CN105885490A - Environmentally friendly coating added with modified nano bamboo charcoal powder and preparation method of environmentally friendly coating - Google Patents

Environmentally friendly coating added with modified nano bamboo charcoal powder and preparation method of environmentally friendly coating Download PDF

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Publication number
CN105885490A
CN105885490A CN201610452074.8A CN201610452074A CN105885490A CN 105885490 A CN105885490 A CN 105885490A CN 201610452074 A CN201610452074 A CN 201610452074A CN 105885490 A CN105885490 A CN 105885490A
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parts
bamboo charcoal
charcoal powder
modified nano
nano bamboo
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CN201610452074.8A
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杨玉双
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杨玉双
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular

Abstract

The invention discloses an environmentally friendly coating added with modified nano bamboo charcoal powder and a preparation method of the environmentally friendly coating. The environmentally friendly coating is prepared from the following raw materials in parts by weight: 10-15 parts of acrylic resin, 15-30 parts of chlorinated polyether resin, 2-4 parts of chlorinated rubber, 5-6 parts of ammonium polyphosphate, 1-3 parts of a titanate coupling agent, 2-3 parts of methylsilicone oil, 5-6 parts of pentaerythritol, 10-20 parts of styrene, 6-8 parts of butyl rubber latex, 2-3 parts of sodium fluosilicate, 5-10 parts of modified nano bamboo charcoal powder, 3-5 parts of bentonite, 5-6 parts of fumed silica, 5-8 parts of perlite, 10-15 parts of lignin, and 8-12 parts of modified tree ash. The environmentally friendly coating added with the modified nano bamboo charcoal powder has the features of excellent adhesiveness, moisture resistance, freezing resistance, flame retardance and the like, can endure influence of low-temperature cycling, is stored stably, does not pollute the environment, is harmless to human bodies, and is environmentally friendly.

