CN106007164A - Magnetorheological fluid recycling treatment device and treatment method based on high-pressure filtering separation effect - Google Patents

Magnetorheological fluid recycling treatment device and treatment method based on high-pressure filtering separation effect Download PDF

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Publication number
CN106007164A
CN106007164A CN201610616686.6A CN201610616686A CN106007164A CN 106007164 A CN106007164 A CN 106007164A CN 201610616686 A CN201610616686 A CN 201610616686A CN 106007164 A CN106007164 A CN 106007164A
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pressure
flow liquid
magnetic flow
filter
breather
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邢战伟
刘鹏
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Maanshan Fulaiyi Environmental Protection Technology Co Ltd
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Maanshan Fulaiyi Environmental Protection Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/48Treatment of water, waste water, or sewage with magnetic or electric fields
    • C02F1/484Treatment of water, waste water, or sewage with magnetic or electric fields using electromagnets
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Water Treatment By Sorption (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention discloses a magnetorheological fluid recycling treatment device and a treatment method based on high-pressure filtering separation effect, belonging to the field of magnetic waste fluid recycling treatment. The device comprises an outer barrel body and a pressure filter device, wherein the pressure filter device is arranged in the outer barrel body and comprises a pressure bearing cavity; a filter screen is arranged at the bottom of the pressure bearing cavity; an adsorption pipe is arranged above the filter screen; multiple filter holes are formed in the bottom wall of the pressure filter device; and a recycling stop valve is arranged on the side wall of the outer barrel body. In the invention, the adsorption pipe is electrified and then generates a magnetic field so that magnetic materials disconnected with carrier fluid are adsorbed on the adsorption pipe; through a form of inert gas (for example, nitrogen and the like) pressurization, the mixed solution is forcibly extruded; and since the magnetic materials are adsorbed by the adsorption pipe and the particle diameter of the carrier fluid is less than that of the magnetic materials, the carrier fluid quickly passes the filter screen while the magnetic materials stay on the adsorption pipe and the filter screen to realize separation of the magnetic materials and the carrier fluid.

Description

A kind of magnetic flow liquid recycling and processing device based on high-pressure filteration centrifugation and processing method
Technical field
The invention belongs to magnetic devil liquor recovery process field, more particularly, it relates to a kind of magnetic based on high-pressure filteration centrifugation Rheology liquid recycling and processing device and processing method.
Background technology
MRF, is the rheological characteristic utilizing Magnetorheologicai polishing liquid in magnetic field technology that workpiece carries out local shape modifications and polishing. Magnetic flow liquid is by carrier fluid (such as water, silicone oil etc.), discrete polarizable micron order magnetosensitive microgranule, surfactant, polishing particles Form with the additive with other functions.Magnetic flow liquid by polishing disk circulation bring into formed between workpiece and polishing disk small between Away from polishing area in, in this region, under the effect of high-gradient magnetic field, there is rheological effect and hardening, viscosity in magnetic flow liquid Increasing, magnetic-particle therein arranges chaining along the direction of magnetic field intensity, is formed and has effigurate protruding ribbon, and its In polishing powder granule not there is magnetic, therefore can be extruded and float to the weak top of magnetic field intensity, so go up edema over the face and one layer of throwing The protruding ribbon of light granule just constitutes one " flexible polishing mould ", when this flexible polishing mould flows through workpiece under the drive of moving coil During the small-gap suture formed with moving coil, surface of the work can be produced the biggest shearing force, realize removing to surface of the work material.? In the whole course of processing, magnetic flow liquid, by blood circulation control, is stored in the comprehensive container tank of aluminum, rear pump deliver to output Pipeline, then be sprayed onto on polishing disk by nozzle, leave the magnetic flow liquid after machining area by recovery pump by recovery pipe, be recovered to In comprehensive container tank.
After using magnetic flow liquid for a long time, the consume of its magnetisable material and carrier fluid and the degeneration of additive, cause its mechanical property The index dramatic decrease such as energy, magnetic performance, response time, the most modal way is for changing magnetic flow liquid, by original performance Variation magnetic flow liquid recycles.Because of the carrier fluid formed containing substantial amounts of ferromagnetic material, multiple compounds matter in magnetic flow liquid, Complicated component, if dealt with improperly, easily works the mischief to environment.But so far, magnetic flow liquid is recycled Device or method are considerably less, only several relevant patent documentations, there is the blank of research.As, Chinese Patent Application No. is 201410508382.9, Shen Qing Publication day it is that the patent application document on January 21st, 2015 discloses a kind of big flow magnetorheological Liquid retracting device, including: it is arranged on magnetic flow liquid and has just departed from the neighbouring position of polishing area and keep flexible wires to contact with buff wheel Recovery head, it goes for receiving by the magnetic flow liquid thrown away bottom buff wheel;The vacuum generating device being connected with described recovery head, It is used for providing the power reclaiming magnetic flow liquid.But the device disclosed in this patent is mainly used for collection leaves polishing region After magnetic flow liquid, be not directed to magnetic flow liquid lost efficacy after recycling.
