CN106149467A - A kind of friction variable color or roll wipe look cheque paper and manufacture method thereof - Google Patents

A kind of friction variable color or roll wipe look cheque paper and manufacture method thereof Download PDF

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Publication number
CN106149467A
CN106149467A CN201510127518.6A CN201510127518A CN106149467A CN 106149467 A CN106149467 A CN 106149467A CN 201510127518 A CN201510127518 A CN 201510127518A CN 106149467 A CN106149467 A CN 106149467A
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China
Prior art keywords
paper
color
roll
variable color
friction variable
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Pending
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CN201510127518.6A
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Chinese (zh)
Inventor
李尧
樊鹏
樊官保
马海龙
卫晋豪
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Individual
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Individual
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Priority to CN201510127518.6A priority Critical patent/CN106149467A/en
Publication of CN106149467A publication Critical patent/CN106149467A/en
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Abstract

The present invention relates to friction variable color or roll look cheque paper of wiping, it is by the variable color or roll and draw the sizing composition of off-color material or coating composition obtains at paper surface of will comprising to rub in paper technology, wherein said friction variable color or roll and draw 0.01-30 weight % that off-color material accounts for described sizing composition or coating composition weight.Cheque paper surface of the present invention has friction variable color or rolls a stroke colour change function;This cheque paper all without producing color change, has only with harder lubricious material friction or rolls stroke this anti-forge paper surface when presswork or when paper carries or when external force pushes or when cutting with cutting knife, and paper surface i.e. can be observed obvious color and changes.

