CN105802486A - Normal-temperature-curable high-temperature-resistant, corrosion-resistant and heat-insulating material for petrochemical pipelines as well as preparation method and applications of material - Google Patents
Normal-temperature-curable high-temperature-resistant, corrosion-resistant and heat-insulating material for petrochemical pipelines as well as preparation method and applications of material Download PDFInfo
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Abstract
The invention discloses a normal-temperature-curable high-temperature-resistant, corrosion-resistant and heat-insulating material for petrochemical pipelines as well as a preparation method and applications of the material. According to the method, normal-temperature film-forming resin, air heat-insulating filler, secondary film-forming powder, a high-temperature-resistant pigment, an inorganic anti-settling agent, an organic silicone reinforcing agent and dimethylbenzene are mixed, and a component I is obtained; a curing agent and an accelerant are mixed, and a component II is obtained; the component I and the component II in the weight ratio being 100:3-100:7 are mixed at the normal temperature, and the material is obtained. The material is curable at the normal temperature, has excellent adhesion, corrosion resistance and heat insulation performance, can resist the high temperature of 500 DEG C or above and is a multifunctional composite material combining traditional corrosion-resistant, heat-insulating and protecting layers, construction procedures are simplified, the construction cost is greatly reduced, and the material is suitable for large-area construction and can be applied to corrosion-resistant and heat-insulating engineering of large high-temperature chemical equipment such as petroleum cracking equipment, high-temperature steam pipelines, high-temperature reaction equipment, pipelines and the like.
Description
Technical field
The present invention relates to high-temperature resistant anti-corrosive field of heat insulating materials, be specifically related to a kind of pipelines and petrochemical pipelines normal temperature solidified high-temperature resistant anti-corrosive insulation material and preparation method thereof and application.
Background technology
At present in the oil refining industry of China, the safeguard procedures of equipment and pipeline are made up of typical " anticorrosive coat+heat insulation layer+overcoat ".Anticorrosive coat is general anti-corrosion primer;Heat insulation layer is traditional rock wool fibers or aluminium silicate volume felt etc., and this material water absorption rate is high, and many genotypes material, seam are many, generally have 10-20cm thick;Overcoat is diameter is galvanized iron sheet or the aluminum skin of 1-2m.Actual petrochemical equipment and pipeline often ratio comparatively dense, traditional syllogic safeguard procedures not only bring very big inconvenience to construction;And this heat insulation system is not easily coated with at the elbow of pipeline, interface, valve place so that it is exposed in atmosphere, be more subject to corrosion, heavy damage heat insulation effect.Corrosion not only causes huge economic loss, bring many hidden danger to safety in production simultaneously, especially petroleum cracking equipment, high-temperature reaction equipment and pipeline have the feature of the corrosive medium of high temperature, high pressure and complexity, and equipment corrosion Resolving probiems is bad will have a strong impact on normal production;Relevant information shows simultaneously, and the energy lost because of heat dissipation of pipeline every year accounts for 30% that petrochemical industry always consumes energy, and the corrosion-resistant thermal insulation work therefore carrying out pipelines and petrochemical pipelines especially high-temperature service and pipeline is most important.
Film formation resin is with Si-O-Si main chain for basic cell structure, and side chain is by Si atom and other various organic groups, as the polycondensation such as methyl, phenyl forms.This special structure, gives the performance of the many excellences of film formation resin, for instance good cementability, excellent solvent resistance and anti-corrosive properties, lasting weatherability, splendid heat-resisting quantity and normal temperature solidified property.Why high temperature resistant this material is, and the bond energy being because film formation resin backbone Si-O-Si is significantly larger than the bond energy of side base C-C key and C-O key, continuous rising along with temperature, side-chain radical in film formation resin such as methyl, phenyl are decomposed gradually, volatilization, when temperature is more than 400 DEG C, two-step film forming powder melts gradually and interacts with the Si-O-Si main chain of film formation resin, film forming again, form new high temperature resistant disilicide layer, i.e. high temperature " two-step film forming " mechanism.Therefore in film formation cold coating, add two-step film forming powder can apply to petrochemical equipment and the pipeline of 500 DEG C of high temperature above.
