CN106145525A - A kind of coking chemical waste water nitrate nitrogen removing means - Google Patents

A kind of coking chemical waste water nitrate nitrogen removing means Download PDF

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Publication number
CN106145525A
CN106145525A CN201610601592.1A CN201610601592A CN106145525A CN 106145525 A CN106145525 A CN 106145525A CN 201610601592 A CN201610601592 A CN 201610601592A CN 106145525 A CN106145525 A CN 106145525A
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CN
China
Prior art keywords
case
sets
waste water
denitrogenation processing
chemical waste
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610601592.1A
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Chinese (zh)
Inventor
李泽峰
尹君贤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Acre Coking and Refractory Engineering Consulting Corp MCC
Original Assignee
Acre Coking and Refractory Engineering Consulting Corp MCC
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Publication date
Application filed by Acre Coking and Refractory Engineering Consulting Corp MCC filed Critical Acre Coking and Refractory Engineering Consulting Corp MCC
Priority to CN201610601592.1A priority Critical patent/CN106145525A/en
Publication of CN106145525A publication Critical patent/CN106145525A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • C02F2101/163Nitrates
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/34Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
    • C02F2103/36Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds
    • C02F2103/365Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds from petrochemical industry (e.g. refineries)
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2203/00Apparatus and plants for the biological treatment of water, waste water or sewage
    • C02F2203/006Apparatus and plants for the biological treatment of water, waste water or sewage details of construction, e.g. specially adapted seals, modules, connections
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes

Abstract

The present invention relates to a kind of coking chemical waste water nitrate nitrogen removing means, including denitrogenation processing case and guarantee case, denitrogenation processing case is connected by communicating pipe with guarantee case;Denitrogenation processing case sets water inlet pipe, and inside sets agitating device;Ensureing that case sets out water pipe, bottom sets oxygen supply equipment, and inside sets floating stuffing, sets screen plate in the guarantee box body before outlet pipe;Denitrogenation processing upper box part is provided with administration apparatus, and administration apparatus is made up of medicament storage tank, compound pump and pharmaceutical pipeline.The present invention uses integrated denitrogenation processing case and ensures the integrated apparatus of case, the coking chemical waste water processed through one-level A/O carries out nitrate nitrogen removing, carries out subsequent treatment in the sedimentation tank of water outlet entrance original system;Apparatus structure is simple, and installation form is flexible, is not limited by site condition, is very suitable for original coking wastewater processing system and carries out transformation and upgrade.

