CN105816354A - Nail polish with sequins, laser powder and rhinestone powder - Google Patents

Nail polish with sequins, laser powder and rhinestone powder Download PDF

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CN105816354A
CN105816354A CN201510468198.0A CN201510468198A CN105816354A CN 105816354 A CN105816354 A CN 105816354A CN 201510468198 A CN201510468198 A CN 201510468198A CN 105816354 A CN105816354 A CN 105816354A
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mixture
added
powder
temperature
add
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CN105816354B (en
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赵明
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Hangzhou Lai Fan Network Technology Co Ltd
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Hangzhou Lai Fan Network Technology Co Ltd
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Abstract

The invention relates to a nail polish with sequins, laser powder and rhinestone powder. The nail polish comprises, by weight, 48 to 52 parts of deionized water, 22 to 25 parts of polyurethane-35, 16 to 17 parts of acrylic acid/VO cross-linked polymer, 4 to 5 parts of hydroxypropyl methyl cellulose, 0.9 to 1.5 parts of triethanolamine, 0.7 to 0.8 part of laurinol polyether-21, 0.01 to 0.05 part of a compound as shown in a formula I, 0.9 to 3 parts of mica, 0.08 to 2 parts of glycerin and 1 to 3 parts of a mixture of sequins, laser powder and rhinestone powder. The nail polish is environment-friendly and nontoxic, poses no harm to the human body and no pollution to the environment and has a brilliant color.

Description

A kind of finger coloured silk being added with diamante, radium-shine powder, artificial diamond powder
Technical field
The present invention relates to cosmetic product, be added with diamante, radium-shine powder, artificial particularly to one The finger of diamond dust is color.
Background technology
Traditional nial polish contains stimulates chemical analysis in a large number, such as acetone, toluene etc., easily allows finger First becomes dry, turns yellow, becomes fragile, and affects health and environmental pollution.
Due to nial polish must possess quick-drying, glossy, adhesive force is strong, painting water-fast, easy and easily The features such as removal, although nial polish technology obtains significant progress along with the development of science and technology, but due to The material that can simultaneously meet the above-mentioned performance of nial polish is little, thus up to the present, market includes The nial polish almost all that international major company produces be by nitrocellulose, modified resin, plasticizer, Multiple mixed solvent forms, but the solvent that can dissolve nitrocellulose is typically all some easily waves Send out, the material of strong toxicity excitatory, recently as universal, the rise of manicure of nial polish, The report of human injury is also got more and more by such as nial polish.
Summary of the invention
It is an object of the invention to provide and a kind of be added with diamante, radium-shine powder, the finger of artificial diamond powder Coloured silk, its environmental protection, nontoxic, harmless, environmentally safe, bright color.
The above-mentioned technical purpose of the present invention has the technical scheme that a kind of interpolation Have diamante, radium-shine powder, artificial diamond powder finger color, its raw materials by weight portion meter, including:
The deionized water of 48-52 part,
Polyurethane-35 of 22-25 part,
The acrylic acid of 16-17 part/VP cross linked polymer,
The hydroxypropyl methyl cellulose of 4-5 part,
The triethanolamine of 0.9-1.5 part,
Laureth-21 of 0.7-0.8 part,
The compound of formula I of 0.01-0.05 part,
0.9-3 part Muscovitum,
0.08-2 part glycerol;
The diamante of 1-3 part, radium-shine powder and rhinestone mixture;
Its compounds of formula I is shown below:
The most also include the coloring agent of 0.3-0.8 part.
The most also include the function monomer of 5-8 part.
Another object of the present invention is to provide one to be added with diamante, radium-shine powder, rhinestone The finger of powder is color, its raw materials by weight portion meter, including:
The deionized water of 49-52 part,
Polyurethane-35 of 23-25 part,
The acrylic acid of 16-17 part/VP cross linked polymer,
The hydroxypropyl methyl cellulose of 4-4.5 part,
The triethanolamine of 0.9-1.5 part,
Laureth-21 of 0.7-0.8 part,
The compound of formula I of 0.01-0.05 part,
The polyethylene terephthalate of 1.2-2.8 part,
The aluminum of 0.05-0.15 part,
0.09-0.15 part glycerol;
The diamante of 1-3 part, radium-shine powder and rhinestone mixture.
The most also include the coloring agent of 0.4-0.5 part.
The most also include the function monomer of 5-8 part.
It is still another object of the present invention to provide the one described in technique scheme and be added with flash of light Sheet, radium-shine powder, the preparation method referring to coloured silk of artificial diamond powder, comprise the steps:
(1) by hydroxypropyl methyl cellulose and triethanolamine mixing and stirring, the first mixing is formed Body, standby;
(2) 30-35 part deionized water is taken, at keeping 60-80 DEG C, by polyurethane-35, acrylic acid / VP cross linked polymer and compound of formula I add in deionized water, and addition manner is, on a time period Add polyurethane-35, acrylic acid/VP cross linked polymer and compound of formula I, add interval 3-5 every time Minute, and added complete in 15-20 minute, be stirred continuously in adding procedure, make both Uniformly mixing in deionized water, after having mixed, at 30-40 DEG C, pressurization stands 1-2h, pressure For 1-2Mpa, thus form the second mixture;
(3) remaining deionized water and laureth-21 are mixed at 40-50 DEG C, form the Three mixtures;
(4) the second mixture was uniformly added in 20-30 minute to the 3rd mixture, and all the time Keep the temperature at 70-90 degree, in both mixed processes, be stirred continuously, when the second mixture After being added completely into the 3rd mixture, continue stirring 1-2h, afterwards heat-insulation pressure keeping 2-4h, keep temperature For 80-85 degree, pressure is 0.5-0.8Mpa;
(5) the first mixture is uniformly added in 1-2h in the mixture that step (4) obtains, Keeping temperature is 60-70 degree, and continuously stirred makes mix homogeneously, when the first mixture has added also After mix homogeneously, heat-insulation pressure keeping 2-4h, temperature is 65-70 degree, and pressure is 0.6-0.8Mpa;
(6) by after glycerol, coloring agent and diamante, radium-shine powder, artificial diamond powder's mixing and stirring Add in the mixture that step (5) obtains, be under 80-90 degree keeping temperature, stir Rear natural cooling obtains nial polish finished product;
Artificial diamond powder is granular, and particle diameter is at 0.2-1mm.
