CN105948720A - Alumina bioceramics material and preparation method therefor - Google Patents

Alumina bioceramics material and preparation method therefor Download PDF

Info

Publication number
CN105948720A
CN105948720A CN201610271570.3A CN201610271570A CN105948720A CN 105948720 A CN105948720 A CN 105948720A CN 201610271570 A CN201610271570 A CN 201610271570A CN 105948720 A CN105948720 A CN 105948720A
Authority
CN
China
Prior art keywords
parts
aluminium oxide
preparation
temperature
bioceramic material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610271570.3A
Other languages
Chinese (zh)
Inventor
尤志刚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Cosmetic New Materials Co Ltd
Original Assignee
Suzhou Cosmetic New Materials Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Cosmetic New Materials Co Ltd filed Critical Suzhou Cosmetic New Materials Co Ltd
Priority to CN201610271570.3A priority Critical patent/CN105948720A/en
Publication of CN105948720A publication Critical patent/CN105948720A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/10—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38—Non-oxide ceramic constituents or additives
    • C04B2235/3804—Borides
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38—Non-oxide ceramic constituents or additives
    • C04B2235/3852—Nitrides, e.g. oxynitrides, carbonitrides, oxycarbonitrides, lithium nitride, magnesium nitride
    • C04B2235/386—Boron nitrides
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38—Non-oxide ceramic constituents or additives
    • C04B2235/3891—Silicides, e.g. molybdenum disilicide, iron silicide
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/40—Metallic constituents or additives not added as binding phase
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/40—Metallic constituents or additives not added as binding phase
    • C04B2235/405—Iron group metals
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/40—Metallic constituents or additives not added as binding phase
    • C04B2235/407—Copper
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance

Abstract

The invention belongs to the field of medical materials and discloses an alumina bioceramics material and a preparation method therefor. The ceramic material is prepared from the ingredients in parts by weight: 16-28 parts of alumina, 3-6 parts of molybdenum boride, 3-5 parts of boron nitride, 2-5 parts of chromium boride, 3-7 parts of tungsten silicide, 4-8 parts of cobalt silicide, 2-4 parts of magnesia, 2-4 parts of copper, 1-3 parts of zirconium, 2-5 parts of rubidium and 1-3 parts of nickel. The preparation method disclosed by the invention comprises the following steps: (1) carrying out mechanical ball-milling on the ingredients (in parts by weight) in a ball mill; (2) after ball-milling, uniformly mixing a mixed cermet material; and (3) carrying out high-temperature sintering on the mixture, which is uniformly mixed in the step (2), in a high-temperature sintering furnace for 3 hours at the temperature of 800 DEG C to 900 DEG C, then, heating the mixture to the temperature of 950 DEG C to 1,050 DEG C, carrying out sintering for 4 hours, and cooling the mixture to room temperature, thereby preparing the alumina bioceramics material.

