CN106215660A - SO in a kind of recovery tail gas2system - Google Patents

SO in a kind of recovery tail gas2system Download PDF

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Publication number
CN106215660A
CN106215660A CN201610721506.0A CN201610721506A CN106215660A CN 106215660 A CN106215660 A CN 106215660A CN 201610721506 A CN201610721506 A CN 201610721506A CN 106215660 A CN106215660 A CN 106215660A
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CN
China
Prior art keywords
pump
reaction tower
scrubber
recovery
short circuit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610721506.0A
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Chinese (zh)
Inventor
叶永乐
马洪文
杜建廷
雒彩军
方世中
方俊文
李文亭
张朝辉
许海敏
董宁宁
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lingbao Jinyuan Chenguang Nonferrous Mining And Metallurgy Co ltd
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Lingbao Jinyuan Chenguang Nonferrous Mining And Metallurgy Co ltd
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Application filed by Lingbao Jinyuan Chenguang Nonferrous Mining And Metallurgy Co ltd filed Critical Lingbao Jinyuan Chenguang Nonferrous Mining And Metallurgy Co ltd
Priority to CN201610721506.0A priority Critical patent/CN106215660A/en
Publication of CN106215660A publication Critical patent/CN106215660A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • B01D53/507Sulfur oxides by treating the gases with other liquids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/10Oxidants
    • B01D2251/106Peroxides

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)

Abstract

The invention discloses SO in a kind of recovery tail gas2System, it includes first order recirculation system and second level recirculation system, first order recirculation system includes scrubber, the first recovery pump, transporting and the first circulating slot, the top of scrubber is provided with outgassing direction scrubber's air inlet down, the bottom of scrubber is provided with scrubber's discharging opening, and scrubber is internally provided with spray direction the first spray head upward;Second level recirculation system includes reaction tower, the second recovery pump and the second circulating slot, the top of reaction tower arranges reaction tower gas outlet, the bottom of reaction tower is provided with reaction tower liquid outlet, the middle and lower part of reaction tower is provided with reaction tower air inlet, and reaction tower is internally provided with the second spray head that spray is directed downward.The invention has the advantages that and be capable of SO in tail gas2Multiple stage circulation reclaim, resource utilization is high, and organic efficiency is high, decreases environmental pollution.