Description

A kind of environmental protection coating material adding modified Nano bamboo charcoal powder and preparation method thereof
Technical field
The present invention relates to technical field of coatings, particularly relate to a kind of environmental protection coating material adding modified Nano bamboo charcoal powder and Its preparation method.
Background technology
Coating, at the entitled paint of Chinese tradition, is to be coated in be protected or decorated body surface, and energy With coated article formed firm attachment continuous film, it is common that based on resin oil or emulsion, add or Without pigment, filler, add corresponding additive, with the formulated thick liquid of organic solvent or water.
The most common building inside and outside wall coating exist coating face adhesive force, moisture resistance, frost resistance, Anti-flammability is difficult to the problem taken into account, and after using a period of time in adverse circumstances, paint film can produce a lot of drawback, as Weathering, be full of cracks come off, and affect health in indoor, affect environment in outdoor;Have in order to improve coating Some performance, in coating, often add some modifying agent, thickener, tackifier, emulsifying agent etc., and these In material, some is poisonous, and some is the most extremely toxic, and majority can produce environmental pollution.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art, it is provided that a kind of environmental protection adding modified Nano bamboo charcoal powder Coating, has the features such as excellent tack, moisture resistance, frost resistance and anti-flammability, is amenable to low-temperature circulating Impact, storage is stable, environmentally safe, environmental protection harmless to human body.
To achieve these goals, the present invention adopts the following technical scheme that
A kind of environmental protection coating material adding modified Nano bamboo charcoal powder, is prepared by the raw materials in: acrylic acid tree Fat 10-15 part, chlorinated polyether resin 15-30 part, chlorinated rubber 2-4 part, APP 5-6 part, titanate esters are occasionally Connection agent 1-3 part, methyl-silicone oil 2-3 part, pentaerythrite 5-6 part, styrene 10-20 part, butyl latex 6-8 part, prodan 2-3 part, modified Nano bamboo charcoal powder 5-10 part, bentonite 3-5 part, gas phase hard charcoal Black 5-6 part, perlite 5-8 part, lignin 10-15 part, modified tree ash 8-12 part.
Described modified Nano bamboo charcoal powder is prepared by following methods: by bamboo charcoal powder 10-15% sodium hydroxide solution Soak 5-8h, be then washed with deionized, dry, add the bay acid alcohol being equivalent to its weight 1-2% Acid sodium, the a-cyanacrylate of 1-3% and the crosslink agent DCP of 1-3%, 3000-5000 rev/min of stirring 30-50 minute, dry, grind to form nanometer powder,.
Described modified tree ash is prepared by following methods: first by 10-15% salt acid soak tree ash 3-5h, Then it is washed with deionized clean, then soaks 3-5h with 10-13% sodium hydroxide solution, then use deionized water Washing, to neutral, is dried, add be equivalent to the wooden sodium sulfonate of tree ash weight 2-4%, 1-3% average Add, the oxidized starch of the ATBC of 2-4%, 2-4%, high speed 1300-1500 rev/min stirring 1-3h, Drying, attrition grinding becomes superfines.
The preparation method of the described environmental protection coating material adding modified Nano bamboo charcoal powder, including following preparation process:
(1) by above-mentioned weight ratio by acrylic resin, APP, methyl-silicone oil, styrene, fourth Base latex, prodan add agitated kettle, be subsequently adding modified Nano bamboo charcoal powder, bentonite, gas-phase silica, Perlite, lignin and modified tree ash, stir 10-15min under 1200-1500 rev/min, and mixing is all Even, being then ground to fineness through sand mill is 50-60um, obtains mill base;
(2) mill base of step (1) is squeezed into join japanning kettle, be sequentially added in japanning kettle by above-mentioned weight ratio Chlorinated polyether resin, chlorinated rubber, titanate coupling agent, pentaerythrite stir under 2000-2500 rev/min 30-35min, mixes and get final product.
Compared with the prior art, beneficial effects of the present invention is as follows:
The environmental protection coating material adding modified Nano bamboo charcoal powder of the present invention, by adding modified Nano bamboo carbon powder, swelling The compositions such as soil, gas-phase silica, perlite, lignin, in coating, adjust formula, and can effectively disappear coating Toxicity and pollution on the environment, add modified tree ash, hence it is evident that improve being uniformly dispersed of each component Property, improve the tack of coating, and there is the feature of low cost, excellent effect.The coating of the present invention has excellent The features such as good tack, moisture resistance, frost resistance and anti-flammability, are amenable to the impact of low-temperature circulating, and storage is steady Fixed, environmentally safe, environmental protection harmless to human body.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further illustrated, but the present invention is not limited only to these embodiments, On the premise of without departing from present inventive concept, within any improvement made all falls within protection scope of the present invention.
Embodiment 1:
A kind of environmental protection coating material adding modified Nano bamboo charcoal powder, is prepared by the raw materials in: acrylic acid tree 10 parts of fat, chlorinated polyether resin 30 parts, chlorinated rubber 2 parts, APP 6 parts, titanate coupling agent 1 part, Methyl-silicone oil 2 parts, pentaerythrite 5 parts, styrene 10 parts, butyl latex 6 parts, prodan 3 parts, Modified Nano bamboo charcoal powder 5 parts, bentonite 3 parts, gas-phase silica 6 parts, perlite 5 parts, lignin 15 Part, modified tree ash 8 parts.
