CN105970720A - Rosin sizing agent - Google Patents
Rosin sizing agent Download PDFInfo
- Publication number
- CN105970720A CN105970720A CN201610313828.1A CN201610313828A CN105970720A CN 105970720 A CN105970720 A CN 105970720A CN 201610313828 A CN201610313828 A CN 201610313828A CN 105970720 A CN105970720 A CN 105970720A
- Authority
- CN
- China
- Prior art keywords
- parts
- sizing agent
- rosin sizing
- rosin
- fatty acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004513 sizing Methods 0.000 title claims abstract description 25
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 title claims abstract description 24
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 title claims abstract description 24
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 title claims abstract description 24
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229920001732 Lignosulfonate Polymers 0.000 claims abstract description 14
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 14
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims abstract description 14
- 239000008367 deionised water Substances 0.000 claims abstract description 14
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 14
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 14
- 239000000194 fatty acid Substances 0.000 claims abstract description 14
- 229930195729 fatty acid Natural products 0.000 claims abstract description 14
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 14
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 14
- 235000017281 sodium acetate Nutrition 0.000 claims abstract description 14
- 239000001632 sodium acetate Substances 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 3
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 claims description 13
- 239000003921 oil Substances 0.000 claims description 12
- JZZIHCLFHIXETF-UHFFFAOYSA-N dimethylsilicon Chemical compound C[Si]C JZZIHCLFHIXETF-UHFFFAOYSA-N 0.000 claims description 11
- 229940008099 dimethicone Drugs 0.000 claims 1
- 239000004205 dimethyl polysiloxane Substances 0.000 claims 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 abstract 2
- 235000019357 lignosulphonate Nutrition 0.000 abstract 2
- 229920002545 silicone oil Polymers 0.000 abstract 2
- 235000012424 soybean oil Nutrition 0.000 abstract 2
- 239000003549 soybean oil Substances 0.000 abstract 2
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 235000004258 Cordia alliodora Nutrition 0.000 description 1
- 244000085692 Cordia alliodora Species 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F1/00—Obtaining purification, or chemical modification of natural resins, e.g. oleo-resins
- C09F1/04—Chemical modification, e.g. esterification
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Paper (AREA)
Abstract
The invention disclosed a rosin sizing agent, belonging to the technical field of rosin deep processing. The rosin sizing agent is prepared from the following raw materials in parts by weight: 100 parts of rosin, 15-20 parts of soybean oil fatty acid, 5-8 parts of phosphoryl trichloride, 1-2 parts of sodium acetate, 6-10 parts of polyethylene glycol, 0.1-0.2 part of sulfonated lignin, 15-25 parts of dimethyl silicone oil and 10-15 parts of deionized water with conductivity less than 5mu S/ cm. By adding the soybean oil fatty acid, the phosphoryl trichloride, the sodium acetate, the polyethylene glycol, the sulfonated lignin, the dimethyl silicone oil and the deionized water with conductivity less than 5mu S/cm into the rosin, the prepared rosin sizing agent has the advantage of being high in stability.
Description
Technical field
The invention belongs to Colophonium deep process technology field, particularly relate to a kind of rosin sizing agent.
Background technology
Sizing agent is the additive of a kind of papermaking, and it can give paper and the anti-ink of cardboard, water resistant, anti-emulsion, the performance such as anticorrosive to improve its smoothness, intensity and validity period.Sizing agent can be divided into internal sizing agent and Cypres, and wherein rosin sizing agent belongs to the one of paper making additive internal sizing agent.
The rosin sizing agent kind that existing market is sold is a lot, but it shows the defect that stability is poor, the shelf-life is too short mostly.
Summary of the invention
The technical problem to be solved is to provide a kind of rosin sizing agent, thus solves the problem that existing rosin sizing agent existence and stability energy is poor, the shelf-life is too short.