Description

SO in a kind of recovery tail gas2System
Technical field
The invention belongs to sulphuric acid manufacturing technology field, particularly relate to SO in a kind of recovery tail gas2System.
Background technology
At present, the sulfuric acid tail gas after two inhale tower absorption still contains a certain amount of SO2, need that it is carried out process and reach Could discharge after mark.But existing process contains SO2The method of tail gas typically uses Ammonia Process, sodium alkali, calcium method, first order reaction Tower absorbs SO2, absorption efficiency is low, and system is difficult to control to, and the purposes such as the ammonium sulfite of generation, sodium sulfite, calcium sulfate is wide, and And after also needing to reprocess, stock stacks, and not only causes the wasting of resources, and pollutes again environment.
Summary of the invention
It is an object of the invention to provide SO in a kind of recovery tail gas2System, it is possible to realize SO in tail gas2Multistage follow Loopback is received, and resource utilization is high, and organic efficiency is high, decreases environmental pollution.
For solving above-mentioned technical problem, the present invention adopts the following technical scheme that SO in a kind of recovery tail gas2System, it Including first order recirculation system and second level recirculation system, first order recirculation system include scrubber, first Recovery pump, transporting and the first circulating slot, scrubber is vertically arranged cylinder, and the top of scrubber is provided with outgassing direction court Under scrubber's air inlet, the bottom of scrubber is provided with scrubber's discharging opening, scrubber be internally located at scrubber's air inlet and Position between scrubber's discharging opening is provided with spray direction the first spray head upward, the inlet and outlet of the first recovery pump Being connected to the first feed tube and the first drain pipe, the first spray head is connected by the first shower and the first drain pipe, the One feed tube and the connection of the first circulating slot;The top of transporting is provided with transporting charging aperture and transporting gas outlet, transporting Bottom be provided with transporting liquid outlet, transporting charging aperture connects with scrubber's discharging opening, transporting liquid outlet pass through first Connecting tube connects with the first circulating slot;
Second level recirculation system includes reaction tower, the second recovery pump and the second circulating slot, and the top of reaction tower arranges reaction Tower gas outlet, the bottom of reaction tower is provided with reaction tower liquid outlet, and the middle and lower part of reaction tower is provided with reaction tower air inlet, reaction The position that tower is internally located between reaction tower air inlet and reaction tower gas outlet is provided with the second spray that spray is directed downward Head;The inlet and outlet of the second recovery pump is connected to the second feed tube and the second drain pipe, and the second spray head passes through second Shower and the connection of the second drain pipe, the second drain pipe also by the connection of return duct and the first circulating slot, the second feed tube and the Two circulating slot connections;Reaction tower liquid outlet is connected with the second circulating slot by the second connecting tube.
It also includes storage tank, and storage tank is connected with described first drain pipe by catheter, and storage tank bottom connects discharging tube, It is provided with the 3rd recovery pump on discharging tube, the discharging tube of the 3rd recovery pump both sides is respectively arranged with valve.
Described 3rd recovery pump is engineering plastic pump.
It also includes chimney, and chimney is connected with described reaction tower gas outlet by exhaustor.
The side of described first recovery pump is parallel with the first stand-by pump, and the first short circuit inlet pipe is passed through in the import of the first stand-by pump Connecting with the first feed tube, the first standby delivery side of pump goes out pipe by the first short circuit and connects with the first drain pipe, and the first short circuit enters Pipe and the first short circuit go out to be provided with valve on pipe;
The side of described second recovery pump is parallel with the second stand-by pump, and the import of the second stand-by pump is by the second short circuit inlet pipe and the Two feed tubes connection, the second standby delivery side of pump by the second short circuit go out pipe connect with the second drain pipe, the second short circuit inlet pipe with Second short circuit goes out to be provided with valve on pipe.
Described first recovery pump, the second recovery pump, the first stand-by pump and the second stand-by pump are engineering plastic pump.
It is all provided with on described first shower, the first feed tube, the first drain pipe, the second feed tube and the second drain pipe It is equipped with valve.
Beneficial effects of the present invention:
The SO contained2Sulfuric acid tail gas enter and the H contained of the first spray head ejection from the scrubber air inlet of scrubber2O2 Liquid and the reverse haptoreaction of dilute sulfuric acid liquid generate the dilute sulfuric acid of about 40% and flow in the first circulating slot, H2O2Strength of fluid continues Continuous reduction, dilute sulfuric acid concentration raises, and mixing liquid needs quantitatively to be drained in storage tank to be deposited.Unabsorbed contain SO2 completely Sulfuric acid tail gas enter back in reaction tower and the H of the second spray head ejection2O2Liquid inversely contacts, and major part SO2Participate in reaction Flowing in the second circulating slot after generating dilute sulfuric acid, the part on a small quantity of the liquid in the second circulating slot seals in the first circulating slot supplements it H2O2The amount of liquid.Reclaim SO2After tail gas through chimney qualified discharge.About 40% dilute sulfuric acid being stored in storage tank passes through the 3rd Recovery pump is for ammonium phosphate system or other production.By above-mentioned flow process, the SO in tail gas2,Reaction obtains sulphuric acid, has reclaimed Sulphur ressource, Decrease environmental pollution, and the system of the present invention is easy to control, the SO in tail gas2Reclaim through multiple stage circulation, the utilization of resources Rate is high, and organic efficiency is high.
The side of described first recovery pump is parallel with the first stand-by pump, and the first short circuit inlet pipe is passed through in the import of the first stand-by pump Connecting with the first feed tube, the first standby delivery side of pump goes out pipe by the first short circuit and connects with the first drain pipe, and the first short circuit enters Pipe and the first short circuit go out to be provided with valve on pipe.First stand-by pump be provided for when the first recovery pump fault use, just The valve that often during work, the first stand-by pump and the first short circuit inlet pipe and the first short circuit go out on pipe is in closed mode, when first time When receiving failure of pump, close the valve on the first feed tube and the first drain pipe, control the first stand-by pump and the first short circuit inlet pipe and The valve that first short circuit goes out on pipe is in open mode, i.e. completes the first stand-by pump and the switching of the first recovery pump.
The side of described second recovery pump is parallel with the second stand-by pump, and the second short circuit inlet pipe is passed through in the import of the second stand-by pump Connecting with the second feed tube, the second standby delivery side of pump goes out pipe by the second short circuit and connects with the second drain pipe, and the second short circuit enters Pipe and the second short circuit go out to be provided with valve on pipe.Being provided for when the second recovery pump fault of second stand-by pump uses, and the Two stand-by pumps and the switching of the second recovery pump, with reference to above-mentioned first stand-by pump and the handoff procedure of the first recovery pump.
Accompanying drawing explanation
Fig. 1 is the systematic schematic diagram of the present invention.
Detailed description of the invention
Elaborating the detailed description of the invention of the present invention below in conjunction with accompanying drawing, in figure, the direction of arrow represents liquid stream To.
As it is shown in figure 1, a kind of of the present invention reclaims SO in tail gas2System, it include first order recirculation system and Second level recirculation system, first order recirculation system includes that scrubber's the 2, first recovery pump 3, transporting 11 and first follow Annular groove 4, scrubber 2 is vertically arranged cylinder, and the top of scrubber 2 is provided with outgassing direction scrubber's air inlet down, The bottom of scrubber 2 is provided with scrubber's discharging opening, and scrubber 2 is internally located between scrubber's air inlet and scrubber's discharging opening Position be provided with spray direction the first spray head 14 upward, the inlet and outlet of the first recovery pump 3 is connected to the One feed tube 16 and the first drain pipe 15, the first spray head 14 is connected with the first drain pipe 15 by the first shower 19, and first Feed tube 16 connects with the first circulating slot 4;The top of transporting 11 is provided with transporting charging aperture and transporting gas outlet, transhipment The bottom of cylinder is provided with transporting liquid outlet, and transporting charging aperture connects with scrubber's discharging opening, and transporting liquid outlet passes through the One connecting tube 21 connects with the first circulating slot 4.
Second level recirculation system includes reaction tower the 6, second recovery pump 7 and the second circulating slot 8, the top of reaction tower 6 Arranging reaction tower gas outlet, the bottom of reaction tower 6 is provided with reaction tower liquid outlet, and the middle and lower part of reaction tower 6 is provided with reaction tower Air inlet, the position that reaction tower 6 is internally located between reaction tower air inlet and reaction tower gas outlet is provided with spray direction court Under the second spray head 31;The inlet and outlet of the second recovery pump 7 is connected to the second feed tube 27 and the second drain pipe 26, Second spray head 31 is connected with the second drain pipe 26 by the second shower 23, and the second drain pipe 26 is also by return duct 22 and the One circulating slot 4 connects, and the second feed tube 27 connects with the second circulating slot 8;Reaction tower liquid outlet is by the second connecting tube 28 and the Two circulating slots 8 connect.