About the recycling of inefficacy magnetic flow liquid, research report little, through retrieval, Chinese Patent Application No. is: 201511025405.1, Shen Qing Publication day is that the patent application document on March 23rd, 2016 discloses a kind of magnetic flow liquid recovery Device and control method thereof and component manufacturing method, this invention is completed mixed liquor by filtration, the adsorption of electro static filtering plate Preliminary treatment, adsorption tube in recycling, lower adsorption tube complete the process to mixed liquor further with ribbed pipe absorption, and set up Heater, agitator and blood circulation, reach magnetisable material and purpose that solvent is completely separated.But the retracting device of this invention Following weak point is there is: (1) is because of its adsorption tube and ribbed pipe limited amount, it is impossible to ensure that solution fills with it during processing Tap is touched, and causes treatment effect low;(2) simultaneously complex-shaped because of adsorption tube and ribbed pipe, is unfavorable for processing, is also unfavorable for Collect the absorption magnetisable material on surface;(3) solution circulating rate in a device is relatively low, and flows to poor controllability, reduces Treatment effeciency.And for example, Chinese Patent Application No. is: 201511025384.3, and Shen Qing Publication day is the special of on April 6th, 2016 Profit application documents disclose a kind of magnetic flow liquid multi-stage treatment units and control method thereof and component manufacturing method, including preposition piston Cylinder, in put piston cylinder, rearmounted piston cylinder, preposition piston, in put piston, rearmounted piston, prefilter case, in put Rose Box, Rearmounted Rose Box, forward filtering net, in put drainage screen, rearmounted drainage screen, described preposition piston cylinder is by bolt and preposition work Plug is connected, and described preposition piston matches with the inner chamber of prefilter case, and described prefilter case is vertically placed, its axis For vertical direction, device disclosed in this patent of invention does not only exist defect present in above-mentioned patent, uses multistage place because of it simultaneously The mode of reason, causes device volume excessive, operation inconvenience, the problem that cost is high.
For the research blank problem existed in current inefficacy magnetic flow liquid recycling field, it is badly in need of developing corresponding equipment and place Reason method, processes discarded magnetic flow liquid, can not only reduce the pollution to environment, and can be to therein relevant Material recycles, and saves the energy.
Summary of the invention
Problem to be solved
Relevant high efficiente callback processing means is lacked for current magnetorheological waste liquid, and to environment after causing it to abandon, And cause the problem of energy waste, the present invention provide a kind of magnetic flow liquid recycling and processing device based on high-pressure filteration centrifugation and The main discrete particles of magnetic flow liquid can be separated by processing method, assembly of the invention and processing method with carrier fluid, is primarily directed to Both are separated, at follow-up recovery by main discrete particles and the magnetic flow liquid high treating effect of carrier fluid soap-free emulsion polymeization effect Reason provides may.
2. technical scheme
In order to solve the problems referred to above, the technical solution adopted in the present invention is as follows:
A kind of magnetic flow liquid recycling and processing device based on high-pressure filteration centrifugation, including exterior bowl, also includes that pressure filtration fills Putting, described pressure filter is arranged in exterior bowl, and pressure filter includes pressure pocket, and the bottom of pressure pocket was provided with Filter screen, drainage screen be arranged over adsorption tube, the diapire of described pressure filter is provided with several filter openings;Outside described The sidewall of staving is provided with recovery stop valve.
Further, the sidewall of described pressure filter is provided with breather and lower breather, described upper breather position In the top of pressure filter, also cross the sidewall of exterior bowl, in pressure pocket, it is passed through gas by described upper breather Apply pressure;Described lower breather position on pressure filter sidewall between drainage screen and adsorption tube, lower ventilation Pipe is also through the sidewall of exterior bowl.
Further, the upper end of described pressure filter is provided with dismountable sealing and covers.
Further, it is connected by bearing between bottom and the bottom of exterior bowl of described pressure filter.
Further, the bottom of described exterior bowl is respectively arranged at two ends with base;In described adsorption tube, coil is set.
Further, the mesh number of described drainage screen is 1000~1200, with sintered material layer on drainage screen.
Further, described sintered material by activated alumina, graphite, stearic acid, phenolic resin, Colophonium, clay with matter Amount, than the ratio mix homogeneously for 1:2:1:2.5:2:9, cools down after being heated to melting and obtains.
