CN106215626A - A kind of high atomization flue gas desulfurization processing method - Google Patents
A kind of high atomization flue gas desulfurization processing method Download PDFInfo
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- CN106215626A CN106215626A CN201610634341.3A CN201610634341A CN106215626A CN 106215626 A CN106215626 A CN 106215626A CN 201610634341 A CN201610634341 A CN 201610634341A CN 106215626 A CN106215626 A CN 106215626A
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- Prior art keywords
- flue gas
- water
- processing method
- buffer agent
- desulfurization
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- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 52
- 239000003546 flue gas Substances 0.000 title claims abstract description 52
- 238000006477 desulfuration reaction Methods 0.000 title claims abstract description 26
- 230000023556 desulfurization Effects 0.000 title claims abstract description 26
- 238000000889 atomisation Methods 0.000 title claims abstract description 12
- 238000003672 processing method Methods 0.000 title claims abstract description 12
- 238000000034 method Methods 0.000 claims abstract description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000007921 spray Substances 0.000 claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 239000007788 liquid Substances 0.000 claims abstract description 9
- 239000002351 wastewater Substances 0.000 claims abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical group [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 14
- 239000004744 fabric Substances 0.000 claims description 14
- 239000007789 gas Substances 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 7
- 238000004140 cleaning Methods 0.000 claims description 7
- 235000021110 pickles Nutrition 0.000 claims description 7
- 238000001556 precipitation Methods 0.000 claims description 7
- 239000011787 zinc oxide Substances 0.000 claims description 7
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- 239000000428 dust Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000002244 precipitate Substances 0.000 claims description 6
- 239000001509 sodium citrate Substances 0.000 claims description 6
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 6
- 239000003517 fume Substances 0.000 claims description 5
- 229910001385 heavy metal Inorganic materials 0.000 claims description 5
- 239000000779 smoke Substances 0.000 claims description 5
- 239000004115 Sodium Silicate Substances 0.000 claims description 4
- 239000008187 granular material Substances 0.000 claims description 4
- 239000010865 sewage Substances 0.000 claims description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052793 cadmium Inorganic materials 0.000 claims description 3
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 239000011651 chromium Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 3
- 230000011218 segmentation Effects 0.000 claims description 3
- 239000011790 ferrous sulphate Substances 0.000 claims description 2
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 2
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 2
- 229960001763 zinc sulfate Drugs 0.000 claims description 2
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- 239000003595 mist Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 238000004064 recycling Methods 0.000 claims 1
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 abstract description 14
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 abstract description 9
- 230000008901 benefit Effects 0.000 abstract description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 2
- 239000005864 Sulphur Substances 0.000 abstract description 2
- 238000003795 desorption Methods 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 150000002894 organic compounds Chemical class 0.000 abstract description 2
- 238000010563 solid-state fermentation Methods 0.000 abstract description 2
- 238000004069 wastewater sedimentation Methods 0.000 abstract description 2
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 239000003344 environmental pollutant Substances 0.000 abstract 1
- 231100000719 pollutant Toxicity 0.000 abstract 1
- 239000002699 waste material Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 230000003009 desulfurizing effect Effects 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 2
- 239000007832 Na2SO4 Substances 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 235000019504 cigarettes Nutrition 0.000 description 2
- 230000009977 dual effect Effects 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 239000006028 limestone Substances 0.000 description 2
- 239000013535 sea water Substances 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical class [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003500 flue dust Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
- B01D53/1481—Removing sulfur dioxide or sulfur trioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D50/00—Combinations of methods or devices for separating particles from gases or vapours
- B01D50/60—Combinations of devices covered by groups B01D46/00 and B01D47/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1487—Removing organic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
- C02F2101/22—Chromium or chromium compounds, e.g. chromates
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/18—Nature of the water, waste water, sewage or sludge to be treated from the purification of gaseous effluents
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Treating Waste Gases (AREA)
Abstract
The invention discloses a kind of high atomization flue gas desulfurization processing method, it is characterised in that: aoxidizing first with buffer agent and both sexes and the pollutant absorption in flue gas removed by the method for spray atomizing, waste water continues with generation white carbon, middle Water Sproading utilizes.Present invention advantage compared with prior art is: the present invention provides a kind of and utilizes containing buffer agent, the liquid of amphoteric oxide, the method mixed by spray atomizing, absorb desorption sulfur dioxide in flue gas, nitrogen oxides and organic compound, reduce the pollution to air, water consumption is few, improve rate of sulphur expulsion, reduce production cost, and the method that after utilizing desulfurization, wastewater sedimentation method generates white carbon, reach solution desulfurization, waste water, Solid state fermentation, and obtain the preferable economic benefit and social benefit achieved many things at one stroke.