Description

A kind of friction variable color or roll wipe look cheque paper and manufacture method thereof
Technical field
The present invention relates to field of anti-counterfeit technology, particularly relate to friction variable color or roll wipe look cheque paper and Manufacture method.
Background technology
The manufacture method of anti-forge paper is a lot, as add various special artificial or natural fiber safety paper, Add altering prevention paper, heat-sensitive color-changing paper that various different chemical material makes etc..
Chinese patent application CN104404835A, provide a kind of cheque paper using body paper to make and Its preparation technology, discloses a kind of technique using body paper to make cheque paper, first by transparent laser film Coating high transparency UV gloss oil, is then combined with body paper, solidifies under uv lamps, dry, by transparent Laser film is peeled off, and obtains transparent highlighted radium-shine paperboard, aluminium coated and light oil reservoir, is then coated with overleaf Humidification layer, cuts, obtains finished product.
Chinese patent application CN104264528A, provides a kind of Novel anti-counterfeit paper and preparation method thereof, Disclose a kind of Novel anti-counterfeit paper and preparation method thereof, use anti-counterfeit paint to coat one layer at paper surface False proof layer, described anti-counterfeit paint is made up of following component by weight percentage: precipitated calcium carbonate 20-40 %, kaolin 15-35%, water repellent agent 1-5%, carboxylic styrene butadiene latex 10-21%, dispersant 3-5%, Rare earth anti-false fiber 2-5%, balance of water, the preparation method of described rare earth anti-false fiber is: (1) adopts It is blended with modified Nano rare earth oxide and high polymer, obtain high polymer earth blend thing, Gao Ju In thing earth blend thing, the content of modified Nano rare earth oxide is 0.5-3%;(2) by step (1) High polymer earth blend thing;(3) fiber obtaining after step (2) melt spinning is prepared short fibre.
This area there is also a kind of anti-paper of divulging a secret, and i.e. surface is through the paper of specially treated.In need for confidentiality Place, only need to be with supporting special pen---scriber divides out.This ink is transparent Colourless, contact with paper and can produce a complicated decorative pattern.Decorative pattern does not hinder the reading of article, but meeting Destroy the normal work of duplicator sensing element, make the local appearance of the secrecy in the article after duplicating one Black-tape, thus reach the purpose of secrecy.
Chinese patent application CN104264532A, provides a kind of procrypsis anti-counterfeit paint and procrypsis is false proof Paper, discloses a kind of procrypsis anti-counterfeit paint and applies the procrypsis cheque paper of this coating, and described procrypsis is false proof Its formula of coating mainly includes each component of following weight portion: leuco dye 1~25 part, developer 1~ 24 parts, auxiliary agent 5~20 parts, filler 97~210 parts, adhesive 50~120 parts;Described procrypsis is prevented Pseudo-coating is prepared according to the method comprising the steps of: be uniformly dispersed leuco dye and part of auxiliary, It is wrapped in described leuco dye in microcapsules by encapsulation technique, prepare and be dispersed with micro-glue The suspension of capsule;Then add filler, developer, adhesive, residue auxiliary agent in described suspension And fully mix.
Chinese patent application CN103966919A, provides a kind of multi-layer colour-changing anti-fake paper, discloses A kind of multi-layer colour-changing anti-fake paper, including paper and the translucent anti false film with picture and text, character, institute State translucent anti false film and there is color A, the picture and text on described translucent anti false film, character have with Color A of translucent anti false film has color B of sharp contrast, and described translucent anti false film is at paper Formed with translucent anti false film in the middle of the different paper of two thickness false proof is discharged during papermaking process Paper, the described anti-forge paper with translucent anti false film by relatively thin one side at natural light naked eyes Observe the picture and text on lower half transparent counterfeiting film, character is color C, visually observes translucent when printing opacity Picture and text on anti false film, character are color D, are visually observed half when printing opacity by relatively thick one side Picture and text on transparent counterfeiting film, character are color E.Here by by with picture and text, character semi-transparent Bright anti false film discharges in the middle of the different paper of two layers of thickness, observes paper by natural light and printing opacity mode Opening two sides, the picture and text on translucent anti false film, character can show three kinds of different colors, thus increase The antiforge function of strong paper.
Chinese patent application CN103757987A, provides a kind of MULTIPLE COMPOSITE type cheque paper and system thereof Make method, disclose a kind of MULTIPLE COMPOSITE type cheque paper and manufacture method thereof, with watermark in its paper, The surface of paper becomes pattern with personalized phosphor pattern or temperature or light becomes pattern or temperature becomes fluorescent dual Composite anti-fake pattern, anti-counterfeiting information is loaded in the pattern of personalization.Herein by false proof for paper production with Information transfer anti-counterfeiting technology organically combines when paper production, produces both with paper production Anti-counterfeiting technology is again with the cheque paper of MULTIPLE COMPOSITE anti-counterfeiting technology of surface anti-counterfeiting information.