A kind of magnetic flow liquid recovery and treatment method, uses above-mentioned magnetic flow liquid based on high-pressure filteration centrifugation recycling dress Put and process, the steps include:
A. magnetic flow liquid is carried out preliminary treatment, make the main discrete particles of magnetic flow liquid and carrier fluid break off annexation;
B. the magnetic flow liquid after step a processes is added in pressure pocket, to the coil electricity in adsorption tube so that it is produce stable Magnetic field;
C. closing lower breather, in utilization, breather is passed through noble gas in pressure pocket, pressurizes magnetic flow liquid therein, And keep 25~30min;
D. the lower breather of recycling is ventilated in pressure pocket, opens breather so that it is be in exhaust condition simultaneously, and the time is 2~3 Min, after close lower breather;
E. step b and step c 4~5 times are repeated;
F. open recovery stop valve, collect solution, from adsorption tube, reclaim magnetisable material.
Further, the magnetic field intensity that step b coil produces is 2.8~3.2T.
Further, the solution collected in step f is again loaded in pressure pocket, repetition step a~e 2~3 times.
3. beneficial effect
Compared to prior art, the invention have the benefit that
(1) present invention magnetic flow liquid based on high-pressure filteration centrifugation retracting device, by pressure filtration and electrical cooperation effect, Main dispersed magnetic material in magnetic flow liquid is reclaimed with carrier fluid isolated, and compared to existing processing means, its structure obtains To being greatly simplified, reducing equipment volume, this device, in magnetic flow liquid processing procedure, makes magnetisable material by breather line And not disturbing between carrier fluid, Magnetic Materials mass-energy is adsorbed equably on adsorption tube surface, is not easily blocked drainage screen, available very short time Reclaiming a large amount of magnetisable material, minimizing equipment repeats to process step, and treatment effeciency is high;
(2) magnetic field is produced first with adsorption tube after the present invention is energized so that break off the magnetisable material of annexation with carrier fluid Absorption, on adsorption tube, recycles the form that noble gas (e.g., nitrogen etc.) pressurizes, extrudes mixed solution by force, due to magnetic Property material be adsorbed pipe absorption, and the particle diameter of carrier fluid is less than the particle diameter of magnetisable material, so that carrier fluid runs through Drainage screen, and magnetisable material is stayed on adsorption tube and drainage screen, thus realize magnetisable material and separate with carrier fluid;
(3) being attached with sintered material on the drainage screen of the present invention, sintered material is by activated alumina, graphite, stearic acid, phenolic aldehyde Resin, Colophonium, the clay ratio mix homogeneously with mass ratio as 1:2:1:2.5:2:9, cools down after being heated to melting and obtains, the present invention In sintered material component be that the carrier fluid character for magnetic flow liquid is specialized in and obtained, the whole of drainage screen can not only be significantly improved Body structural strength, even if drainage screen is rolled into cylindric being not easy to and comes off, and carrier fluid is with good adherence of blocking mesh on drainage screen, The resistance to corrosion of drainage screen is also significantly improved so that the whole service life of drainage screen extends about 25%;
(4) high-pressure filteration is separated and combines with Magneto separate by the present invention dexterously, utilize modified inorganic agent by main discrete particles and Annexation between carrier fluid is cut off, and then realizes magnetisable material and the separation of carrier fluid, recovery, magnetisable material in a device The response rate be up to more than 95%, there is the advantages such as the response rate is high, the used time is short, good in economic efficiency;
(5) in the present invention, seal between lid and pressure filter, between breather and pressure filter, be equipped with sealing rubber Cushion rubber, it is ensured that the gas tightness in pressure pocket so that filter efficiency is guaranteed.
Accompanying drawing explanation
Fig. 1 is the structural representation of magnetic flow liquid recycling and processing device based on high-pressure filteration centrifugation in the present invention.
In figure: 1, exterior bowl;2, base;3, bearing;4, pressure filter;401, filter opening;402, pressure pocket;5、 Seal lid;6, drainage screen;7, adsorption tube;8, upper breather;9, lower breather;10, stop valve is reclaimed.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is further described below.