In order to solve above-mentioned technical problem, the technical solution adopted in the present invention is:
It is prepared by the raw material of following weight portion:
Colophonium 100 parts, soy(a)-bean oil fatty acid 15 parts～20 parts, phosphorus oxychloride 5 parts～8 parts, sodium acetate 1 part～2 parts, Polyethylene Glycol 6 parts～10 parts, lignosulfonate 0.1 part～0.2 part, dimethyl-silicon 15 parts～25 parts and the electrical conductivity deionized water 10 parts～15 parts less than 5 μ S/cm.
In technique scheme, more specifically technical scheme is: Colophonium 100 parts, soy(a)-bean oil fatty acid 15 parts, phosphorus oxychloride 5 parts, sodium acetate 2 parts, Polyethylene Glycol 8 parts, lignosulfonate 0.15 part, dimethyl-silicon 20 parts and the electrical conductivity deionized water 15 parts less than 5 μ S/cm；
Further, Colophonium 100 parts, soy(a)-bean oil fatty acid 17 parts, phosphorus oxychloride 8 parts, sodium acetate 1 part, Polyethylene Glycol 10 parts, lignosulfonate 0.1 part, dimethyl-silicon 15 parts and the electrical conductivity deionized water 12 parts less than 5 μ S/cm；
Further, Colophonium 100 parts, soy(a)-bean oil fatty acid 20 parts, phosphorus oxychloride 6 parts, sodium acetate 1.5 parts, Polyethylene Glycol 6 parts, lignosulfonate 0.2 part, dimethyl-silicon 25 parts and the electrical conductivity deionized water 10 parts less than 5 μ S/cm.
Owing to using technique scheme, there is advantages that
The present invention is by adding soy(a)-bean oil fatty acid, phosphorus oxychloride, sodium acetate, Polyethylene Glycol, lignosulfonate, dimethyl-silicon and the electrical conductivity deionized water less than 5 μ S/cm in Colophonium, so that the product rosin sizing agent prepared has the advantage that stability is strong.
Detailed description of the invention
Below in conjunction with instantiation, the invention will be further described:
Embodiment 1
The preparation method of this rosin sizing agent is as follows:
Under stirring, first Colophonium 100 kg is added thermal melting, it is subsequently adding soy(a)-bean oil fatty acid 15 kg, phosphorus oxychloride 5kg, sodium acetate 2kg, Polyethylene Glycol 8kg, lignosulfonate 0.15kg, dimethyl-silicon 20kg and the electrical conductivity deionized water 15kg less than 5 μ S/cm, it is then heated to 80 DEG C, isothermal reaction 2 hours.
The rosin sizing agent good stability that the present embodiment prepares, can store 2 years when 40 DEG C.
Embodiment 2
This rosin sizing agent includes following preparation process:
Under stirring, first Colophonium 100 kg is added thermal melting, it is subsequently adding soy(a)-bean oil fatty acid 17 kg, phosphorus oxychloride 8kg, sodium acetate 1kg, Polyethylene Glycol 10kg, lignosulfonate 0.1kg, dimethyl-silicon 15kg and the electrical conductivity deionized water 12kg less than 5 μ S/cm, it is then heated to 65 DEG C, isothermal reaction 2 hours.
The rosin sizing agent good stability that the present embodiment prepares, can store 2 years when 40 DEG C.
Embodiment 3
This rosin sizing agent includes following preparation process:
Under stirring, first Colophonium 100 kg is added thermal melting, it is subsequently adding soy(a)-bean oil fatty acid 20 kg, phosphorus oxychloride 6kg, sodium acetate 1.5kg, Polyethylene Glycol 6kg, lignosulfonate 0.2kg, dimethyl-silicon 25kg and the electrical conductivity deionized water 10kg less than 5 μ S/cm, it is then heated to 60 DEG C, isothermal reaction 1 hour.
The rosin sizing agent good stability that the present embodiment prepares, can store 2 years when 40 DEG C.