Chinese patent application CN103628358A, provides a kind of Double-colour horn wire cheque paper and production method, Disclose a kind of Double-colour horn wire cheque paper and production method, body paper adds chromonic materials and colour development material; Two kinds of chromonic material colourless under normal circumstances, a kind of encapsulation that uses, another kind of through grinding Process.At paper after the link friction that rows dry, utilize the small heat producing, colour development material in paper In electronq donor material with ground become granular chromonic materials moment melt, occur chemistry anti- Answer and color development;When firmly ruling on paper, contain the microcapsules rupture of another chromonic materials, Chromonic materials flows out, and with the electronq donor material generation chemical reaction in colour development material and color development, produces Another color raw.On paper, two kinds of different colours lines are thus produced because score pressure is different, Reach false proof purpose.
Chinese patent application CN203174438U, provides a kind of pressure-sensitive cheque paper of variable color, practical new Type relates to the field being coated between page by material, a kind of pressure-sensitive cheque paper of variable color, including common paper Layer (1), a side surface of common ply of paper (1) is provided with coloured power and becomes security coating (2), and this is coloured Power becomes security coating (2) top impressing and becomes coloured power change security pattern.
Chinese patent application CN102304878A provides a kind of use environment-friendly type azoic dyes insoluble azo dyes The developing anti-fake paper manufacturing and preparation method, disclose a kind of use environment-friendly type azoic dyes insoluble azo dyes system The preparation method of the developing anti-fake paper made, uses following steps to prepare: (1) carries out defibrination to slurry, Use fiber dissociation device that slurry is fully dispersed;(2) in slurry, add azoic coupling component dyestuff, continue dispersion, Azoic coupling component dyestuff is made to be uniformly dispersed in the slurry;(3) in slurry, sizing solution and oxidized starch are added, Continue dispersion;(4) slurry is poured in handsheet machine, carry out handsheet, obtain l Water Paper page;(5) from copying Take off l Water Paper page on the copper mesh of piece machine to be placed in woollen blanket, woollen blanket is placed in hydraulic press and squeezes;(6) It is placed on the l Water Paper page having squeezed in drier and carry out being vacuum dried the paper substrate obtaining with azoic coupling component dyestuff; (7) color base dyestuff diazotising is obtained color base liquid, color base liquid is coated on the paper substrate with azoic coupling component dyestuff; (8) paper substrate is placed in drying box drying, i.e. obtains described developing anti-fake paper.
Banker's check altering prevention paper, adds special chemical raw material in papermaking process, with not Same chemical reagent is smeared, and manifests different colors, reaches anti-correction purpose.
But there is not yet friction variable color in the prior art or roll look cheque paper of wiping.
Content of the invention
It is an object of the invention to provide a kind of friction variable color or roll look cheque paper and preparation method thereof of wiping. The antifalse effect of paper of the present invention is good and prepares simple, conveniently.
The invention provides a kind of friction variable color or roll look cheque paper of wiping, it is by paper technology To comprise to rub variable color or roll and draw the sizing composition of off-color material or coating composition at paper Surface and obtain, wherein said friction variable color or roll draw an off-color material account for described sizing composition or painting 0.01-30 weight % of feed composition weight.
The friction variable color of the present invention or roll look cheque paper of wiping, is different from fluorescent anti-forge paper, temperature-sensitive false proof Paper, fluorescent fiber cheque paper etc., the light fastness of this cheque paper is fine, friction variable color or roll look of wiping Material manufacture paper with pulp into paper after the term of validity more than 20 years and preparation method is simple.
Detailed description of the invention
The friction variable color of the present invention or roll look cheque paper of wiping, its outward appearance can be the anti-of colorless or colored Pseudo-paper, the so-called colourless appearance color referring to cheque paper detects by an unaided eye and is hardly visible color;So-called Coloured appearance color referring to cheque paper detects by an unaided eye and can clearly recognize color.Through friction of exerting oneself Or after rolling and drawing, with the naked eye clearly recognizable can there are other colors different from paper color in paper surface, For example red.
The friction variable color of the present invention or roll look cheque paper of wiping and become by friction will be comprised in paper technology Look or roll and draw the sizing composition of off-color material or coating composition obtains at paper surface, Wherein said friction variable color or roll draw an off-color material account for described sizing composition or coating composition weight 0.01-30 weight %.Described sizing composition or the painting comprising friction variable color or rolling stroke off-color material Material that feed composition uses except normal (as calcium carbonate, kaolin, water soluble starch, adhesive, Auxiliary agent, water etc.) outward, possibly together with 0.01-30 weight % friction variable color or roll draw an off-color material.And After with the addition of friction variable color or roll stroke off-color material in sizing composition or coating composition, friction Variable color or roll draw an off-color material do not change the sizing composition in known papermaking process or coating group The function of compound, is only to the sizing composition in known papermaking process or coating composition Increase a friction variable color or roll a stroke colour change function.
