CN105906881A - Antibacterial sole material and preparing method thereof - Google Patents
Antibacterial sole material and preparing method thereof Download PDFInfo
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- CN105906881A CN105906881A CN201610461320.6A CN201610461320A CN105906881A CN 105906881 A CN105906881 A CN 105906881A CN 201610461320 A CN201610461320 A CN 201610461320A CN 105906881 A CN105906881 A CN 105906881A
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- weight portion
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- zinc oxide
- silane
- lithopone
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides an antibacterial sole material and a preparing method thereof. The antibacterial sole material is prepared from isoprene rubber, butadiene rubber, butadiene styrene rubber, white carbon black, diethylene glycol, modified zinc oxide, sepiolite, zeolite, lithopone modified by silane, stearic acid, accelerant D, accelerant M, accelerant TT, antiager 1010 and sulfur, wherein modified zinc oxide, sepiolite, zeolite and lithopone modified by silane have good antibacterial performance, all the components take effect synergistically, on one hand, it is ensured that the prepared sole material has good elasticity, and on the other hand, the antibacterial performance of the prepared sole material is greatly enhanced.
Description
Technical field
The present invention relates to material for sole of shoe technical field, particularly relate to a kind of antibacterial sole material and preparation method thereof.
Background technology
Along with the progress of society, expanding economy, people are more and more higher to the requirement of quality of life, to clothing, footwear
Requiring the most rigorous, the footwear materials that market produces also gets more and more, but existing material for sole of shoe wearability is not high enough,
Breathability is the best, the when that the time being long the most on foot, impacts the meridians on foot, foot has a lot of acupuncture point, on market
Material for sole of shoe, it is impossible to meet the demand of foot health.
When walking, the sweat gland on foot can secret out of secretions to people, the meeting under antibacterial, mycete are decomposed of these secretions
Produce abnormal flavour, and after strenuous exercise, particularly evident after substantial amounts of perspiration, improve it is thought that often change shoe pad, in a short time
Effect is it is also possible that the most still can recur, so this way simply cured the symptoms, not the disease.If this not solved is asked
If topic, not only have abnormal flavour, allow people become estranged, also can produce the disease of tinea pedis, the health of harm people.
Material for sole of shoe is mostly synthetic rubber the most on the market, uses wide and cheap.In order to adapt to different operating ring
Border, so can be further improved performance in synthetic rubber, but the material for sole of shoe antibacterial effect of these modifications is bad, it is impossible to have
Imitate plays antibacterial action.
Summary of the invention
Present invention solves the technical problem that and be to provide a kind of antibacterial sole material and preparation method thereof, good springiness, have
Good anti-microbial property.
In view of this, the invention provides a kind of antibacterial sole material, including following components:
Isoprene rubber 20 ~ 30 weight portion；
Butadiene rubber 20 ~ 30 weight portion；
Butadiene-styrene rubber 30 ~ 40 weight portion；
White carbon 20 ~ 30 weight portion；
Diethylene glycol 1 ~ 2 weight portion；
Modified zinc oxide 3 ~ 4 weight portion；
Meerschaum 1 ~ 3 weight portion；
Zeolite 2 ~ 3 weight portion；
Silane-modified lithopone 3 ~ 5 weight portion；
Stearic acid 1 ~ 3 weight portion；
Diphenylguanidine 1 ~ 3 weight portion；
Captax 1 ~ 3 weight portion；
Accelerator TT 0.01 ~ 0.03 weight portion；
Age resistor 1,010 0.5 ~ 1 weight portion；
Sulfur 1 ~ 3 weight portion.
