts of crystallization TiO2Continuing to be ground to particle diameter is 15 μm, adds 80 parts of water stirring 30min, centrifugation, filter
Cake is washed with deionized, and dry, pulverize, and obtains prefabricated material；By weight by 12 parts of Oleum Ricini vacuum drying 10min, it is dried
Temperature is 120 DEG C, removes vacuum, is cooled to 60 DEG C, add under stirring 9 parts of di-2-ethylhexylphosphine oxides (4-phenyl isocyanate), 2 parts
Prefabricated material, continues stirring 40min, is warming up to 90 DEG C, continues stirring 20min, is stirred for 20min, is down to room temperature under vacuum state
Obtain modified castor oil.
Embodiment 4
The one wear-resisting water proof building insulating brick that the present invention proposes, its raw material includes by weight: bentonite 35 parts, powder
Coal ash 8 parts, aluminium oxide 6 parts, blanc fixe 3 parts, calcinated argil 6 parts, natural diabase 2 parts, 1 part of phenolic resin, poly-alkyl third
Olefin(e) acid ester 2 parts, carboxymethyl cellulose 4 parts, modified castor oil 2 parts.
Modified castor oil uses following technique to prepare: by weight by 6 parts of opal powder body, 0.1 part of sodium polyacrylate, 40
Part water grinds, and adds 10 parts of crystallization TiO2Continuing to be ground to particle diameter is 35 μm, adds 40 parts of water stirring 50min, centrifugation, filter
Cake is washed with deionized, and dry, pulverize, and obtains prefabricated material；By weight by 8 parts of Oleum Ricini vacuum drying 30min, it is dried temperature
Degree is 110 DEG C, removes vacuum, is cooled to 70 DEG C, add under stirring 4 parts of di-2-ethylhexylphosphine oxides (4-phenyl isocyanate), 10 parts
Prefabricated material, continues stirring 20min, is warming up to 98 DEG C, continues stirring 10min, is stirred for 40min, is down to room temperature under vacuum state
Obtain modified castor oil.
Embodiment 5
The one wear-resisting water proof building insulating brick that the present invention proposes, its raw material includes by weight: bentonite 30 parts, powder
Coal ash 10 parts, aluminium oxide 5 parts, blanc fixe 4 parts, calcinated argil 5 parts, natural diabase 2.3 parts, 0.8 part of phenolic resin, poly-alkane
Base acrylate 2.7 parts, carboxymethyl cellulose 3.4 parts, modified castor oil 3 parts.
Modified castor oil uses following technique to prepare: by weight by 4 parts of opal powder body, 0.15 part of sodium polyacrylate,
35 parts of water grind, and add 15 parts of crystallization TiO2Continuing to grind, add 60 parts of water stirrings, centrifugation, filter cake is washed with deionized water
Wash, dry, pulverize, obtain prefabricated material；By weight by 10 parts of Oleum Ricini vacuum drying, removing vacuum, cooling, under stirring
Add 6 parts of di-2-ethylhexylphosphine oxides (4-phenyl isocyanate), 6 parts of prefabricated material, continue stirring, heat up, continue stirring, under vacuum state again
Stirring, is down to room temperature and obtains modified castor oil.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.
Claims (7)
1. a wear-resisting water proof building insulating brick, it is characterised in that its raw material includes by weight: bentonite 20～40 parts,
Flyash 5～15 parts, aluminium oxide 2～8 parts, blanc fixe 2～6 parts, calcinated argil 2～8 parts, natural diabase 1～4 parts, phenol
Urea formaldehyde 0.5～1.2 parts, polyalkyl acrylate 1～4 parts, carboxymethyl cellulose 2～5 parts, modified castor oil 1～5 parts.
The most wear-resisting water proof building insulating brick, it is characterised in that modified castor oil uses following technique
Preparation: opal powder body, sodium polyacrylate, water are ground, adds crystallization TiO2Continue to grind, add water and stir, centrifugation,
Filter cake is washed with deionized, and dry, pulverize, and obtains prefabricated material；By weight Oleum Ricini is vacuum dried, removes vacuum, cold
But, add di-2-ethylhexylphosphine oxide (4-phenyl isocyanate), prefabricated material under stirring, continue stirring, heat up, continue stirring, vacuum
It is stirred under state, is down to room temperature and obtains modified castor oil.
