CN106085210A - A kind of rust-proofing steel alloy anticorrosive paint and preparation method thereof - Google Patents

A kind of rust-proofing steel alloy anticorrosive paint and preparation method thereof Download PDF

Info

Publication number
CN106085210A
CN106085210A CN201610545200.4A CN201610545200A CN106085210A CN 106085210 A CN106085210 A CN 106085210A CN 201610545200 A CN201610545200 A CN 201610545200A CN 106085210 A CN106085210 A CN 106085210A
Authority
CN
China
Prior art keywords
mentioned
add
acid
minute
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201610545200.4A
Other languages
Chinese (zh)
Inventor
戴宇钧
祝盆鑫
祝秀凤
汪鹏程
孙巨福
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TIANCHANG YINHU PAINT Co Ltd
Original Assignee
TIANCHANG YINHU PAINT Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TIANCHANG YINHU PAINT Co Ltd filed Critical TIANCHANG YINHU PAINT Co Ltd
Priority to CN201610545200.4A priority Critical patent/CN106085210A/en
Publication of CN106085210A publication Critical patent/CN106085210A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D179/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09D161/00 - C09D177/00
    • C09D179/02Polyamines
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02Polyamines
    • C08G73/026Wholly aromatic polyamines
    • C08G73/0266Polyanilines or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/0605Polycondensates containing five-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms
    • C08G73/0611Polycondensates containing five-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms with only one nitrogen atom in the ring, e.g. polypyrroles
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a kind of rust-proofing steel alloy anticorrosive paint, it is made up of the raw material of following weight parts;Dodecenylsuccinic acid 46, octyl phenyl cyclotetrasiloxane 0.3 1, aniline 50 60, sulfosalicylic acid 79, epoxy resin E513 4, Ammonium persulfate. 1.3 2, molybdic acid 46, polyamide 35, n-butyl alcohol 160 170, butyl glycol ether 20 30, pyrroles 30 40, dibutyl maleate 12, nonyl phenol 0.1 0.2, triethanolamine borate 12, tin ash 0.1 0.2, Triton X-100 0.6 1, abienol 4.5 6, Sodium fluoroborate 12.The dodecenylsuccinic acid of present invention addition, triethanolamine borate etc., can effectively improve the rust-resisting property of finished product coating.