Air heat insulation filler microballon macroscopically white powder, belongs to soda lime borosilicate glass material.Being the nature of glass spheroid of many thin-walleds, closing, hollow on microcosmic, ball interior wraps up a certain amount of gas, and spheroid size differs.Due to its inner hollow, parcel gas, therefore there is light weight, the feature such as heat conductivity is low, anti-pressure ability is strong, excellent in stability;Spheroid size can not form mutually supplementing on particle diameter first so that cenosphere application has the feature rationally plugged the gap in the composite;Heat conductivity is low makes this applying filler in composite, it is possible to give the heat-insulating property that material is excellent.In sum, air heat insulation filler joins the heat-insulating property that can be greatly increased this material in film formation resin.
Summary of the invention
The present invention be directed to petrochemical equipment and pipeline, especially the shortcoming and defect of the existing traditional safeguard procedures of petroleum cracking equipment, high-temperature reaction equipment and pipeline, it is provided that a kind of pipelines and petrochemical pipelines normal temperature solidified high-temperature resistant anti-corrosive insulation material and preparation method thereof and application.The present invention is by film formation resin and has the two-step film forming powder of high temperature " two-step film forming " mechanism and effectively combines, by adding air heat insulation filler, it is achieved high temperature resistant, anticorrosion, heat insulation integrated.This material can realize normal temperature cure, has high temperature " two-step film forming " characteristic, it is possible to resistance to 500 DEG C of high temperature above;This material has relatively low heat conductivity, excellent thermal insulation performance;This material and ground have cementability and the anticorrosive property of excellence.
Traditional " anticorrosive coat+heat insulation layer+overcoat " is merged into a kind of multifunctional composite by another object of the present invention, had both simplified operational procedure, and had been substantially reduced construction cost;There is again the function of three kinds of materials simultaneously, and various performance optimizes further.
The purpose of the present invention is achieved through the following technical solutions.
A kind of pipelines and petrochemical pipelines is with normal temperature solidified high-temperature resistant anti-corrosive insulation material, and this material is made up of first component and second component, and described first component is made up of the component of following parts by weight meter:
Described second component is made up of the component of following parts by weight meter:
Firming agent 5~97;
Accelerator 3~95.
Wherein, the weight ratio of first, second component is 100:3~100:70.
Described film formation resin is one or more the mixture in neat silicone KR-213 (organosilicon company of SHIN-ETSU HANTOTAI), epoxy modified silicone resin YN-W304 and acryl-modified silicone resin resin YN-W301 (Changzhou Yuan En synthetic material company limited).
Described air heat insulation filler is one or more mixture in hollow ceramic microspheres, hollow glass micropearl, expanded perlite and silica aerogel.Described hollow ceramic microspheres is one or more the mixture in HCB-1 and HCB-2 (Ge Run Asia, Shanghai nano material company limited);Described hollow glass micropearl is one or more the mixture in HGB-1 and HGB-2 (Minnesota Mining and Manufacturing Company);Described expanded perlite is EPL (Ao Jie foreign trade company limited of Zhengzhou City);Described silica aerogel is one or more the mixture in CPA-100 and CPA-200 (Zhong Shankebang chemical materials company limited).
Described two-step film forming powder is one or more the mixture in watery fusion glass dust D240, D245 and D250 (Ou Ke Chuan De powder body company limited).
Described high-temperature resisting pigment is one or more the mixture in high temperature resistant Chinese white, high temperature resistant black pigment and high temperature resistant yellow uitramarine.Wherein said high temperature resistant Chinese white is one or more the mixture in titanium white, zinc oxide and Griffith's zinc white.;Described high temperature resistant yellow uitramarine is one or more the mixture in strontium yellow and chrome yellow;Described high temperature resistant black pigment be manganese dioxide and ferrochrome black in one or more mixture.