It is still another object of the present invention to provide the one described in technique scheme and be added with flash of light Sheet, radium-shine powder, the preparation method referring to coloured silk of artificial diamond powder, comprise the steps:
(1) by hydroxypropyl methyl cellulose and triethanolamine mixing and stirring, the first mixing is formed Body, standby;
(2) take 30-35 part deionized water, keeping at 60-80 DEG C, by the polyurethane-35 of 23-28 part, The acrylic acid of 15-20 part/VP cross linked polymer and compound of formula I add in deionized water, interpolation side Formula is, adds polyurethane-35, acrylic acid/VP cross linked polymer and compound of formula I on a time period, Add interval 3-5 minute every time, and added complete in 15-20 minute, in adding procedure not Disconnected stirring, makes both the most uniformly mix, and after having mixed, holding temperature is 70-80 Degree, adds functional monomer, continues stirring 10-20 minute, at being cooled to 30-40 DEG C, Pressurization stands 1-2h, and pressure is 1-2Mpa, thus forms the second mixture;
(3) remaining deionized water and laureth-21 are mixed at 40-50 DEG C, form the Three mixtures;
(4) the second mixture was uniformly added in 20-30 minute to the 3rd mixture, and all the time Keep the temperature at 70-90 degree, in both mixed processes, be stirred continuously, when the first mixture After being added completely into the second mixture, continue stirring 1-2h, afterwards heat-insulation pressure keeping 2-4h, keep temperature For 80-85 degree, pressure is 0.5-0.8Mpa;
(5) the first mixture is uniformly added in 1-2h in the mixture that step (4) obtains, Keeping temperature is 60-70 degree, and continuously stirred makes mix homogeneously, when the first mixture has added also After mix homogeneously, heat-insulation pressure keeping 2-4h, temperature is 65-70 degree, and pressure is 0.6-0.8Mpa;
(6) by after glycerol, coloring agent and diamante, radium-shine powder, artificial diamond powder's mixing and stirring Add in the mixture that step (5) obtains, be under 80-90 degree keeping temperature, stir Rear natural cooling obtains nial polish finished product;
Artificial diamond powder is granular, and particle diameter is at 0.2-1mm.
It is still another object of the present invention to provide the one described in technique scheme and be added with flash of light Sheet, radium-shine powder, the preparation method referring to coloured silk of artificial diamond powder, comprise the steps:
(1) by hydroxypropyl methyl cellulose and triethanolamine mixing and stirring, the first mixing is formed Body, standby;
(2) 30-35 part deionized water is taken, at keeping 60-80 DEG C, by polyurethane-35, acrylic acid / VP cross linked polymer and compound of formula I add in deionized water, and addition manner is, on a time period Add polyurethane-35, acrylic acid/VP cross linked polymer and compound of formula I, add interval 3-5 every time Minute, and added complete in 15-20 minute, be stirred continuously in adding procedure, make both Deionized water uniformly mixes, after having mixed, improves temperature and to 90-95 degree and keep, add Polyethylene terephthalate, after being uniformly mixed, naturally cools to 30-40 DEG C, and At a temperature of Gai, pressurization stands 1-2h, and pressure is 1-2Mpa, thus forms the second mixture;
(3) remaining deionized water and laureth-21 are mixed at 40-50 DEG C, form the Three mixtures;
(4) the second mixture was uniformly added in 20-30 minute to the 3rd mixture, and all the time Keep the temperature at 70-90 degree, in both mixed processes, be stirred continuously, when the second mixture After being added completely into the 3rd mixture, continue stirring 1-2h, afterwards heat-insulation pressure keeping 2-4h, keep temperature For 80-85 degree, pressure is 0.5-0.8Mpa;
(5) the first mixture is uniformly added in 1-2h in the mixture that step (4) obtains, Keeping temperature is 60-70 degree, and continuously stirred makes mix homogeneously, when the first mixture has added also After mix homogeneously, heat-insulation pressure keeping 2-4h, temperature is 65-70 degree, and pressure is 0.6-0.8Mpa;
(6) add after aluminum, coloring agent and diamante, radium-shine powder, artificial diamond powder's mixing and stirring Add in the mixture that step (5) obtains, be under 80-90 degree keeping temperature, after stirring Natural cooling obtains nial polish finished product;
Artificial diamond powder is granular, and particle diameter is at 0.2-1mm.
It is still another object of the present invention to provide the one described in technique scheme and be added with flash of light Sheet, radium-shine powder, the preparation method referring to coloured silk of artificial diamond powder, comprise the steps:
(1) by hydroxypropyl methyl cellulose and triethanolamine mixing and stirring, the first mixing is formed Body, standby;
(2) 30-35 part deionized water is taken, at keeping 60-80 DEG C, by polyurethane-35, acrylic acid / VP cross linked polymer and compound of formula I add in deionized water, and addition manner is, on a time period Add polyurethane-35, acrylic acid/VP cross linked polymer and compound of formula I, add interval 3-5 every time Minute, and added complete in 15-20 minute, be stirred continuously in adding procedure, make both Deionized water uniformly mixes, after having mixed, improves temperature and to 90-95 degree and keep, add Polyethylene terephthalate, after being uniformly mixed, is cooled to 70-80 degree and keeps, then Add functional monomer, continue stirring 10-20 minute, naturally cool to 30-40 DEG C, and at this At a temperature of pressurization stand 1-2h, pressure is 1-2Mpa, thus forms the second mixture;
(3) remaining deionized water and laureth-21 are mixed at 40-50 DEG C, form the Three mixtures;
(4) the second mixture was uniformly added in 20-30 minute to the 3rd mixture, and all the time Keep the temperature at 70-90 degree, in both mixed processes, be stirred continuously, when the second mixture After being added completely into the 3rd mixture, continue stirring 1-2h, afterwards heat-insulation pressure keeping 2-4h, keep temperature For 80-85 degree, pressure is 0.5-0.8Mpa;
(5) the first mixture is uniformly added in 1-2h in the mixture that step (4) obtains, Keeping temperature is 60-70 degree, and continuously stirred makes mix homogeneously, when the first mixture has added also After mix homogeneously, heat-insulation pressure keeping 2-4h, temperature is 65-70 degree, and pressure is 0.6-0.8Mpa;
(6) add after aluminum, coloring agent and diamante, radium-shine powder, artificial diamond powder's mixing and stirring Add in the mixture that step (5) obtains, be under 80-90 degree keeping temperature, after stirring Natural cooling obtains nial polish finished product;
Artificial diamond powder is granular, and particle diameter is at 0.2-1mm.
Preferred as the present invention, the preparation method of described triethanolamine is:
(1) oxirane, ammonia are sent in reactor, in reaction temperature 35-38 DEG C, reaction pressure Under power 100-300kPa, carry out condensation reaction generate one, two, triethanolamine mixed liquor;
(2) at 100-110 DEG C after dehydration concentrates, send into three vacuum rectification tower and carry out decompression steaming Evaporate, intercept fraction by different boiling, thus obtain triethanolamine semi-finished product;
(3) remove the removal of impurity with vapor distillation, and add sodium hydroxide and make triethanolamine become alkali metal Salt and separate out, neutralize after separation, then carry out decompression and distill to obtain triethanolamine sterling.
Preferred as the present invention, the preparation method of described hydroxypropyl methyl cellulose is:
(1), after purified cotton fibre element alkali liquor being soaked half an hour at 50-60 DEG C, squeezing is taken out, will Cellulose is pulverized, and carries out the most aging at 40-50 DEG C;
(2) alkali fiber is put into etherification kettle, be sequentially added into expoxy propane and chloromethanes, at 55-70 DEG C Lower etherificate 6-7h, holding pressure is 1.5-2MPa;
(3) in the hot water of 70-80 DEG C, then add appropriate hydrochloric acid and oxalic acid washing material, make volume Expand, and with centrifuge dewatering, wash to neutral, when in material, water content is less than 60%, with The hot-air fluidized drying of more than 130 DEG C prepares to moisture content less than 5%.
Preferred as the present invention, the preparation method of described rhinestone, comprise the steps:
(1) preparation of raw material: be calculated by weight as: the lead oxide of 40-50 part, the dioxy of 30-35 part SiClx, the sodium carbonate of 20-25 part, the calcium carbonate of 30-40 part, the hair of 20-30 part;
(2) crushing raw material in powdery and mix, carrying out refinery, temperature is 2200-2500 degree, Cool down after 20-25h, form semi-finished product;
(3) semi-finished product being carried out the molding of high temperature high pressure process 10-25h, temperature is 2000-2200 degree, Pressure is 2500-3000 normal atmosphere;
(4) broken, polishing, obtain finished product.