Description

A kind of rust-proofing steel alloy anticorrosive paint and preparation method thereof
Technical field
The present invention relates to anticorrosive paint technical field, particularly relate to a kind of rust-proofing steel alloy anticorrosive paint and preparation side thereof Method.
Background technology
Polyaniline increasingly causes the attention of people as a kind of novel conducting polymer composite in recent years.It synthesizes work Skill is simple, environmentally safe, low cost have the features such as stable thermodynamic property and chemical property and make it lead at each Territory is all widely used.Particularly its excellent antiseptic property makes it the most extensive in the application of corrosion-resistant field.But its paint film Fragile adhesive force and slightly solubility are applied to create the biggest restriction.If by chemical corrosion resistance excellent for polyaniline and ring The adhesive force of epoxy resins excellence and mechanical property combine prepares blended coating, and this will be greatly improved epoxy coating Antiseptic power, also overcomes the weakness of polyaniline paint simultaneously, thus is greatly improved its range of application and antiseptic property;
Polyaniline film can carry out protection in acid medium to ferrous materials makes its surface soul and the erosion medium resistance that is not corroded, This discovery starts so that polyaniline is shown up prominently at corrosion-resistant field.Showed through the substantial amounts of experimental data of research worker later, poly- Aniline has scratch resistance and the effect of anti-spot corrosion of uniqueness, and after it mixes with epoxy resin, Xu is overlying on the anticorrosion of metal surface Having exceeded during performance-based only coated with resins and got well all times of even an order of magnitude, it is harsh that it also can be suitably used for ocean and Aero-Space etc. Condition makes this material increasingly be taken seriously.Additionally also there is polyaniline in fields such as microelectronics packaging and electronic package Figure;
Polyaniline bad dispersibility in polyaniline/cold coating and poor adhesive force etc. the most all greatly reduce the anti-of polyaniline Rotten performance, the physics impermeabilisation ability of polyaniline does not reaches the most far away the use condition requirement of harshness simultaneously.So how improve The insoluble energy of polyaniline, dispersive property and impermeabilisation ability are to improve the key of anticorrosive polyaniline ability, are also to promote it Practical, the key of extensiveization;.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of rust-proofing steel alloy anticorrosive paint and system thereof Preparation Method.
The present invention is achieved by the following technical solutions:
A kind of rust-proofing steel alloy anticorrosive paint, it is made up of the raw material of following weight parts;
Dodecenylsuccinic acid 4-6, octyl phenyl cyclotetrasiloxane 0.3-1, aniline 50-60, sulfosalicylic acid 7-9, asphalt mixtures modified by epoxy resin Fat E513-4, Ammonium persulfate. 1.3-2, molybdic acid 4-6, polyamide 3-5, n-butyl alcohol 160-170, butyl glycol ether 20-30, pyrrole Cough up 30-40, dibutyl maleate 1-2, nonyl phenol 0.1-0.2, triethanolamine borate 1-2, tin ash 0.1- 0.2, Triton X-100 0.6-1, abienol 4.5-6, Sodium fluoroborate 1-2.
The preparation method of a kind of described rust-proofing steel alloy anticorrosive paint, comprises the following steps:
(1) Ammonium persulfate. is joined in its weight 21-25 times deionized water, stir, obtain initiator solution;
(2) above-mentioned nonyl phenol is joined in abienol, stir, add above-mentioned polyamide, protect at 80-86 DEG C Temperature 10-15 minute, obtains modified polyamide alcohol liquid;
(3) above-mentioned Sodium fluoroborate is joined in the deionized water of its weight 17-20 times, stir, add Polyethylene Glycol pungent Base phenyl ether, insulated and stirred 3-4 minute at 60-65 DEG C, obtain aqueous dispersions;