Description

A kind of aluminium oxide bioceramic material and preparation method thereof
Technical field
The invention belongs to biological material field, relate to a kind of aluminium oxide bioceramic material and preparation method thereof.
Background technology
Along with development and the raising of manufacturing technology of science and technology, aluminium oxide ceramics is in modern industry and modern science skill Art is increasingly widely applied in field.Such as in mechanical aspects, there are wear-resisting alumina ceramic lining brick, liner plate, liner, Aluminium oxide ceramics is followed closely, ceramic seal, black aluminium oxide ceramic cutter, red oxidization aluminum ceramic plunger etc..At electronics, electricity Power aspect has various aluminium oxide ceramics base plate, substrate, ceramic membrane, high-pressure mercury lamp transparent alumina ceramics and various aluminium oxide pottery Porcelain electric insulation porcelain piece, electronic material, magnetic material etc..Aluminium oxide ceramic artificial bone, hydroxyapatite coating layer is had in terms of medical science The artificial tooth of polycrystalline alumina ceramic, artificial joint etc..Alumina ceramic material have high temperature resistant, hardness is big, intensity is high, corrosion resistant The premium properties such as erosion, electric insulation, air-tightness are good, the ceramic new material that in current oxide ceramics, purposes is the widest, yield is maximum.But Being as other ceramic materials, this pottery enbrittles this intrinsic deadly defect so that making of alumina ceramic material It is severely limited with scope and life-span thereof.In recent years, in aluminium oxide ceramics, introduce the Al/ of metallic aluminium Plastic phase Al2O3 Ceramic matric composite is a very active research field.
Summary of the invention
Solve the technical problem that: it is an object of the invention in alumina ceramic material, add other ceramic metals Point, improve the mechanical strength of alumina ceramic material, including hot strength, comprcssive strength etc..
Technical scheme: in order to solve the problems referred to above, the invention discloses a kind of aluminium oxide bioceramic material, described oxygen Change aluminum bioceramic material and include the composition of following weight:
Aluminium oxide 16-28 part,
Molybdenum boride 3-6 part,
Boron nitride 3-5 part,
Chromium boride 2-5 part,
Tungsten silicide 3-7 part,
Cobalt silicide 4-8 part,
Magnesium oxide 2-4 part,
Copper 2-4 part,
Zirconium 1-3 part,
Rubidium 2-5 part,
Nickel 1-3 part.
Preferably, described a kind of aluminium oxide bioceramic material includes the composition of following weight:
Aluminium oxide 20-24 part,
Molybdenum boride 4-5 part,
Boron nitride 3-4 part,
Chromium boride 3-4 part,
Tungsten silicide 4-6 part,
Cobalt silicide 5-7 part,
Magnesium oxide 3-4 part,
Copper 2-3 part,
Zirconium 1-2 part,
Rubidium 3-4 part,
Nickel 2-3 part.
The preparation method of a kind of aluminium oxide bioceramic material, comprises the following steps:
Step 1: according to weight portion respectively by aluminium oxide 16-28 part, molybdenum boride 3-6 part, boron nitride 3-5 part, chromium boride 2-5 part, Tungsten silicide 3-7 part, cobalt silicide 4-8 part, magnesium oxide 2-4 part, copper 2-4 part, zirconium 1-3 part, rubidium 2-5 part, nickel 1-3 part are in ball mill Mechanical ball milling；
Step 2: after ball milling, remixes hybrid metal ceramic material uniformly；
Step 3: by the compound high temperature sintering in high temperature sintering furnace after step (2) mix homogeneously, be 800-900 DEG C in temperature Lower sintering 3h, then rise high-temperature and be 950-1050 DEG C, sinter 4h, be cooled to room temperature, be prepared as aluminium oxide bioceramic material.
The preparation method of described a kind of aluminium oxide bioceramic material, in described step 1, in ball mill, ratio of grinding media to material is 20:1-30:1, Ball-milling Time is 2-4h.
First the preparation method of described a kind of aluminium oxide bioceramic material, be 850 DEG C in temperature in described step 3 Lower sintering 3h.
The preparation method of described a kind of aluminium oxide bioceramic material, rising high-temperature in described step 3 again is 1000 DEG C, sinter 4h.
The preparation method of described a kind of aluminium oxide bioceramic material, uses high-speed mixer to enter in described step 2 Row mixing, mixing rotating speed is 200rpm-400rpm.
Beneficial effect: the hot strength of aluminium oxide bioceramic material, comprcssive strength and the hardness of the present invention are the highest, Can meet the alumina ceramic material needs for various fields, the alumina ceramic material prepared also can be as novel Inorganic bio is in medical domain.And the preparation method of the present invention has preparation process advantage simple, efficient.
Detailed description of the invention
Embodiment 1
Step 1: according to weight portion respectively by aluminium oxide 28 parts, molybdenum boride 3 parts, boron nitride 5 parts, chromium boride 2 parts, tungsten silicide 3 parts, Cobalt silicide 4 parts, magnesium oxide 4 parts, copper 2 parts, zirconium 3 parts, rubidium 2 parts, 3 parts of mechanical ball millings in ball mill of nickel, ratio of grinding media to material in ball mill For 30:1, Ball-milling Time is 2h；