In sum, the method have the advantages that the water-base resin fingernail that the present invention makes Oil, content of volatile organic compound be less than 15 grams per liters, without toluene, formaldehyde, ethyl acetate, The materials such as DBP, nontoxic, tasteless, to human body fanout free region, environmentally safe, drying time is short, Simultaneously under the fusion of each raw material, there is good adhesive force and resistance to water, paint film brightness Height, bright in colour, colour retention is strong;And the technique of the present invention is unique, in the system of the second mixture Standby, the second mixture and the combination of the 3rd mixture and the first mixture and second and third mixture In in conjunction with, segmentation or persistence is used to add raw material the mode stirred under keeping uniform temperature, Contribute to being sufficiently mixed and cross-linking between the two, and heat-insulation pressure keeping process afterwards, it is beneficial to improve Molecular activity, is more beneficial for the most preferably blending, and eliminates the stress combined and produce;Month The mode that laureth-21 mixes at different periods as wetting agent with glycerol, is also beneficial to improve Nial polish moistening effect, makes the most sparkling and crystal-clear water of nial polish bright;Add the interpolation of functional monomer, have It is beneficial to improve the resistance to water of nial polish and adhesive force.
The more important thing is, the compositions of the present invention add natural extract compound of formula I after, Can effectively prevent the fungus dip-dye to fingernail.
Embodiment
Below by embodiment, the invention will be further described.It should be understood that the present invention is real Method described in example of executing is only used for the present invention rather than limitation of the present invention being described, at this Under bright concept thereof, the simple modifications to preparation method of the present invention broadly falls into claimed Scope.All raw materials, solvent and the strain used in embodiment are purchased from Sigma Biochemical and Organic Compounds for Research and Diagnostic Clinical Reagents company.
The preparation embodiment of compound of formula I:
With Folium Ginkgo as raw material, pulverized and by soak with ethanol and extract 2~4 times, every time 12h~72h, obtains described Folium Ginkgo extract extractum after being merged, filter and concentrate by extracting solution; Wherein ethanol: Folium Ginkgo=3~4:1, weight ratio.
By after above-mentioned Folium Ginkgo extract extractum acetone solution with for 2~5 weight of described extractum Times 60~120 mesh silica gel mixing after dry column-packing, then with volume ratio be followed successively by 9:1,8:2, Grade chloroform-the methanol solution of 7:3,6:4,5:5 carries out gradient elution, collects and wherein uses volume ratio The eluent obtained during for the chloroform-methanol eluting of 9:1, the referred to as first eluent;By above-mentioned First eluent with silica gel column chromatography continue separate, with volume ratio be followed successively by 15:1,10:1,5:1, The chloroform-acetone solution of 2:1 carries out gradient elution, by molten for chloroform-acetone that wherein volume is 10:1 The eluent obtained during liquid eluting is referred to as the second eluent.By above-mentioned second eluent silica gel column layer Analysis continues to separate, and is followed successively by the petroleum ether-acetic acid second of 9:1,8:2,7:3,6:4,5:5 by volume ratio Ester solution carries out gradient elution, obtains during by petroleum ether-ethyl acetate eluting that wherein volume ratio is 7:3 To eluent be referred to as the 3rd eluent.
Above-mentioned 3rd eluent is passed through high pressure liquid chromatography, and (pressure is in the anti-phase preparation of 5-15Mpa Chromatograph) carry out isolated and purified, this high pressure liquid chromatography use 21.2mm × 250mm, 5 μm C18Chromatographic column, flowing is the methanol aqueous solution of 60wt% mutually, and flow rate of mobile phase is 12mL/min, UV-detector detection wavelength is 374nm, and the 3rd each Jin Yang of eluent 60~150 μ L collects The eluent that after sample introduction, chromatographic peak retention time is corresponding when being 31min every time, after desolvation Obtain described compound of formula I
After obtaining above-mentioned compound of formula I, methanol solution can be again dissolved in, and with methanol solution be Flowing phase, carries out chromatography by gel column, can purify described compound of formula I further.
Formula I is yellow powder;Following list compound of formula I ultraviolet spectra, The key structural feature peak of infrared spectrum and proton magnetic.
Ultraviolet spectra (solvent is methanol): λmax(log ε) 210 (4.36), 266 (3.82), 374(3.68)nm;
Infrared spectrum (pressing potassium bromide troche): vmax3452,2924,2615,1668,1612,1516, 1437,1316,1247,1182,1083,1022,868,722cm-1
1H NMR(500MHz,CDCl3,ppm)δ:10.7(s-OH),9.48(s-OH) 6.28-7.52(d,-CH 5H),6.57(s,1H),6.18(s 1H),3.27(d,-CH2),1.99-3.81 (d,-CH39H).
Embodiment 1:
A kind of finger coloured silk being added with diamante, radium-shine powder, artificial diamond powder, its raw material is by weight Number meter, including: the deionized water of 49.81 parts, polyurethane-35 of 24.01 parts, the third of 16.81 parts Olefin(e) acid/VP cross linked polymer, the hydroxypropyl methyl cellulose of 4.32 parts, the triethanolamine of 1.02 parts, Laureth-21 of 0.78 part, the compound of formula I of 0.01 part, the poly terephthalic acid of 2.6 parts Glycol ester, the aluminum of 0.14 part, the glycerol of 0.1 part, the coloring agent of 0.42 part, wherein 0.11 part White, the redness of 0.31 part, the diamante of 2 parts, radium-shine powder and rhinestone mixture.
It is prepared as follows:
(1) by hydroxypropyl methyl cellulose and triethanolamine mixing and stirring, the first mixing is formed Body, standby;
(2) taking 30-35 part deionized water, embodiment is 33 parts, at keeping 60-80 DEG C, preferably 75 degree, polyurethane-35, acrylic acid/VP cross linked polymer, the compound of formula I of 0.01 part are added In deionized water, addition manner is, adds polyurethane-35, the crosslinking of acrylic acid/VP on a time period poly- Compound and compound of formula I, add interval 3-5 minute every time, and added in 15-20 minute Finish, be stirred continuously in adding procedure, make both the most uniformly mix, after having mixed, Improve temperature to 90-95 degree and to keep, preferably 95 degree, add polyethylene terephthalate Ester, after being uniformly mixed, naturally cools to 30-40 DEG C, preferably 35 degree, and at such a temperature Pressurization stands 1-2h, preferably 1.5h, and pressure is 1-2Mpa, preferably 1.8Mpa, thus forms the Two mixtures;
(3) remaining deionized water and laureth-21 are mixed at 40-50 DEG C, preferably 35 Degree, forms the 3rd mixture;
(4) the second mixture was uniformly added in 20-30 minute to the 3rd mixture, and all the time Keep the temperature at 70-90 degree, preferably 85 degree, in both mixed processes, be stirred continuously, After the second mixture is added completely into the 3rd mixture, continue stirring 1-2h, afterwards heat-insulation pressure keeping 2-4h, keeping temperature is 80-85 degree, and preferably 85 degree, pressure is 0.5-0.8Mpa, preferably 0.7Mpa;
(5) the first mixture is uniformly added in 1-2h in the mixture that step (4) obtains, Keeping temperature is 60-70 degree, preferably 65 degree, and continuously stirred makes mix homogeneously, when first is mixed Zoarium has added and after mix homogeneously, heat-insulation pressure keeping 2-4h, and temperature is 65-70 degree, and preferably 70 Degree, pressure is the preferred 0.7Mpa of 0.6-0.8Mpa;
(6) add after aluminum, coloring agent and diamante, radium-shine powder, artificial diamond powder's mixing and stirring Add in the mixture that step (5) obtains, be under 80-90 degree keeping temperature, preferably 85 degree, After stirring, natural cooling obtains nial polish finished product.