(4) taking the 10-12% of above-mentioned n-butyl alcohol weight, add triethanolamine borate, at 60-70 DEG C, insulated and stirred 3-5 is divided Clock, adds above-mentioned epoxy resin, rises high-temperature and is 86-90 DEG C, continues insulation 4-7 minute, add above-mentioned octyl phenyl ring four silicon Oxygen alkane, stirring, to room temperature, obtains epoxy silane alcohol liquid;
(5) above-mentioned sulfosalicylic acid is joined in the deionized water of its weight 47-50 times, magnetic agitation 20-30 minute, add Aniline, stirs, and drips the 47-50% of above-mentioned initiator solution weight, regulates temperature and be 20-25 DEG C after dropping, stirring React 10-12 hour, add above-mentioned dodecenylsuccinic acid, stir, filter, precipitation acetone, distilled water are washed successively Wash 3-4 time, be dried 10-12 hour at 60-65 DEG C, obtain acid doped polyaniline;
(6) molybdic acid is joined in the deionized water of its weight 60-65 times, stir, add above-mentioned pyrroles, magnetic agitation 50-60 minute, drip remaining initiator solution, regulate temperature after dropping and be 0-5 DEG C, stirring reaction 6-7 hour, successively Add above-mentioned aqueous dispersions, tin ash, stir, filter, the ethanol of precipitation 30-35% is washed 2-3 time, at 70-85 DEG C Under be dried 6-8 hour, obtain acid doping polypyrrole;
(7) by remaining n-butyl alcohol, butyl glycol ether mixing, stir, obtain mixed solvent;
(8) take the 50-60% of above-mentioned mixed solvent weight, add above-mentioned acid doped polyaniline, ultrasonic 10-15 minute, add above-mentioned Epoxy silane alcohol liquid, stirring reaction 40-50 minute, obtain epoxy emulsion;
(9) above-mentioned acid doping polypyrrole is joined in remaining mixed solvent, stirs, add modified polyamide alcohol liquid, Ultrasonic 30-40 minute, obtain polyamide emulsion;
(10) by above-mentioned epoxy emulsion, the mixing of polyamide emulsion, adding the dimethicone of compound weight 1-2%, stirring is all Even, add and remain each raw material, be passed through the steam of 80-90 DEG C, heat aging 30-40 minute, cool down, obtain described coating.
A kind of rust-proofing steel alloy anticorrosive paint and preparation method thereof, the using method of described coating is:
Be applied to paint brush of the present invention to clean up, dried alloy steel material working electrode surface, control coating thickness one Cause, as in baking oven, be dried 20-25 hour at 60-70 DEG C,.
The invention have the advantage that the doped polypyrrole of the present invention is conduction, during as anti-corrosion material protection metal, always Be first with surface metal generation partial reaction, make surface metal corrode purification, corrosion potential presents and generally reduces, molybdic acid official's energy Group, as a kind of anti-corrosion function functional group, may depart from also faster when touching metal material from polypyrrole strand React with metal, make metal surface protected and be passivated, and use being total to of the sulfosalisylic acid doping of bigger organic group Polymers is embedded in copolymer molecule interchain because of large scale counter ion, it is possible to increases the extension degree of polymer chain and expands interchain Away from, organic macromolecule sulfonic acid group has strong surface-active action, makes the dissolubility of subject polymer be improved, simultaneously Have both good electrical conductivity, can be formed different electric field, the direction of the electric field of formation and corrosion when it acts on metal surface When reaction occurs, electronics flowing is in opposite direction, and therefore this electric field is equal to being applied with a counteracting force to corrosion reaction, hinders Electronics, to the movement of metal surface, makes corrosion reaction by a definite limitation, the polyphenyl that this sulfosalisylic acid doping is formed simultaneously Amine is blended with polypyrrole so that the grain diameter of copolymer diminishes, and granule is uniform, careful, piles up more tight, agglomeration Basic disappear, the coating of the present invention can effectively improve the ability of passive metal so that steel alloy Surface Creation one floor height The oxide-film of consistency, preferably isolating metal base material and corrosive medium, enhance the ability of its suppression anode reaction, show Preferably corrosion resistance;The dodecenylsuccinic acid of present invention addition, triethanolamine borate etc., can effectively improve into The rust-resisting property of product coating.