Preferably, including following components:
Isoprene rubber 25 ~ 30 weight portion；
Butadiene rubber 20 ~ 27 weight portion；
Butadiene-styrene rubber 30 ~ 36 weight portion；
White carbon 24 ~ 30 weight portion；
Diethylene glycol 1 ~ 2 weight portion；
Modified zinc oxide 3 ~ 4 weight portion；
Meerschaum 2 ~ 3 weight portion；
Zeolite 2 ~ 3 weight portion；
Silane-modified lithopone 4 ~ 5 weight portion；
Stearic acid 1 ~ 3 weight portion；
Diphenylguanidine 1 ~ 3 weight portion；
Captax 1 ~ 3 weight portion；
Accelerator TT 0.01 ~ 0.03 weight portion；
Age resistor 1,010 0.5 ~ 1 weight portion；
Sulfur 1 ~ 3 weight portion.
Preferably, described modified zinc oxide is prepared as follows: in a nitrogen atmosphere, by low for dihydroxy poly dimethyl
Siloxanes adds to the chloroform being suspended with zinc oxide nano-particle, and return stirring, by products therefrom centrifugation, will separate
To solid chloroform repeatedly clean, vacuum drying, obtain modified zinc oxide.
Preferably, the granularity of described meerschaum is 90-100 mesh.
Preferably, the granularity of described zeolite is 30-50 mesh.
Preferably, the granularity of described silane-modified nanometer lithopone meets D90Less than 50nm, whiteness is more than 90%, described silicon
Alkane is methyl dimethyl TMOS.
Preferably, described silane-modified nanometer lithopone is prepared as follows: water-soluble to the ethanol that volume ratio is 1:1
Liquid adds 0.15M hydrochloric acid solution regulation pH value to 4.0, obtain mixed solution；Nanometer lithopone is dispersed in described mixing
In solution, in the water-bath of 45 DEG C under the rotating speed stirring of 600r/min, drip methyl dimethyl TMOS, stir 5-
8h, sucking filtration, washing, dry, pulverize at 60-70 DEG C, obtain silane-modified lithopone.
Accordingly, the present invention also provides for the preparation method of a kind of antibacterial sole material, comprises the following steps: by isoamyl rubber
Glue, butadiene rubber and butadiene-styrene rubber are put into mill and are carried out mill, thin logical 5-10 time, cool down；Blend glue stuff after mill is added
Enter white carbon, diethylene glycol, modified zinc oxide, meerschaum, zeolite, silane-modified lithopone, stearic acid, diphenylguanidine, accelerator
M, accelerator TT, age resistor 1010, sulfur send into banbury banburying；The material preforms that will obtain after banburying, puts into cooling bath
Cooling；The material cures molding that will have cooled down, obtains rubber soles material.
Preferably, described modified zinc oxide is prepared as follows: in a nitrogen atmosphere, by low for dihydroxy poly dimethyl
Siloxanes adds to the chloroform being suspended with zinc oxide nano-particle, and return stirring, by products therefrom centrifugation, will separate
To solid chloroform repeatedly clean, vacuum drying, obtain modified zinc oxide.
Preferably, described silane-modified nanometer lithopone is prepared as follows: water-soluble to the ethanol that volume ratio is 1:1
Liquid adds 0.15M hydrochloric acid solution regulation pH value to 4.0, obtain mixed solution；Nanometer lithopone is dispersed in described mixing
In solution, in the water-bath of 45 DEG C under the rotating speed stirring of 600r/min, drip methyl dimethyl TMOS, stir 5-
8h, sucking filtration, washing, dry, pulverize at 60-70 DEG C, obtain silane-modified lithopone.
The invention provides a kind of antibacterial sole material and preparation method thereof with isoprene rubber, butadiene rubber, butadiene-styrene rubber,
White carbon, diethylene glycol, modified zinc oxide, meerschaum, zeolite, silane-modified lithopone, stearic acid, diphenylguanidine, captax,
Accelerator TT, age resistor 1010, sulfur are raw material, and wherein, modified zinc oxide, meerschaum, zeolite, silane-modified lithopone are equal
There is good anti-microbial property, each composition synergism, on the one hand ensure that the material for sole of shoe of preparation has good elasticity,
On the other hand, the anti-microbial property making the material for sole of shoe of preparation is greatly enhanced.