Wherein, described modified Nano bamboo charcoal powder is prepared by following methods: bamboo charcoal powder is molten with 10% NaOH Immersion bubble 8h, is then washed with deionized, dries, add the laurate alkyd being equivalent to its weight 1% Sodium, the a-cyanacrylate of 1% and the crosslink agent DCP of 3%, 3000 revs/min are stirred 50 minutes, dry, Grind to form nanometer powder,.
Described modified tree ash is prepared by following methods: first by 10% salt acid soak tree ash 5h, then It is washed with deionized clean, then soaks 5h with 10% sodium hydroxide solution, then be washed with deionized to neutrality, Dry, add and be equivalent to the wooden sodium sulfonate of tree ash weight 2%, the peregal of 1%, the citric acid three of 2% Butyl ester, the oxidized starch of 2%, 1300 revs/min of stirring 3h, dry at a high speed, and attrition grinding becomes superfines i.e. Can.
The preparation method of the described environmental protection coating material adding modified Nano bamboo charcoal powder, including following preparation process:
(1) by above-mentioned weight ratio by acrylic resin, APP, methyl-silicone oil, styrene, fourth Base latex, prodan add agitated kettle, be subsequently adding modified Nano bamboo charcoal powder, bentonite, gas-phase silica, Perlite, lignin and modified tree ash, stir 15min under 1200 revs/min, mix, then Being ground to fineness through sand mill is 50um, obtains mill base;
(2) mill base of step (1) is squeezed into join japanning kettle, be sequentially added in japanning kettle by above-mentioned weight ratio Chlorinated polyether resin, chlorinated rubber, titanate coupling agent, pentaerythrite stir 35min under 2000 revs/min, mixed Close uniformly and get final product.
Embodiment 2:
A kind of environmental protection coating material adding modified Nano bamboo charcoal powder, is prepared by the raw materials in: acrylic acid tree 12 parts of fat, chlorinated polyether resin 20 parts, chlorinated rubber 3 parts, APP 6 parts, titanate coupling agent 2 parts, Methyl-silicone oil 3 parts, pentaerythrite 6 parts, styrene 15 parts, butyl latex 7 parts, prodan 2 parts, Modified Nano bamboo charcoal powder 6 parts, bentonite 4 parts, gas-phase silica 6 parts, perlite 6 parts, lignin 13 Part, modified tree ash 10 parts.
Wherein, described modified Nano bamboo charcoal powder is prepared by following methods: bamboo charcoal powder is molten with 12% NaOH Immersion bubble 6h, is then washed with deionized, dries, add the laurate alkyd being equivalent to its weight 2% Sodium, the a-cyanacrylate of 2% and the crosslink agent DCP of 2%, 4000 revs/min are stirred 40 minutes, dry, Grind to form nanometer powder,.
Described modified tree ash is prepared by following methods: first by 12% salt acid soak tree ash 4h, then It is washed with deionized clean, then soaks 3h with 12% sodium hydroxide solution, then be washed with deionized to neutrality, Dry, add and be equivalent to the wooden sodium sulfonate of tree ash weight 3%, the peregal of 2%, the citric acid three of 3% Butyl ester, the oxidized starch of 3%, 1400 revs/min of stirring 2h, dry at a high speed, and attrition grinding becomes superfines i.e. Can.
The preparation method of the described environmental protection coating material adding modified Nano bamboo charcoal powder, including following preparation process:
(1) by above-mentioned weight ratio by acrylic resin, APP, methyl-silicone oil, styrene, fourth Base latex, prodan add agitated kettle, be subsequently adding modified Nano bamboo charcoal powder, bentonite, gas-phase silica, Perlite, lignin and modified tree ash, stir 12min under 1300 revs/min, mix, then Being ground to fineness through sand mill is 55um, obtains mill base;
(2) mill base of step (1) is squeezed into join japanning kettle, be sequentially added in japanning kettle by above-mentioned weight ratio Chlorinated polyether resin, chlorinated rubber, titanate coupling agent, pentaerythrite stir 35min under 2200 revs/min, mixed Close uniformly and get final product.
Embodiment 3:
A kind of environmental protection coating material adding modified Nano bamboo charcoal powder, is prepared by the raw materials in: acrylic acid tree 5 parts of fat, chlorinated polyether resin 30 parts, chlorinated rubber 4 parts, APP 5 parts, titanate coupling agent 3 parts, Methyl-silicone oil 3 parts, pentaerythrite 6 parts, styrene 20 parts, butyl latex 8 parts, prodan 3 parts, Modified Nano bamboo charcoal powder 10 parts, bentonite 5 parts, gas-phase silica 5, perlite 8 parts, 15 parts of lignin, Modified tree ash 12 parts.
Described modified Nano bamboo charcoal powder is prepared by following methods: bamboo charcoal powder soaked with 15% sodium hydroxide solution 5h, is then washed with deionized, dry, add be equivalent to the laurate alkyd sodium of its weight 2%, 3% A-cyanacrylate and the crosslink agent DCP of 3%, 5000 revs/min stir 30 minutes, dry, grind Become nanometer powder,.
Described modified tree ash is prepared by following methods: first by 15% salt acid soak tree ash 3h, then It is washed with deionized clean, then soaks 3h with 13% sodium hydroxide solution, then be washed with deionized to neutrality, Dry, add and be equivalent to the wooden sodium sulfonate of tree ash weight 4%, the peregal of 3%, the citric acid three of 4% Butyl ester, the oxidized starch of 4%, 1500 revs/min of stirring 1h, dry, attrition grinding at a high speed.
The preparation method of the described environmental protection coating material adding modified Nano bamboo charcoal powder, including following preparation process:
(1) by above-mentioned weight ratio by acrylic resin, APP, methyl-silicone oil, styrene, fourth Base latex, prodan add agitated kettle, be subsequently adding modified Nano bamboo charcoal powder, bentonite, gas-phase silica, Perlite, lignin and modified tree ash, stir 10min under 1500 revs/min, mix, then Being ground to fineness through sand mill is 60um, obtains mill base;
(2) mill base of step (1) is squeezed into join japanning kettle, be sequentially added in japanning kettle by above-mentioned weight ratio Chlorinated polyether resin, chlorinated rubber, titanate coupling agent, pentaerythrite stir 30min under 2500 revs/min, mixed Close uniformly and get final product.
The performance test results of the coating of the present embodiment 1,2,3 is as shown in the table:

Claims (4)

1. the environmental protection coating material adding modified Nano bamboo charcoal powder, it is characterised in that: former by following weight portion Material is made: acrylic resin 10-15 part, chlorinated polyether resin 15-30 part, chlorinated rubber 2-4 part, APP 5-6 part, titanate coupling agent 1-3 part, methyl-silicone oil 2-3 part, pentaerythrite 5-6 part, styrene 10-20 Part, butyl latex 6-8 part, prodan 2-3 part, modified Nano bamboo charcoal powder 5-10 part, bentonite 3-5 Part, gas-phase silica 5-6 part, perlite 5-8 part, lignin 10-15 part, modified tree ash 8-12 Part.
The environmental protection coating material of interpolation modified Nano bamboo charcoal powder the most according to claim 1, it is characterised in that: Described modified Nano bamboo charcoal powder is prepared by following methods: soaked by bamboo charcoal powder 10-15% sodium hydroxide solution 5-8h, is then washed with deionized, dry, add be equivalent to its weight 1-2% laurate alkyd sodium, The a-cyanacrylate of 1-3% and the crosslink agent DCP of 1-3%, 3000-5000 rev/min of stirring 30-50 divides Clock, dries, grinds to form nanometer powder,.
The environmental protection coating material of interpolation modified Nano bamboo charcoal powder the most according to claim 1, it is characterised in that: Described modified tree ash is prepared by following methods: first by 10-15% salt acid soak tree ash 3-5h, so After be washed with deionized clean, then with 10-13% sodium hydroxide solution immersion 3-5h, then be washed with deionized water Wash to neutrality, dry, add be equivalent to the wooden sodium sulfonate of tree ash weight 2-4%, the peregal of 1-3%, The ATBC of 2-4%, the oxidized starch of 2-4%, high speed 1300-1500 rev/min stirring 1-3h, dry, Attrition grinding becomes superfines.
The preparation method of the environmental protection coating material of interpolation modified Nano bamboo charcoal powder the most according to claim 1, its It is characterised by: include following preparation process:
(1) by above-mentioned weight ratio by acrylic resin, APP, methyl-silicone oil, styrene, fourth Base latex, prodan add agitated kettle, be subsequently adding modified Nano bamboo charcoal powder, bentonite, gas-phase silica, Perlite, lignin and modified tree ash, stir 10-15min under 1200-1500 rev/min, and mixing is all Even, being then ground to fineness through sand mill is 50-60um, obtains mill base;
(2) mill base of step (1) is squeezed into join japanning kettle, be sequentially added in japanning kettle by above-mentioned weight ratio Chlorinated polyether resin, chlorinated rubber, titanate coupling agent, pentaerythrite stir under 2000-2500 rev/min 30-35min, mixes and get final product.
CN201610452074.8A 2016-06-22 2016-06-22 Environmentally friendly coating added with modified nano bamboo charcoal powder and preparation method of environmentally friendly coating Pending CN105885490A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106634082A (en) * 2016-11-17 2017-05-10 铜陵祥云消防科技有限责任公司 Adsorbing odor-removing environment-friendly fireproof coating and preparation method thereof
CN106747178A (en) * 2016-11-24 2017-05-31 安庆市凯瑞建材有限公司 A kind of dry-mixed warming plate decorative mortar and preparation method thereof
CN107384031A (en) * 2017-08-26 2017-11-24 安徽智博新材料科技有限公司 A kind of protective coating on the holder of medical test tubes
CN107573803A (en) * 2017-08-25 2018-01-12 安徽新骏士箱包有限公司 A kind of coating inside box body of draw-bar box and preparation method thereof
CN107629520A (en) * 2017-08-26 2018-01-26 巢湖鹏远金属焊管有限公司 A kind of coating on metal connecting tube and preparation method thereof
CN108937001A (en) * 2017-05-10 2018-12-07 陈丹红 A kind of manufacturing method of pearl paint and preparation method thereof and girasol pearl

