CN106219773A - A kind of salt-soda soil sprinkling irrigation equipment scale inhibitor special and preparation method thereof - Google Patents

A kind of salt-soda soil sprinkling irrigation equipment scale inhibitor special and preparation method thereof Download PDF

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Publication number
CN106219773A
CN106219773A CN201610762219.4A CN201610762219A CN106219773A CN 106219773 A CN106219773 A CN 106219773A CN 201610762219 A CN201610762219 A CN 201610762219A CN 106219773 A CN106219773 A CN 106219773A
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China
Prior art keywords
parts
sodium
phosphate
salt
water
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CN201610762219.4A
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Chinese (zh)
Inventor
王胜
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Shandong Sunway Garden Technology Co Ltd
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Shandong Sunway Garden Technology Co Ltd
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Priority to CN201610762219.4A priority Critical patent/CN106219773A/en
Publication of CN106219773A publication Critical patent/CN106219773A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/08Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
    • C02F5/10Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
    • C02F5/14Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing phosphorus
    • C02F5/145Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing phosphorus combined with inorganic substances

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of salt-soda soil sprinkling irrigation equipment scale inhibitor special, its raw material includes by weight: hydroxy ethylidene sodium ascorbyl phosphate 8 15 parts, sodium polyacrylate 35 parts, 13 parts of mercapto benzothiazole sodium, sodium hexameta phosphate 5 10 parts, ethylenediamine tetraacetic methene sodium phosphate 37 parts, 12 parts of benzotriazole sodium, methylbenzene 6 15 parts of three nitrogen of a pair of horses going side by side, polyvinylpyrrolidone 6 10 parts, lignin 48 parts, surplus is water.The present invention adds lignin in antisludging agent; lignin is dispersibility scale inhibition material, can strengthen the corrosion mitigating effect of antisludging agent, with mercapto benzothiazole sodium mating reaction; preferably equipment is protected; ion in water is dissipated, ion can be flowed along with water, and containing multiple coordinate bonds in sodium hexameta phosphate; can simultaneously with multiple ions binding; such that it is able to well avoid the appearance of scale removal, and this performance of antisludging agent is more stable, has good heat stability.