Detailed description of the invention
In order to be further appreciated by the present invention, below in conjunction with embodiment, the preferred embodiment of the invention is described, but
Should be appreciated that these describe simply as to further illustrate the features and advantages of the present invention rather than to the claims in the present invention
Limit.
The embodiment of the invention discloses a kind of antibacterial sole material, including following components:
Isoprene rubber 20 ~ 30 weight portion；
Butadiene rubber 20 ~ 30 weight portion；
Butadiene-styrene rubber 30 ~ 40 weight portion；
White carbon 20 ~ 30 weight portion；
Diethylene glycol 1 ~ 2 weight portion；
Modified zinc oxide 3 ~ 4 weight portion；
Meerschaum 1 ~ 3 weight portion；
Zeolite 2 ~ 3 weight portion；
Silane-modified lithopone 3 ~ 5 weight portion；
Stearic acid 1 ~ 3 weight portion；
Diphenylguanidine 1 ~ 3 weight portion；
Captax 1 ~ 3 weight portion；
Accelerator TT 0.01 ~ 0.03 weight portion；
Age resistor 1,010 0.5 ~ 1 weight portion；
Sulfur 1 ~ 3 weight portion.
Preferably, described antibacterial sole material includes following components:
Isoprene rubber 25 ~ 30 weight portion；
Butadiene rubber 20 ~ 27 weight portion；
Butadiene-styrene rubber 30 ~ 36 weight portion；
White carbon 24 ~ 30 weight portion；
Diethylene glycol 1 ~ 2 weight portion；
Modified zinc oxide 3 ~ 4 weight portion；
Meerschaum 2 ~ 3 weight portion；
Zeolite 2 ~ 3 weight portion；
Silane-modified lithopone 4 ~ 5 weight portion；
Stearic acid 1 ~ 3 weight portion；
Diphenylguanidine 1 ~ 3 weight portion；
Captax 1 ~ 3 weight portion；
Accelerator TT 0.01 ~ 0.03 weight portion；
Age resistor 1,010 0.5 ~ 1 weight portion；
Sulfur 1 ~ 3 weight portion.
Preferably, described modified zinc oxide is prepared as follows: in a nitrogen atmosphere, and dihydroxy is oligomeric
Dimethyl siloxane adds to the chloroform being suspended with zinc oxide nano-particle, return stirring, by products therefrom centrifugation, and will
The solid chloroform of isolated cleans repeatedly, vacuum drying, obtains modified zinc oxide.Wherein, the temperature of described return stirring
Being preferably 100 DEG C, the time of return stirring is preferably 25-35h, more preferably 30h；Vacuum drying temperature is preferably 70-90
DEG C, more preferably 80 DEG C；The vacuum drying time is preferably 10-20h, more preferably 15h.
Meerschaum be a kind of layer of chain structure containing Shuifu County's magnesium silicate clay mineral, be typically block, earthy or fiber
Shape aggregation, color is white, light grey, dull gray, yellowish-brown, rose, pale bluish green, has sliding sense and astringent sense, glues tongue,
Under dry state, property is crisp, and shrinkage factor is low, and plasticity is good, and specific surface is big, and adsorptivity is strong, makes material for sole of shoe can divide with quick adsorption sweat gland
Secretion, and there is the effect of quick dehumidifying.Preferably, the granularity of described meerschaum is 90-100 mesh；Described zeolite
Granularity is 30-50 mesh.
Preferably, the granularity of described silane-modified nanometer lithopone meets D90Less than 50nm, whiteness is more than 90%,
Described silane is methyl dimethyl TMOS.Described silane-modified nanometer lithopone is made the most as follows
Standby: add in the ethanol water that volume ratio is 1:1 0.15M hydrochloric acid solution regulation pH value to 4.0, obtain mixed solution；
Nanometer lithopone is dispersed in described mixed solution, in the water-bath of 45 DEG C under the rotating speed stirring of 600r/min, drips methyl
Dimethyl TMOS, stirs 5-8h, sucking filtration, washing, dry, pulverize, obtain silane-modified vertical moral at 60-70 DEG C
Powder.
