CN105837949A - Modified polypropylene film - Google Patents

Modified polypropylene film Download PDF

Info

Publication number
CN105837949A
CN105837949A CN201610446280.8A CN201610446280A CN105837949A CN 105837949 A CN105837949 A CN 105837949A CN 201610446280 A CN201610446280 A CN 201610446280A CN 105837949 A CN105837949 A CN 105837949A
Authority
CN
China
Prior art keywords
parts
nano
calcium carbonate
polypropylene
polypropylene film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610446280.8A
Other languages
Chinese (zh)
Inventor
魏松
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anqing Tianhong New Material Technology Co Ltd
Original Assignee
Anqing Tianhong New Material Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anqing Tianhong New Material Technology Co Ltd filed Critical Anqing Tianhong New Material Technology Co Ltd
Priority to CN201610446280.8A priority Critical patent/CN105837949A/en
Publication of CN105837949A publication Critical patent/CN105837949A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10—Homopolymers or copolymers of propene
    • C08J2323/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/002—Physical properties
    • C08K2201/003—Additives being defined by their diameter
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/017—Additives being an antistatic agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/14—Gas barrier composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00—Crosslinking

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a modified polypropylene film, which is prepared from the following raw materials in parts by weight: 50 to 100 parts of polypropylene, 10 to 30 parts of ethylene-vinyl alcohol copolymer, 2 to 5 parts of maleic anhydride grafted polypropylene, 0.2 to 1.5 parts of polyvinyl methyl ether, 0.5 to 1 part of N,N'-dicyclohexyl-2,6-naphthalene dicarboamide, 0.2 to 1 part of calcium suberate, 0.5 to 1.5 parts of dilauryl thiodipropionate, 0.2 to 0.5 part of phosphite ester, 0.3 to 2 parts of benzotriazole, 0.1 to 1 part of antistatic agent, 2 to 5 parts of nano calcium carbonate, 0.2 to 1.5 parts of nano-zinc oxide, 2 to 5 parts of chitosan, 0.1 to 1.5 parts of nanometer zirconia, and 0.1 to 0.5 part of glutaraldehyde. The modified polypropylene film provided by the invention has good antibacterial property, excellent hydrophilia and anti-fouling performance, and excellent gas barrier property.