Description

A kind of coking chemical waste water nitrate nitrogen removing means
Technical field
The present invention relates to Technologies of Coke Plant Wastewater Treatment field, the coking chemical waste water nitrate nitrogen particularly relating to a kind of integrated form takes off Except device.
Background technology
At present, Treatment of Coking Effluent commonly used A/O Biological Denitrification Treatment Technologies, after process, coking chemical waste water can reach state Family's integrated wastewater discharge standard, the ammonia nitrogen in waste water can control at below 10mg/L;Integrated wastewater discharge standard was the most right in the past This index of total nitrogen claims, actual measurement Treatment of Coking Effluent station water outlet total nitrogen surplus higher, often reach 40mg/L with On, the water outlet total nitrogen of minority waste water processing station is even as high as more than 70mg/L.
Rise on January 1st, 2015 in " the coking chemistry emission of industrial pollutants standard " implemented in full, add and coking is given up Total nitrogen index request in water outlet after water process, its direct emission limit is 20mg/L.By to water outlet after Treatment of Coking Effluent Analysis detection display, in water outlet with nitrate salts exist nitrogen account for 77%~89% of total nitrogen in water outlet, therefore, handle well Nitrate nitrogen, so that it may realize total nitrogen removing up to standard.
Pretreatment, A/O is sequentially passed through owing to existing coal chemical enterprise uses one-level A/O to process technique, i.e. coking chemical waste water mostly Water outlet after the process of biochemical treatment tank, sedimentation tank, successive depths;Limited by the field, it is difficult to be further added by new process pond.
Summary of the invention
The invention provides a kind of coking chemical waste water nitrate nitrogen removing means, use integrated denitrogenation processing case and ensure case Integrated apparatus, carries out nitrate nitrogen removing to the coking chemical waste water processed through one-level A/O, and water outlet enters the sedimentation tank of original system In carry out subsequent treatment;Apparatus structure is simple, and installation form is flexible, is not limited by site condition, is very suitable for original coking Waste Water Treatment carries out transformation and upgrade.
In order to achieve the above object, the present invention realizes by the following technical solutions:
A kind of coking chemical waste water nitrate nitrogen removing means, including denitrogenation processing case and guarantee case, denitrogenation processing case and guarantee Case is set up in parallel composition integrated apparatus, and denitrogenation processing case connects by being located at the communicating pipe bottom space bar with guarantee case;Institute The outer upper stating denitrogenation processing case sets water inlet pipe, and inside sets agitating device;Ensureing that the outer upper of case sets out water pipe, bottom sets Oxygen supply equipment, inside sets floating stuffing, sets screen plate in the guarantee box body before outlet pipe;Denitrogenation processing upper box part is provided with dispensing Equipment, administration apparatus is made up of medicament storage tank, compound pump and pharmaceutical pipeline, and the drug entering side of pharmaceutical pipeline connects medicine by compound pump Agent storage tank, medicine outlet end is positioned close in the denitrogenation processing case of water inlet pipe.
Described oxygen supply equipment is aerator, or the air line with multiple ventholes.
Described floating stuffing is VPVC goods.
The water inlet absolute altitude of described water inlet pipe is higher than the outlet absolute altitude of outlet pipe.
Described screen plate is arranged in guarantee case by screen plate support.
Described agitating device is propeller or stirring paddle under liquid.
Compared with prior art, the invention has the beneficial effects as follows:
1) use integrated denitrogenation processing case and ensure the integrated apparatus of case, the coking chemical waste water processed through one-level A/O is entered Row nitrate nitrogen removes, and carries out subsequent treatment in the sedimentation tank of water outlet entrance original system;
2) apparatus structure is simple, and floor space is little, is not limited by site condition, and treatment effect is reliable and stable, is especially suitable for Transformation and upgrade are carried out in original coking wastewater processing system;
3) installation form is flexible, can not affect existing coking wastewater processing system properly functioning in the case of, fast side Just, in access system, high efficiency realizes the target that water outlet total nitrogen is up to standard.
Accompanying drawing explanation
Fig. 1 is the structural representation of coking chemical waste water nitrate nitrogen removing means of the present invention.
Fig. 2 is the signal that coking chemical waste water nitrate nitrogen removing means of the present invention accesses original coking wastewater processing system Figure.
In figure: 1. denitrogenation processing case 11. medicament mixed zone 12. agitating device 2. ensures case 21. oxygen supply equipment 22. Floating stuffing 23. screen plate 3. administration apparatus 31. medicament storage tank 32. compound pump 33. pharmaceutical pipeline 4. communicating pipe 5. enters Water pipe 6. outlet pipe
Detailed description of the invention
Below in conjunction with the accompanying drawings the detailed description of the invention of the present invention is described further:
As it is shown in figure 1, a kind of coking chemical waste water nitrate nitrogen removing means of the present invention, including denitrogenation processing case 1 and guarantor Barrier case 2, denitrogenation processing case 1 and guarantee case 2 are set up in parallel composition integrated apparatus, denitrogenation processing case 1 and guarantee case 2 by being located at Communicating pipe 4 bottom space bar connects;The outer upper of described denitrogenation processing case 1 sets water inlet pipe 5, and inside sets agitating device 12; Ensureing that the outer upper of case 2 sets out water pipe 6, bottom sets oxygen supply equipment 21, and inside sets floating stuffing, the guarantee case 2 before outlet pipe 6 Screen plate 23 is set in casing;Denitrogenation processing case 1 top is provided with administration apparatus 3, and administration apparatus 3 is by medicament storage tank 31, compound pump 32 Forming with pharmaceutical pipeline 33, the drug entering side of pharmaceutical pipeline 33 connects medicament storage tank 31 by compound pump 32, and medicine outlet end is arranged on to be leaned on In the denitrogenation processing case 1 of nearly water inlet pipe 5.
Described oxygen supply equipment 21 is aerator, or the air line with multiple ventholes.
Described floating stuffing 22 is VPVC goods.
The water inlet absolute altitude of described water inlet pipe 5 is higher than the outlet absolute altitude of outlet pipe.
Described screen plate 23 is arranged in guarantee case by screen plate support.
Described agitating device 12 is propeller or stirring paddle under liquid.
As in figure 2 it is shown, during a kind of coking chemical waste water nitrate nitrogen removing means application of the present invention, by water inlet pipe 5 one end Being connected with the outlet of A/O biochemical treatment apparatus, outlet pipe 6 one end connects sedimentation tank;At pretreatment and one-level A/O biochemistry Coking chemical waste water after reason enters in denitrogenation processing case 1 by water inlet pipe 5, first the dosing mixed zone 11 near water inlet pipe 5 and throwing The medicament that medicine equipment 3 puts into is sufficiently mixed, and subsequently into reaction zone, carries out hybrid reaction under the stirring of agitating device 12, Flow into by the communicating pipe 4 bottom space bar in ensureing case 2;Ensure that case 2 is internal and be provided with oxygen supply equipment 21, Aeration tank can be played Effect, oxygen supply equipment 21 is arranged over floating stuffing 22, and floating stuffing 22 uses VPVC goods, and its specific surface area is big, space Many, it is particularly suitable for biofilm development, and ageing-resistant.For preventing floating stuffing 22 to run off with water outlet, ensure case 2 outlet water at tail end pipe 6 Before be provided with screen plate 23, floating stuffing 22 is played crown_interception.
The offerd medicine agent of administration apparatus 3, as carbon source, can be the one in methanol, sodium acetate or glucose, routinely than Example mixes.
[embodiment]
One 100m of certain coal chemical enterprise3The coking wastewater processing system of/h, former water outlet total nitrogen is 37~51mg/L.By Original system increases coking chemical waste water nitrate nitrogen removing means of the present invention, puts into methanol and water by administration apparatus 3 Mixing, total residence time 5h.To going out water sampling detection after device debugging normal operation, total nitrogen content is 12.4mg/L, less than total Standard-required within nitrogen 20mg/L, can qualified discharge.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto, Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.