The antibacterial sole material of the present invention adds a small amount of silane-modified nanometer lithopone, improves the anti-ageing of material for sole of shoe
Changing performance, it contains zinc sulfide nano photocatalytic particle, effectively can absorb ultraviolet thus eliminate ultraviolet to material for sole of shoe
Aging action.Easily there is light-catalyzed reaction in nanoparticle simultaneously, gives the effect that material for sole of shoe has sterilization.
Accordingly, the present invention also provides for the preparation method of a kind of antibacterial sole material, comprises the following steps: by isoamyl rubber
Glue, butadiene rubber and butadiene-styrene rubber are put into mill and are carried out mill, thin logical 5-10 time, cool down；By the blend glue stuff after mill
Add white carbon, diethylene glycol, modified zinc oxide, meerschaum, zeolite, silane-modified lithopone, stearic acid, diphenylguanidine, accelerator
M, accelerator TT, age resistor 1010, sulfur send into banbury banburying；The material preforms that will obtain after banburying, puts into cooling bath
Cooling；The material cures molding cooled down, obtains rubber soles material.Wherein, banbury temperature is preferably 100-120 DEG C, more
It is preferably 110 DEG C；The banburying time is preferably 1-5 minute, more preferably 2 minutes.
From above scheme it can be seen that the present invention with isoprene rubber, butadiene rubber, butadiene-styrene rubber, white carbon, diethylene glycol,
Modified zinc oxide, meerschaum, zeolite, silane-modified lithopone, stearic acid, diphenylguanidine, captax, accelerator TT, anti-old
Agent 1010, sulfur are raw material, and wherein, modified zinc oxide, meerschaum, zeolite, silane-modified lithopone are respectively provided with good antibacterial
Performance, each composition synergism, on the one hand ensure that the material for sole of shoe of preparation has good elasticity, on the other hand, make system
The anti-microbial property of standby material for sole of shoe is greatly enhanced.
In order to be further appreciated by the present invention, the technical scheme provided the present invention below in conjunction with embodiment is carried out specifically
Bright, protection scope of the present invention is not limited by the following examples.
Raw material and chemical reagent that the embodiment of the present invention uses are commercial.
The raw material source used in the embodiment of the present invention is as follows:
Butadiene rubber (Dongguan Nan Guan raw stock company limited)；
Butadiene-styrene rubber (Dongguan Nan Guan raw stock company limited)；
White carbon (Guangzhou Li Ben rubber raw materials company limited)；
Diethylene glycol (Bo Zhen Chemical Co., Ltd. of Foshan City)；
Zinc oxide (hundred million trade Co., Ltd's product indirect method 99.7% Zinc Oxides are opened up in Guangzhou)；
Stearic acid (reported in Tianhe district of Guangzhou grand sight intelligence industry chemical products 1801 stearic acid)；
Accelerator (Shanghai Mei Hua Chemical Co., Ltd.)；
Sulfur (SINOPEC Beijing Yanshan Mountain Chemical Co., Ltd.).
Embodiment 1
Prepare modified zinc oxide:
100g dihydroxy oligodimethylsiloxanes is joined in the 2000g chloroform being suspended with 400g zinc oxide nano-particle,
At N2Under atmosphere, return stirring 30h at 100 DEG C, by products therefrom centrifugation, by the solid chloroform of isolated
After repeatedly cleaning 5 times, place and vacuum drying oven is dried at 80 DEG C 15h, obtain modified zinc oxide.
Embodiment 2
Prepare silane-modified lithopone:
First dose volume is than the ethanol water for 1:1, then with the hydrochloric acid solution regulation pH value of 0.15M to 4.0；
Nanometer lithopone is dispersed in above-mentioned solution, in the water-bath of 45 DEG C under the rotating speed stirring of 600r/min, dropping
Methyl dimethyl TMOS, stirs 5h, sucking filtration, washing, fully dry, pulverize, obtain silane-modified at 70 DEG C
Lithopone.