Description

A kind of modified polypropylene film
Technical field
The present invention relates to polypropylene screen technical field, particularly relate to a kind of modified polypropylene film.
Background technology
Polypropylene belongs to thermoplastic, and mean molecule quantity is 10-15 ten thousand, and proportion is 0.89-0.91cm3, fusing point is 164- 170℃.Owing to polypropylene molecule is to be formed by nonpolar propylene catalytic polymerization, molecular structure is carbon-to-carbon and carbon-hydrogen saturated Key, therefore it has the electrical insulating property of excellence, chemical stability.Owing to polypropylene has excellent performance, its film at present the most by It is largely used to the fields such as battery industry, water process, air cleaning.But polyacrylic hydrophily is poor, easy static electrification, and antibiotic property Can be less desirable, hinder the further expansion of its application.
Summary of the invention
The technical problem existed based on background technology, the present invention proposes a kind of modified polypropylene film, and its antibiotic property is good, Hydrophily and antifouling property are excellent, and have the gas barrier property of excellence.
A kind of modified polypropylene film that the present invention proposes, its raw material includes by weight: polypropylene 50-100 part, second Alkene-ethenol copolymer 10-30 part, maleic anhydride inoculated polypropylene 2-5 part, polyvinyl methyl ether 0.2-1.5 part, N, N '- Dicyclohexyl-2,6-aphthalimide 0.5-1 part, calcium suberate 0.2-1 part, dilauryl thiodipropionate 0.5-1.5 part, Asia Phosphoesterase 30 .2-0.5 part, BTA 0.3-2 part, antistatic additive 0.1-1 part, nano-calcium carbonate 2-5 part, nano zine oxide 0.2-1.5 part, shitosan 2-5 part, nano zircite 0.1-1.5 part, glutaraldehyde 0.1-0.5 part.
Preferably, its raw material includes by weight: polypropylene 65-80 part, ethylene-vinyl alcohol copolymer 20-25 part, Malaysia Anhydride-grafted polypropylene 3.2-4 part, polyvinyl methyl ether 0.7-1.1 part, N, N '-dicyclohexyl-2,6-aphthalimide 0.65-0.85 part, calcium suberate 0.5-1 part, dilauryl thiodipropionate 1-1.3 part, phosphite ester 0.3-0.4 part, benzo Triazole 1-1.5 part, antistatic additive 0.45-0.8 part, nano-calcium carbonate 2.9-3.4 part, nano zine oxide 0.7-1.1 part, shitosan 3.2-4 part, nano zircite 0.5-1.1 part, glutaraldehyde 0.32-0.4 part.
Preferably, its raw material includes by weight: polypropylene 70 parts, ethylene-vinyl alcohol copolymer 22 parts, maleic anhydride connect Branch polypropylene 3.6 parts, polyvinyl methyl ether 1 part, N, N '-dicyclohexyl-2,6-aphthalimide 0.7 part, calcium suberate 0.65 part, dilauryl thiodipropionate 1.2 parts, phosphite ester 0.35 part, BTA 1.2 parts, 0.6 part of antistatic additive, receive Rice 3 parts of calcium carbonate, nano zine oxide 1 part, shitosan 3.6 parts, nano zircite 1 part, glutaraldehyde 0.35 part.
Preferably, described polypropylene is polyethylene glycol graft modification polypropylene.
Preferably, described antistatic additive is carbon black, polyethylene glycol, sorbitan monostearate, glycerol monostearate One or more mixture in ester.
Preferably, described nano-calcium carbonate be average grain diameter be the nano-calcium carbonate of 200-250nm, average grain diameter be 5- The nano-calcium carbonate of 20nm, average grain diameter are that the nano-calcium carbonate of 35-50nm is by weight the mixture for 3-10:1-5:1-5.
Preferably, described shitosan is modification of chitosan；Described modification of chitosan is hydroxypropyl chitosan, carboxymethyl chitosan One or more mixture in sugar, chitosan quaternary ammonium salt, carboxymethyl chitosan quaternary ammonium salt.
Modified polypropylene film of the present invention can be prepared from according to conventional polypropylene film preparation technology.
In the present invention, with polypropylene as major ingredient, and add ethylene-vinyl alcohol copolymer, maleic anhydride inoculated polypropylene It is modified with polyvinyl methyl ether, by controlling ethylene-vinyl alcohol copolymer, maleic anhydride inoculated polypropylene and polyethylene Ylmethyl ether and polyacrylic ratio, make the performance of four work in coordination with, improve the gas barrier property of film, hydrophily and anti-soil Performance, improves the processing characteristics of film simultaneously；Add N, N '-dicyclohexyl-2,6-aphthalimide and calcium suberate, with Time add dilauryl thiodipropionate, phosphite ester and BTA, give the excellent resistance to ag(e)ing of film and thermally-stabilised Property；The nano-calcium carbonate, nano zine oxide and the nano zircite that add have mating reaction, improve thin film strength and tough Property, overcome the defect that the intensity caused because of the addition of ethylene-vinyl alcohol copolymer reduces；In shitosan addition system, penta Under the effect of dialdehyde, crosslink reaction, thus improve the compatibility of itself and system, further increase the hydrophily of film And antibiotic property, give the antifouling property that film is excellent simultaneously.
