CN106145766A - A kind of material repairing pottery porcelain body - Google Patents
A kind of material repairing pottery porcelain body Download PDFInfo
- Publication number
- CN106145766A CN106145766A CN201510201823.5A CN201510201823A CN106145766A CN 106145766 A CN106145766 A CN 106145766A CN 201510201823 A CN201510201823 A CN 201510201823A CN 106145766 A CN106145766 A CN 106145766A
- Authority
- CN
- China
- Prior art keywords
- porcelain body
- epoxy resin
- porcelain
- pottery porcelain
- particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052573 porcelain Inorganic materials 0.000 title claims abstract description 34
- 239000000463 material Substances 0.000 title claims abstract description 25
- 239000003822 epoxy resin Substances 0.000 claims abstract description 21
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 15
- 230000000977 initiatory effect Effects 0.000 claims abstract description 13
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910000077 silane Inorganic materials 0.000 claims abstract description 11
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 7
- 239000000945 filler Substances 0.000 claims abstract description 7
- 239000002245 particle Substances 0.000 claims description 73
- 239000000203 mixture Substances 0.000 claims description 26
- 239000005995 Aluminium silicate Substances 0.000 claims description 24
- 235000012211 aluminium silicate Nutrition 0.000 claims description 24
- 239000003795 chemical substances by application Substances 0.000 claims description 24
- 150000001768 cations Chemical group 0.000 claims description 23
- 239000010453 quartz Substances 0.000 claims description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 22
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims description 21
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 20
- 230000008569 process Effects 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 7
- 238000000227 grinding Methods 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 3
- 230000007547 defect Effects 0.000 abstract description 8
- 230000008439 repair process Effects 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 4
- 238000007639 printing Methods 0.000 abstract description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 abstract description 3
- 239000002131 composite material Substances 0.000 abstract description 2
- 125000002091 cationic group Chemical group 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 230000004048 modification Effects 0.000 abstract 1
- 238000012986 modification Methods 0.000 abstract 1
- 230000007306 turnover Effects 0.000 abstract 1
- 239000000843 powder Substances 0.000 description 7
- 239000008187 granular material Substances 0.000 description 5
- 229910000323 aluminium silicate Inorganic materials 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 4
- 230000005540 biological transmission Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000004308 accommodation Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
Landscapes
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses a kind of material repairing pottery porcelain body, by weight percentage, epoxy resin 35～50%, auxiliary agent 0.1～5%, filler 45～65%, the present invention uses silane coupler to carry out surface modification to repairing material therefor, make it and with the epoxy resin of thermal initiation cationic curing, there is good affinity, using Gypsum Fibrosum overmolded, prepare the shape of porcelain porcelain body defect, and mould is close to the position being fixed on porcelain porcelain body defect, make and repair body again.The most general way is with Gypsum Fibrosum or to be filled with the porcelain body that talcous epoxy resin composite material passes through the method duplication porcelain defect of turn over the mold type.This way can restore the shape of porcelain body defect exactly, but the effect of its sound tapped and printing opacity exists significant difference with genuine piece.It is contemplated that manufacture a kind of shape that can not only restore porcelain body defect exactly, and the effect of the sound that taps and printing opacity is close with genuine piece, has high intensity, high verisimilitude.
Description
Technical field
The present invention relates to field of fine chemical, particularly relate to a kind of material repairing pottery porcelain body.
Background technology
The most general way is with Gypsum Fibrosum or to be filled with talcous epoxy resin composite material by turning over
The method of mold forming replicates the porcelain body of porcelain defect.This way can restore porcelain body defect exactly
Shape, but there is significant difference in effect and the genuine piece of its sound tapped and printing opacity, it is impossible to meets Gu
The prescription that porcelain is repaired by pottery trade market.
Present invention
In view of the repair materials of current pottery exists above-mentioned deficiency, the present invention provides the one can not only
Enough shapes restoring porcelain body defect the most exactly, and the effect of the sound that taps and printing opacity connects with genuine piece
Near material, the texture presenting old china device itself as much as possible.