Embodiment 3
A kind of antibacterial sole material, including following component:
Isoprene rubber IR180 25 parts；
Butadiene rubber 30 parts；
1,502 40 parts of butadiene-styrene rubber；
White carbon 20 parts；
Diethylene glycol 2 parts；
Modified zinc oxide 3 parts；
Meerschaum 3 parts；
2 parts of zeolite；
5 parts of silane-modified lithopone；
Stearic acid 1 part；
Diphenylguanidine 3 parts；
Captax 3 parts；
Accelerator TT 0.01 part；
1,010 1 parts of age resistor；
1 part of sulfur.
Preparation method is as follows:
Isoprene rubber IR180, butadiene rubber and butadiene-styrene rubber 1502 are put into mill and carries out mill, mill roll spacing 0.8,
Thin logical 8 times, cooling；
Blend glue stuff after mill is added white carbon, diethylene glycol, meerschaum, zeolite, silane-modified lithopone, stearic acid, rush
Entering agent D, captax, accelerator TT, age resistor 1010, sulfur feeding banbury banburying, banbury temperature is 110 DEG C, close
Refine 2 minutes；
The material preforms that will obtain after banburying, puts into cooling bath and cools down 24 hours；
The material cures molding cooled down, obtains antibacterial sole material.
The performance Detection results of antibacterial sole material prepared by the present embodiment is as follows: antibiotic rate 99.2%, shore hardness (A)
51, hot strength/MPa:21.1, elongation at break/%:143.
Embodiment 4
A kind of antibacterial sole material, including following component:
Isoprene rubber IR180 30 parts；
Butadiene rubber 25 parts；
1,502 36 parts of butadiene-styrene rubber；
White carbon 24 parts；
Diethylene glycol 1 part；
Modified zinc oxide 4 parts；
Meerschaum 2 parts；
2 parts of zeolite；
5 parts of silane-modified lithopone；
Stearic acid 1 part；
Diphenylguanidine 3 parts；
Captax 3 parts；
Accelerator TT 0.01 part；
1,010 1 parts of age resistor；
1 part of sulfur.
Preparation method is as follows:
Isoprene rubber IR180, butadiene rubber and butadiene-styrene rubber 1502 are put into mill and carries out mill, mill roll spacing 0.8,
Thin logical 8 times, cooling；
Blend glue stuff after mill is added white carbon, diethylene glycol, meerschaum, zeolite, silane-modified lithopone, stearic acid, rush
Entering agent D, captax, accelerator TT, age resistor 1010, sulfur feeding banbury banburying, banbury temperature is 110 DEG C, close
Refine 2 minutes；
The material preforms that will obtain after banburying, puts into cooling bath and cools down 24 hours；
The material cures molding cooled down, obtains antibacterial sole material.
The performance Detection results of antibacterial sole material prepared by the present embodiment is as follows: antibiotic rate 99.1%, shore hardness (A)
51, hot strength/MPa:21.5, elongation at break/%:141.
Embodiment 5
A kind of antibacterial sole material, including following component:
Isoprene rubber IR180 28 parts；
Butadiene rubber 22 parts；
1,502 36 parts of butadiene-styrene rubber；
White carbon 24 parts；
Diethylene glycol 1 part；
Modified zinc oxide 3 parts；
Meerschaum 2 parts；
3 parts of zeolite；
5 parts of silane-modified lithopone；
Stearic acid 1 part；
Diphenylguanidine 3 parts；
Captax 3 parts；
Accelerator TT 0.01 part；
1,010 1 parts of age resistor；
1 part of sulfur.
Preparation method is as follows:
Isoprene rubber IR180, butadiene rubber and butadiene-styrene rubber 1502 are put into mill and carries out mill, mill roll spacing 0.8,
Thin logical 8 times, cooling；
Blend glue stuff after mill is added white carbon, diethylene glycol, meerschaum, zeolite, silane-modified lithopone, stearic acid, rush
Entering agent D, captax, accelerator TT, age resistor 1010, sulfur feeding banbury banburying, banbury temperature is 110 DEG C, close
Refine 2 minutes；
The material preforms that will obtain after banburying, puts into cooling bath and cools down 24 hours；
The material cures molding cooled down, obtains antibacterial sole material.