Claims (6)

1. a coking chemical waste water nitrate nitrogen removing means, it is characterised in that include denitrogenation processing case and ensure case, denitrogenation processing Case and guarantee case are set up in parallel composition integrated apparatus, and denitrogenation processing case and guarantee case are by being located at the communicating pipe bottom space bar Connection;The outer upper of described denitrogenation processing case sets water inlet pipe, and inside sets agitating device;Ensure that the outer upper of case sets out water Pipe, bottom sets oxygen supply equipment, and inside sets floating stuffing, sets screen plate in the guarantee box body before outlet pipe;On denitrogenation processing case Portion is provided with administration apparatus, and administration apparatus is made up of medicament storage tank, compound pump and pharmaceutical pipeline, and medicine is passed through in the drug entering side of pharmaceutical pipeline Agent pump connects medicament storage tank, and medicine outlet end is positioned close in the denitrogenation processing case of water inlet pipe.
A kind of coking chemical waste water nitrate nitrogen removing means the most according to claim 1, it is characterised in that described oxygen supply equipment For aerator, or the air line with multiple ventholes.
A kind of coking chemical waste water nitrate nitrogen removing means the most according to claim 1, it is characterised in that described floating stuffing For VPVC goods.
A kind of coking chemical waste water nitrate nitrogen removing means the most according to claim 1, it is characterised in that described water inlet pipe Water inlet absolute altitude is higher than the outlet absolute altitude of outlet pipe.
A kind of coking chemical waste water nitrate nitrogen removing means the most according to claim 1, it is characterised in that described screen plate leads to Cross screen plate support to be arranged in guarantee case.
A kind of coking chemical waste water nitrate nitrogen removing means the most according to claim 1, it is characterised in that described agitating device For propeller under liquid or stirring paddle.
CN201610601592.1A 2016-07-28 2016-07-28 A kind of coking chemical waste water nitrate nitrogen removing means Pending CN106145525A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610601592.1A CN106145525A (en) 2016-07-28 2016-07-28 A kind of coking chemical waste water nitrate nitrogen removing means

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Application Number Priority Date Filing Date Title
CN201610601592.1A CN106145525A (en) 2016-07-28 2016-07-28 A kind of coking chemical waste water nitrate nitrogen removing means

Publications (1)

Publication Number Publication Date
CN106145525A true CN106145525A (en) 2016-11-23

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201923882U (en) * 2011-01-11 2011-08-10 彭永臻 Single stage autotroph denitrification device for low C/N (carbon/nitrogen) high ammonia nitrogen wastewater
CN201932988U (en) * 2011-01-22 2011-08-17 黄江丽 Anaerobic/aerobic contact oxidation membrane bioreactor
CN204298147U (en) * 2014-11-29 2015-04-29 镇江清水环境科技有限公司 The multistage SND nitrogen rejection facility of a kind of integral type
CN105129986A (en) * 2015-08-27 2015-12-09 上海晶宇环境工程股份有限公司 Process for deeply removing total nitrogen in waste water by means of biological method and device of process
CN105502837A (en) * 2016-01-14 2016-04-20 上海晶宇环境工程股份有限公司 Process and device for conducting deep denitrification on nitrogen-containing organic waste water
CN205974169U (en) * 2016-07-28 2017-02-22 中冶焦耐(大连)工程技术有限公司 Coking wastewater nitrate nitrogen removing device

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201923882U (en) * 2011-01-11 2011-08-10 彭永臻 Single stage autotroph denitrification device for low C/N (carbon/nitrogen) high ammonia nitrogen wastewater
CN201932988U (en) * 2011-01-22 2011-08-17 黄江丽 Anaerobic/aerobic contact oxidation membrane bioreactor
CN204298147U (en) * 2014-11-29 2015-04-29 镇江清水环境科技有限公司 The multistage SND nitrogen rejection facility of a kind of integral type
CN105129986A (en) * 2015-08-27 2015-12-09 上海晶宇环境工程股份有限公司 Process for deeply removing total nitrogen in waste water by means of biological method and device of process
CN105502837A (en) * 2016-01-14 2016-04-20 上海晶宇环境工程股份有限公司 Process and device for conducting deep denitrification on nitrogen-containing organic waste water
CN205974169U (en) * 2016-07-28 2017-02-22 中冶焦耐(大连)工程技术有限公司 Coking wastewater nitrate nitrogen removing device

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