Detailed description of the invention
A kind of rust-proofing steel alloy anticorrosive paint, it is made up of the raw material of following weight parts;
Dodecenylsuccinic acid 4, octyl phenyl cyclotetrasiloxane 0.3, aniline 50, sulfosalicylic acid 7, epoxy resin E513, mistake Ammonium sulfate 1.3, molybdic acid 4, polyamide 3, n-butyl alcohol 160, butyl glycol ether 20, pyrroles 30, dibutyl maleate 1, Nonyl phenol 0.1, triethanolamine borate 1, tin ash 0.1, Triton X-100 0.6, abienol 4.5, fluorine boron Acid sodium 1.
The preparation method of a kind of described rust-proofing steel alloy anticorrosive paint, comprises the following steps:
(1) Ammonium persulfate. is joined in 21 times of deionized waters of its weight, stir, obtain initiator solution;
(2) above-mentioned nonyl phenol is joined in abienol, stir, add above-mentioned polyamide, be incubated at 80 DEG C 10 minutes, obtain modified polyamide alcohol liquid;
(3) above-mentioned Sodium fluoroborate is joined in the deionized water of its weight 17 times, stir, add Polyethylene Glycol octyl group benzene Base ether, at 60 DEG C, insulated and stirred 3 minutes, obtain aqueous dispersions;
(4) taking the 10% of above-mentioned n-butyl alcohol weight, add triethanolamine borate, insulated and stirred 3 minutes at 60 DEG C, in addition Stating epoxy resin, rising high-temperature is 86 DEG C, continues insulation 4 minutes, adds above-mentioned octyl phenyl cyclotetrasiloxane, and stirring is to often Temperature, obtains epoxy silane alcohol liquid;
(5) above-mentioned sulfosalicylic acid is joined in the deionized water of its weight 47 times, magnetic agitation 20 minutes, add aniline, Stirring, drip the 47% of above-mentioned initiator solution weight, regulating temperature after dropping is 20 DEG C, stirring reaction 10 hours, Add above-mentioned dodecenylsuccinic acid, stir, filter, precipitation acetone, distilled water are washed successively 3 times, at 60 DEG C It is dried 10 hours, obtains acid doped polyaniline;
(6) molybdic acid is joined in the deionized water of its weight 60 times, stir, add above-mentioned pyrroles, magnetic agitation 50 points Clock, drips remaining initiator solution, and regulating temperature after dropping is 0 DEG C, and stirring reaction 6 hours is sequentially added into above-mentioned water Dispersion liquid, tin ash, stir, and filters, and precipitation is washed 2 times with the ethanol of 30%, is dried 6 hours, obtains sour mixing at 70 DEG C Heteromeric pyrroles;
(7) by remaining n-butyl alcohol, butyl glycol ether mixing, stir, obtain mixed solvent;
(8) take the 50% of above-mentioned mixed solvent weight, add above-mentioned acid doped polyaniline, ultrasonic 10 minutes, add above-mentioned epoxy silicon Alkanol liquid, stirring reaction 40 minutes, obtain epoxy emulsion;
(9) above-mentioned acid doping polypyrrole is joined in remaining mixed solvent, stirs, add modified polyamide alcohol liquid, Ultrasonic 30 minutes, obtain polyamide emulsion;
(10) by above-mentioned epoxy emulsion, the mixing of polyamide emulsion, add the dimethicone of compound weight 1%, stir, Add and remain each raw material, be passed through the steam of 80 DEG C, heat aging 30 minutes, cool down, obtain described coating.
Described a kind of rust-proofing steel alloy anticorrosive paint and preparation method thereof, the using method of described coating is:
Be applied to paint brush of the present invention to clean up, dried alloy steel material working electrode surface, control coating thickness one Cause, as in baking oven, be dried 20 hours at 60 DEG C,.
Performance test with the coating formation film of the present invention:
Impact strength: 51kg.cm;
Hardness: 3H.