Detailed description of the invention
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
A kind of modified polypropylene film that the present invention proposes, its raw material includes by weight: polypropylene 100 parts, ethene-second Enol copolymer 10 part, maleic anhydride inoculated polypropylene 5 parts, polyvinyl methyl ether 0.2 part, N, N '-dicyclohexyl-2,6-naphthalene Diformamide 1 part, calcium suberate 0.2 part, dilauryl thiodipropionate 1.5 parts, phosphite ester 0.2 part, BTA 2 parts, 0.1 part of antistatic additive, nano-calcium carbonate 5 parts, nano zine oxide 0.2 part, shitosan 5 parts, nano zircite 0.1 part, glutaraldehyde 0.5 part.
Embodiment 2
A kind of modified polypropylene film that the present invention proposes, its raw material includes by weight: polypropylene 50 parts, ethene-second Enol copolymer 30 parts, maleic anhydride inoculated polypropylene 2 parts, polyvinyl methyl ether 1.5 parts, N, N '-dicyclohexyl-2,6-naphthalene Diformamide 0.5 part, calcium suberate 1 part, dilauryl thiodipropionate 0.5 part, phosphite ester 0.5 part, BTA 0.3 Part, 1 part of antistatic additive, nano-calcium carbonate 2 parts, nano zine oxide 0.5 part, shitosan 2 parts, nano zircite 1.5 parts, glutaraldehyde 0.1 part.
Embodiment 3
A kind of modified polypropylene film that the present invention proposes, its raw material includes by weight: polypropylene 80 parts, ethene-second Enol copolymer 20 parts, maleic anhydride inoculated polypropylene 4 parts, polyvinyl methyl ether 0.7 part, N, N '-dicyclohexyl-2,6-naphthalene Diformamide 0.85 part, calcium suberate 0.5 part, dilauryl thiodipropionate 1.3 parts, phosphite ester 0.3 part, BTA 1.5 parts, sorbitan monostearate 0.45 part, nano-calcium carbonate 3.4 parts, nano zine oxide 0.7 part, hydroxypropyl chitosan 3.2 parts, nano zircite 1.1 parts, glutaraldehyde 0.32 part；
Wherein, described nano-calcium carbonate be average grain diameter be the nano-calcium carbonate of 250nm, average grain diameter be the nanometer of 5nm Calcium carbonate, average grain diameter are that the nano-calcium carbonate of 50nm is by weight the mixture for 3:5:1.
Embodiment 4
A kind of modified polypropylene film that the present invention proposes, its raw material includes by weight: polypropylene 65 parts, ethene-second Enol copolymer 25 parts, maleic anhydride inoculated polypropylene 3.2 parts, polyvinyl methyl ether 1.1 parts, N, N '-dicyclohexyl-2,6- Aphthalimide 0.65 part, calcium suberate 1 part, dilauryl thiodipropionate 1 part, phosphite ester 0.4 part, BTA 1 part, Polyethylene glycol 0.1 part, sorbitan monostearate 0.3 part, glyceryl monostearate 0.4 part, nano-calcium carbonate 2.9 parts, Nano zine oxide 1.1 parts, chitosan quaternary ammonium salt 2 parts, carboxymethyl chitosan quaternary ammonium salt 2 parts, nano zircite 0.5 part, glutaraldehyde 0.4 part；
Wherein, described nano-calcium carbonate be average grain diameter be the nano-calcium carbonate of 200nm, average grain diameter be the nanometer of 20nm Calcium carbonate, average grain diameter are that the nano-calcium carbonate of 35nm is by weight the mixture for 10:1:5.
Embodiment 5
A kind of modified polypropylene film that the present invention proposes, its raw material includes by weight: polypropylene is that polyethylene glycol connects Branch modified polypropene 70 parts, ethylene-vinyl alcohol copolymer 22 parts, maleic anhydride inoculated polypropylene 3.6 parts, polyvinyl methyl ether 1 part, N, N '-dicyclohexyl-2,6-aphthalimide 0.7 part, calcium suberate 0.65 part, dilauryl thiodipropionate 1.2 parts, Phosphite ester 0.35 part, BTA 1.2 parts, carbon black 0.4 part, polyethylene glycol 0.2 part, nano-calcium carbonate 3 parts, nano zine oxide 1 part, hydroxypropyl chitosan 0.5 part, carboxymethyl chitosan 1 part, chitosan quaternary ammonium salt 1 part, carboxymethyl chitosan quaternary ammonium salt 1.1 Part, nano zircite 1 part, glutaraldehyde 0.35 part；
Wherein, described nano-calcium carbonate be average grain diameter be the nano-calcium carbonate of 220nm, average grain diameter be the nanometer of 15nm Calcium carbonate, average grain diameter are that the nano-calcium carbonate of 40nm is by weight the mixture for 5:4:3.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto, Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.