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103555090A (en) * 2013-09-26 2014-02-05 芜湖杰诺科技有限公司 Nano waterproof paint
CN103788911A (en) * 2014-02-20 2014-05-14 铜陵祥云消防科技有限责任公司 Environment-friendly adhesive containing modified nanometer bamboo charcoal powder
CN103788781A (en) * 2014-02-20 2014-05-14 铜陵祥云消防科技有限责任公司 Modified nano zeolite powder added fireproof coating material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103555090A (en) * 2013-09-26 2014-02-05 芜湖杰诺科技有限公司 Nano waterproof paint
CN103788911A (en) * 2014-02-20 2014-05-14 铜陵祥云消防科技有限责任公司 Environment-friendly adhesive containing modified nanometer bamboo charcoal powder
CN103788781A (en) * 2014-02-20 2014-05-14 铜陵祥云消防科技有限责任公司 Modified nano zeolite powder added fireproof coating material

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106634082A (en) * 2016-11-17 2017-05-10 铜陵祥云消防科技有限责任公司 Adsorbing odor-removing environment-friendly fireproof coating and preparation method thereof
CN106747178A (en) * 2016-11-24 2017-05-31 安庆市凯瑞建材有限公司 A kind of dry-mixed warming plate decorative mortar and preparation method thereof
CN108937001A (en) * 2017-05-10 2018-12-07 陈丹红 A kind of manufacturing method of pearl paint and preparation method thereof and girasol pearl
CN107573803A (en) * 2017-08-25 2018-01-12 安徽新骏士箱包有限公司 A kind of coating inside box body of draw-bar box and preparation method thereof
CN107384031A (en) * 2017-08-26 2017-11-24 安徽智博新材料科技有限公司 A kind of protective coating on the holder of medical test tubes
CN107629520A (en) * 2017-08-26 2018-01-26 巢湖鹏远金属焊管有限公司 A kind of coating on metal connecting tube and preparation method thereof

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Application publication date: 20160824