Artificial diamond powder is granular, and particle diameter is at 0.2-1mm.
The present embodiment is paillette pink colour shape, and in performance, detection obtains, and the present embodiment has good resistance to Aqueous and adhesive force, water absorption rate is less than 3.5%;For the detection of traditional performance, as follows: with general Logical coating method, as much as possible coating are uniformly;Being 32 DEG C in temperature, humidity is 50%, sea Water soaking is Sanya Yalongwan holiday resort sea water;All washings are general water-washing method, respectively mould Intend having a bath, go that hands is dirty, do housework, swimming etc., the suds of employing are general alkaline soap water, Detergent is regular powder, and this experiment uses carving board.
After being dried 30 minutes, under room temperature washing state, after 60 minutes, film is still without variable color, Without coming off;Under 40 degree of warm water washing states, after 60 minutes, film is still without variable color, without coming off; Under suds washing state, after 20 minutes, film is still without variable color, without coming off;Wash at detergent Under state, after 60 minutes, film is the most unchanged, without coming off;Under sea water immersion state, 80 points After clock, film is still without variable color, without coming off;Under accidental collision impact, film has and comes off.
Embodiment 2:
A kind of finger coloured silk being added with diamante, radium-shine powder, artificial diamond powder, its raw material is by weight Number meter, including: the deionized water of 52 parts, polyurethane-35 of 25 parts, the acrylic acid/VP of 17 parts Cross linked polymer, the hydroxypropyl methyl cellulose of 4.5 parts, the triethanolamine of 1.5 parts, 0.8 part Laureth-21, the compound of formula I of 0.02 part, the polyethylene terephthalate of 2.8 parts, The aluminum of 0.15 part, the glycerol of 0.15 part, the coloring agent of 0.5 part, depending on concrete color can be with demand, The diamante of 3 parts, radium-shine powder and rhinestone mixture.
Its preparation method is similar to embodiment 1, and in addition to color, its performance parameter is close to embodiment 1。
Embodiment 3:
A kind of finger coloured silk being added with diamante, radium-shine powder, artificial diamond powder, its raw material is by weight Number meter, including: the deionized water of 49 parts, polyurethane-35 of 23 parts, the acrylic acid/VP of 16 parts Cross linked polymer, the hydroxypropyl methyl cellulose of 4 parts, the triethanolamine of 0.9 part, the moon of 0.7 part Laureth-21, the compound of formula I of 0.03 part, the polyethylene terephthalate of 1.2 parts, The aluminum of 0.05 part, the glycerol of 0.09 part, the coloring agent of 0.4 part, depending on concrete color can be with demand, The diamante of 1 part, radium-shine powder and rhinestone mixture.
Its preparation method is similar to embodiment 1, and in addition to color, its performance parameter is close to embodiment 1。
Embodiment 4:
A kind of finger coloured silk being added with diamante, radium-shine powder, artificial diamond powder, its raw material is by weight Number meter, including: the deionized water of 49.81 parts, polyurethane-35 of 24.01 parts, the third of 16.81 parts Olefin(e) acid/VP cross linked polymer, the hydroxypropyl methyl cellulose of 4.32 parts, the triethanolamine of 1.02 parts, Laureth-21 of 0.78 part, the compound of formula I of 0.04 part, the poly terephthalic acid of 2.6 parts Glycol ester, the aluminum of 0.14 part, the glycerol of 0.1 part, the coloring agent of 0.42 part, wherein 0.11 part White, the redness of 0.31 part, the diamante of 2 parts, radium-shine powder and rhinestone mixture, 7 The functional monomer of part, functional monomer can be acrylamide.
Its preparation method, comprises the steps:
(1) by hydroxypropyl methyl cellulose and triethanolamine mixing and stirring, the first mixing is formed Body, standby;
(2) 30-35 part deionized water is taken, preferably 33 parts, at keeping 60-80 DEG C, preferably 70 Degree, goes polyurethane-35, acrylic acid/VP cross linked polymer, the compound of formula I addition of 0.04 part In ionized water, addition manner is, adds polyurethane-35, acrylic acid/VP cross-linked polymeric on a time period Thing and compound of formula I, add interval 3-5 minute every time, and added complete in 15-20 minute, Adding procedure is stirred continuously, makes both the most uniformly mix, after having mixed, carry High-temperature is to 90-95 degree and keeps, and preferably 95 degree, adds polyethylene terephthalate, After being uniformly mixed, it is cooled to 70-80 degree and keeps, preferably 75 degree, adding functional Monomer, continues stirring 10-20 minute, naturally cools to 30-40 DEG C, preferably 35 degree, and at this At a temperature of pressurization stand 1-2h, pressure is 1-2Mpa, preferably 1.8Mpa, thus formed second mix Fit;
(3) remaining deionized water and laureth-21 are mixed at 40-50 DEG C, preferably 45 Degree, forms the 3rd mixture;
(4) the second mixture was uniformly added in 20-30 minute to the 3rd mixture, and all the time Keep the temperature at 70-90 degree, preferably 85 degree, in both mixed processes, be stirred continuously, After the second mixture is added completely into the 3rd mixture, continue stirring 1-2h, afterwards heat-insulation pressure keeping 2-4h, keeping temperature is 80-85 degree, and preferably 85 degree, pressure is 0.5-0.8Mpa, preferably 0.7Mpa;
(5) the first mixture is uniformly added in 1-2h in the mixture that step (4) obtains, Keeping temperature is 60-70 degree, preferably 65 degree, and continuously stirred makes mix homogeneously, when first is mixed Zoarium has added and after mix homogeneously, heat-insulation pressure keeping 2-4h, and temperature is 65-70 degree, and preferably 70 Degree, pressure is 0.6-0.8Mpa, preferably 0.7Mpa;
(6) add after aluminum, coloring agent and diamante, radium-shine powder, artificial diamond powder's mixing and stirring Add in the mixture that step (5) obtains, be under 80-90 degree keeping temperature, preferably 85 degree, After stirring, natural cooling obtains nial polish finished product.
Artificial diamond powder is granular, and particle diameter is at 0.2-1mm.
The present embodiment is paillette pink colour shape, and in performance, detection obtains, and the present embodiment has good resistance to Aqueous and adhesive force, water absorption rate is less than 2.3%, and by the increase to functional monomer addition And minimizing, find when addition is 5-8 part, and resistance to water is preferable, the most outstanding when 7 parts;Right In the detection of traditional performance, as follows: with common coating method, coating is uniformly as much as possible;? Temperature is 32 DEG C, and humidity is 50%, and sea water immersion is Sanya Yalongwan holiday resort sea water;All Washing is general water-washing method, respectively simulation have a bath, go that hands is dirty, do housework, swimming etc., adopt Suds be general alkaline soap water, detergent is regular powder, this experiment use carving board.