Description
Technical field
The present invention relates to fume treatment technical field, specifically refer to a kind of high atomization flue gas desulfurization processing method.
Background technology
Along with industrial expansion and the raising of people's living standard, environmental pollution is day by day serious and people to environmental problem also
Increasingly paying attention to, how improving environmental quality is the problem that people are solving always, China's sulfur dioxide and discharged nitrous oxides
Measuring huge, sulfur dioxide and nitrogen oxides are the main matter of environmental pollution, in order to process sulfur dioxide and the nitrogen oxidation of generation
Thing countries in the world exploitation desulphurization denitration technology be up to hundreds of, the current application on site of China mainly have limestone-gypsum, ammonia
The multiple desulphurization denitration technology such as method desulfurization, seawater method, Dual alkali.
Limestone-based process: being at present most in China's the method in order to desulfurization, reason is technology maturation, and raw material easily takes
, but consume substantial amounts of limestone resource, desulfurization produces substantial amounts of CO2, operating cost is high, investment greatly, easily block, easily cause
Secondary pollution；In waste discharge flue gas easily the lowest with the component efficiency containing Desulphurization, cause atmospheric pollution to increase the weight of.
Dual alkali: complex process, unmanageable, desulphurization denitration fluctuation are big, desulfurization afterproduct doped with various ash and
The more difficult life of NaSO4, NaSO4, need to constantly supplement NaOH, thus add the consumption of alkali, and waste residue is difficult.
Seawater method: easily polluted by heavy metals, limited by region, invest greatly.
Ammonia process: transport storage difficulty, complex process, investment are big.General medium-sized and small enterprises cannot invest.
Along with the environmental protection of desulphurization denitration is put more effort by China, a lot of technology have not caught up with the development of national conditions, and investment is big, work
Skill is complicated, waste residue utilization rate is low, power consumption is high, shipping storage is difficult, and easily causes haze formation, is badly in need of one and invests little, technique
Simply, Automated condtrol, the new desulfurizing and denitrifying process discharged without waste water and dregs it are prone to, in order to be adapted to large, medium and small multiple stove
The application of type.
Summary of the invention
The technical problem to be solved in the present invention be overcome above technological deficiency to provide one little, the technique of investment is simple, be prone to
Automated condtrol, the new desulfurizing and denitrifying process discharged without waste water and dregs, in order to be adapted to the application of the large, medium and small multiple type of furnace
A kind of high atomization flue gas desulfurization processing method.