The performance Detection results of antibacterial sole material prepared by the present embodiment is as follows: antibiotic rate 98.9%, shore hardness (A)
50, hot strength/MPa:21.3, elongation at break/%:142.
The explanation of above example is only intended to help to understand method and the core concept thereof of the present invention.It is right to it should be pointed out that,
For those skilled in the art, under the premise without departing from the principles of the invention, it is also possible to the present invention is carried out
Some improvement and modification, these improve and modify in the protection domain also falling into the claims in the present invention.
Described above to the disclosed embodiments, makes professional and technical personnel in the field be capable of or uses the present invention.
Multiple amendment to these embodiments will be apparent from for those skilled in the art, as defined herein
General Principle can realize without departing from the spirit or scope of the present invention in other embodiments.Therefore, the present invention
It is not intended to be limited to the embodiments shown herein, and is to fit to and principles disclosed herein and features of novelty phase one
The widest scope caused.
Claims (10)
1. an antibacterial sole material, it is characterised in that include following components:
Isoprene rubber 20 ~ 30 weight portion；
Butadiene rubber 20 ~ 30 weight portion；
Butadiene-styrene rubber 30 ~ 40 weight portion；
White carbon 20 ~ 30 weight portion；
Diethylene glycol 1 ~ 2 weight portion；
Modified zinc oxide 3 ~ 4 weight portion；
Meerschaum 1 ~ 3 weight portion；
Zeolite 2 ~ 3 weight portion；
Silane-modified lithopone 3 ~ 5 weight portion；
Stearic acid 1 ~ 3 weight portion；
Diphenylguanidine 1 ~ 3 weight portion；
Captax 1 ~ 3 weight portion；
Accelerator TT 0.01 ~ 0.03 weight portion；
Age resistor 1,010 0.5 ~ 1 weight portion；
Sulfur 1 ~ 3 weight portion.
Antibacterial sole material the most according to claim 1, it is characterised in that include following components:
Isoprene rubber 25 ~ 30 weight portion；
Butadiene rubber 20 ~ 27 weight portion；
Butadiene-styrene rubber 30 ~ 36 weight portion；
White carbon 24 ~ 30 weight portion；
Diethylene glycol 1 ~ 2 weight portion；
Modified zinc oxide 3 ~ 4 weight portion；
Meerschaum 2 ~ 3 weight portion；
Zeolite 2 ~ 3 weight portion；
Silane-modified lithopone 4 ~ 5 weight portion；
Stearic acid 1 ~ 3 weight portion；
Diphenylguanidine 1 ~ 3 weight portion；
Captax 1 ~ 3 weight portion；
Accelerator TT 0.01 ~ 0.03 weight portion；
Age resistor 1,010 0.5 ~ 1 weight portion；
Sulfur 1 ~ 3 weight portion.
Antibacterial sole material the most according to claim 1, it is characterised in that described modified zinc oxide is made as follows
Standby:
In a nitrogen atmosphere, dihydroxy oligodimethylsiloxanes is added to the chloroform being suspended with zinc oxide nano-particle,
Return stirring, by products therefrom centrifugation, cleans repeatedly by the solid chloroform of isolated, vacuum drying, obtains modification
Zinc oxide.
Antibacterial sole material the most according to claim 1, it is characterised in that the granularity of described meerschaum is 90-100 mesh.
Antibacterial sole material the most according to claim 1, it is characterised in that the granularity of described zeolite is 30-50 mesh.
Antibacterial sole material the most according to claim 1, it is characterised in that the granularity of described silane-modified nanometer lithopone
Meet D90Less than 50nm, whiteness is more than 90%, and described silane is methyl dimethyl TMOS.