Described inorganic anti-settling agent is one or more the mixture in aerosil R106, R202, R972 and R812 (Germany's goldschmidt chemical corporation).
Described organosilicon reinforcing agent is one or more the mixture in KH550, KH560 and KH602 (Chemical Industry in Guangzhou reagent company limited).
Described firming agent is one or more the mixture in amine curing agent and modified amine curing agent.Amine curing agent is diethylenetriamine, N, one or more the mixture in N dimethylamine base propylamine, m-diaminobenzene. and MDA;Modified amine curing agent is 593#、591#, phenolic aldehyde amine curing agent 810#、910#, polyamide-based firming agent 650#Or 651#In one or more mixture.
Described accelerator is one or more the mixture in three-2-ethylhexoate of triethanolamine, dimethylaniline, 2,4,6-tri-(dimethylaminomethyl) phenol and 2,4,6-tri-(dimethylaminomethyl) phenol.
Above-described a kind of pipelines and petrochemical pipelines preparation method of normal temperature solidified high-temperature resistant anti-corrosive insulation material, comprises the following steps:
By the film formation resin of 10~90 weight portions, the air heat insulation filler of 3~50 weight portions, the two-step film forming powder of 5~75 weight portions, the high-temperature resisting pigment of 0~10 weight portion, the inorganic anti-settling agent of 0~5 weight portion, the organosilicon reinforcing agent of 0~6 weight portion, the dimethylbenzene mix and blend of 0~15 weight portion obtains first component;By the firming agent of 5~97 weight portions, the accelerator mix and blend of 3~95 weight portions obtains second component;It is that 100:3~100:70 room temperature mixing and stirring obtains the normal temperature solidified high-temperature resistant anti-corrosive insulation material of a kind of pipelines and petrochemical pipelines by first, second component according to weight ratio.
Above-described a kind of pipelines and petrochemical pipelines is applied in the corrosion-resistant thermal insulation engineering of the large high-temperature chemical industry equipments such as petroleum cracking equipment, high temperature steam pipeline, high-temperature reaction equipment and pipeline with normal temperature solidified high-temperature resistant anti-corrosive insulation material.
The present invention possesses following outstanding advantages and effect relative to prior art:
1) present invention is with film formation resin for base material, adds firming agent and accelerator, and double-component system realizes normal temperature cure, improves the cementability of material and base material, has antiseptic property and the mechanical property of excellence, and the strength of materials is high, excellent in te pins of durability;High-temperature-resistant thermal-insulation material of the present invention adds two-step film forming powder, when temperature is more than 400 DEG C, melted and with film formation resin the Si-O-Si main chain of two-step film forming powder interacts, film forming again, namely there is high temperature " two-step film forming " mechanism, improve the heat-resisting quantity of this material, expand the application of this material;
2) high-temperature-resistant thermal-insulation materials'use air heat insulation filler of the present invention replaces traditional rock wool fibers or aluminium silicate felt, has the advantages that heat conductivity is low, heat insulating ability is excellent;Overcome that traditional insulation material seam is many, construction trouble, water absorption rate are high, not anti-vibration, service life short, also need the shortcoming and defect such as water layer or outer jacket of setting up defences;
3) traditional " anticorrosive coat+heat insulation layer+overcoat " is merged into a kind of multifunctional composite by the present invention, simplify operational procedure, greatly reducing construction cost, the present invention not only has the function of three kinds of materials simultaneously, and various performances is optimized further.
4) the high-temperature resistant anti-corrosive insulation material of the present invention belongs to double-component system, normal temperature cure, provides for large-area construction and is likely to;Solid content is high, decreases the pollution to environment.Can be applicable in the corrosion-resistant thermal insulation engineering of the large high-temperature chemical industry equipments such as petroleum cracking equipment, high temperature steam pipeline, high-temperature reaction equipment and pipeline.
Detailed description of the invention
Below in conjunction with embodiment, the present invention done further detailed description, but embodiments of the present invention are not limited to this.