Embodiment 1
As it is shown in figure 1, a kind of magnetic flow liquid recycling and processing device based on high-pressure filteration centrifugation, including exterior bowl 1 with add Press filtering device 4, the two ends, bottom of exterior bowl 1 are equipped with base 2;Pressure filter 4 is arranged in exterior bowl 1, pressurization The concrete structure of defecator 4 is the container of hollow, upper end open, and opening part is provided with dismountable sealing lid 5, seals lid 5 It is provided with sealing rubber ring, it is ensured that seal the sealing between lid 5 and pressure filter 4, within pressure filter 4 Cavity is pressure pocket 402, and the bottom of pressure pocket 402 is provided with drainage screen 6, drainage screen 6 be arranged over adsorption tube 7, absorption Arranging coil in pipe 7, can produce magnetic field in the surrounding of adsorption tube 7 after coil electricity, one end of coil connects controller, controls The magnetic field intensity that coil produces;The diapire of pressure filter 4 is provided with several filter openings 401, a diameter of about 4mm in hole, Outflow for liquid;Breather 8 and lower breather 9, upper breather 8 it is equipped with on the two side of pressure filter 4 It is positioned at the top of pressure filter 4, also cross the sidewall of exterior bowl 1, pressure pocket 402 is connected with extraneous pressue device, In pressure pocket 402, it is passed through gas by upper breather 8 and magnetic flow liquid therein is applied pressure;Lower breather 9 presses through adding Filter device 4 sidewall on position between drainage screen 6 and adsorption tube 7, lower breather 9 also through the sidewall of exterior bowl 1, Pressure pocket 402 is connected with extraneous pressue device.The sidewall of exterior bowl 1 is provided with recovery stop valve 10, controls in exterior bowl 1 Liquid flow out.It is connected by bearing 3 between the bottom of pressure filter 4 and the bottom of exterior bowl 1.The mesh of drainage screen 6 Number is about 1200, and with sintered material layer on drainage screen 6, sintered material is by activated alumina, graphite, stearic acid, phenolic aldehyde Resin, Colophonium, the clay ratio mix homogeneously with mass ratio as 1:2:1:2.5:2:9, cools down after being heated to melting and obtains, this sintering The component of material layer is specific to the carrier fluid character of magnetic flow liquid and specializes in and obtain, and can significantly improve the overall knot of drainage screen Structure intensity, even if drainage screen is rolled into cylindric being not easy to and comes off, and carrier fluid is not with good adherence of blocking mesh on drainage screen, clean Being also convenient for, the resistance to corrosion of drainage screen increases significantly compared with existing drainage screen so that the overall of drainage screen uses the longevity Life extends about 25%.
The magnetic flow liquid that the magnetic flow liquid processed in the present embodiment is is surfactant main component with oleic acid, discrete particles is hydroxyl Base iron powder, magnetic saturation is 2.1T, and carrier fluid is mineral oil, and this magnetic flow liquid waste liquid pending in the present embodiment is to use at it Exceeding the solution after its shear fatigue life-span, now the variable quantity of its zero-shear viscosity and adjustable multiple all exceedes in checkout procedure ± 10%;Magnetic flow liquid recycling and processing device based on high-pressure filteration centrifugation described in employing processes, and the steps include:
A. magnetic flow liquid is carried out preliminary treatment, make the main discrete particles of magnetic flow liquid and carrier fluid break off annexation;
B. the magnetic flow liquid after step a processes is added in pressure pocket 402, to the coil electricity in adsorption tube 7 so that it is produce Raw stable magnetic field, magnetic field intensity is 2.8T;
C. closing lower breather 9, in utilization, breather 8 is passed through noble gas in pressure pocket 402, to magnetic flow liquid therein Pressurizeing, and keep 30min, pressure meetsWherein, P is pressure value, units MPa;λ is Number, value is 2.84;B is field strength value, and unit is T;C is the concentration values of magnetisable material in magnetic flow liquid, logical Being often 20~40g/mL, in the magnetic flow liquid processed in the present embodiment, the concentration of magnetisable material is about 40g/mL, therefore this reality Execute and example controls pressure P=3.46MPa in pressure pocket 402;
D. the lower breather 9 of recycling is ventilated in pressure pocket 402, opens breather 8 so that it is be in exhaust condition simultaneously, Time is 2min, after close lower breather 9;
E. repeat step b and step c, be repeated 4 times altogether;
F. open recovery stop valve 10, collect solution, from adsorption tube 7, reclaim magnetisable material.
In order to improve the organic efficiency of magnetisable material in magnetic flow liquid, the solution collected can be again loaded into pressure pocket in step f In 402, repeat step a~e 3 times so that the separation degree of main discrete particles and carrier fluid is up to 96%.