For solving above-mentioned technical problem, the technical scheme that the present invention provides is: a kind of high atomization flue gas desulfurization processing method,
Comprise the following steps:
(1), choosing buffer agent and amphoteric oxide mixes with water as mixture, mixture concentration in water is 1 ‰
～5 ‰；
(2), fume pipe and spray atomizing tower or is dynamically connected except fog chamber, described spray atomizing tower or dynamically remove in fog chamber
Portion's structure mainly includes housing, is provided with at smoke inlet and is sequentially provided with sprinkler head, cold plate, flue gas sieve in described housing
Net, blower fan and exhanst gas outlet, the bottom of described housing is additionally provided with discharge outlet；Flue gas is carried out the most clear by spray atomizing
Washing, the flue gas after cleaning is condensed by the segmentation of cold plate, then makes flue gas enter flue gas screen cloth by negative pressure and screens out in flue gas
Dust granules, the flue gas after process is discharged from exhanst gas outlet；
(3), the sewage in step 2 is sent into detention tank, after precipitation, clear liquid is collected and enter next process；
(4) clear liquid, after precipitation is acid pickle, is mixed with sodium silicate solution by acid pickle, and the material of generation is adsorbable to give up
The heavy metals such as cadmium in water, hydrargyrum, lead, chromium；
(5), being separated from water by the precipitate in step 4, the middle water separated may be used on, in step 1, playing circulation
The purpose utilized；
(6), the precipitate of isolated in step 5 is dried obtains white carbon；
Described buffer agent is citric acid, sodium citrate, ferrous sulfate, zinc sulfate, and described amphoteric oxide is oxidation
Zinc, magnesium oxide.
The wash tub pipe for rinsing flue gas screen cloth 4 it is additionally provided with in described housing 1.
The buffer agent used is sodium citrate, and amphoteric oxide used is zinc oxide.
Present invention advantage compared with prior art is: the present invention provides a kind of and utilizes containing buffer agent, both sexes oxidation
The liquid of thing, the method mixed by spray atomizing, absorb desorption sulfur dioxide in flue gas, nitrogen oxides and organic compound,
Reducing the pollution to air, water consumption is few, improves rate of sulphur expulsion, reduces production cost, and utilizes wastewater sedimentation method life after desulfurization
The method becoming white carbon, has reached solution desulfurization, waste water, Solid state fermentation, and obtain the preferable economic benefit achieved many things at one stroke and
Social benefit.
Accompanying drawing explanation
Fig. 1 is the process chart of the present invention a kind of high atomization flue gas desulfurization processing method.
Fig. 2 is the structural representation of the present invention a kind of high atomization flue gas desulfurization processing method.
As shown in the figure: 1, housing, 2, sprinkler head, 3, cold plate, 4, flue gas screen cloth, 5, blower fan, 6, exhanst gas outlet, 7, draining
Mouthful, 8, smoke inlet, 9, flue gas screen cloth rotating shaft.
Detailed description of the invention
The present invention is described in further detail with embodiment below in conjunction with the accompanying drawings.
Current domestic desulphurization denitration technology has obtained rapid progress, high efficiency, low cost, more conveniently desulfurizing agent also meet the tendency and
Raw, but after desulfurization, waste water solves without good way, and after desulfurization, waste residue is more intractable, and heavy metals content is higher.
A kind of high atomization flue gas desulfurization processing method, it is characterised in that: comprise the following steps:
(1), choose sodium citrate and zinc oxide mixes with water as mixture, mixture concentration in water be 1 ‰～
5‰；
(2), fume pipe and spray atomizing tower or is dynamically connected except fog chamber, described spray atomizing tower or dynamically remove in fog chamber
Portion's structure mainly includes housing 1, is provided with at smoke inlet and is sequentially provided with sprinkler head 2, cold plate 3, flue gas in described housing 1
Screen cloth 4, blower fan 5 and exhanst gas outlet 6, the bottom of described housing 1 is additionally provided with discharge outlet 7；By spray atomizing, flue gas carried out
Once cleaning, the flue gas after cleaning is condensed by the segmentation of cold plate, then makes flue gas enter flue gas screen cloth by negative pressure and screens out cigarette
Dust granules in gas, the flue gas after process is discharged from exhanst gas outlet；
(3), the sewage in step 2 is sent into detention tank, after precipitation, clear liquid is collected and enter next process；
(4) clear liquid, after precipitation is acid pickle, is mixed with sodium silicate solution by acid pickle, and the material of generation is adsorbable to give up
The heavy metals such as cadmium in water, hydrargyrum, lead, chromium；
(5), being separated from water by the precipitate in step 4, the middle water separated may be used on, in step 1, playing circulation
The purpose utilized；
(6), the precipitate of isolated in step 5 is dried obtains white carbon；
The wash tub pipe for rinsing flue gas screen cloth 4 it is additionally provided with in described housing 1.