After being dried 30 minutes, under room temperature washing state, after 60 minutes, film is still without variable color, Without coming off;Under 40 degree of warm water washing states, after 60 minutes, film is still without variable color, without coming off; Under suds washing state, after 20 minutes, film is still without variable color, without coming off;Wash at detergent Under state, after 60 minutes, film is the most unchanged, without coming off;Under sea water immersion state, 80 points After clock, film is still without variable color, without coming off;Under accidental collision impact, film has and comes off.
Embodiment 5:
A kind of finger coloured silk being added with diamante, radium-shine powder, artificial diamond powder, its raw material is by weight Number meter, including: the deionized water of 51.25 parts, polyurethane-35 of 23.87 parts, the third of 16.66 parts Olefin(e) acid/VP cross linked polymer, the hydroxypropyl methyl cellulose of 4.28 parts, the triethanolamine of 1.01 parts, Laureth-21 of 0.77 part, the compound of formula I of 0.05 part, the poly terephthalic acid of 1.51 parts Glycol ester, the aluminum of 0.08 part, the glycerol of 0.12 part, the coloring agent of 0.46 part, wherein 0.12 The redness of part, the black of 0.34 part, the diamante of 2 parts, radium-shine powder and rhinestone mixture.
Its preparation method is similar to embodiment 1, and its color is purple, and its performance parameter is close to reality Execute example 1.
Embodiment 6:
A kind of finger coloured silk being added with diamante, radium-shine powder, artificial diamond powder, its raw material is by weight Number meter, including: the deionized water of 49.78 parts, polyurethane-35 of 23.79 parts, the third of 16.61 parts Olefin(e) acid/VP cross linked polymer, the hydroxypropyl methyl cellulose of 4.26 parts, the triethanolamine of 1.01 parts, Laureth-21 of 0.77 part, the compound of formula I of 0.02 part, 2.81 parts of Muscovitums, 0.19 part sweet Oil, the coloring agent of 0.78 part, wherein 0.01 part of redness, 0.77 part of black, the diamante of 2 parts, Radium-shine powder and rhinestone mixture.
The preparation method of the present embodiment, comprises the steps:
(1) by hydroxypropyl methyl cellulose and triethanolamine mixing and stirring, the first mixing is formed Body, standby;
(2) 30-35 part deionized water is taken, preferably 33 parts, at keeping 60-80 DEG C, preferably 70 Degree, goes polyurethane-35, acrylic acid/VP cross linked polymer, the compound of formula I addition of 0.02 part In ionized water, addition manner is, adds polyurethane-35, acrylic acid/VP cross-linked polymeric on a time period Thing and compound of formula I, add interval 3-5 minute every time, and added complete in 15-20 minute, Adding procedure is stirred continuously, makes both the most uniformly mix, after having mixed, At 30-40 DEG C, preferably 35 degree, pressurization stands 1-2h, and pressure is 1-2Mpa, preferably 1.8Mpa, Thus form the second mixture;
(3) remaining deionized water and laureth-21 are mixed at 40-50 DEG C, preferably 45 Degree, forms the 3rd mixture;
(4) the second mixture was uniformly added in 20-30 minute to the 3rd mixture, and all the time Keep the temperature at 70-90 degree, preferably 85 degree, in both mixed processes, be stirred continuously, After the second mixture is added completely into the 3rd mixture, continue stirring 1-2h, afterwards heat-insulation pressure keeping 2-4h, keeping temperature is 80-85 degree, and preferably 85 degree, pressure is 0.5-0.8Mpa, preferably 0.7Mpa;
(5) the first mixture is uniformly added in 1-2h in the mixture that step (4) obtains, Keeping temperature is 60-70 degree, preferably 65 degree, and continuously stirred makes mix homogeneously, when first is mixed Zoarium has added and after mix homogeneously, heat-insulation pressure keeping 2-4h, and temperature is 65-70 degree, and preferably 70 Degree, pressure is 0.6-0.8Mpa, preferably 0.7Mpa;
(6) by after glycerol, coloring agent and diamante, radium-shine powder, artificial diamond powder's mixing and stirring Add in the mixture that step (5) obtains, be under 80-90 degree keeping temperature, preferably 85 Degree, after stirring, natural cooling obtains nial polish finished product.
Artificial diamond powder is granular, and particle diameter is at 0.2-1mm.
The present embodiment is that pearly-lustre is blue, and in performance, detection obtains, and the present embodiment has good water-fast Property and adhesive force, water absorption rate be less than 3.7%;For the detection of traditional performance, as follows: with commonly Coating method, coating is uniformly as much as possible;Being 32 DEG C in temperature, humidity is 50%, sea water Soak for Sanya Yalongwan holiday resort sea water;All washings are general water-washing method, simulate respectively Have a bath, go that hands is dirty, do housework, swimming etc., the suds of employing are general alkaline soap water, wash Clothing powder is regular powder, and this experiment uses carving board.
After being dried 30 minutes, under room temperature washing state, after 60 minutes, film is still without variable color, Without coming off;Under 40 degree of warm water washing states, after 60 minutes, film is still without variable color, without coming off; Under suds washing state, after 20 minutes, film is still without variable color, without coming off;Wash at detergent Under state, after 60 minutes, film is the most unchanged, without coming off;Under sea water immersion state, 80 points After clock, film is still without variable color, without coming off;Under accidental collision impact, film has and comes off.
Embodiment 7:
A kind of finger coloured silk being added with diamante, radium-shine powder, artificial diamond powder, its raw material is by weight Number meter, including: the deionized water of 52 parts, polyurethane-35 of 25 parts, the acrylic acid/VP of 17 parts Cross linked polymer, the hydroxypropyl methyl cellulose of 5 parts, the triethanolamine of 1.5 parts, the moon of 0.8 part Laureth-21, the compound of formula I of 0.03 part, 3 parts of Muscovitums, 2 parts of glycerol, the coloring of 0.8 part Agent, depending on concrete color can be with demand, the diamante of 3 parts, radium-shine powder and rhinestone mixture.
Its preparation method is similar to embodiment 6, and in addition to color, its performance parameter is close to embodiment 6。
Embodiment 8:
A kind of finger coloured silk being added with diamante, radium-shine powder, artificial diamond powder, its raw material is by weight Number meter, including: the deionized water of 48 parts, polyurethane-35 of 22 parts, the acrylic acid/VP of 16 parts Cross linked polymer, the hydroxypropyl methyl cellulose of 4 parts, the triethanolamine of 0.9 part, the moon of 0.7 part Laureth-21, the compound of formula I of 0.04 part, 0.9 part of Muscovitum, 0.08 part of glycerol, 0.3 part Coloring agent, depending on concrete color can be with demand, the diamante of 1 part, radium-shine powder and rhinestone are mixed Compound.
Its preparation method is similar to embodiment 6, and in addition to color, its performance parameter is close to embodiment 6。
Embodiment 9:
A kind of finger coloured silk being added with diamante, radium-shine powder, artificial diamond powder, its raw material is by weight Number meter, including: the deionized water of 49.78 parts, polyurethane-35 of 23.79 parts, the third of 16.61 parts Olefin(e) acid/VP cross linked polymer, the hydroxypropyl methyl cellulose of 4.26 parts, the triethanolamine of 1.01 parts, Laureth-21 of 0.77 part, the compound of formula I of 0.05 part, 2.81 parts of Muscovitums, 0.19 part sweet Oil, the coloring agent of 0.78 part, wherein 0.01 part of redness, 0.77 part of black, the diamante of 2 parts, Radium-shine powder and rhinestone mixture, the functional monomer of 6 parts, functional monomer can be propylene Amide.