Step 2: after ball milling, remixes hybrid metal ceramic material uniformly；
Step 3: by the compound high temperature sintering in high temperature sintering furnace after step (2) mix homogeneously, burns at temperature is 900 DEG C Knot 3h, then to rise high-temperature be 1050 DEG C, sinters 4h, is cooled to room temperature, is prepared as aluminium oxide bioceramic material.
Embodiment 2
Step 1: according to weight portion respectively by aluminium oxide 16 parts, molybdenum boride 6 parts, boron nitride 3 parts, chromium boride 5 parts, tungsten silicide 7 parts, Cobalt silicide 8 parts, magnesium oxide 2 parts, copper 4 parts, zirconium 1 part, rubidium 5 parts, 1 part of mechanical ball milling in ball mill of nickel, ratio of grinding media to material in ball mill For 20:1, Ball-milling Time is 4h；
Step 2: after ball milling, remixes hybrid metal ceramic material uniformly；
Step 3: by the compound high temperature sintering in high temperature sintering furnace after step (2) mix homogeneously, burns at temperature is 800 DEG C Knot 3h, then to rise high-temperature be 950 DEG C, sinters 4h, is cooled to room temperature, is prepared as aluminium oxide bioceramic material.
Embodiment 3
Step 1: according to weight portion respectively by aluminium oxide 20 parts, molybdenum boride 5 parts, boron nitride 3 parts, chromium boride 3 parts, tungsten silicide 6 parts, Cobalt silicide 5 parts, magnesium oxide 4 parts, copper 3 parts, zirconium 1 part, rubidium 4 parts, 3 parts of mechanical ball millings in ball mill of nickel, ratio of grinding media to material in ball mill For 20:1, Ball-milling Time is 4h；
Step 2: after ball milling, remixes hybrid metal ceramic material uniformly；
Step 3: by the compound high temperature sintering in high temperature sintering furnace after step (2) mix homogeneously, burns at temperature is 900 DEG C Knot 3h, then to rise high-temperature be 1050 DEG C, sinters 4h, is cooled to room temperature, is prepared as aluminium oxide bioceramic material.
Embodiment 4
Step 1: according to weight portion respectively by aluminium oxide 24 parts, molybdenum boride 4 parts, boron nitride 4 parts, chromium boride 4 parts, tungsten silicide 4 parts, Cobalt silicide 7 parts, magnesium oxide 3 parts, copper 2 parts, zirconium 2 parts, rubidium 3 parts, 2 parts of mechanical ball millings in ball mill of nickel, ratio of grinding media to material in ball mill For 30:1, Ball-milling Time is 2h；
Step 2: after ball milling, remixes hybrid metal ceramic material uniformly；
Step 3: by the compound high temperature sintering in high temperature sintering furnace after step (2) mix homogeneously, burns at temperature is 800 DEG C Knot 3h, then to rise high-temperature be 950 DEG C, sinters 4h, is cooled to room temperature, is prepared as aluminium oxide bioceramic material.
Embodiment 5
Step 1: according to weight portion respectively by aluminium oxide 22 parts, molybdenum boride 4 parts, boron nitride 3 parts, chromium boride 4 parts, tungsten silicide 5 parts, Cobalt silicide 6 parts, magnesium oxide 3 parts, copper 2 parts, zirconium 2 parts, rubidium 3 parts, 3 parts of mechanical ball millings in ball mill of nickel, ratio of grinding media to material in ball mill For 25:1, Ball-milling Time is 3h；
Step 2: after ball milling, remixes hybrid metal ceramic material uniformly；
Step 3: by the compound high temperature sintering in high temperature sintering furnace after step (2) mix homogeneously, burns at temperature is 800 DEG C Knot 3h, then to rise high-temperature be 950 DEG C, sinters 4h, is cooled to room temperature, is prepared as aluminium oxide bioceramic material.
Comparative example 1
Step 1: according to weight portion respectively by aluminium oxide 28 parts, molybdenum boride 3 parts, boron nitride 5 parts, cobalt silicide 4 parts, magnesium oxide 4 parts, Copper 2 parts, zirconium 3 parts, rubidium 2 parts, 3 parts of mechanical ball millings in ball mill of nickel, in ball mill, ratio of grinding media to material is 30:1, and Ball-milling Time is 2h；
Step 2: after ball milling, remixes hybrid metal ceramic material uniformly；
Step 3: by the compound high temperature sintering in high temperature sintering furnace after step (2) mix homogeneously, burns at temperature is 900 DEG C Knot 3h, then to rise high-temperature be 1050 DEG C, sinters 4h, is cooled to room temperature, is prepared as aluminium oxide bioceramic material.
Comparative example 2
Step 1: according to weight portion respectively by aluminium oxide 28 parts, chromium boride 2 parts, tungsten silicide 3 parts, cobalt silicide 4 parts, magnesium oxide 4 parts, Copper 2 parts, zirconium 3 parts, rubidium 2 parts, 3 parts of mechanical ball millings in ball mill of nickel, in ball mill, ratio of grinding media to material is 30:1, and Ball-milling Time is 2h；
Step 2: after ball milling, remixes hybrid metal ceramic material uniformly；
Step 3: by the compound high temperature sintering in high temperature sintering furnace after step (2) mix homogeneously, burns at temperature is 900 DEG C Knot 3h, then to rise high-temperature be 1050 DEG C, sinters 4h, is cooled to room temperature, is prepared as aluminium oxide bioceramic material.
Determine embodiment 1 to 5 and the hot strength of aluminium oxide bioceramic material of comparative example 1 and 2, comprcssive strength and Bending strength:

Claims (7)

1. an aluminium oxide bioceramic material, it is characterised in that described aluminium oxide bioceramic material includes following weight Composition:
Aluminium oxide 16-28 part,
Molybdenum boride 3-6 part,
Boron nitride 3-5 part,
Chromium boride 2-5 part,
Tungsten silicide 3-7 part,
Cobalt silicide 4-8 part,
Magnesium oxide 2-4 part,
Copper 2-4 part,
Zirconium 1-3 part,
Rubidium 2-5 part,
Nickel 1-3 part.
A kind of aluminium oxide bioceramic material the most according to claim 1, it is characterised in that described aluminium oxide biology pottery Ceramic material includes the composition of following weight:
Aluminium oxide 20-24 part,
Molybdenum boride 4-5 part,
Boron nitride 3-4 part,
Chromium boride 3-4 part,
Tungsten silicide 4-6 part,
Cobalt silicide 5-7 part,
Magnesium oxide 3-4 part,
Copper 2-3 part,
Zirconium 1-2 part,
Rubidium 3-4 part,
Nickel 2-3 part.
3. the preparation method of an aluminium oxide bioceramic material, it is characterised in that the system of described aluminium oxide bioceramic material Preparation Method comprises the following steps:
Step 1: according to weight portion respectively by aluminium oxide 16-28 part, molybdenum boride 3-6 part, boron nitride 3-5 part, chromium boride 2-5 part, Tungsten silicide 3-7 part, cobalt silicide 4-8 part, magnesium oxide 2-4 part, copper 2-4 part, zirconium 1-3 part, rubidium 2-5 part, nickel 1-3 part are in ball mill Mechanical ball milling；Step 2: after ball milling, remixes hybrid metal ceramic material uniformly；
Step 3: by the compound high temperature sintering in high temperature sintering furnace after step (2) mix homogeneously, be 800-900 DEG C in temperature Lower sintering 3h, then rise high-temperature and be 950-1050 DEG C, sinter 4h, be cooled to room temperature, be prepared as aluminium oxide bioceramic material.
The preparation method of a kind of aluminium oxide bioceramic material the most according to claim 3, it is characterised in that described step In rapid 1, in ball mill, ratio of grinding media to material is 20:1-30:1, and Ball-milling Time is 2-4h.
The preparation method of a kind of aluminium oxide bioceramic material the most according to claim 3, it is characterised in that described step First at temperature is 850 DEG C, 3h is sintered in rapid 3.
The preparation method of a kind of aluminium oxide bioceramic material the most according to claim 3, it is characterised in that described step Rising high-temperature in rapid 3 again is 1000 DEG C, sinters 4h.
The preparation method of a kind of aluminium oxide bioceramic material the most according to claim 3, it is characterised in that described step Using high-speed mixer to mix in rapid 2, mixing rotating speed is 200rpm-400rpm.
CN201610271570.3A 2016-04-28 2016-04-28 Alumina bioceramics material and preparation method therefor Pending CN105948720A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610271570.3A CN105948720A (en) 2016-04-28 2016-04-28 Alumina bioceramics material and preparation method therefor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610271570.3A CN105948720A (en) 2016-04-28 2016-04-28 Alumina bioceramics material and preparation method therefor

Publications (1)