Sodium citrate, zinc oxide are as follows with the reaction formula of flue gas:
SO2+RCOONa+H2O→NaHSO3+RCOOH
NaHSO2+1/2O2+RCOONa→Na2SO4+RCOOH
ZnO+SO2+2.5H2O→ZnSO3·2.5H2O
ZnO+2SO2+H2O→Zn(HSO3)2
After desulfurization, acid pickle is as follows with sodium silicate solution precursor reactant formula:
Na2O·nSiO2+H2SO4→Na2SO4+nSiO3·H2O
White carbon is used for the sector application such as coating, rubber, and middle water can continue reuse, reaches to cause secondary dirty without waste water and dregs
The purpose of dye.
In a particular embodiment, long in time limit due to spray atomizing tower cost height, it is adaptable to large-scale flue gas desulfurization, for little
The flue gas desulfurization of type can use dynamically except fog chamber, dynamically can the size of desulfurization fume amount according to specific needs set except fog chamber
Fixed, low cost.
Flue gas enters spray atomizing tower or dynamically except fog chamber, carries out cleaning for the first time to flue gas by spray atomizing, due to
Containing moisture in flue gas after cleaning, can will be discharged after the condensate moisture in flue gas by cold plate, flue gas enters dynamic screen cloth
Dust granules in flue gas can be separated, mesh density can be set according to the smoke density processed, by power set (electricity
Machine) drive dynamic screen cloth to rotate, dynamic screen cloth is again to flue gas and filtering dust, and the droplet of condensation throws tank wall by rotation, for
Avoid the strong adsorptivity of flue dust, wash tub pipe is installed in housing, automatically screen cloth carried out variable interval according to pressure change clear
Washing, sewage is discharged by discharge outlet, is sent to detention tank, and after precipitation, clear liquid enters next operation use, reaches to control cigarette
The purpose that in gas, dust and droplet dam.
The present invention process to flue gas, does not has waste water, waste residue, non-secondary pollution, and treatment effect is preferable.
Being described the present invention and embodiment thereof above, this description does not has restricted, shown in accompanying drawing yet
Simply one of embodiments of the present invention, actual structure is not limited thereto.If the generally speaking ordinary skill of this area
Personnel are enlightened by it, in the case of without departing from the invention objective, design and this technical scheme phase without creative
As frame mode and embodiment, protection scope of the present invention all should be belonged to.
Claims (3)
1. a high atomization flue gas desulfurization processing method, it is characterised in that: comprise the following steps:
(1), choose buffer agent and amphoteric oxide mixes with water as mixture, mixture concentration in water be 1 ‰～
5‰；
(2), fume pipe and spray atomizing tower or is dynamically connected except fog chamber, described spray atomizing tower or dynamically remove fog chamber internal junction
Structure mainly includes housing (1), be provided with at smoke inlet in described housing (1) be sequentially provided with sprinkler head (2), cold plate (3),
Flue gas screen cloth (4), blower fan (5) and exhanst gas outlet (6), the bottom of described housing (1) is additionally provided with discharge outlet (7)；By spray mist
Changing and carry out flue gas cleaning for the first time, the flue gas after cleaning is condensed by the segmentation of cold plate, then makes flue gas enter by negative pressure
Flue gas screen cloth screens out the dust granules in flue gas, and the flue gas after process is discharged from exhanst gas outlet；
(3), the sewage in step 2 is sent into detention tank, after precipitation, clear liquid is collected and enter next process；
(4), precipitation after clear liquid be acid pickle, acid pickle is mixed with sodium silicate solution, in the adsorbable waste water of material of generation
Cadmium, hydrargyrum, lead, the heavy metal such as chromium；
(5), being separated from water by the precipitate in step 4, the middle water separated may be used on, in step 1, playing and recycling
Purpose；
(6), the precipitate of isolated in step 5 is dried obtains white carbon；
Described buffer agent is citric acid, sodium citrate, ferrous sulfate, zinc sulfate, and described amphoteric oxide is zinc oxide, oxygen
Change magnesium.