Described first shower the 19, first feed tube the 16, first drain pipe the 15, second feed tube 27 and second goes out liquid It is provided with valve on pipe 26.
Present invention additionally comprises storage tank 5, storage tank 5 is connected with described first drain pipe 15 by catheter 20, and storage tank 5 bottom is even It is connected to discharging tube 29, discharging tube 29 is provided with the 3rd recovery pump 30, the discharging tube 29 of the 3rd recovery pump 30 both sides sets respectively It is equipped with valve.
Present invention additionally comprises chimney 10, chimney 10 is connected with described reaction tower gas outlet by exhaustor 13.
The side of described first recovery pump 3 is parallel with the first stand-by pump 31, and the import of the first stand-by pump 31 is short by first Tapping into pipe 18 to connect with the first feed tube 16, the outlet of the first stand-by pump 31 goes out pipe 17 and the first drain pipe 15 by the first short circuit Connection, the first short circuit inlet pipe 18 and the first short circuit go out and are provided with valve on pipe 17.Being provided for of first stand-by pump 31 Using during one recovery pump 3 fault, during normal work, the first stand-by pump 31 and the first short circuit inlet pipe 18 and the first short circuit go out on pipe 17 Valve be in closed mode, when the first recovery pump 3 fault, close the valve on the first feed tube 16 and the first drain pipe 15 Door, controls the first stand-by pump 31 and the first short circuit inlet pipe 18 and valve that the first short circuit goes out on pipe 17 is in open mode, i.e. Complete the first stand-by pump 31 and switching of the first recovery pump 3.
The side of described second recovery pump 7 is parallel with the second stand-by pump 71, and the import of the second stand-by pump 71 is short by second Tapping into pipe 25 to connect with the second feed tube 27, the outlet of the second stand-by pump 71 goes out pipe 24 and the second drain pipe 26 by the second short circuit Connection, the second short circuit inlet pipe 25 and the second short circuit go out and are provided with valve on pipe 24.Being provided for of second stand-by pump 71 Use during two recovery pump 7 faults, the second stand-by pump 71 and switching of the second recovery pump 7, with reference to above-mentioned first stand-by pump 31 and the The handoff procedure of one recovery pump 7.
Described first recovery pump the 3, second recovery pump the 7, the 3rd recovery pump the 30, first stand-by pump 21 and the second stand-by pump 71 are equal For engineering plastic pump, engineering plastic pump has acid resistance, meets practical application request.
When the present invention works, inhale, through two, the SO contained that tower outlet comes2Sulfuric acid tail gas from scrubber's air inlet of scrubber 2 Mouth entrance and the first recovery pump 3 are pumped into the H contained of the first spray head 142O2Liquid and the reverse haptoreaction of dilute sulfuric acid liquid The dilute sulfuric acid generating about 40% flows in the first circulating slot 4 through transporting 11 and the first connecting tube 21, H2O2Strength of fluid continues Reducing, dilute sulfuric acid concentration raises, and mixing liquid needs quantitatively to be drained in storage tank 5 to be deposited.Unabsorbed contain SO2's completely Sulfuric acid tail gas enters back into the H being pumped into the second spray head 31 in reaction tower 6 with the second recovery pump 72O2Liquid inversely contacts, and greatly Part SO2Participating in reaction and generate dilute sulfuric acid, dilute sulfuric acid footpath second connecting tube 28 of generation flows in the second circulating slot 8, and second follows Liquid in annular groove 8 part on a small quantity seals in supplements its H in the first circulating slot 42O2The amount of liquid.Reclaim SO2After tail gas through chimney 10 qualified discharges.About 40% dilute sulfuric acid being stored in storage tank 5 supplies ammonium phosphate system or other production by the 3rd recovery pump 30. By above-mentioned flow process, peroxide passivation is utilized to process the SO in sulfuric acid tail gas2,, and react obtain sulphuric acid, reclaimed Sulphur ressource, reduce Environmental pollution, and the system of the present invention is easy to control, SO in tail gas2Reclaiming through multiple stage circulation, resource utilization is high, Organic efficiency is high.
Above example is only in order to illustrative not limiting technical scheme, although with reference to above-described embodiment to this Bright be described in detail, it will be understood by those within the art that: still the present invention can be modified or etc. With replacing, any modification or partial replacement without departing from the spirit and scope of the present invention, it all should contain the power in the present invention In the middle of profit claimed range.