Claims (3)

1. a rust-proofing steel alloy anticorrosive paint, it is characterised in that it is made up of the raw material of following weight parts;
Dodecenylsuccinic acid 4-6, octyl phenyl cyclotetrasiloxane 0.3-1, aniline 50-60, sulfosalicylic acid 7-9, asphalt mixtures modified by epoxy resin Fat E513-4, Ammonium persulfate. 1.3-2, molybdic acid 4-6, polyamide 3-5, n-butyl alcohol 160-170, butyl glycol ether 20-30, pyrrole Cough up 30-40, dibutyl maleate 1-2, nonyl phenol 0.1-0.2, triethanolamine borate 1-2, tin ash 0.1- 0.2, Triton X-100 0.6-1, abienol 4.5-6, Sodium fluoroborate 1-2.
2. the preparation method of a rust-proofing steel alloy anticorrosive paint as claimed in claim 1, it is characterised in that include following step Rapid:
(1) Ammonium persulfate. is joined in its weight 21-25 times deionized water, stir, obtain initiator solution;
(2) above-mentioned nonyl phenol is joined in abienol, stir, add above-mentioned polyamide, protect at 80-86 DEG C Temperature 10-15 minute, obtains modified polyamide alcohol liquid;
(3) above-mentioned Sodium fluoroborate is joined in the deionized water of its weight 17-20 times, stir, add Polyethylene Glycol pungent Base phenyl ether, insulated and stirred 3-4 minute at 60-65 DEG C, obtain aqueous dispersions;
(4) taking the 10-12% of above-mentioned n-butyl alcohol weight, add triethanolamine borate, at 60-70 DEG C, insulated and stirred 3-5 is divided Clock, adds above-mentioned epoxy resin, rises high-temperature and is 86-90 DEG C, continues insulation 4-7 minute, add above-mentioned octyl phenyl ring four silicon Oxygen alkane, stirring, to room temperature, obtains epoxy silane alcohol liquid;
(5) above-mentioned sulfosalicylic acid is joined in the deionized water of its weight 47-50 times, magnetic agitation 20-30 minute, add Aniline, stirs, and drips the 47-50% of above-mentioned initiator solution weight, regulates temperature and be 20-25 DEG C after dropping, stirring React 10-12 hour, add above-mentioned dodecenylsuccinic acid, stir, filter, precipitation acetone, distilled water are washed successively Wash 3-4 time, be dried 10-12 hour at 60-65 DEG C, obtain acid doped polyaniline;
(6) molybdic acid is joined in the deionized water of its weight 60-65 times, stir, add above-mentioned pyrroles, magnetic agitation 50-60 minute, drip remaining initiator solution, regulate temperature after dropping and be 0-5 DEG C, stirring reaction 6-7 hour, successively Add above-mentioned aqueous dispersions, tin ash, stir, filter, the ethanol of precipitation 30-35% is washed 2-3 time, at 70-85 DEG C Under be dried 6-8 hour, obtain acid doping polypyrrole;
(7) by remaining n-butyl alcohol, butyl glycol ether mixing, stir, obtain mixed solvent;
(8) take the 50-60% of above-mentioned mixed solvent weight, add above-mentioned acid doped polyaniline, ultrasonic 10-15 minute, add above-mentioned Epoxy silane alcohol liquid, stirring reaction 40-50 minute, obtain epoxy emulsion;
(9) above-mentioned acid doping polypyrrole is joined in remaining mixed solvent, stirs, add modified polyamide alcohol liquid, Ultrasonic 30-40 minute, obtain polyamide emulsion;
(10) by above-mentioned epoxy emulsion, the mixing of polyamide emulsion, adding the dimethicone of compound weight 1-2%, stirring is all Even, add and remain each raw material, be passed through the steam of 80-90 DEG C, heat aging 30-40 minute, cool down, obtain described coating.
3. according to a kind of rust-proofing steel alloy anticorrosive paint described in claim 1-2 and preparation method thereof, it is characterised in that described The using method of coating be:
Be applied to paint brush of the present invention to clean up, dried alloy steel material working electrode surface, control coating thickness one Cause, as in baking oven, be dried 20-25 hour at 60-70 DEG C,.
CN201610545200.4A 2016-07-12 2016-07-12 A kind of rust-proofing steel alloy anticorrosive paint and preparation method thereof Withdrawn CN106085210A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610545200.4A CN106085210A (en) 2016-07-12 2016-07-12 A kind of rust-proofing steel alloy anticorrosive paint and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610545200.4A CN106085210A (en) 2016-07-12 2016-07-12 A kind of rust-proofing steel alloy anticorrosive paint and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106085210A true CN106085210A (en) 2016-11-09

Family

ID=57219801

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610545200.4A Withdrawn CN106085210A (en) 2016-07-12 2016-07-12 A kind of rust-proofing steel alloy anticorrosive paint and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106085210A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106700834A (en) * 2016-12-20 2017-05-24 铜陵市经纬流体科技有限公司 Anticorrosive paint for flame-retardant low-carbon steel valve and preparing method thereof
CN106752708A (en) * 2016-12-20 2017-05-31 铜陵市经纬流体科技有限公司 A kind of epoxy mild steel valve anticorrosive paint and preparation method thereof
CN106752709A (en) * 2016-12-20 2017-05-31 铜陵市经纬流体科技有限公司 A kind of hydrophobic mild steel valve anticorrosive paint and preparation method thereof
CN106810996A (en) * 2016-12-20 2017-06-09 铜陵市经纬流体科技有限公司 A kind of anti-oxidant mild steel valve anticorrosive paint and preparation method thereof
CN107043584A (en) * 2016-12-20 2017-08-15 铜陵市经纬流体科技有限公司 A kind of environmentally friendly mild steel valve anticorrosive paint and preparation method thereof
CN109097780A (en) * 2018-09-18 2018-12-28 苏州市金翔钛设备有限公司 A kind of process of surface treatment of copper-titanium alloy tubing