Embodiment 1
By 5 weight portion neat silicone KR-213 (organosilicon company of SHIN-ETSU HANTOTAI), 5 parts by weight of acrylic acid modified organic silicone resin YN-W301 (Changzhou Yuan En synthetic material company limited), 50 weight portion hollow ceramic microspheres HCB-1,5 weight portion watery fusion glass dust D240,7 part by weight of zinc oxide, 3 weight portion manganese dioxide, 5 weight portion aerosil R106,5 weight portion KH550,15 parts by weight of xylene mixing and stirring obtain first component;By 80.5 weight portion amine curing agent diethylenetriamines, 19.5 weight portion accelerator triethanolamine mixing and stirring obtain second component.During use, the first and second components (100g first component, 30g second component) are obtained high-temperature resistant anti-corrosive insulation material by the part by weight mixing and stirring of 100:30.
Embodiment 2
By 90 parts by weight of acrylic acid modified organic silicone resin YN-W301 (Changzhou Yuan En synthetic material company limited), 3 weight portion expanded perlite EPL (Ao Jie foreign trade company limited of Zhengzhou City), 5 weight portion watery fusion glass dust D245,0.2 weight portion titanium white, 0.1 weight portion manganese dioxide, 0.4 weight portion aerosil R202,0.3 weight portion KH560,1 parts by weight of xylene mixing and stirring obtains first component;By 97 weight portion amine curing agent N, N dimethylamine base propylamine, 3 weight portion accelerator dimethylaniline mixing and stirring obtain second component.During use, the first and second components (100g first component, 21g second component) are obtained high-temperature resistant anti-corrosive insulation material by the part by weight mixing and stirring of 100:21.
Embodiment 3
By 48 parts by weight epoxy modified organic silicone resin YN-W304,13.5 weight portion hollow glass micropearl HGB-1,23 weight portion watery fusion glass dust D250 (Ou Ke Chuan De powder body company limited), 2.2 weight portion Griffith's zinc white .s, 1.3 weight portion manganese dioxide, 1 weight portion aerosil R972,2 weight portion KH602 (Chemical Industry in Guangzhou reagent company limited), 9 parts by weight of xylene mixing and stirring obtain first component;By 90 part by weight modified amine curing agents 593#, 4 part by weight modified amine curing agents 591#, 6 weight portion accelerator 2,4,6-tri-(dimethylaminomethyl) phenol mixing and stirring obtain second component.During use, the first and second components (100g first component, 43g second component) are obtained high-temperature resistant anti-corrosive insulation material by the part by weight mixing and stirring of 100:43.
Embodiment 4
By 20 weight neat silicone KR-213 (organosilicon company of SHIN-ETSU HANTOTAI), 13 parts by weight of acrylic acid modified organic silicone resin YN-W301 (Changzhou Yuan En synthetic material company limited), 32.5 weight portion hollow ceramic microspheres HCB-2 (Ge Run Asia, Shanghai nano material company limited), 11.5 weight portion watery fusion glass dust D240, 5 weight portion watery fusion glass dust D245, 4.3 part by weight of zinc oxide, 2.7 weight portion ferrochrome are black, 2.2 weight portion aerosil R812 (Germany's goldschmidt chemical corporation), 2.8 weight portion KH550, 15 parts by weight of xylene mixing and stirring obtain first component;By 80.2 parts by weight of phenolic amine curing agents 910#, 10 parts by weight of phenolic amine curing agents 810#, three-2-ethylhexoate mixing and stirring of 9.8 weight portion accelerator 2,4,6-tri-(dimethylaminomethyl) phenol obtains second component.During use, the first and second components (100g first component, 3g second component) are obtained high-temperature resistant anti-corrosive insulation material by the part by weight mixing and stirring of 100:3.