Claims (7)

1. one kind is reclaimed SO in tail gas2System, it is characterised in that: it include first order recirculation system and the second level circulation Recovery system, first order recirculation system includes scrubber, the first recovery pump, transporting and the first circulating slot, and scrubber is Vertically arranged cylinder, the top of scrubber is provided with outgassing direction scrubber's air inlet down, and the bottom of scrubber is arranged Having scrubber's discharging opening, the position that scrubber is internally located between scrubber's air inlet and scrubber's discharging opening is provided with spray Direction the first spray head upward, the inlet and outlet of the first recovery pump is connected to the first feed tube and the first drain pipe, First spray head is connected by the first shower and the first drain pipe, the first feed tube and the connection of the first circulating slot;Transporting Top is provided with transporting charging aperture and transporting gas outlet, and the bottom of transporting is provided with transporting liquid outlet, and transporting enters Material mouth connects with scrubber's discharging opening, and transporting liquid outlet is connected with the first circulating slot by the first connecting tube;
Second level recirculation system includes reaction tower, the second recovery pump and the second circulating slot, and the top of reaction tower arranges reaction Tower gas outlet, the bottom of reaction tower is provided with reaction tower liquid outlet, and the middle and lower part of reaction tower is provided with reaction tower air inlet, reaction The position that tower is internally located between reaction tower air inlet and reaction tower gas outlet is provided with the second spray that spray is directed downward Head;The inlet and outlet of the second recovery pump is connected to the second feed tube and the second drain pipe, and the second spray head passes through second Shower and the connection of the second drain pipe, the second drain pipe also by the connection of return duct and the first circulating slot, the second feed tube and the Two circulating slot connections;Reaction tower liquid outlet is connected with the second circulating slot by the second connecting tube.
SO in recovery tail gas the most according to claim 12System, it is characterised in that: it also includes storage tank, and storage tank passes through Catheter connects with described first drain pipe, and storage tank bottom connects discharging tube, and discharging tube is provided with the 3rd recovery pump, and the 3rd It is respectively arranged with valve on the discharging tube of recovery pump both sides.
SO in recovery tail gas the most according to claim 22System, it is characterised in that: described 3rd recovery pump is engineering plastic Material pump.
SO in recovery tail gas the most according to claim 1 and 22System, it is characterised in that: it also includes chimney, chimney lead to Cross exhaustor to connect with described reaction tower gas outlet.
SO in recovery tail gas the most according to claim 42System, it is characterised in that: the side of described first recovery pump is also Being associated with the first stand-by pump, the import of the first stand-by pump is connected by the first short circuit inlet pipe and the first feed tube, the first stand-by pump Exporting to go out to manage by the first short circuit and connect with the first drain pipe, the first short circuit inlet pipe and the first short circuit go out to be provided with valve on pipe Door;
The side of described second recovery pump is parallel with the second stand-by pump, and the import of the second stand-by pump is by the second short circuit inlet pipe and the Two feed tubes connection, the second standby delivery side of pump by the second short circuit go out pipe connect with the second drain pipe, the second short circuit inlet pipe with Second short circuit goes out to be provided with valve on pipe.
SO in recovery tail gas the most according to claim 52System, it is characterised in that: described first recovery pump, second time Receive pump, the first stand-by pump and the second stand-by pump and be engineering plastic pump.
SO in recovery tail gas the most according to claim 12System, it is characterised in that: described first shower, It is provided with valve on one feed tube, the first drain pipe, the second feed tube and the second drain pipe.
CN201610721506.0A 2016-08-25 2016-08-25 SO in a kind of recovery tail gas2system Pending CN106215660A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111841249A (en) * 2019-04-26 2020-10-30 宁德时代新能源科技股份有限公司 Exhaust gas purification system
CN112107983A (en) * 2020-08-17 2020-12-22 南京汇仁化工设备有限公司 Hydrogen peroxide desulfurization process

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Publication number Priority date Publication date Assignee Title
CN111841249A (en) * 2019-04-26 2020-10-30 宁德时代新能源科技股份有限公司 Exhaust gas purification system
CN112107983A (en) * 2020-08-17 2020-12-22 南京汇仁化工设备有限公司 Hydrogen peroxide desulfurization process

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Application publication date: 20161214