The inorganic agent using oleic acid modified in the present embodiment carries out preliminary treatment to magnetic flow liquid, and inorganic agent includes solvent first and solute Second, constituent and each constituent mass percentage ratio of solvent first is: potassium permanganate 0.3%, sodium hydroxide 13%, attapulgite 2%, remaining is water.Attapulgite needs to carry out preliminary pretreatment, and processing procedure is: use waterpower sorting to purify attapulgite, Attapulgite breeze and deionized water are mixed in container, stir 40min with the rotating speed of 200r/min, then stand 3h, Discard the supernatant and lower floor's sandy soil, obtain the suspension of attapulgite, the attapulgite that will obtain after suspension centrifugation It is placed in baking oven and is dried;Attapulgite in solvent first can promote that potassium permanganate plays a role so that it is oxidation rate and efficiency all obtain Significantly to improve;Constituent and each constituent mass percentage ratio of solute second is: manganese dioxide 92%, and potassium salt is 2%, its Yu Weishui;The mass values of solvent first and solute second is 58:1, and concrete using method is as follows:
(1) a certain amount of solvent first being poured in discarded magnetic flow liquid and stir, mixing speed is so that the mean flow rate of mixed liquor is 0.2m/s, mixing time is 3min, and wherein, the quality of solvent first is the 4% of magnetic flow liquid gross mass;
(2) continuing to be proportionally added into the stirring of solute second, mixing speed is so that the mean flow rate of mixed liquor is 0.4m/s, stirring Time is 5min;
(3) by oxygen in mixed liquor, the purity of oxygen is 90%, the intake 2L/ (m of oxygen3Min), when being passed through Between be 15min, mixed liquor is heated simultaneously, maintains the temperature between 60 DEG C, temperature retention time is 25min, after insulation from So it is cooled to 30 DEG C;
(4) after being cooled to 30 DEG C, after placing 25min, in mixed liquor, carbon dioxide it is passed through, the intake of carbon dioxide For 4L/ (m3Min), the time that is passed through is 6min;
(5) mixed liquor is heated to 240 DEG C, and is incubated 8min;
(6) mixed liquor being positioned under sunlight (intensity of illumination is at about the 4.5 ten thousand lx) 3h that is exposed to the sun, the purpose being exposed to the sun is so that Unnecessary potassium permanganate decomposes completely;The most main discrete particles with carrier fluid renunciation, then recycling the present embodiment in Magnetic flow liquid recycling and processing device based on high-pressure filteration centrifugation processes, and is adsorbed by main dispersion liquid, thus reaches to separate Purpose.
In the present embodiment, carrying out high-pressure filteration when separating, the pressure in pressure pocket 402 is to consider magnetic field intensity and magnetorheological In liquid, the concentration of magnetisable material selects, and finds in research process, according toPressure when setting separation, separates Effect best, the plugging rate of drainage screen have dropped about 15%, and separation efficiency is significantly improved.
Embodiment 2
As it is shown in figure 1, a kind of magnetic flow liquid recycling and processing device based on high-pressure filteration centrifugation, including exterior bowl 1 with add Press filtering device 4, the two ends, bottom of exterior bowl 1 are equipped with base 2;Pressure filter 4 is arranged in exterior bowl 1, pressurization The concrete structure of defecator 4 is the container of hollow, upper end open, and opening part is provided with dismountable sealing lid 5, internal sky Chamber is pressure pocket 402, and the bottom of pressure pocket 402 is provided with drainage screen 6, drainage screen 6 be arranged over adsorption tube 7, adsorption tube Coil is set in 7, after coil electricity, magnetic field can be produced in the surrounding of adsorption tube 7, if the diapire of pressure filter 4 is provided with Dry filter opening 401, a diameter of about 7mm in hole, for the outflow of liquid;It is equipped with on the two side of pressure filter 4 Upper breather 8 and lower breather 9, upper breather 8 is positioned at the top of pressure filter 4, also cross the side of exterior bowl 1 Wall, connects pressure pocket 402 with extraneous pressue device, is passed through gas to therein by upper breather 8 in pressure pocket 402 Magnetic flow liquid applies pressure;The lower breather 9 position on pressure filter 4 sidewall be positioned at drainage screen 6 and adsorption tube 7 it Between, pressure pocket 402, also through the sidewall of exterior bowl 1, is connected by lower breather 9 with extraneous pressue device.The side of exterior bowl 1 Wall is provided with recovery stop valve 10, controls the liquid in exterior bowl 1 and flows out.The bottom of pressure filter 4 and exterior bowl 1 Connected by bearing 3 between Di Bu.The mesh number of drainage screen 6 is about 1000, with sintered material layer on drainage screen 6, and sintering Material is mixed by ratio with mass ratio as 1:2:1:2.5:2:9 of activated alumina, graphite, stearic acid, phenolic resin, Colophonium, clay Closing uniformly, cool down and obtain after being heated to melting, the carrier fluid character that the component of this sintered material layer is specific to magnetic flow liquid is special Research obtains, and can significantly improve the overall construction intensity of drainage screen, even if drainage screen is rolled into cylindric being not easy to and comes off, and Carrier fluid is not with good adherence of blocking mesh on drainage screen, cleaning is also convenient for, and the resistance to corrosion of drainage screen is compared with existing drainage screen Increase significantly so that the whole service life of drainage screen extends about 25%.