Claims (7)

1. a modified polypropylene film, it is characterised in that its raw material includes by weight: polypropylene 50-100 part, ethene-second Enol copolymer 1 0-30 part, maleic anhydride inoculated polypropylene 2-5 part, polyvinyl methyl ether 0.2-1.5 part, N, N '-two hexamethylene Base-2,6-aphthalimide 0.5-1 part, calcium suberate 0.2-1 part, dilauryl thiodipropionate 0.5-1.5 part, phosphite ester 0.2-0.5 part, BTA 0.3-2 part, antistatic additive 0.1-1 part, nano-calcium carbonate 2-5 part, nano zine oxide 0.2-1.5 Part, shitosan 2-5 part, nano zircite 0.1-1.5 part, glutaraldehyde 0.1-0.5 part.
Modified polypropylene film the most according to claim 1, it is characterised in that its raw material includes by weight: polypropylene 65- 80 parts, ethylene-vinyl alcohol copolymer 20-25 part, maleic anhydride inoculated polypropylene 3.2-4 part, polyvinyl methyl ether 0.7-1.1 Part, N, N '-dicyclohexyl-2,6-aphthalimide 0.65-0.85 part, calcium suberate 0.5-1 part, dilauryl thiodipropionate 1-1.3 part, phosphite ester 0.3-0.4 part, BTA 1-1.5 part, antistatic additive 0.45-0.8 part, nano-calcium carbonate 2.9- 3.4 parts, nano zine oxide 0.7-1.1 part, shitosan 3.2-4 part, nano zircite 0.5-1.1 part, glutaraldehyde 0.32-0.4 part.
Modified polypropylene film the most according to claim 1 or claim 2, it is characterised in that its raw material includes by weight: polypropylene 70 parts, ethylene-vinyl alcohol copolymer 22 parts, maleic anhydride inoculated polypropylene 3.6 parts, polyvinyl methyl ether 1 part, N, N '-two Cyclohexyl-2,6-aphthalimide 0.7 part, calcium suberate 0.65 part, dilauryl thiodipropionate 1.2 parts, phosphite ester 0.35 part, BTA 1.2 parts, 0.6 part of antistatic additive, nano-calcium carbonate 3 parts, nano zine oxide 1 part, shitosan 3.6 parts, receive Rice zirconium oxide 1 part, glutaraldehyde 0.35 part.
4. according to modified polypropylene film according to any one of claim 1-3, it is characterised in that described polypropylene is poly-second two Alcohol graft modification polypropylene.
5. according to modified polypropylene film according to any one of claim 1-4, it is characterised in that described antistatic additive is charcoal One or more mixture in black, polyethylene glycol, sorbitan monostearate, glyceryl monostearate.
6. according to modified polypropylene film according to any one of claim 1-5, it is characterised in that described nano-calcium carbonate is flat All particle diameter be the nano-calcium carbonate of 200-250nm, average grain diameter be the nano-calcium carbonate of 5-20nm, average grain diameter be 35-50nm Nano-calcium carbonate by weight for the mixture of 3-10:1-5:1-5.
7. according to modified polypropylene film according to any one of claim 1-6, it is characterised in that described shitosan is modified shell Glycan；Described modification of chitosan is hydroxypropyl chitosan, carboxymethyl chitosan, chitosan quaternary ammonium salt, carboxymethyl chitosan quaternary ammonium One or more mixture in salt.
CN201610446280.8A 2016-06-21 2016-06-21 Modified polypropylene film Pending CN105837949A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610446280.8A CN105837949A (en) 2016-06-21 2016-06-21 Modified polypropylene film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610446280.8A CN105837949A (en) 2016-06-21 2016-06-21 Modified polypropylene film

Publications (1)

Publication Number Publication Date
CN105837949A true CN105837949A (en) 2016-08-10