Its preparation method, comprises the steps:
(1) by hydroxypropyl methyl cellulose and triethanolamine mixing and stirring, the first mixing is formed Body, standby;
(2) 30-35 part deionized water is taken, preferably 33 parts, at keeping 60-80 DEG C, preferably 70 Degree, goes polyurethane-35, acrylic acid/VP cross linked polymer, the compound of formula I addition of 0.05 part In ionized water, addition manner is, adds polyurethane-35, acrylic acid/VP cross-linked polymeric on a time period Thing and compound of formula I, add interval 3-5 minute every time, and added complete in 15-20 minute, Adding procedure is stirred continuously, makes both the most uniformly mix, after having mixed, protect Holding temperature is 70-80 degree, preferably 75 degree, adds functional monomer, continues stirring 10-20 Minute, at being cooled to 30-40 DEG C, preferably 35 degree, pressurization stands 1-2h, and pressure is 1-2Mpa, Preferably 1.8Mpa, thus form the second mixture;
(3) remaining deionized water and laureth-21 are mixed at 40-50 DEG C, preferably 45 Degree, forms the 3rd mixture;
(4) the second mixture was uniformly added in 20-30 minute to the 3rd mixture, and all the time Keep the temperature at 70-90 degree, preferably 85 degree, in both mixed processes, be stirred continuously, After the first mixture is added completely into the second mixture, continue stirring 1-2h, afterwards heat-insulation pressure keeping 2-4h, keeping temperature is 80-85 degree, and preferably 85 degree, pressure is 0.5-0.8Mpa, preferably 0.7Mpa;
(5) the first mixture is uniformly added in 1-2h in the mixture that step (4) obtains, Keeping temperature is 60-70 degree, preferably 65 degree, and continuously stirred makes mix homogeneously, when first is mixed Zoarium has added and after mix homogeneously, heat-insulation pressure keeping 2-4h, and temperature is 65-70 degree, and preferably 70 Degree, pressure is 0.6-0.8Mpa, preferably 0.7Mpa;
(6) by after glycerol, coloring agent and diamante, radium-shine powder, artificial diamond powder's mixing and stirring Add in the mixture that step (5) obtains, be under 80-90 degree keeping temperature, preferably 85 Degree, after stirring, natural cooling obtains nial polish finished product.
Artificial diamond powder is granular, and particle diameter is at 0.2-1mm.
The present embodiment is that pearly-lustre is blue, and in performance, detection obtains, and the present embodiment has good water-fast Property and adhesive force, water absorption rate be less than 2.2%, and research and development in the middle of find, when the weight of acrylamide When amount number is positioned at 5-8 part, resistance to water is preferable, and when being in 6 parts, effect reaches optimum, at this In embodiment, when acrylamide is less than 5 parts or is more than 8 parts, water absorption rate substantially gradually rises; For the detection of traditional performance, as follows: with common coating method, coating is uniformly as much as possible; Being 32 DEG C in temperature, humidity is 50%, and sea water immersion is Sanya Yalongwan holiday resort sea water;Institute Have washing to be general water-washing method, respectively simulation have a bath, go that hands is dirty, do housework, swimming etc., The suds used are general alkaline soap water, and detergent is regular powder, and this experiment uses carving Board.
After being dried 30 minutes, under room temperature washing state, after 60 minutes, film is still without variable color, Without coming off;Under 40 degree of warm water washing states, after 60 minutes, film is still without variable color, without coming off; Under suds washing state, after 20 minutes, film is still without variable color, without coming off;Wash at detergent Under state, after 60 minutes, film is the most unchanged, without coming off;Under sea water immersion state, 80 points After clock, film is still without variable color, without coming off;Under accidental collision impact, film has and comes off.
Embodiment 10:
A kind of finger coloured silk being added with diamante, radium-shine powder, artificial diamond powder, its raw material is by weight Number meter, including: the deionized water of 51.24 parts, polyurethane-35 of 24.99 parts, the third of 16.43 parts Olefin(e) acid/VP cross linked polymer, the hydroxypropyl methyl cellulose of 4.19 parts, the triethanolamine of 0.99 part, Laureth-21 of 0.75 part, the compound of formula I of 0.01 part, 0.99 part of Muscovitum, 0.09 part sweet Oil, the coloring agent of 0.33 part, coloring agent is white, the diamante of 1.8 parts, radium-shine powder and artificial Diamond mixture.
Its preparation method is similar to embodiment 6, and color is weak golden, and its performance parameter is close to reality Execute example 6.
Embodiment 11:
A kind of finger coloured silk being added with diamante, radium-shine powder, artificial diamond powder, its raw material is by weight Number meter, including: the deionized water of 51.04 parts, polyurethane-35 of 24.39 parts, the third of 16.03 parts Olefin(e) acid/VP cross linked polymer, the hydroxypropyl methyl cellulose of 4.09 parts, the triethanolamine of 0.99 part, Laureth-21 of 0.75 part, the compound of formula I of 0.02 part, 0.99 part of Muscovitum, 0.09 part sweet Oil, the coloring agent of 0.34 part, coloring agent is white, the diamante of 1.8 parts, radium-shine powder and artificial Diamond mixture, 0.7 part of functional monomer, functional monomer can be acrylamide.
Its preparation method is similar to embodiment 9, and color is weak golden, and its performance parameter is close to reality Execute example 9.
Embodiment 12: the preparation method of the triethanolamine involved by embodiment 1-11:
(1) oxirane, ammonia are sent in reactor, in reaction temperature 35-38 DEG C, preferably 37 Degree, under reaction pressure 100-300kPa, preferably 280kPa, carry out condensation reaction generate one, two, Triethanolamine mixed liquor;
(2) at 100-110 DEG C after dehydration concentrates, send into three vacuum rectification tower and carry out decompression steaming Evaporate, intercept fraction by different boiling, thus obtain triethanolamine semi-finished product;
(3) remove the removal of impurity with vapor distillation, and add sodium hydroxide and make triethanolamine become alkali metal Salt and separate out, neutralize after separation, then carry out decompression and distill to obtain triethanolamine sterling.
Embodiment 13: the preparation method of the hydroxypropyl methyl cellulose involved by embodiment 1-11 is:
(1), after purified cotton fibre element alkali liquor being soaked half an hour at 50-60 DEG C, preferably 55 degree, take Go out squeezing, cellulose is pulverized, and carries out the most aging at 40-50 DEG C;
(2) alkali fiber is put into etherification kettle, be sequentially added into expoxy propane and chloromethanes, at 55-70 DEG C Lower etherificate 6-7h, preferably 60 degree, holding pressure is 1.5-2Mpa, preferably 1.8Mpa;
(3) in the hot water of 70-80 DEG C, then add appropriate hydrochloric acid and oxalic acid washing material, make volume Expand, and with centrifuge dewatering, wash to neutral, when in material, water content is less than 60%, with The hot-air fluidized drying of more than 130 DEG C prepares to moisture content less than 5%.