A kind of magnetic flow liquid recovery and treatment method, magnetic flow liquid based on high-pressure filteration centrifugation recycling described in employing Device processes, and the steps include:
A. magnetic flow liquid is carried out preliminary treatment, make the main discrete particles of magnetic flow liquid and carrier fluid break off annexation;
B. the magnetic flow liquid after step a processes is added in pressure pocket 402, to the coil electricity in adsorption tube 7 so that it is produce Raw stable magnetic field, magnetic field intensity is 3.2T;
C. closing lower breather 9, in utilization, breather 8 is passed through noble gas in pressure pocket 402, to magnetic flow liquid therein Pressurizeing, and keep 25min, pressure meetsWherein, P is pressure value, units MPa;λ is Number, value is 2.84;B is field strength value, and unit is T;C is the concentration values of magnetisable material in magnetic flow liquid, logical Being often 20~40g/mL, in the magnetic flow liquid processed in the present embodiment, the concentration of magnetisable material is about 20g/mL, therefore this reality Execute and example controls pressure P=2.41MPa in pressure pocket 402;
D. the lower breather 9 of recycling is ventilated in pressure pocket 402, opens breather 8 so that it is be in exhaust condition simultaneously, Time is 3min, after close lower breather 9;
E. repeat step b and step c, be repeated 5 times altogether;
F. open recovery stop valve 10, collect solution, from adsorption tube 7, reclaim magnetisable material.
In order to improve the organic efficiency of magnetisable material in magnetic flow liquid, the solution collected can be again loaded into pressure pocket in step f In 402, repeating step a~e, number of repetition is 2 times so that the separation degree of main discrete particles and carrier fluid is up to 94.3%.
The inorganic agent using oleic acid modified in the present embodiment carries out preliminary treatment to magnetic flow liquid, and inorganic agent includes solvent first and solute Second, constituent and each constituent mass percentage ratio of solvent first is: potassium permanganate 0.2%, sodium hydroxide 10%, attapulgite 3%, remaining is water.Attapulgite needs to carry out preliminary pretreatment, and processing procedure is: use waterpower sorting to purify attapulgite, Attapulgite breeze and deionized water are mixed in container, stir 40min with the rotating speed of 200r/min, then stand 3h, Discard the supernatant and lower floor's sandy soil, obtain the suspension of attapulgite, the attapulgite that will obtain after suspension centrifugation It is placed in baking oven and is dried;Attapulgite in solvent first can promote that potassium permanganate plays a role so that it is oxidation rate and efficiency all obtain Significantly to improve;Constituent and each constituent mass percentage ratio of solute second is: manganese dioxide 90%, and potassium salt is 1%, its Yu Weishui;The mass values of solvent first and solute second is 55:1, and concrete using method is as follows:
(1) a certain amount of solvent first being poured in discarded magnetic flow liquid and stir, mixing speed is so that the mean flow rate of mixed liquor is 0.1m/s, mixing time is 2min, and wherein, the quality of solvent first is the 3% of magnetic flow liquid gross mass;
(2) continuing to be proportionally added into the stirring of solute second, mixing speed is so that the mean flow rate of mixed liquor is 0.3m/s, stirring Time is 4min;
(3) by oxygen in mixed liquor, the purity of oxygen is 60%, the intake 1L/ (m of oxygen3Min), when being passed through Between be 10min, mixed liquor is heated simultaneously, maintains the temperature between 40 DEG C, temperature retention time is 20min, after insulation from So it is cooled to 25 DEG C;
(4) after being cooled to 25 DEG C, after placing 30min, in mixed liquor, carbon dioxide it is passed through, the intake of carbon dioxide For 2L/ (m3Min), the time that is passed through is 5min;
(5) mixed liquor is heated to 200 DEG C, and is incubated 10min;
(6) mixed liquor is positioned under sunlight (intensity of illumination is at about 8.5 ten thousand lx), and be exposed to the sun 2h.The purpose being exposed to the sun is so that Unnecessary potassium permanganate decomposes completely;The most main discrete particles with carrier fluid renunciation, then recycling the present embodiment in Magnetic flow liquid recycling and processing device based on high-pressure filteration centrifugation processes, and is adsorbed by main dispersion liquid, thus reaches to separate Purpose.
In the present embodiment, carrying out high-pressure filteration when separating, the pressure in pressure pocket 402 is to consider magnetic field intensity and magnetorheological In liquid, the concentration of magnetisable material selects, and finds in research process, according toPressure when setting separation, separation Effect is best, and the plugging rate of drainage screen have dropped about 17%, and separation efficiency is significantly improved.