Family

ID=56576343

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610446280.8A Pending CN105837949A (en) 2016-06-21 2016-06-21 Modified polypropylene film

Country Status (1)

Country Link
CN (1) CN105837949A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106317636A (en) * 2016-08-31 2017-01-11 金田集团（桐城）塑业有限公司 Modified polypropylene film
CN107057187A (en) * 2017-04-12 2017-08-18 芜湖扬展新材料科技服务有限公司 A kind of medical antibacterial packaging bag
CN107245192A (en) * 2017-08-02 2017-10-13 苏州新区特氟龙塑料制品厂 A kind of PET antistatic protection films
CN107674305A (en) * 2017-10-25 2018-02-09 安徽国泰印务有限公司 A kind of antimildew polyacrylic film

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102164738A (en) * 2008-09-29 2011-08-24 博里利斯股份公司 Polyolefin composition
CN104004272A (en) * 2014-06-20 2014-08-27 江苏兆鋆新材料股份有限公司 Modified polypropylene composite material and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102164738A (en) * 2008-09-29 2011-08-24 博里利斯股份公司 Polyolefin composition
CN104004272A (en) * 2014-06-20 2014-08-27 江苏兆鋆新材料股份有限公司 Modified polypropylene composite material and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
张景: "《一通检索记录表》", 8 February 2018 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106317636A (en) * 2016-08-31 2017-01-11 金田集团（桐城）塑业有限公司 Modified polypropylene film
CN107057187A (en) * 2017-04-12 2017-08-18 芜湖扬展新材料科技服务有限公司 A kind of medical antibacterial packaging bag
CN107245192A (en) * 2017-08-02 2017-10-13 苏州新区特氟龙塑料制品厂 A kind of PET antistatic protection films
CN107674305A (en) * 2017-10-25 2018-02-09 安徽国泰印务有限公司 A kind of antimildew polyacrylic film

Similar Documents

Publication Publication Date Title
CN105837949A (en) Modified polypropylene film
US9085678B2 (en) Clean flame retardant compositions with carbon nano tube for enhancing mechanical properties for insulation of wire and cable
KR101634076B1 (en) Composition for sheet using biomass, eco-friendly composite sheet, and fabrication method for thereof
JP2011168697A (en) Composition for electric wire-coating material, insulated wire, and wire harness
JP6344201B2 (en) Flame retardant resin composition and flame retardant insulated wire / cable
JP6344200B2 (en) Flame retardant resin composition and flame retardant insulated wire / cable
JP6121742B2 (en) Conductive thermoplastic resin composition and cable
JPWO2016084840A1 (en) Silage film, feed packaging and feed storage method
CN105038098B (en) A kind of plastic gear low-friction coefficient wear-resistant polyformaldehyde composite and preparation method thereof
JP6418138B2 (en) Flame retardant resin composition and flame retardant cable
CN102816390B (en) Blending type rubber compound and preparation method thereof
CN106832507A (en) A kind of heat-resisting heat conduction PE cable material
WO2015163437A1 (en) Ethylene-vinyl alcohol resin composition, molded article, and multi-layer structure
CN104861369A (en) Fire, weather and high temperature resistant polyvinyl chloride tube and production method thereof
JP2018154671A (en) Resin composition and molding
US11820883B2 (en) Resin formed body and resin composition
JP6418137B2 (en) Flame retardant resin composition and flame retardant cable
CN114044987A (en) Oil-resistant ethylene propylene insulating material
JP2018522760A (en) Multi-layer film incorporating starch and article comprising the same
JP6490391B2 (en) Nanocomposite containing magnesium hydroxide and polyolefin and method for producing the same
Xiang et al. Lignin-based functional nanocomposites
JP6819435B2 (en) Resin composition and electric wire
JP2010095315A (en) Container for agricultural chemical
CN109094161B (en) Plastic film easy to corona and high in flatness and preparation method thereof
JP2005054147A (en) Thermoplastic resin/rubber composite composition, manufacturing method therefor, and part with gas barrier properties

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20160810

RJ01 Rejection of invention patent application after publication