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105001759A (en) * 2015-07-21 2015-10-28 中国科学院金属研究所 Molybdate doped polypyrrole/epoxy resin self-healing coating, preparation method thereof and application thereof
CN105368304A (en) * 2015-09-23 2016-03-02 航天科工防御技术研究试验中心 Anticorrosive paint and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105001759A (en) * 2015-07-21 2015-10-28 中国科学院金属研究所 Molybdate doped polypyrrole/epoxy resin self-healing coating, preparation method thereof and application thereof
CN105368304A (en) * 2015-09-23 2016-03-02 航天科工防御技术研究试验中心 Anticorrosive paint and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106700834A (en) * 2016-12-20 2017-05-24 铜陵市经纬流体科技有限公司 Anticorrosive paint for flame-retardant low-carbon steel valve and preparing method thereof
CN106752708A (en) * 2016-12-20 2017-05-31 铜陵市经纬流体科技有限公司 A kind of epoxy mild steel valve anticorrosive paint and preparation method thereof
CN106752709A (en) * 2016-12-20 2017-05-31 铜陵市经纬流体科技有限公司 A kind of hydrophobic mild steel valve anticorrosive paint and preparation method thereof
CN106810996A (en) * 2016-12-20 2017-06-09 铜陵市经纬流体科技有限公司 A kind of anti-oxidant mild steel valve anticorrosive paint and preparation method thereof
CN107043584A (en) * 2016-12-20 2017-08-15 铜陵市经纬流体科技有限公司 A kind of environmentally friendly mild steel valve anticorrosive paint and preparation method thereof
CN109097780A (en) * 2018-09-18 2018-12-28 苏州市金翔钛设备有限公司 A kind of process of surface treatment of copper-titanium alloy tubing

Similar Documents

Publication Publication Date Title
CN106085210A (en) A kind of rust-proofing steel alloy anticorrosive paint and preparation method thereof
CN106147592A (en) A kind of titanate esters steel alloy anticorrosive paint and preparation method thereof
CN106189811A (en) A kind of pliable and tough steel alloy anticorrosive paint and preparation method thereof
CN106085205A (en) A kind of saponification steel alloy anticorrosive paint and preparation method thereof
CN106189815A (en) One is resistance to scrubs steel alloy anticorrosive paint and preparation method thereof
CN106085208A (en) A kind of steel alloy coating and preparation method thereof
CN101851459B (en) Water-based polypyrrole anticorrosive paint and preparation method thereof
CN106065277A (en) A kind of hydrophobic steel alloy anticorrosive paint and preparation method thereof
CN106147594A (en) A kind of hard alloy steel anticorrosive paint and preparation method thereof
CN106752708A (en) A kind of epoxy mild steel valve anticorrosive paint and preparation method thereof
CN103709903B (en) High solid conduction type epoxy zinc rich primer
CN106189817A (en) A kind of antibacterial anticorrosive paint of steel alloy and preparation method thereof
CN104988482A (en) Polyacid metal surface treating agent and preparation method thereof
CN106085207A (en) A kind of nano alloyed steel anticorrosive paint and preparation method thereof
CN106189812A (en) A kind of stable type steel alloy anticorrosive paint and preparation method thereof
CN102277064A (en) Epoxy coal pitch anticorrosive paint
CN106189813A (en) A kind of Compound-acid modified alloy steel anticorrosive paint and preparation method thereof
CN104987802A (en) Rustproof metal surface treatment agent and preparation method thereof
CN105602312A (en) Modified waterborne polyaniline epoxy resin coating and preparation method thereof
CN106085209A (en) A kind of composite resin base alloy-steel anticorrosive paint and preparation method thereof
CN106047145A (en) Heat-resisting alloy-steel anticorrosive coating and preparing method thereof
CN106189814A (en) A kind of flame-retardant alloy steel anticorrosive paint and preparation method thereof
CN106147593A (en) A kind of oxidation-resistant alloy steel anticorrosive paint and preparation method thereof
CN106189816A (en) A kind of environmental protection steel alloy anticorrosive paint and preparation method thereof
CN106189818A (en) A kind of polymer steel alloy anticorrosive paint and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication

Application publication date: 20161109

WW01 Invention patent application withdrawn after publication