Antibacterial sole material the most according to claim 1, it is characterised in that described silane-modified nanometer lithopone is according to such as
Prepared by lower section method:
Add in the ethanol water that volume ratio is 1:1 0.15M hydrochloric acid solution regulation pH value to 4.0, obtain mixed solution；
Nanometer lithopone is dispersed in described mixed solution, in the water-bath of 45 DEG C under the rotating speed stirring of 600r/min, dropping
Methyl dimethyl TMOS, stirs 5-8h, sucking filtration, washing, dry, pulverize, obtain silane-modified at 60-70 DEG C
Lithopone.
8. the preparation method of the antibacterial sole material described in a claim 1-7 any one, it is characterised in that include following
Step:
Isoprene rubber, butadiene rubber and butadiene-styrene rubber are put into mill and carries out mill, thin logical 5-10 time, cool down；
Blend glue stuff after mill is added white carbon, diethylene glycol, modified zinc oxide, meerschaum, zeolite, silane-modified vertical moral
Powder, stearic acid, diphenylguanidine, captax, accelerator TT, age resistor 1010, sulfur send into banbury banburying；
The material preforms that will obtain after banburying, puts into cooling bath cooling；
The material cures molding that will have cooled down, obtains rubber soles material.
Preparation method the most according to claim 8, it is characterised in that described modified zinc oxide is prepared as follows:
In a nitrogen atmosphere, dihydroxy oligodimethylsiloxanes is added to the chloroform being suspended with zinc oxide nano-particle,
Return stirring, by products therefrom centrifugation, cleans repeatedly by the solid chloroform of isolated, vacuum drying, obtains modification
Zinc oxide.
Preparation method the most according to claim 8, it is characterised in that described silane-modified nanometer lithopone is according to as follows
Prepared by method:
Add in the ethanol water that volume ratio is 1:1 0.15M hydrochloric acid solution regulation pH value to 4.0, obtain mixed solution；
Nanometer lithopone is dispersed in described mixed solution, in the water-bath of 45 DEG C under the rotating speed stirring of 600r/min, dropping
Methyl dimethyl TMOS, stirs 5-8h, sucking filtration, washing, dry, pulverize, obtain silane-modified at 60-70 DEG C
Lithopone.
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| CN201610461320.6A CN105906881A (en) | 2016-06-23 | 2016-06-23 | Antibacterial sole material and preparing method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610461320.6A CN105906881A (en) | 2016-06-23 | 2016-06-23 | Antibacterial sole material and preparing method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107964141A (en) * | 2017-12-12 | 2018-04-27 | 温州市小林鞋材有限公司 | A kind of tear-proof sole and preparation method thereof |
| CN108219223A (en) * | 2018-02-12 | 2018-06-29 | 唐旭 | A kind of environment-friendly rubber composition and its application |
| CN112625320A (en) * | 2020-12-28 | 2021-04-09 | 广州增威胶业有限公司 | Preparation method of semi-finished blank for shoe outsole and forming method of shoe outsole |
| CN114702719A (en) * | 2022-04-06 | 2022-07-05 | 茂泰(福建)鞋材有限公司 | Cold-resistant anti-slip rubber foamed sole and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107964141A (en) * | 2017-12-12 | 2018-04-27 | 温州市小林鞋材有限公司 | A kind of tear-proof sole and preparation method thereof |
| CN107964141B (en) * | 2017-12-12 | 2020-09-08 | 温州市小林鞋材有限公司 | Anti-tearing sole and preparation method thereof |
| CN108219223A (en) * | 2018-02-12 | 2018-06-29 | 唐旭 | A kind of environment-friendly rubber composition and its application |
| CN112625320A (en) * | 2020-12-28 | 2021-04-09 | 广州增威胶业有限公司 | Preparation method of semi-finished blank for shoe outsole and forming method of shoe outsole |
| CN114702719A (en) * | 2022-04-06 | 2022-07-05 | 茂泰(福建)鞋材有限公司 | Cold-resistant anti-slip rubber foamed sole and preparation method thereof |
| CN114702719B (en) * | 2022-04-06 | 2023-05-23 | 茂泰(福建)新材料科技有限公司 | Cold-resistant and anti-skid rubber foam sole and preparation method thereof |
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