Description

A kind of salt-soda soil sprinkling irrigation equipment scale inhibitor special and preparation method thereof
Technical field
The present invention relates to water-treatment technology field, be specially a kind of salt-soda soil sprinkling irrigation equipment scale inhibitor special and preparation side thereof Method.
Background technology
Antisludging agent be have can slightly solubility inorganic salt in disperse water, inhibit or interfere with slightly solubility inorganic salt in metal surface Precipitation, fouling function, and maintain hardware to have a class medicament of good heat-transfer effect, from the mechanism of action from the point of view of, resistance The effect of dirt agent can be divided into sequestration, dispersion and distortion of lattice three part.And in laboratory evaluation is tested, peptizaiton is sequestration The remedial measure of effect, distortion of lattice effect is the remedial measure of peptizaiton, in the region in salt-soda soil, containing a large amount of in water Metal ion group and nonmetallic ion group, easily form sedimentation and be attached to the surface of equipment, affect the use of equipment.
Summary of the invention
It is an object of the invention to provide a kind of salt-soda soil sprinkling irrigation equipment scale inhibitor special and preparation method thereof, possessing can Effectively avoid equipment surface that the advantage of fouling occurs, solve the problem that structure easily occurs in ground, salt-soda soil carrying device.
For achieving the above object, the present invention provides following technical scheme: a kind of salt-soda soil sprinkling irrigation equipment scale inhibitor special, its Raw material includes by weight: hydroxy ethylidene sodium ascorbyl phosphate 8-15 part, sodium polyacrylate 3-5 part, mercapto benzothiazole sodium 1-3 part, Sodium hexameta phosphate 5-10 part, ethylenediamine tetraacetic methene sodium phosphate 3-7 part, benzotriazole sodium 1-2 part, methylbenzene a pair of horses going side by side three nitrogen 6-15 Part, polyvinylpyrrolidone 6-10 part, lignin 4-8 part, surplus is water.
Preferably, hydroxy ethylidene sodium ascorbyl phosphate 12 parts, sodium polyacrylate 3.5 parts, 1.5 parts of mercapto benzothiazole sodium, six is inclined Sodium phosphate 6 parts, ethylenediamine tetraacetic methene sodium phosphate 6 parts, 2 parts of benzotriazole sodium, methylbenzene 12 parts of three nitrogen of a pair of horses going side by side, polyvinylpyrrolidine Ketone 9 parts, lignin 5 parts, surplus is water.
Preferably, hydroxy ethylidene sodium ascorbyl phosphate 10 parts, sodium polyacrylate 4 parts, 2 parts of mercapto benzothiazole sodium, hexa metaphosphoric acid 8 parts of sodium, ethylenediamine tetraacetic methene sodium phosphate 5 parts, 1 part of benzotriazole sodium, methylbenzene 10 parts of three nitrogen of a pair of horses going side by side, polyvinylpyrrolidone 8 Part, lignin 6 parts, surplus is water.
Preferably, hydroxy ethylidene sodium ascorbyl phosphate 9 parts, sodium polyacrylate 5 parts, 3 parts of mercapto benzothiazole sodium, sodium hexameta phosphate 7 parts, ethylenediamine tetraacetic methene sodium phosphate 4 parts, 1.5 parts of benzotriazole sodium, methylbenzene 9 parts of three nitrogen of a pair of horses going side by side, polyvinylpyrrolidone 7.5 Part, lignin 6.5 parts, surplus is water.
Invention further provides the preparation method of above-mentioned salt-soda soil sprinkling irrigation equipment scale inhibitor special, this preparation method bag Include following steps:
S1, by weight weigh hydroxy ethylidene sodium ascorbyl phosphate, sodium polyacrylate, mercapto benzothiazole sodium, lignin, six Polymeric sodium metaphosphate. and ethylenediamine tetraacetic methene sodium phosphate add appropriate water and carry out mix homogeneously, make mixture;
S2, weigh benzotriazole sodium, methylbenzene a pair of horses going side by side three nitrogen and polyvinylpyrrolidone by weight, then with step The mixture produced in S1 proportionally carries out mix and blend;
S3, it is placed on mixture in the environment of 70-90 degree to place and is dried for 1-3 hour, then take out grinding.
Compared with prior art, beneficial effects of the present invention is as follows:
1, the present invention makes antisludging agent by being used in conjunction with each other according to specific ratio by multiple macromolecular material, permissible Form sedimentation between the effective ionic group reduced in water and be attached to equipment surface, it is to avoid affect the use of equipment, reduce water The dirt corrosion to equipment, in the service life of extension device, by adding mercapto benzothiazole sodium in antisludging agent, has been possible not only to To the effect of inhibition, and one layer of fine and close protecting film can be formed on the surface of equipment, while slowing down destructing, by water Ion can be circulated flowing along with water always, it is also possible to equipment is protected, it is to avoid incrustation scale attachment at equipment Surface, thus preferably play the effect of scale inhibition.
2, the present invention is by adding lignin in antisludging agent, and lignin is dispersibility scale inhibition material, can strengthen scale inhibition The corrosion mitigating effect of agent, with mercapto benzothiazole sodium mating reaction, preferably protects equipment, carries out the ion in water sending out Dissipate, ion can be flowed along with water, and containing multiple coordinate bonds in sodium hexameta phosphate, it is possible to simultaneously with multiple ions binding, Such that it is able to well avoid the appearance of scale removal, and this performance of antisludging agent is more stable, has good heat stability, it is not easy to Decomposed, it is simple to store, and go for, in multiple water, using convenient.