Embodiment 5
By 30 weight portion neat silicone KR-213 (organosilicon company of SHIN-ETSU HANTOTAI), 8 parts by weight epoxy modified organic silicone resin YN-W304,20 weight portions hollow glass micropearl HGB-2 (Minnesota Mining and Manufacturing Company), 10 weight portion watery fusion glass dust D240,10 weight portion watery fusion glass dust D250 (Ou Ke Chuan De powder body company limited), 4 weight portion chrome yellow, 3 weight portion aerosil R812 (Germany's goldschmidt chemical corporation), 3 weight portion KH560,12 parts by weight of xylene mixing and stirring obtain first component;By 92 weight portion amine curing agent m-diaminobenzene .s, 8 weight portion accelerator triethanolamine mixing and stirring obtain second component.During use, the part by weight mixing and stirring of the first and second components (100g first component, 70g second component) 100:70 by weight is obtained high-temperature resistant anti-corrosive insulation material.
Embodiment 6
By 23 parts by weight epoxy modified organic silicone resin YN-W304, 7 parts by weight of acrylic acid modified organic silicone resin YN-W301 (Changzhou Yuan En synthetic material company limited), 10 weight portion hollow glass micropearl HGB-1, 14 weight portion silica aerogel CPA-100 (Zhong Shankebang chemical materials company limited), 13 weight portion watery fusion glass dust D245, 15 weight portion watery fusion glass dust D250 (Ou Ke Chuan De powder body company limited), 4 weight portion strontium yellows, 1.7 weight portion aerosil R202, 6 weight portion KH602 (Chemical Industry in Guangzhou reagent company limited), 7.3 parts by weight of xylene mixing and stirring obtain first component;By 88.5 weight portion amine curing agent MDAs, 11.5 weight portion accelerator dimethylaniline mixing and stirring obtain second component.During use, the ratio mixing and stirring of the first and second components (100g first component, 55g second component) 100:55 by weight is obtained high-temperature resistant anti-corrosive insulation material.
Embodiment 7
By 4 weight portion neat silicone KR-213 (organosilicon company of SHIN-ETSU HANTOTAI), 6 parts by weight epoxy modified organic silicone resin YN-W304,2 weight portions hollow glass micropearl HGB-2 (Minnesota Mining and Manufacturing Company), 3 weight portion expanded perlite EPL (Ao Jie foreign trade company limited of Zhengzhou City), 75 weight portion watery fusion glass dust D240,2 weight portion titanium whites, 0.6 weight portion ferrochrome is black, 0.9 weight portion aerosil R106,0.5 weight portion KH550,6 parts by weight of xylene mixing and stirring obtain first component;By 97 weight portion amine curing agents 650#, 3 weight portion accelerator 2,4,6-tri-(dimethylaminomethyl) phenol mixing and stirring obtain second component.During use, the ratio mixing and stirring of the first and second components (100g first component, 68g second component) 100:68 by weight is obtained high-temperature resistant anti-corrosive insulation material.
Embodiment 8
By 20 parts by weight epoxy modified organic silicone resin YN-W304,22.5 weight portion hollow glass micropearl HGB-2,22.5 weight portion silica aerogel CPA-200 (Zhong Shankebang chemical materials company limited), 15 weight portion watery fusion glass dust D245,0.9 weight portion Griffith's zinc white., 0.6 weight portion ferrochrome is black, 3.2 weight portion aerosil R972,2.3 weight portion organosilicon reinforcing agent KH560,13 parts by weight of xylene mixing and stirring obtain first component;By 5 weight portion amine curing agents 651#, three-2-ethylhexoate mixing and stirring of 95 weight portion accelerator 2,4,6-tri-(dimethylaminomethyl) phenol obtains second component.During use, the first and second components (100g first component, 18g second component) are obtained high-temperature resistant anti-corrosive insulation material by the part by weight mixing and stirring of 100:18.
Table 1 is the mechanical property parameters table of the example 1-8 high-temperature resistant anti-corrosive insulation material prepared.
Table 1
A test condition: 7 days b test conditions of 23 DEG C of maintenances: after 23 DEG C of maintenances 7 days, 500 DEG C of calcinations 3 hours
By the analysis of these sample results:
1) the invention provides one high-temperature resistant anti-corrosive insulation material with high temperature " two-step film forming " mechanism and preparation method thereof, this high-temperature resistant anti-corrosive insulation material is normal temperature solidified, high temperature resistant for a long time, is suitable for large-area construction.