Claims (4)
1. a rosin sizing agent, it is characterised in that prepared by the raw material of following weight portion:
Colophonium 100 parts, soy(a)-bean oil fatty acid 15 parts～20 parts, phosphorus oxychloride 5 parts～8 parts, sodium acetate 1 part～2 parts, Polyethylene Glycol 6 parts～10 parts, lignosulfonate 0.1 part～0.2 part, dimethicone 15 parts～25 parts and the electrical conductivity deionized water 10 parts～15 parts less than 5 μ S/cm.
Rosin sizing agent the most according to claim 1, it is characterised in that: Colophonium 100 parts, soy(a)-bean oil fatty acid 15 parts, phosphorus oxychloride 5 parts, sodium acetate 2 parts, Polyethylene Glycol 8 parts, lignosulfonate 0.15 part, dimethyl-silicon 20 parts and the electrical conductivity deionized water 15 parts less than 5 μ S/cm.
Rosin sizing agent the most according to claim 1, it is characterised in that: Colophonium 100 parts, soy(a)-bean oil fatty acid 17 parts, phosphorus oxychloride 8 parts, sodium acetate 1 part, Polyethylene Glycol 10 parts, lignosulfonate 0.1 part, dimethyl-silicon 15 parts and the electrical conductivity deionized water 12 parts less than 5 μ S/cm.
Rosin sizing agent the most according to claim 1, it is characterised in that: Colophonium 100 parts, soy(a)-bean oil fatty acid 20 parts, phosphorus oxychloride 6 parts, sodium acetate 1.5 parts, Polyethylene Glycol 6 parts, lignosulfonate 0.2 part, dimethyl-silicon 25 parts and the electrical conductivity deionized water 10 parts less than 5 μ S/cm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610313828.1A CN105970720A (en) | 2016-05-12 | 2016-05-12 | Rosin sizing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610313828.1A CN105970720A (en) | 2016-05-12 | 2016-05-12 | Rosin sizing agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105970720A true CN105970720A (en) | 2016-09-28 |
Family
ID=56992405
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610313828.1A Pending CN105970720A (en) | 2016-05-12 | 2016-05-12 | Rosin sizing agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105970720A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116289300A (en) * | 2023-02-20 | 2023-06-23 | 天津科技大学 | Lignin rosin sizing agent, preparation method and application |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1215444A (en) * | 1996-02-02 | 1999-04-28 | 赫尔克里士公司 | Emulsifier system for rosin sizing agents |
| CN1281390A (en) * | 1997-10-10 | 2001-01-24 | 联合碳化化学品及塑料技术公司 | Spray application of additive composition to sheet materials |
| CN101255668A (en) * | 2008-04-09 | 2008-09-03 | 广西壮族自治区化工研究院 | High stability cation dispersion rosin size and manufacture method thereof |
| CN101880989A (en) * | 2010-06-24 | 2010-11-10 | 杭州杭化播磨造纸化学品有限公司 | Rosin emulsion sizing agent for temperature-resistant paper |
-
2016
- 2016-05-12 CN CN201610313828.1A patent/CN105970720A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1215444A (en) * | 1996-02-02 | 1999-04-28 | 赫尔克里士公司 | Emulsifier system for rosin sizing agents |
| CN1281390A (en) * | 1997-10-10 | 2001-01-24 | 联合碳化化学品及塑料技术公司 | Spray application of additive composition to sheet materials |
| CN101255668A (en) * | 2008-04-09 | 2008-09-03 | 广西壮族自治区化工研究院 | High stability cation dispersion rosin size and manufacture method thereof |
| CN101880989A (en) * | 2010-06-24 | 2010-11-10 | 杭州杭化播磨造纸化学品有限公司 | Rosin emulsion sizing agent for temperature-resistant paper |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116289300A (en) * | 2023-02-20 | 2023-06-23 | 天津科技大学 | Lignin rosin sizing agent, preparation method and application |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160928 |