Wear-resisting water proof building insulating brick the most according to claim 1 or claim 2, it is characterised in that modified castor oil uses as follows
Prepared by technique: 2～6 parts of opal powder body, 0.1～0.2 part of sodium polyacrylate, 30～40 parts of water are ground by weight, add
10～20 parts of crystallization TiO2Continuing to grind, add 40～80 parts of water stirrings, centrifugation, filter cake is washed with deionized, and is dried,
Pulverize, obtain prefabricated material；By weight by 8～12 parts of Oleum Ricini vacuum drying, remove vacuum, cooling, under stirring, add 4
～9 parts of di-2-ethylhexylphosphine oxides (4-phenyl isocyanate), 2～10 parts of prefabricated material, continue stirring, heat up, continue stirring, under vacuum state
It is stirred for, is down to room temperature and obtains modified castor oil.
4. according to water proof building insulating brick wear-resisting described in any one of claim 1-3, it is characterised in that modified castor oil uses
Prepared by following technique: 2～6 parts of opal powder body, 0.1～0.2 part of sodium polyacrylate, 30～40 parts of water are ground by weight,
Add 10～20 parts of crystallization TiO2Continuing to be ground to particle diameter is 15～35 μm, adds 40～80 parts of water stirrings 30～50min, centrifugal
Separating, filter cake is washed with deionized, and dry, pulverize, and obtains prefabricated material；By weight by 8～12 parts of Oleum Ricini vacuum drying
10～30min, baking temperature is 110～120 DEG C, removes vacuum, is cooled to 60～70 DEG C, adds 4～9 parts of Asias under stirring
Methyl double (4-phenyl isocyanate), 2～10 parts of prefabricated material, continue stirring 20～40min, be warming up to 90～98 DEG C, continue to stir
Mix and under 10～20min, vacuum state, be stirred for 20～40min, be down to room temperature and obtain modified castor oil.
5. according to water proof building insulating brick wear-resisting described in any one of claim 1-4, it is characterised in that phenolic resin, poly-alkane
Base acrylate, carboxymethyl cellulose, the weight ratio of modified castor oil are 0.6～1:2～3:3～4:2～4.
6. according to water proof building insulating brick wear-resisting described in any one of claim 1-4, it is characterised in that bentonite, flyash,
Aluminium oxide, blanc fixe, calcinated argil, natural diabase, the weight ratio of modified castor oil be 25～35:8～12:4～6:3～
5:4～6:2～3:2～4.
7. according to water proof building insulating brick wear-resisting described in any one of claim 1-4, it is characterised in that its raw material is by weight
Including: bentonite 25～35 parts, flyash 8～12 parts, aluminium oxide 4～6 parts, blanc fixe 3～5 parts, calcinated argil 4～6 parts,
Natural diabase 2～3 parts, phenolic resin 0.6～1 part, polyalkyl acrylate 2～3 parts, carboxymethyl cellulose 3～4 parts, change
Property Oleum Ricini 2～4 parts.
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| CN201610740501.2A CN106242520A (en) | 2016-08-26 | 2016-08-26 | A kind of wear-resisting water proof building insulating brick |
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| CN201610740501.2A CN106242520A (en) | 2016-08-26 | 2016-08-26 | A kind of wear-resisting water proof building insulating brick |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106336213A (en) * | 2016-08-29 | 2017-01-18 | 天长市中德电子有限公司 | MnZn soft magnetic ferrite material with high magnetic conductivity |
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| CN101100531A (en) * | 2007-07-10 | 2008-01-09 | 伍强贤 | Hydrophilic natural macromolecule modified by polyurethane micro-sphere and preparation method thereof |
| CN102993785A (en) * | 2012-11-13 | 2013-03-27 | 王丕轩 | Preparation method for TiO2/opal composite powder material |
| CN105731976A (en) * | 2016-01-20 | 2016-07-06 | 广西丛欣实业有限公司 | Insulating brick and preparation method thereof |
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2016
- 2016-08-26 CN CN201610740501.2A patent/CN106242520A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101100531A (en) * | 2007-07-10 | 2008-01-09 | 伍强贤 | Hydrophilic natural macromolecule modified by polyurethane micro-sphere and preparation method thereof |
| CN102993785A (en) * | 2012-11-13 | 2013-03-27 | 王丕轩 | Preparation method for TiO2/opal composite powder material |
| CN105731976A (en) * | 2016-01-20 | 2016-07-06 | 广西丛欣实业有限公司 | Insulating brick and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106336213A (en) * | 2016-08-29 | 2017-01-18 | 天长市中德电子有限公司 | MnZn soft magnetic ferrite material with high magnetic conductivity |
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