2) normal temperature solidified high-temperature resistant anti-corrosive insulation material provided by the invention, uses air heat insulation filler to replace traditional rock wool fibers or aluminium silicate felt, has the advantages that heat conductivity is low, heat insulating ability is excellent;Overcome that tradition section bar insulation material seam is many, construction trouble, water absorption rate are high, not anti-vibration, service life short, also need the shortcoming and defect such as water layer or outer jacket of setting up defences.
3) normal temperature solidified high-temperature resistant anti-corrosive insulation material provided by the invention has the mechanical property of excellence, antiseptic property and heat-insulating property, and the strength of materials is high, excellent in te pins of durability.
Above-mentioned enforcement example is normal temperature solidified high-temperature resistant anti-corrosive insulation material provided by the invention and preparation method thereof and its more excellent embodiment applied in the corrosion-resistant thermal insulation engineering of large high-temperature chemical industry equipment; but embodiments of the present invention are not limited by above-mentioned enforcement example; the change made under other any spirit without departing from the present invention and principle, modification, replacement, combination, simplification; all should equivalence substitute mode, be included within protection scope of the present invention.
Claims (10)
1. a pipelines and petrochemical pipelines is with normal temperature solidified high-temperature resistant anti-corrosive insulation material, it is characterised in that this material is made up of first component and second component, and described first component is made up of the component of following parts by weight meter:
Film formation resin 10 ~ 90;
Air heat insulation filler 3 ~ 50;
Two-step film forming powder 5 ~ 75;
High-temperature resisting pigment 0 ~ 10;
Inorganic anti-settling agent 0 ~ 5;
Organosilicon reinforcing agent 0 ~ 6;
Dimethylbenzene 0 ~ 15;
Described second component is made up of the component of following parts by weight meter:
Firming agent 5 ~ 97;
Accelerator 3 ~ 95;
Wherein, the weight ratio of first, second component is 100:3 ~ 100:70.
2. a kind of pipelines and petrochemical pipelines according to claim 1 is with normal temperature solidified high-temperature resistant anti-corrosive insulation material, it is characterized in that, described film formation resin is one or more the mixture in epoxy modified silicone resin YN-W304, the neat silicone KR-213 of organosilicon company of SHIN-ETSU HANTOTAI and the acryl-modified silicone resin resin YN-W301 of Changzhou Yuan En synthetic material company limited.
3. a kind of pipelines and petrochemical pipelines according to claim 1 is with normal temperature solidified high-temperature resistant anti-corrosive insulation material, it is characterized in that, described air heat insulation filler is one or more the mixture in hollow ceramic microspheres, hollow glass micropearl, expanded perlite and silica aerogel;Described hollow ceramic microspheres is one or more the mixture in the HCB-2 of HCB-1 and Ge Run Asia, Shanghai nano material company limited;Described hollow glass micropearl is one or more the mixture in the HGB-2 of HGB-1, Minnesota Mining and Manufacturing Company;Described expanded perlite is the EPL of Ao Jie foreign trade company limited of Zhengzhou City;Described silica aerogel is one or more the mixture in CPA-100 and the CPA-200 of Zhong Shankebang chemical materials company limited.
4. a kind of pipelines and petrochemical pipelines according to claim 1 is with normal temperature solidified high-temperature resistant anti-corrosive insulation material, it is characterized in that, described two-step film forming powder is one or more the mixture in the watery fusion glass dust D250 of watery fusion glass dust D240, D245 and Ou Ke Chuan De powder body company limited.