Detailed description of the invention
Below the technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment It is only a part of embodiment of the present invention rather than whole embodiments.Based on the embodiment in the present invention, the common skill in this area The every other embodiment that art personnel are obtained under not making creative work premise, broadly falls into the model of present invention protection Enclose.
Embodiment 1
A kind of salt-soda soil sprinkling irrigation equipment scale inhibitor special, its raw material includes by weight: hydroxy ethylidene sodium ascorbyl phosphate 12 parts, Sodium polyacrylate 3.5 parts, 1.5 parts of mercapto benzothiazole sodium, sodium hexameta phosphate 6 parts, ethylenediamine tetraacetic methene sodium phosphate 6 parts, benzene a pair of horses going side by side Triazole sodium 2 parts, methylbenzene 12 parts of three nitrogen of a pair of horses going side by side, polyvinylpyrrolidone 9 parts, lignin 5 parts, surplus is water.
The preparation method of a kind of salt-soda soil sprinkling irrigation equipment scale inhibitor special, comprises the following steps:
S1, by weight weigh hydroxy ethylidene sodium ascorbyl phosphate, sodium polyacrylate, mercapto benzothiazole sodium, lignin, six Polymeric sodium metaphosphate. and ethylenediamine tetraacetic methene sodium phosphate add appropriate water and carry out mix homogeneously, make mixture;
S2, weigh benzotriazole sodium, methylbenzene a pair of horses going side by side three nitrogen and polyvinylpyrrolidone by weight, then with step The mixture produced in S1 proportionally carries out mix and blend;
S3, it is placed on mixture in the environment of 70-90 degree to place and is dried for 1-3 hour, then take out grinding.
Embodiment 2
A kind of salt-soda soil sprinkling irrigation equipment scale inhibitor special, its raw material includes by weight: hydroxy ethylidene sodium ascorbyl phosphate 10 parts, Sodium polyacrylate 4 parts, 2 parts of mercapto benzothiazole sodium, sodium hexameta phosphate 8 parts, ethylenediamine tetraacetic methene sodium phosphate 5 parts, benzene a pair of horses going side by side three nitrogen 1 part of azoles sodium, methylbenzene 10 parts of three nitrogen of a pair of horses going side by side, polyvinylpyrrolidone 8 parts, lignin 6 parts, surplus is water.
The preparation method of a kind of salt-soda soil sprinkling irrigation equipment scale inhibitor special, comprises the following steps:
S1, by weight weigh hydroxy ethylidene sodium ascorbyl phosphate, sodium polyacrylate, mercapto benzothiazole sodium, lignin, six Polymeric sodium metaphosphate. and ethylenediamine tetraacetic methene sodium phosphate add appropriate water and carry out mix homogeneously, make mixture;
S2, weigh benzotriazole sodium, methylbenzene a pair of horses going side by side three nitrogen and polyvinylpyrrolidone by weight, then with step The mixture produced in S1 proportionally carries out mix and blend;
S3, it is placed on mixture in the environment of 80 degree to place and is dried for 2.5 hours, then take out grinding.
Embodiment 3
A kind of salt-soda soil sprinkling irrigation equipment scale inhibitor special, its raw material includes by weight: hydroxy ethylidene sodium ascorbyl phosphate 9 parts, Sodium polyacrylate 5 parts, 3 parts of mercapto benzothiazole sodium, sodium hexameta phosphate 7 parts, ethylenediamine tetraacetic methene sodium phosphate 4 parts, benzene a pair of horses going side by side three nitrogen 1.5 parts of azoles sodium, methylbenzene 9 parts of three nitrogen of a pair of horses going side by side, polyvinylpyrrolidone 7.5 parts, lignin 6.5 parts, surplus is water.
The preparation method of a kind of salt-soda soil sprinkling irrigation equipment scale inhibitor special, comprises the following steps:
S1, by weight weigh hydroxy ethylidene sodium ascorbyl phosphate, sodium polyacrylate, mercapto benzothiazole sodium, lignin, six Polymeric sodium metaphosphate. and ethylenediamine tetraacetic methene sodium phosphate add appropriate water and carry out mix homogeneously, make mixture;
S2, weigh benzotriazole sodium, methylbenzene a pair of horses going side by side three nitrogen and polyvinylpyrrolidone by weight, then with step The mixture produced in S1 proportionally carries out mix and blend;
S3, it is placed on mixture in the environment of 90 degree to place and is dried for 2 hours, then take out grinding.
To sum up: this salt-soda soil sprinkling irrigation equipment scale inhibitor special and preparation method thereof, by by multiple macromolecular material according to Specific ratio is used in conjunction with each other makes antisludging agent, can effectively reduce and form sedimentation attachment between the ionic group in water In equipment surface, it is to avoid affect the use of equipment, reduce the incrustation scale corrosion to equipment, the service life of extension device, by Antisludging agent adds mercapto benzothiazole sodium, is possible not only to play the effect of inhibition, and one can be formed on the surface of equipment The protecting film that layer is fine and close, while slowing down destructing, can be circulated flowing along with water by the ion in water always, also may be used So that equipment is protected, it is to avoid incrustation scale attachment in equipment surface, thus preferably play the effect of scale inhibition, solve saline and alkaline The problem that structure easily occurs in ground, ground carrying device.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, permissible Understand and these embodiments can be carried out multiple change without departing from the principles and spirit of the present invention, revise, replace And modification, the scope of the present invention be defined by the appended.