According to one embodiment of the invention, described friction variable color or roll look cheque paper of wiping and used Friction variable color or roll draw an off-color material be non-chemical stain microcapsules.Described microcapsules light fastness exists More than 3 grades (International Wool sun-proof classification standards).Described microcapsules are with the hot polymerization producing microcapsules Resin (such as melamine formaldehyde resin) is by the colored pigment being dissolved in high boiling solvent or dyestuff (state Pigment more than 3 grades for the border wool sun-proof classification standard or dyestuff, such as oil red) it is rolled into microcapsules. The appearance color of microcapsules is shallow as far as possible, and the particle size of microcapsules can not affect the skill of paper technology Art requires.
According to one embodiment of the invention, friction variable color or roll draw an off-color material be series pigments or Based dye etc..
Described friction variable color or roll look cheque paper of wiping, nondiscolouring (this under having the pressurization of bigger gravity Point is different from chemical stain).Even above-mentioned hot polymerizable resin (such as melamine formaldehyde resin) By the colored pigment being dissolved in high boiling solvent or dyestuff (International Wool sun-proof classification standard 3 grades with On pigment or dyestuff) microcapsules that are rolled into, cheque paper when presswork or during paper carrying or When external force pushes, cheque paper surface, all without producing color change, has only and is used by harder smooth object Color change is produced, as with the rubbed variable color of scratching of the edge of coin or roll and draw the present invention and prevent during power scratching Pseudo-paper surface, paper surface is become the visibly different color with paper color by colourless or light colour, Such as redness;Or paper surface is become redness etc. by green phase-black discoloration.Additionally due to the particle diameter of microcapsules is little In paper sheet thickness, when cutting with cutting knife, cheque paper surface changes all without producing color.
Friction variable color in described papermaking process or roll wipe look sizing composition or Coating material composition Thing, refers to the sizing composition in single gummed paper or wood-free paper or coating paper production process or Coating material composition Thing.
In a preferred embodiment of the invention, described friction variable color or roll draw an off-color material account for institute State 0.05-15 weight % of sizing composition or coating composition weight, preferably 0.1-10 weight %, More preferably 0.2-5 weight %.
The present invention also provides a kind of method preparing cheque paper of the present invention, and it includes sizing composition Or coating composition and friction variable color or roll and draw an off-color material and mix and grind;Ground comprising is rubbed Wipe variable color or roll and draw the sizing composition of off-color material or coating composition at paper surface;So After coated paper is dried to obtain described cheque paper.The inventive method is simple, can be with successful Application In the paper making technique of prior art.
Example below illustrates the present invention, but present disclosure is not limited to embodiment.
Embodiment 1
Sizing composition (comprises water soluble starch, adhesive, auxiliary agent, water)
99.5 weight %
Friction variable color or roll draw off-color material (black) 0.5 weight %
Add up to 100 weight %
By sizing composition 99.5 parts with friction variable color or roll draw an off-color material 0.5 part mix, through grinding Grinding machine is ground to required particle diameter, and barrelling is standby.Ground friction variable color or roll look sizing agent of wiping Composition is coated in paper surface, and coated weight is performed by normal paper production technique.Coated paper is through drying The technique such as dry, completes friction variable color or the production rolling look cheque paper of wiping.With coin rim friction or roll Drawing anti-forge paper surface, paper surface can be observed obvious redness.
Embodiment 2
Coating composition (comprises calcium carbonate, kaolin, water soluble starch, adhesive, auxiliary agent, water etc.)
98 weight %
Friction variable color or roll draw off-color material (microcapsules) 2 weight %
Add up to 100 weight %
Described microcapsules are the oil soluble red packets being dissolved in high boiling solvent with melamine formaldehyde resin Microcapsules obtained by wrapping up in.
By coating composition 98 parts with friction variable color or roll draw an off-color material 2 parts mix, ground machine grinds Being ground to required particle diameter, barrelling is standby.Ground friction variable color or roll look coating composition of wiping is applied Overlaying on paper surface, coated weight is performed by normal paper production technique.The techniques such as coated paper drying, Complete friction variable color or the production rolling look cheque paper of wiping.With coin rim friction or roll draw an anti-forge paper Surface, paper surface can be observed obvious redness.