For reaching above-mentioned purpose, the present invention adopts the following technical scheme that
A kind of material repairing pottery porcelain body, is made up of following component by weight percentage:
Epoxy resin 35～50%；
Auxiliary agent 0.1～5%；
Filler 45～65%；
Preferably, following component composition by weight percentage:
Epoxy resin 49%；
Auxiliary agent 1%；
Filler 50%；
Preferably, described auxiliary agent is cation curing agent and thermal initiation cation curing agent；
Preferably, described filler is by quartz particles, aluminum silicate particles, kaolin particle extremely
Few one；
Preferably, described quartz particles particle diameter is 1～10um, and described aluminum silicate particles particle diameter is
5～20um, described kaolin particle particle diameter is 1～20um；
Preferably, described quartz particles, aluminum silicate particles, kaolin particle silane coupler
Process；
The preparation method of a kind of material repairing pottery porcelain body, comprises the following steps, is not limited to following sequence,
Epoxy resin solidifies in advance with cation curing agent, obtains the first mixture；
Described first mixture mixes with the stirring of thermal initiation cation curing agent, obtains the second mixture；
Grind quartz particles, aluminum silicate particles, kaolin particle；
The quartz particles after described grinding, aluminum silicate particles, kaolin particle is processed with silane coupler；
Quartz particles that described second mixture processes with silane coupler with described again, aluminium silicate
Grain, kaolin particle mix and blend
First mixture of the present invention is obtained by epoxy resin solidifies in advance with cation curing agent
Mixture,
Second mixture of the present invention is the first described mixture and thermal initiation cation curing agent
Mixture obtained by stirring mixing,
Advantages of the present invention has: 1, the epoxy resin used by the present invention processes with cation curing agent in advance,
Mixing with the stirring of thermal initiation cation curing agent, after obtained material solidification, intensity is obviously improved.
2, the powder body grinding size controlling used by the present invention is within the scope of certain, can make the ceramic surface of reparation
Feel is as good as with genuine piece.3, the silane coupler of powder body used by the present invention processes, the powder body energy after process
With epoxy resin, there is more preferable affinity, do not appear in after stirring parks, sedimentation layering occurs
Situation, and during subsequent cure, the pottery of reparation can be made to repair position and not repair position
Intensity keep consistent.4, the powder body used by the present invention selects quartz particles, aluminum silicate particles, Kaolin
Granule, has the strongest particle diameter complementary between them.5, pottery is repaired with the material of the present invention,
By the process control of diameter of particle, powder body processed with silane coupler and to epoxy resin, always
Technical scheme, reached the pottery making reparation repair position tap sound and light transmission in terms of with
Genuine piece is as good as substantially.6, the present invention serves positive impetus to the protection of ancient pottery and porcelain.
Detailed description of the invention
Below in conjunction with embodiment, further illustrate present disclosure.Should be appreciated that the reality of the present invention
Execute and be not limited to the following examples, any pro forma accommodation that the present invention is done and/or
Change and fall within scope.
In the present invention, if not refering in particular to all of equipment and raw material etc. and being all commercially available or the industry
Commonly use.Method in following embodiment, if no special instructions, is the conventional method of this area.
Embodiment 1
A kind of material repairing pottery porcelain body, component proportion is as follows, 35kg epoxy resin, 2.5kg cation
Firming agent, 2.5kg thermal initiation cation curing agent, the quartz particles of 60kg
Embodiment 2
A kind of material repairing pottery porcelain body, component proportion is as follows, 50kg epoxy resin, 0.05kg positive from
Sub-firming agent, 0.05kg thermal initiation cation curing agent, the quartz particles of 20kg, 29.9kg aluminium silicate
Granule
Embodiment 3
A kind of material repairing pottery porcelain body, component proportion is as follows, 50kg epoxy resin, and 2kg cation is solid
Agent, 3kg thermal initiation cation curing agent, the quartz particles of 10kg, 10kg aluminum silicate particles, 25kg
Kaolin particle
Embodiment 4
A kind of material repairing pottery porcelain body, component proportion is as follows, 30kg epoxy resin, and 2kg cation is solid
Agent, 3kg thermal initiation cation curing agent, the quartz particles of 20kg, 20kg aluminum silicate particles, 25kg
Kaolin particle
Embodiment 5
A kind of material repairing pottery porcelain body, component proportion is as follows, 49kg epoxy resin, 0.5kg cation
Firming agent, 0.5kg thermal initiation cation curing agent, the quartz particles of 20kg, 10kg aluminium silicate
Grain, 20kg kaolin particle
The present invention, about the preparation method of a kind of material repairing pottery porcelain body, comprises the following steps, but
It is not limited to following sequence,
49kg epoxy resin solidifies in advance with 0.5kg cation curing agent, obtains the first mixture；
Described first mixture mixes with the stirring of 0.5kg thermal initiation cation curing agent, obtains the second mixture；
With fluid bed, gaseous blast is ground quartz particles, aluminum silicate particles, kaolin particle, after making grinding
Particle diameter be quartz particles particle diameter 1～10um, screen out excessive and too small granule, aluminum silicate particles particle diameter
5～20um, screen out excessive and too small granule, kaolin particle particle diameter 1～20um, screen out excessive and mistake
Little granule, the particle diameter of grinding to reach the requirement used, the ceramic surface after reparation just can be made to have
Homogeneity, feel concordance；
With silane coupler process described in grind particle diameter reach the quartz particles of requirement, aluminum silicate particles,
Kaolin particle；
Quartz particles that the second described mixture processes with silane coupler with described again, aluminium silicate
Grain, kaolin particle mix and blend, i.e. obtain the repair materials of required ceramic porcelain body；With this
Method, can make powder body and epoxy resin have more preferable affinity, does not appears in after stirring parks,
The situation of sedimentation layering occurs, and during subsequent cure, the pottery of reparation can be made in reparation portion
The intensity of position keeps consistent, in this method, will strictly control the particle size range of powder body, can make obtain to repair
Complex is as good as with ceramic surface feel and genuine piece, and the pottery repaired by this method can make the reparation portion of pottery
Sound and light transmission aspect that position taps are as good as substantially with genuine piece.