A kind of high atomization flue gas desulfurization processing method the most according to claim 1, it is characterised in that: described housing (1)
Inside it is additionally provided with the wash tub pipe for rinsing flue gas screen cloth (4).
A kind of high atomization flue gas desulfurization processing method the most according to claim 1, it is characterised in that: the buffer agent used
For sodium citrate, amphoteric oxide used is zinc oxide.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106731608A (en) * | 2017-01-04 | 2017-05-31 | 长沙汇聚环境技术有限公司 | A kind of administering method of waste gas containing lead |
| CN107051152A (en) * | 2017-01-04 | 2017-08-18 | 长沙汇聚环境技术有限公司 | A kind of method of the leaded treating flour dust of sintering machine wet desulfurization flue gas |
| CN108043198A (en) * | 2017-12-06 | 2018-05-18 | 安徽凤阳赛吉元无机材料有限公司 | A kind of method for preparing doctor solution using waterglass water quenching water |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101530730A (en) * | 2009-04-17 | 2009-09-16 | 华东理工大学 | Method for simultaneously treating waste gas pollution of NOX and SO2 |
| CN201815236U (en) * | 2010-10-13 | 2011-05-04 | 中国石油化工股份有限公司 | Gas-liquid cross-flow contact device |
| CN205269381U (en) * | 2015-11-25 | 2016-06-01 | 龙南县京利有色金属有限责任公司 | Aeration tower on europia production line |
-
2016
- 2016-08-04 CN CN201610634341.3A patent/CN106215626A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101530730A (en) * | 2009-04-17 | 2009-09-16 | 华东理工大学 | Method for simultaneously treating waste gas pollution of NOX and SO2 |
| CN201815236U (en) * | 2010-10-13 | 2011-05-04 | 中国石油化工股份有限公司 | Gas-liquid cross-flow contact device |
| CN205269381U (en) * | 2015-11-25 | 2016-06-01 | 龙南县京利有色金属有限责任公司 | Aeration tower on europia production line |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106731608A (en) * | 2017-01-04 | 2017-05-31 | 长沙汇聚环境技术有限公司 | A kind of administering method of waste gas containing lead |
| CN107051152A (en) * | 2017-01-04 | 2017-08-18 | 长沙汇聚环境技术有限公司 | A kind of method of the leaded treating flour dust of sintering machine wet desulfurization flue gas |
| CN108043198A (en) * | 2017-12-06 | 2018-05-18 | 安徽凤阳赛吉元无机材料有限公司 | A kind of method for preparing doctor solution using waterglass water quenching water |
| CN108355464A (en) * | 2018-04-27 | 2018-08-03 | 马鞍山金安环境科技有限公司 | A kind of stuffing spray-washing sewage deodorizing device |
| CN108355464B (en) * | 2018-04-27 | 2024-07-16 | 马鞍山金安环境科技有限公司 | Filling type spraying and washing sewage deodorizing device |
| CN112772972A (en) * | 2019-11-06 | 2021-05-11 | 上海新型烟草制品研究院有限公司 | Water smoke filters smoking set |
| CN112772972B (en) * | 2019-11-06 | 2025-03-18 | 上海新型烟草制品研究院有限公司 | A water mist filtering smoking device |
| CN120204909A (en) * | 2025-03-31 | 2025-06-27 | 江苏敏禾科技有限公司 | Industrial flue gas water glass desulfurization device and desulfurization method |
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