Embodiment 14: the preparation method of rhinestone involved by embodiment 1-11:
(1) preparation of raw material: be calculated by weight as: the lead oxide of 40-50 part, the dioxy of 30-35 part SiClx, the sodium carbonate of 20-25 part, the calcium carbonate of 30-40 part, the hair of 20-30 part;
(2) crushing raw material in powdery and mix, carrying out refinery, temperature is 2200-2500 degree, excellent Select 2300 degree, cool down after 20-25h, form semi-finished product;
(3) semi-finished product being carried out the molding of high temperature high pressure process 10-25h, temperature is 2000-2200 degree, Pressure is 2500-3000 normal atmosphere, preferably 2800 normal atmospheres;
(4) broken, polishing, obtain finished product.
Obtained rhinestone, corner angle are the most intensive, and light emission direction is the most regular, anaclasis degree More colorful, agile and bright under height, and illumination.
Activity experiment:
1, compound of formula I activity experiment
Antibacterial (trichophyton, trichophyton gypseum and Epidermophvton trichophyton) is suspended in MH In culture medium, dispersion concentration is about 105Cfu mL-1, bacterium solution is added to (every hole on 96 orifice plates Add bacterium solution 100 μ L), with culture medium as blank, replace tested material as feminine gender using DMSO Comparison, with itraconazole (Xian-Janssen Pharmaceutical Ltd.) as positive control.By compound of formula I It is dissolved in DMSO and is made into 800,400,200,100,50,25 μ g mL respectively-1Solution is (right In MIC50Less than 5 μ g mL-1, when carrying out a step experiment, the Concentraton gradient of preparation is 50, 25,12.5,6.25,3.1,1.5 μ g mL-1), join 96 orifice plates with the amount of every hole 11 μ L It is upper that [ultimate density of medicinal liquid is respectively 80,40,20,10,5,2.5 μ g mL-1(for the latter It is 5,2.5,1.25,0.63,0.31 and 0.15 μ g mL-1)], each Concentraton gradient does four and puts down Row experiment.96 orifice plates are put into cultivation 24h in the incubator of 37 DEG C, and then every hole adds 25 μ L Every mL PBS containing 4mg MTT, then under similarity condition, cultivate 4h, every hole adds 100 μ LSDS Lysate (95mL tri-distilled water+10gSDS+5mL isopropanol+0.1mL concentrated hydrochloric acid) cultivates 12h afterwards. Measuring OD value under 570nm by microplate reader, percent inhibition is calculated as follows:
The height of activity is with semi-inhibit rate MIC50Represent, MIC50The least, the activity of compound The highest, result is: compound of formula I is to trichophyton, trichophyton gypseum and Epidermophvton hair Tinea bacterium semi-inhibit rate MIC50It is respectively 0.63,0.60 and 0.82;Itraconazole to trichophyton, Trichophyton gypseum and Epidermophvton trichophyton semi-inhibit rate MIC50It is respectively 0.63,0.70 and 0.65。
2, agent activity experiment:
Use preparation described in embodiment 1-6, the activity experiment being discussed below:
Cutting about 0.5mm from the corner of Cornu Bovis seu Bubali thick, the small pieces of 1.5 × 3cm size also use embodiment 1-6 preparation processes half side, once a day, continuous five days.Then this sheet is fixed on a tide Above aqueous agar surface in moist chamber on the metal column of about 0.5cm, the half side-view processed is down. The whole side of Cornu Bovis seu Bubali upward inoculates the microgonidium suspension of Trichophyton mentagrophytes in dots. Then, bacterium colony form is stored 10 days at 28 DEG C.
The pretreatment 5 times of preparation of embodiment of the present invention 1-6 is used completely at half back side of Cornu Bovis seu Bubali Fungal spore is prevented to germinate at whole end face.The most after 90 days, still can not be at microscope Under observe vaccination at whole apical view.Therefore, the embodiment 1-6 preparation containing compound of formula I Can the growth of effective pre-anti-fungal.
According to the method described above, carrying out control experiment, difference is in preparation described in embodiment 1-6 all Without compound of formula I, fungus has minority growing point on the Cornu Bovis seu Bubali side processed, but another half On observed the good growth of fungus.
Being provided without the blank of invention formulation process after inoculation, fungus is the most raw on Cornu Bovis seu Bubali surface Long.

Claims (10)

1. the finger coloured silk being added with diamante, radium-shine powder, artificial diamond powder, it is characterised in that Its raw materials by weight portion meter, including:
The deionized water of 48-52 part,
Polyurethane-35 of 22-25 part,
The acrylic acid of 16-17 part/VP cross linked polymer,
The hydroxypropyl methyl cellulose of 4-5 part,
The triethanolamine of 0.9-1.5 part,
Laureth-21 of 0.7-0.8 part,
The compound of formula I of 0.01-0.05 part,
0.9-3 part Muscovitum,
0.08-2 part glycerol,
The diamante of 1-3 part, radium-shine powder and rhinestone mixture;
Its compounds of formula I is shown below:
The most according to claim 1 it is added with diamante, radium-shine powder, artificial diamond powder Refer to coloured silk, it is characterised in that also include the coloring agent of 0.3-0.8 part.
The most according to claim 1 it is added with diamante, radium-shine powder, artificial diamond powder Refer to coloured silk, it is characterised in that also include the function monomer of 5-8 part.
The most according to claim 1 it is added with diamante, radium-shine powder, artificial diamond powder Refer to coloured silk, it is characterised in that including:
The deionized water of 49-52 part,
Polyurethane-35 of 23-25 part,
The acrylic acid of 16-17 part/VP cross linked polymer,
The hydroxypropyl methyl cellulose of 4-4.5 part,
The triethanolamine of 0.9-1.5 part,
Laureth-21 of 0.7-0.8 part,
The compound of formula I of 0.01~0.05 part,
The polyethylene terephthalate of 1.2-2.8 part,
The aluminum of 0.05-0.15 part,
0.09-0.15 part glycerol;
The diamante of 1-3 part, radium-shine powder and rhinestone mixture;
Its compounds of formula I is shown below:
The most according to claim 4 it is added with diamante, radium-shine powder, artificial diamond powder Refer to coloured silk, it is characterised in that also include the coloring agent of 0.4-0.5 part.
One the most according to claim 4 is added with diamante, radium-shine powder, rhinestone The finger of powder is color, it is characterised in that also include the function monomer of 5-8 part.
7. the finger coloured silk being added with diamante, radium-shine powder, artificial diamond powder described in claim 1 Preparation method, it is characterised in that comprise the steps:
(1) by hydroxypropyl methyl cellulose and triethanolamine mixing and stirring, the first mixing is formed Body, standby;
(2) 48-52 part deionized water is taken, at keeping 60-80 DEG C, by polyurethane-35, acrylic acid / VP cross linked polymer and 0.01-0.05 part compound of formula I add in deionized water, addition manner For, add polyurethane-35, acrylic acid/VP cross linked polymer and compound of formula I on a time period, often Secondary interpolation is spaced 3-5 minute, and adds complete in 15-20 minute, in adding procedure constantly Stirring, makes both the most uniformly mix, after having mixed, at 30-40 DEG C, and pressurization Standing 1-2h, pressure is 1-2Mpa, thus forms the second mixture;
(3) remaining deionized water and laureth-21 are mixed at 40-50 DEG C, form the Three mixtures;
(4) the second mixture was uniformly added in 20-30 minute to the 3rd mixture, and all the time Keep the temperature at 70-90 DEG C, in both mixed processes, be stirred continuously, when the second mixture After being added completely into the 3rd mixture, continue stirring 1-2h, afterwards heat-insulation pressure keeping 2-4h, keep temperature For 80-85 DEG C, pressure is 0.5-0.8Mpa;
(5) the first mixture is uniformly added in 1-2h in the mixture that step (4) obtains, Keep temperature to be 60-70 DEG C, and continuously stirred make mix homogeneously, when the first mixture has added also After mix homogeneously, heat-insulation pressure keeping 2-4h, temperature is 65-70 DEG C, and pressure is 0.6-0.8Mpa;
(6) by after glycerol, coloring agent and diamante, radium-shine powder, artificial diamond powder's mixing and stirring Add in the mixture that step (5) obtains, at keeping temperature to be 80-90 DEG C, stir Rear natural cooling obtains nial polish finished product;
Artificial diamond powder is granular, and particle diameter is at 0.2-1mm.