Last it is noted that above example only in order to the present invention is described and and unrestricted described in the invention
Technical scheme；Therefore, although this specification is detailed to present invention has been with reference to each above-mentioned embodiment
Thin explanation, but, it will be understood by those within the art that, still the present invention can be carried out
Amendment or equivalent；And all are without departing from the technical scheme of the spirit and scope of the present invention and improvement thereof,
It all should be contained in scope of the presently claimed invention.
Claims (7)
1. the material repairing pottery porcelain body, it is characterised in that by weight percentage
Following component composition:
Epoxy resin 35～50%；
Auxiliary agent 0.1～5%；
Filler 45～65%.
2. to remove a kind of material repairing pottery porcelain body described in 1 according to right, it is characterised in that press
The following component composition of percentage by weight meter:
Epoxy resin 49%；
Auxiliary agent 1%；
Filler 50%.
A kind of material repairing pottery porcelain body the most according to claim 1 or claim 2, it is characterised in that
Described auxiliary agent is cation curing agent and thermal initiation cation curing agent.
A kind of material repairing pottery porcelain body, it is characterised in that institute
State filler be by quartz particles, aluminum silicate particles, kaolin particle at least one.
A kind of material repairing pottery porcelain body, it is characterised in that institute
The particle diameter stating quartz particles is 1～10um, and the particle diameter of described aluminum silicate particles is 5～20um, institute
The particle diameter stating kaolin particle is 1～20um.
A kind of material repairing pottery porcelain body, it is characterised in that institute
State quartz particles, aluminum silicate particles, kaolin particle silane coupler process.
7. a preparation method for a kind of material repairing pottery porcelain body as described in claim 1 or 3,
Comprise the following steps,
Epoxy resin solidifies in advance with cation curing agent, obtains the first mixture；
Described first mixture stirs with thermal initiation cation curing agent again, obtains the second mixture；
Grind quartz particles, aluminum silicate particles, kaolin particle；
The quartz particles after described grinding, aluminum silicate particles, kaolin particle is processed with silane coupler；
Quartz particles that described second mixture processes with silane coupler with described again, aluminum silicate particles,
Kaolin particle mix and blend.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510201823.5A CN106145766A (en) | 2015-04-26 | 2015-04-26 | A kind of material repairing pottery porcelain body |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510201823.5A CN106145766A (en) | 2015-04-26 | 2015-04-26 | A kind of material repairing pottery porcelain body |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106145766A true CN106145766A (en) | 2016-11-23 |
Family
ID=57347085
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510201823.5A Pending CN106145766A (en) | 2015-04-26 | 2015-04-26 | A kind of material repairing pottery porcelain body |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106145766A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106747216A (en) * | 2016-11-24 | 2017-05-31 | 景德镇陶瓷大学 | A kind of porcelain product after the preparation method of porcelain carcass novel inorganic repair materials and its reparation |
| CN108839496A (en) * | 2018-06-14 | 2018-11-20 | 中国社会科学院考古研究所 | A kind of historical relic restorative procedure of inner support cluster |
| CN114274558A (en) * | 2021-12-28 | 2022-04-05 | 国家石油天然气管网集团有限公司 | Special-shaped B-shaped sleeve repairing method for large deformation defect of long oil and gas pipeline |
-
2015
- 2015-04-26 CN CN201510201823.5A patent/CN106145766A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106747216A (en) * | 2016-11-24 | 2017-05-31 | 景德镇陶瓷大学 | A kind of porcelain product after the preparation method of porcelain carcass novel inorganic repair materials and its reparation |
| CN106747216B (en) * | 2016-11-24 | 2019-01-29 | 景德镇陶瓷大学 | The application method and its porcelain product after reparation of a kind of inorganic repair materials of porcelain carcass |
| CN108839496A (en) * | 2018-06-14 | 2018-11-20 | 中国社会科学院考古研究所 | A kind of historical relic restorative procedure of inner support cluster |
| CN114274558A (en) * | 2021-12-28 | 2022-04-05 | 国家石油天然气管网集团有限公司 | Special-shaped B-shaped sleeve repairing method for large deformation defect of long oil and gas pipeline |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20161123 |