Claims (8)

1. rub variable color or roll a look cheque paper of wiping, and it will be by will comprise to rub in paper technology Variable color or roll and draw the sizing composition of off-color material or coating composition obtains at paper surface Arrive, wherein said friction variable color or roll draw an off-color material account for described sizing composition or coating composition 0.01-30 weight % of weight.
2. friction variable color or roll look cheque paper of wiping according to claim 1, it is characterised in that Its outward appearance is the cheque paper of colorless or colored.
3. friction variable color or roll look cheque paper of wiping according to claim 1 and 2, its feature exists In, described friction variable color or roll draw an off-color material be non-chemical stain microcapsules.
4. friction variable color or roll look cheque paper of wiping according to claim 1 and 2, its feature exists In, described friction variable color or roll draw an off-color material be series pigments or based dye.
5. the friction variable color according to according to any one of claim 1-4 or roll look cheque paper of wiping, its Being characterised by, this cheque paper is when presswork or when paper carries or when external force pushes or uses cutting knife When cutting, cheque paper surface, all without producing color change, has only and is firmly drawn by harder smooth object Color change is produced during wiping.
6. the friction variable color according to according to any one of claim 1-5 or roll look cheque paper of wiping, its Be characterised by, described friction variable color or roll draw an off-color material be present in described cheque paper papermaking process In sizing composition or coating composition in, and described sizing composition or coating composition divide Do not refer to the sizing composition in single gummed paper or wood-free paper or coating paper production process or Coating material composition Thing.
7. the friction variable color according to according to any one of claim 1-6 or roll look cheque paper of wiping, its Described in friction variable color or roll and draw off-color material and account for described sizing composition or coating composition weight 0.05-15 weight %, preferably 0.1-10 weight %, more preferably 0.2-5 weight %.
8. the friction variable color according to according to any one of claim 1-7 or roll look cheque paper manufacture of wiping Method, it includes sizing composition or coating composition and friction variable color or rolls and draw an off-color material and mix Merge and grind;Ground is comprised rub variable color or sizing composition or the painting of rolling stroke off-color material Feed composition is coated in paper surface;Then coated paper is dried to obtain described cheque paper.
CN201510127518.6A 2015-03-23 2015-03-23 A kind of friction variable color or roll wipe look cheque paper and manufacture method thereof Pending CN106149467A (en)

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CN201510127518.6A CN106149467A (en) 2015-03-23 2015-03-23 A kind of friction variable color or roll wipe look cheque paper and manufacture method thereof

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Application Number Priority Date Filing Date Title
CN201510127518.6A CN106149467A (en) 2015-03-23 2015-03-23 A kind of friction variable color or roll wipe look cheque paper and manufacture method thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109835084A (en) * 2017-11-27 2019-06-04 吴宁飞 Application of the antifalse material in anti-fake payment and currency security, bank card etc.
CN114592378A (en) * 2022-03-04 2022-06-07 浙江一树纸业集团有限公司 Temperature-variable anti-counterfeiting paperboard and production process thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008143009A (en) * 2006-12-08 2008-06-26 Mitsubishi Paper Mills Ltd Curtain coating dispersion and single layer-type self-coloring pressure sensitive recording paper using this dispersion
CN101410465A (en) * 2006-03-27 2009-04-15 资讯卡有限公司 Printing inks with property enhancing microcapsules
CN104109421A (en) * 2013-04-16 2014-10-22 北京万垟防伪技术有限责任公司 Non-reactive dash chromatic ink
CN104264532A (en) * 2014-09-26 2015-01-07 广东冠豪高新技术股份有限公司 Leuco anti-counterfeiting coating and leuco anti-counterfeiting paper

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101410465A (en) * 2006-03-27 2009-04-15 资讯卡有限公司 Printing inks with property enhancing microcapsules
JP2008143009A (en) * 2006-12-08 2008-06-26 Mitsubishi Paper Mills Ltd Curtain coating dispersion and single layer-type self-coloring pressure sensitive recording paper using this dispersion
CN104109421A (en) * 2013-04-16 2014-10-22 北京万垟防伪技术有限责任公司 Non-reactive dash chromatic ink
CN104264532A (en) * 2014-09-26 2015-01-07 广东冠豪高新技术股份有限公司 Leuco anti-counterfeiting coating and leuco anti-counterfeiting paper

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109835084A (en) * 2017-11-27 2019-06-04 吴宁飞 Application of the antifalse material in anti-fake payment and currency security, bank card etc.
CN114592378A (en) * 2022-03-04 2022-06-07 浙江一树纸业集团有限公司 Temperature-variable anti-counterfeiting paperboard and production process thereof

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Application publication date: 20161123