Publication Number Publication Date
CN105948720A true CN105948720A (en) 2016-09-21

Family

ID=56915734

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610271570.3A Pending CN105948720A (en) 2016-04-28 2016-04-28 Alumina bioceramics material and preparation method therefor

Country Status (1)

Country Link
CN (1) CN105948720A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107602132A (en) * 2017-07-25 2018-01-19 西南交通大学 A kind of preparation method of MoAlB ceramic powders

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87102385A (en) * 1986-03-31 1987-10-14 陶氏化学公司 The composition of new pottery, sintering metal or metal-powder and production method thereof
CN102731071A (en) * 2011-04-06 2012-10-17 鲁东大学 Preparation method of Al-Ti-B and rare metal synergistically-toughened alumina
CN104388793A (en) * 2014-11-14 2015-03-04 苏州蔻美新材料有限公司 Medical metal ceramic material and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87102385A (en) * 1986-03-31 1987-10-14 陶氏化学公司 The composition of new pottery, sintering metal or metal-powder and production method thereof
CN102731071A (en) * 2011-04-06 2012-10-17 鲁东大学 Preparation method of Al-Ti-B and rare metal synergistically-toughened alumina
CN104388793A (en) * 2014-11-14 2015-03-04 苏州蔻美新材料有限公司 Medical metal ceramic material and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
曲远方: "《现代陶瓷材料及技术》", 31 May 2008, 华南理工大学出版社 *
李家杰: "《加工中心培训教程》", 30 August 2015, 机械工业出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107602132A (en) * 2017-07-25 2018-01-19 西南交通大学 A kind of preparation method of MoAlB ceramic powders
CN107602132B (en) * 2017-07-25 2020-06-19 西南交通大学 Preparation method of MoAlB ceramic powder

Similar Documents

Publication Publication Date Title
Shi et al. Enhancing copper infiltration into alumina using spark plasma sintering to achieve high performance Al2O3/Cu composites
CN108516820B (en) A kind of short route sintering process of tin indium oxide target material
CN101218188B (en) Sintered yttria, anticorrosion member and process for producing the same
CN101456749A (en) Titanium and titanium alloy melting kettle refractory materials and preparation method of kettle
CN104310976A (en) Highly wear-resistant high-temperature ceramic
CN110655404A (en) Titanium silicon carbide based composite ceramic material and preparation process thereof
Zhang et al. Effects of particle size of raw materials on the characteristics of TiB2–SiC composites fabricated from B4C, TiC and Si powders
CN103820691B (en) A kind of normal pressure-sintered preparation method of FeAl/TiC matrix material
CN102203032A (en) Molybdenum silicide composite material
CN104387073A (en) Method for manufacturing ultrafine high-toughness silicon carbide ceramic material based on reaction sintering technology
Guo et al. Ultrafast high-temperature sintering to avoid metal loss toward high-performance and scalable cermets
CN112939603B (en) Method for sintering yttrium oxide ceramic crucible at low temperature
KR102084452B1 (en) MANUFACTURING METHOD OF Mo-Si-B ALLOY
CN107311675A (en) A kind of air brick prepared by industry byproduct aluminium chromium slag and preparation method thereof
CN108251670A (en) The preparation method of compound alloy between refractory metal
CN112011717B (en) High-strength low-expansion composite material and preparation method thereof
CN102167591B (en) Preparation method of ZrB2 based composite materials
CN109761622A (en) A kind of silicon nitride base gradient composite material and preparation method thereof based on outfield ancillary technique
CN105948720A (en) Alumina bioceramics material and preparation method therefor
CN105777162A (en) Y2O3 doped BaZrO3 refractory material
CN105803283A (en) Nb-Si-Ti-W-Cr alloy bar and production method thereof
CN106636738B (en) Titanium silicon material and preparation method thereof
CN110922195A (en) Method for preparing magnesium aluminate spinel-silicon carbide composite material by in-situ reaction
CN115433011A (en) High-entropy carbide (VNbTaMoW) C 5 -SiC complex phase ceramics
CN107417271A (en) A kind of preparation method of the bar-shaped brilliant enhancing dimension stone of magnesia alumina spinel of rare earth aluminium (silicon) hydrochlorate

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20160921

RJ01 Rejection of invention patent application after publication