Embodiment 3
As it is shown in figure 1, a kind of magnetic flow liquid recycling and processing device based on high-pressure filteration centrifugation, its structure is with embodiment 1. The method using this device to recycle magnetic flow liquid is:
A. magnetic flow liquid is carried out preliminary treatment, make the main discrete particles of magnetic flow liquid and carrier fluid break off annexation;
B. the magnetic flow liquid after step a processes is added in pressure pocket 402, to the coil electricity in adsorption tube 7 so that it is produce Raw stable magnetic field, magnetic field intensity is 3.0T;
C. closing lower breather 9, in utilization, breather 8 is passed through noble gas in pressure pocket 402, to magnetic flow liquid therein Pressurizeing, and keep 30min, pressure meetsWherein, P is pressure value, units MPa;λ is Number, value is 2.84;B is field strength value, and unit is T;C is the concentration values of magnetisable material in magnetic flow liquid, logical Being often 20~40g/mL, in the magnetic flow liquid processed in the present embodiment, the concentration of magnetisable material is about 30g/mL, therefore this reality Execute and example controls pressure P=2.94MPa in pressure pocket 402;
D. the lower breather 9 of recycling is ventilated in pressure pocket 402, opens breather 8 so that it is be in exhaust condition simultaneously, Time is 3min, after close lower breather 9;
E. repeat step b and step c, be repeated 4 times altogether;
F. open recovery stop valve 10, collect solution, from adsorption tube 7, reclaim magnetisable material.
In order to improve the organic efficiency of magnetisable material in magnetic flow liquid, the solution collected can be again loaded into pressure pocket in step f In 402, repeating step a~e, number of repetition is 2 times so that the separation degree of main discrete particles and carrier fluid is up to 97%.
The inorganic agent using oleic acid modified in the present embodiment carries out preliminary treatment to magnetic flow liquid, and inorganic agent includes solvent first and solute Second, constituent and each constituent mass percentage ratio of solvent first is: potassium permanganate 0.5%, sodium hydroxide 14%, attapulgite 3%, remaining is water.Attapulgite needs to carry out preliminary pretreatment, and processing procedure is: use waterpower sorting to purify attapulgite, Attapulgite breeze and deionized water are mixed in container, stir 40min with the rotating speed of 200r/min, then stand 3h, Discard the supernatant and lower floor's sandy soil, obtain the suspension of attapulgite, the attapulgite that will obtain after suspension centrifugation It is placed in baking oven and is dried;Attapulgite in solvent first can promote that potassium permanganate plays a role so that it is oxidation rate and efficiency all obtain Significantly to improve;Constituent and each constituent mass percentage ratio of solute second is: manganese dioxide 94%, and potassium salt is 1%, its Yu Weishui;The mass values of solvent first and solute second is 56:1, and concrete using method is as follows:
(1) a certain amount of solvent first being poured in discarded magnetic flow liquid and stir, mixing speed is so that the mean flow rate of mixed liquor is 0.15m/s, mixing time is 2.5min, and wherein, the quality of solvent first is the 3.5% of magnetic flow liquid gross mass;
(2) continuing to be proportionally added into the stirring of solute second, mixing speed is so that the mean flow rate of mixed liquor is 0.35m/s, stirring Time is 4.5min;
(3) by oxygen in mixed liquor, the purity of oxygen is 80%, the intake 1.5L/ (m of oxygen3Min), it is passed through Time is 13min, heats mixed liquor simultaneously, maintains the temperature between 50 DEG C, and temperature retention time is 23min, after insulation Naturally cool to 25 DEG C;
(4) after being cooled to 25 DEG C, after placing 25min, in mixed liquor, carbon dioxide it is passed through, the intake of carbon dioxide For 3L/ (m3Min), the time that is passed through is 5min;
(5) mixed liquor is heated to 220 DEG C, and is incubated 9min;
(6) mixed liquor is positioned under sunlight (intensity of illumination is at about the 60000 lx) 2.5h that is exposed to the sun.The purpose being exposed to the sun is so that Unnecessary potassium permanganate decomposes completely;The most main discrete particles with carrier fluid renunciation, then recycling the present embodiment in Magnetic flow liquid recycling and processing device based on high-pressure filteration centrifugation processes, and is adsorbed by main dispersion liquid, thus reaches to separate Purpose.
In the present embodiment, carrying out high-pressure filteration when separating, the pressure in pressure pocket 402 is to consider magnetic field intensity and magnetorheological In liquid, the concentration of magnetisable material selects, and finds in research process, according toPressure when setting separation, separation Effect is best, and the plugging rate of drainage screen have dropped about 17%, and separation efficiency is significantly improved.

Claims (10)

1. a magnetic flow liquid recycling and processing device based on high-pressure filteration centrifugation, including exterior bowl (1), it is characterised in that: Also include that pressure filter (4), described pressure filter (4) are arranged in exterior bowl (1), pressure filter (4) include that pressure pocket (402), the bottom of pressure pocket (402) are provided with drainage screen (6), drainage screen (6) be arranged over inhale Attached pipe (7), the diapire of described pressure filter (4) is provided with several filter openings (401);Described exterior bowl (1) Sidewall be provided with recovery stop valve (10).