5. a kind of pipelines and petrochemical pipelines according to claim 1 is with normal temperature solidified high-temperature resistant anti-corrosive insulation material, it is characterized in that, described high-temperature resisting pigment is one or more the mixture in high temperature resistant Chinese white, high temperature resistant black pigment and high temperature resistant yellow uitramarine;Wherein, described high temperature resistant Chinese white is one or more the mixture in titanium white, zinc oxide and Griffith's zinc white.;Described high temperature resistant yellow uitramarine is one or more the mixture in strontium yellow and chrome yellow;Described high temperature resistant black pigment be manganese dioxide and ferrochrome black in one or more mixture.
6. a kind of pipelines and petrochemical pipelines according to claim 1 is with normal temperature solidified high-temperature resistant anti-corrosive insulation material, it is characterized in that, described inorganic anti-settling agent is one or more the mixture in the aerosil R812 of aerosil R106, R202, R972 and Germany's goldschmidt chemical corporation;Described organosilicon reinforcing agent is one or more the mixture in the KH602 of KH550, KH560 and Chemical Industry in Guangzhou reagent company limited.
7. a kind of pipelines and petrochemical pipelines according to claim 1 is with normal temperature solidified high-temperature resistant anti-corrosive insulation material, it is characterised in that described firming agent is one or more the mixture in amine curing agent and modified amine curing agent;Described amine curing agent is diethylenetriamine, N, one or more the mixture in N dimethylamine base propylamine, m-diaminobenzene. and MDA;Described modified amine curing agent is 593#、591#, phenolic aldehyde amine curing agent 810#, phenolic aldehyde amine curing agent 910#, Versamid class firming agent 650#With Versamid class firming agent 651#In one or more mixture.
8. a kind of pipelines and petrochemical pipelines according to claim 1 is with normal temperature solidified high-temperature resistant anti-corrosive insulation material, it is characterized in that, described accelerator be triethanolamine, dimethylaniline, 2,4,6-tri-(dimethylaminomethyl) phenol and 2, one or more mixture in the three-2-ethylhexoate of 4,6-tri-(dimethylaminomethyl) phenol.
9. the preparation a kind of pipelines and petrochemical pipelines method of normal temperature solidified high-temperature resistant anti-corrosive insulation material described in claim 1, it is characterised in that comprise the following steps:
First by the film formation resin of 10 ~ 90 weight portions, the air heat insulation filler of 3 ~ 50 weight portions, the two-step film forming powder of 5 ~ 75 weight portions, the high-temperature resisting pigment of 0 ~ 10 weight portion, the inorganic anti-settling agent of 0 ~ 5 weight portion, the organosilicon reinforcing agent of 0 ~ 6 weight portion, the dimethylbenzene mixing and stirring of 0 ~ 15 weight portion, obtain first component;Again by the firming agent of 5 ~ 97 weight portions, the accelerator mixing and stirring of 3 ~ 95 weight portions, obtain second component;It is finally 100:3 ~ 100:70 room temperature mixing and stirring by first, second component according to weight ratio, obtains the normal temperature solidified high-temperature resistant anti-corrosive insulation material of a kind of pipelines and petrochemical pipelines.
10. a kind of pipelines and petrochemical pipelines described in any one of claim 1 ~ 8 is applied to normal temperature solidified high-temperature resistant anti-corrosive insulation material in the corrosion-resistant thermal insulation engineering of the large high-temperature chemical industry equipment of petroleum cracking equipment, high temperature steam pipeline, high-temperature reaction equipment and pipeline.
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101633818A (en) * | 2008-07-24 | 2010-01-27 | 中冶集团建筑研究总院 | Organosilicon high-temperature resistant coating being solidifiable at normal temperature |
CN102260458A (en) * | 2010-05-31 | 2011-11-30 | 北京化工大学 | Anticorrosion coating for high-temperature condensed water recovering device |
-
2016
- 2016-03-31 CN CN201610206772.XA patent/CN105802486A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101633818A (en) * | 2008-07-24 | 2010-01-27 | 中冶集团建筑研究总院 | Organosilicon high-temperature resistant coating being solidifiable at normal temperature |
CN102260458A (en) * | 2010-05-31 | 2011-11-30 | 北京化工大学 | Anticorrosion coating for high-temperature condensed water recovering device |
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