The most according to claim 3 it is added with diamante, radium-shine powder, artificial diamond powder Refer to color preparation method, it is characterised in that comprise the steps:
(1) by hydroxypropyl methyl cellulose and triethanolamine mixing and stirring, the first mixing is formed Body, standby;
(2) take 30-35 part deionized water, keeping at 60-80 DEG C, by the polyurethane-35 of 23-28 part, The acrylic acid of 15-20 part/VP cross linked polymer and 0.01-0.05 part compound of formula I add deionization In water, addition manner is, add on a time period polyurethane-35, acrylic acid/VP cross linked polymer and Compound of formula I, adds interval 3-5 minute every time, and added complete in 15-20 minute, Adding procedure is stirred continuously, makes both the most uniformly mix, after having mixed, keep Temperature is 70-80 DEG C, adds functional monomer, continues stirring 10-20 minute, is cooled to At 30-40 DEG C, pressurization stands 1-2h, and pressure is 1-2Mpa, thus forms the second mixture;
(3) remaining deionized water and laureth-21 are mixed at 40-50 DEG C, form the Three mixtures;
(4) the second mixture was uniformly added in 20-30 minute to the 3rd mixture, and all the time Keep the temperature at 70-90 DEG C, in both mixed processes, be stirred continuously, when the first mixture After being added completely into the second mixture, continue stirring 1-2h, afterwards heat-insulation pressure keeping 2-4h, keep temperature For 80-85 DEG C, pressure is 0.5-0.8Mpa;
(5) the first mixture is uniformly added in 1-2h in the mixture that step (4) obtains, Keep temperature to be 60-70 DEG C, and continuously stirred make mix homogeneously, when the first mixture has added also After mix homogeneously, heat-insulation pressure keeping 2-4h, temperature is 65-70 DEG C, and pressure is 0.6-0.8Mpa;
(6) by after glycerol, coloring agent and diamante, radium-shine powder, artificial diamond powder's mixing and stirring Add in the mixture that step (5) obtains, at keeping temperature to be 80-90 DEG C, stir Rear natural cooling obtains nial polish finished product;
Artificial diamond powder is granular, and particle diameter is at 0.2-1mm.
9. the finger coloured silk being added with diamante, radium-shine powder, artificial diamond powder described in claim 5 Preparation method, it is characterised in that comprise the steps:
(1) by hydroxypropyl methyl cellulose and triethanolamine mixing and stirring, the first mixing is formed Body, standby;
(2) 30-35 part deionized water is taken, at keeping 60-80 DEG C, by polyurethane-35, acrylic acid / VP cross linked polymer and 0.01-0.05 part compound of formula I add in deionized water, and addition manner is, Add polyurethane-35, acrylic acid/VP cross linked polymer and compound of formula I on a time period, add every time Add interval 3-5 minute, and added complete in 15-20 minute, be stirred continuously in adding procedure, Make both the most uniformly mix, after having mixed, improve temperature and to 90-95 degree and keep, Add polyethylene terephthalate, after being uniformly mixed, naturally cool to 30-40 DEG C, And pressurization stands 1-2h at such a temperature, pressure is 1-2Mpa, thus forms the second mixture; (3) remaining deionized water and laureth-21 are mixed at 40-50 DEG C, form the 3rd and mix Fit;
(4) the second mixture was uniformly added in 20-30 minute to the 3rd mixture, and all the time Keep the temperature at 70-90 degree, in both mixed processes, be stirred continuously, when the second mixture After being added completely into the 3rd mixture, continue stirring 1-2h, afterwards heat-insulation pressure keeping 2-4h, keep temperature For 80-85 degree, pressure is 0.5-0.8Mpa;
(5) the first mixture is uniformly added in 1-2h in the mixture that step (4) obtains, Keeping temperature is 60-70 degree, and continuously stirred makes mix homogeneously, when the first mixture has added also After mix homogeneously, heat-insulation pressure keeping 2-4h, temperature is 65-70 degree, and pressure is 0.6-0.8Mpa;
(6) add after aluminum, coloring agent and diamante, radium-shine powder, artificial diamond powder's mixing and stirring Add in the mixture that step (5) obtains, be under 80-90 degree keeping temperature, after stirring Natural cooling obtains nial polish finished product;
Artificial diamond powder is granular, and particle diameter is at 0.2-1mm.
10. a kind of described in claim 6 is added with diamante, radium-shine powder, artificial diamond powder Refer to color preparation method, it is characterised in that comprise the steps:
(1) by hydroxypropyl methyl cellulose and triethanolamine mixing and stirring, the first mixing is formed Body, standby;
(2) 30-35 part deionized water is taken, at keeping 60-80 DEG C, by polyurethane-35, acrylic acid / VP cross linked polymer and 0.01-0.05 part compound of formula I add in deionized water, and addition manner is, Add polyurethane-35, acrylic acid/VP cross linked polymer and compound of formula I on a time period, add every time Add interval 3-5 minute, and added complete in 15-20 minute, be stirred continuously in adding procedure, Make both the most uniformly mix, after having mixed, improve temperature and to 90-95 degree and keep, Add polyethylene terephthalate, after being uniformly mixed, be cooled to 70-80 degree and protect Hold, add functional monomer, continue stirring 10-20 minute, naturally cool to 30-40 DEG C, And pressurization stands 1-2h at such a temperature, pressure is 1-2Mpa, thus forms the second mixture;
(3) remaining deionized water and laureth-21 are mixed at 40-50 DEG C, form the Three mixtures;
(4) the second mixture was uniformly added in 20-30 minute to the 3rd mixture, and all the time Keep the temperature at 70-90 degree, in both mixed processes, be stirred continuously, when the second mixture After being added completely into the 3rd mixture, continue stirring 1-2h, afterwards heat-insulation pressure keeping 2-4h, keep temperature For 80-85 degree, pressure is 0.5-0.8Mpa;
(5) the first mixture is uniformly added in 1-2h in the mixture that step (4) obtains, Keeping temperature is 60-70 degree, and continuously stirred makes mix homogeneously, when the first mixture has added also After mix homogeneously, heat-insulation pressure keeping 2-4h, temperature is 65-70 degree, and pressure is 0.6-0.8Mpa;
(6) add after aluminum, coloring agent and diamante, radium-shine powder, artificial diamond powder's mixing and stirring Add in the mixture that step (5) obtains, be under 80-90 degree keeping temperature, after stirring Natural cooling obtains nial polish finished product;
Artificial diamond powder is granular, and particle diameter is at 0.2-1mm.
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