A kind of magnetic flow liquid recycling and processing device based on high-pressure filteration centrifugation the most according to claim 1, its feature Being: the sidewall of described pressure filter (4) is provided with breather (8) and lower breather (9), described is upper logical Trachea (8) is positioned at the top of pressure filter (4), also cross the sidewall of exterior bowl (1), by described upper ventilation Pipe (8) is passed through gas in pressure pocket (402) and applies pressure;Described lower breather (9) is in pressure filter (4) Position on sidewall is positioned between drainage screen (6) and adsorption tube (7), and lower breather (9) is also through the side of exterior bowl (1) Wall.
A kind of magnetic flow liquid recycling and processing device based on high-pressure filteration centrifugation the most according to claim 1 and 2, its It is characterised by: the upper end of described pressure filter (4) is provided with dismountable sealing and covers (5).
A kind of magnetic flow liquid recycling and processing device based on high-pressure filteration centrifugation the most according to claim 3, its feature It is: be connected by bearing (3) between bottom and the bottom of exterior bowl (1) of described pressure filter (4).
A kind of magnetic flow liquid recycling and processing device based on high-pressure filteration centrifugation the most according to claim 4, its feature It is: the two ends, bottom of described exterior bowl (1) are equipped with base (2);In described adsorption tube (7), coil is set.
A kind of magnetic flow liquid recycling and processing device based on high-pressure filteration centrifugation the most according to claim 1, its feature Being: the mesh number of described drainage screen (6) is 1000~1200, drainage screen (6) is upper with sintered material layer.
A kind of magnetic flow liquid recycling and processing device based on high-pressure filteration centrifugation the most according to claim 6, its feature It is: described sintered material by activated alumina, graphite, stearic acid, phenolic resin, Colophonium, clay with mass ratio is 1:2:1:2.5:2:9 ratio mix homogeneously, be heated to melted after cool down and obtain.
8. a magnetic flow liquid recovery and treatment method, it is characterised in that: use pressing through based on height described in claim 1 or 2 The magnetic flow liquid recycling and processing device of filter centrifugation processes, and the steps include:
A. magnetic flow liquid is carried out preliminary treatment, make the main discrete particles of magnetic flow liquid and carrier fluid break off annexation;
B. the magnetic flow liquid after step a processes is added in pressure pocket (402), to the coil electricity in adsorption tube (7), It is made to produce stable magnetic field;
C. closing lower breather (9), in utilization, breather (8) is passed through noble gas in pressure pocket (402), to therein Magnetic flow liquid pressurizes, and keeps 25~30min;
D. the ventilation in pressure pocket (402) of the lower breather (9) of recycling, opens breather (8) so that it is the row of being in simultaneously Gaseity, the time is 2~3min, after close lower breather (9);
E. step b and step c4~5 times are repeated;
F. open recovery stop valve (10), collect solution, from adsorption tube (7), reclaim magnetisable material.
A kind of magnetic flow liquid recovery and treatment method the most according to claim 8, it is characterised in that: step b coil produces Magnetic field intensity be 2.8~3.2T.
A kind of magnetic flow liquid recovery and treatment method the most according to claim 8, it is characterised in that: by what step f was collected Solution is again loaded in pressure pocket (402), repetition step a~e2~3 times.
CN201610616686.6A 2016-07-29 2016-07-29 Magnetorheological fluid recycling treatment device and treatment method based on high-pressure filtering separation effect Withdrawn CN106007164A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111217485A (en) * 2020-02-11 2020-06-02 龙岩学院 Magnetic seed separation device and mining underground water purification system thereof
CN112246193A (en) * 2020-11-11 2021-01-22 北京大学 Device and method for cyclic reaction and continuous separation of magnetic particles in heterogeneous reaction
CN114367266A (en) * 2021-12-22 2022-04-19 赵宇 Modified asphalt production equipment

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111217485A (en) * 2020-02-11 2020-06-02 龙岩学院 Magnetic seed separation device and mining underground water purification system thereof
CN112246193A (en) * 2020-11-11 2021-01-22 北京大学 Device and method for cyclic reaction and continuous separation of magnetic particles in heterogeneous reaction
CN112246193B (en) * 2020-11-11 2024-05-17 北京大学 Device and method for cyclic reaction and continuous separation of magnetic particles in heterogeneous reactions
CN114367266A (en) * 2021-12-22 2022-04-19 赵宇 Modified asphalt production equipment
CN114367266B (en) * 2021-12-22 2024-02-20 浙江威肯特智能机械有限公司 Modified asphalt production equipment

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