Claims (5)

1. a salt-soda soil sprinkling irrigation equipment scale inhibitor special, it is characterised in that its raw material includes by weight: hydroxy ethylidene phosphoric acid Sodium salt 8-15 part, sodium polyacrylate 3-5 part, mercapto benzothiazole sodium 1-3 part, sodium hexameta phosphate 5-10 part, ethylenediamine tetraacetic methene Sodium phosphate 3-7 part, benzotriazole sodium 1-2 part, methylbenzene a pair of horses going side by side three nitrogen 6-15 parts, polyvinylpyrrolidone 6-10 part, lignin 4-8 part, surplus is water.
A kind of salt-soda soil the most according to claim 1 sprinkling irrigation equipment scale inhibitor special, it is characterised in that its raw material is by weight Part includes: hydroxy ethylidene sodium ascorbyl phosphate 12 parts, sodium polyacrylate 3.5 parts, 1.5 parts of mercapto benzothiazole sodium, sodium hexameta phosphate 6 Part, ethylenediamine tetraacetic methene sodium phosphate 6 parts, 2 parts of benzotriazole sodium, methylbenzene 12 parts of three nitrogen of a pair of horses going side by side, polyvinylpyrrolidone 9 parts, Lignin 5 parts, surplus is water.
A kind of salt-soda soil the most according to claim 1 sprinkling irrigation equipment scale inhibitor special, it is characterised in that its raw material is by weight Part includes: hydroxy ethylidene sodium ascorbyl phosphate 10 parts, sodium polyacrylate 4 parts, 2 parts of mercapto benzothiazole sodium, sodium hexameta phosphate 8 parts, second Diamidogen four methene sodium phosphate 5 parts, 1 part of benzotriazole sodium, methylbenzene 10 parts of three nitrogen of a pair of horses going side by side, polyvinylpyrrolidone 8 parts, lignin 6 parts, surplus is water.
A kind of salt-soda soil the most according to claim 1 sprinkling irrigation equipment scale inhibitor special, it is characterised in that its raw material is by weight Part includes: hydroxy ethylidene sodium ascorbyl phosphate 9 parts, sodium polyacrylate 5 parts, 3 parts of mercapto benzothiazole sodium, sodium hexameta phosphate 7 parts, second two Amine four methene sodium phosphate 4 parts, 1.5 parts of benzotriazole sodium, methylbenzene 9 parts of three nitrogen of a pair of horses going side by side, polyvinylpyrrolidone 7.5 parts, wooden Element 6.5 parts, surplus is water.
5. the preparation method of a salt-soda soil sprinkling irrigation equipment scale inhibitor special, it is characterised in that comprise the following steps:
S1, weigh hydroxy ethylidene sodium ascorbyl phosphate, sodium polyacrylate, mercapto benzothiazole sodium, lignin, six inclined phosphorus by weight Acid sodium and ethylenediamine tetraacetic methene sodium phosphate add appropriate water and carry out mix homogeneously, make mixture;
S2, weigh benzotriazole sodium, methylbenzene a pair of horses going side by side three nitrogen and polyvinylpyrrolidone by weight, then with in step S1 The mixture produced proportionally carries out mix and blend;
S3, it is placed on mixture in the environment of 70-90 degree to place and is dried for 1-3 hour, then take out grinding.
CN201610762219.4A 2016-08-30 2016-08-30 A kind of salt-soda soil sprinkling irrigation equipment scale inhibitor special and preparation method thereof Pending CN106219773A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111324020A (en) * 2018-12-17 2020-06-23 乐凯华光印刷科技有限公司 Thermosensitive positive image CTP plate developing solution

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CN103352226A (en) * 2013-06-19 2013-10-16 余丽 Corrosion inhibitor used for preventing corrosion of brass
CN105565517A (en) * 2015-12-16 2016-05-11 江苏盖亚环境工程有限公司 Scale inhibitor for cooling water and preparation method of scale inhibitor
CN105600957A (en) * 2015-12-30 2016-05-25 青岛文晟汽车零部件有限公司 Scale and corrosion inhibitor

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101967024B (en) * 2010-06-04 2012-06-27 内蒙古天晨科技有限责任公司 Phosphorus-free corrosion and scale inhibitor
CN103352226A (en) * 2013-06-19 2013-10-16 余丽 Corrosion inhibitor used for preventing corrosion of brass
CN105565517A (en) * 2015-12-16 2016-05-11 江苏盖亚环境工程有限公司 Scale inhibitor for cooling water and preparation method of scale inhibitor
CN105600957A (en) * 2015-12-30 2016-05-25 青岛文晟汽车零部件有限公司 Scale and corrosion inhibitor

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111324020A (en) * 2018-12-17 2020-06-23 乐凯华光印刷科技有限公司 Thermosensitive positive image CTP plate developing solution

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Application publication date: 20161214

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