CN105801115A - 一种牙科用氧化锆基底饰面瓷及其制备方法 - Google Patents
一种牙科用氧化锆基底饰面瓷及其制备方法 Download PDFInfo
- Publication number
- CN105801115A CN105801115A CN201610118726.4A CN201610118726A CN105801115A CN 105801115 A CN105801115 A CN 105801115A CN 201610118726 A CN201610118726 A CN 201610118726A CN 105801115 A CN105801115 A CN 105801115A
- Authority
- CN
- China
- Prior art keywords
- ceramic
- zirconia
- substrate
- zirconium oxide
- veneering
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000758 substrate Substances 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 title abstract description 38
- 239000000919 ceramic Substances 0.000 title abstract description 20
- 239000000843 powder Substances 0.000 claims abstract description 11
- 239000003381 stabilizer Substances 0.000 claims abstract description 7
- 238000005245 sintering Methods 0.000 claims abstract description 5
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 4
- 239000002270 dispersing agent Substances 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 4
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 33
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 33
- 229910052573 porcelain Inorganic materials 0.000 claims description 22
- 239000002131 composite material Substances 0.000 claims description 9
- 238000009413 insulation Methods 0.000 claims description 3
- 238000007711 solidification Methods 0.000 claims description 3
- 230000008023 solidification Effects 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 7
- 230000008859 change Effects 0.000 abstract description 6
- 239000002241 glass-ceramic Substances 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 abstract description 4
- 230000008569 process Effects 0.000 abstract description 3
- 238000005266 casting Methods 0.000 abstract 1
- 229910010293 ceramic material Inorganic materials 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000004321 preservation Methods 0.000 abstract 1
- 230000008901 benefit Effects 0.000 description 3
- 239000005548 dental material Substances 0.000 description 3
- 230000007704 transition Effects 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 210000000214 mouth Anatomy 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/64—Burning or sintering processes
- C04B35/645—Pressure sintering
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
- C04B2235/3225—Yttrium oxide or oxide-forming salts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Dental Preparations (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
本发明涉及一种牙科用氧化锆基底饰面瓷及其制备方法。本发明将氧化锆(ZrO2)细粉加入稳定剂Y2O323％、CaO7％，氧化锆(ZrO2)总量约70％，以该复合细粉、交联剂和分散剂为原料，通过注凝成型制备生坯，在T＝1700℃条件下(保温2‑4h)热压烧结制备本发明陶瓷。强度为800～1000MPa，韧性达20～25MPa·m↑。本发明提出氧化锆与饰面瓷难以匹配的关键在于二者膨胀系数的不匹配以及氧化锆相变过程中的体积突变，并通过对氧化锆陶瓷基底成分的调整解决二者匹配问题，同时降低玻璃陶瓷软化点，使其在氧化锆陶瓷相变区间处于软化状态，对陶瓷的体积变化不敏感突破以氧化锆陶瓷作为基底组分取代氧化铝的技术瓶颈，复合成新的牙科全瓷材料。
Description
技术领域
本发明属生物医药领域，具体涉及一种牙科用氧化锆基底饰面瓷及其制备方法。
背景技术
目前，氧化锆因具有高韧性、高强度等优点被认为是更为理想的口腔全瓷材料。但其与饰面瓷的结合问题成为它在此领域应用的瓶颈问题。国内大部分研究是通过对饰面瓷的调整，来满足与氧化锆陶瓷的匹配问题，但所研制饰面瓷的颜色难以达到临床应用的要求。
发明内容
针对现有技术的不足，本发明一种牙科用氧化锆基底饰面瓷及其制备方法。通过对氧化锆基底成分的调整和改变烧结技术来达到与玻璃饰面瓷相匹配，从而形成新的牙科全瓷材料。
一种牙科用氧化锆基底饰面瓷，该基底饰面瓷为以氧化锆为基底、Y2O3、CaO为稳定剂复合基底基底饰面瓷。
各组分比例按照摩尔比为为氧化锆70％、Y2O323％、CaO7％。
一种牙科用氧化锆基底饰面瓷的制备方法，按照以下步骤进行：
(1)将氧化锆(ZrO2)细粉加入稳定剂CaO7，ZrO2制备成复合细粉，组分比例按照摩尔比为氧化锆70％、Y2O323％、CaO7％；
(2)以该复合细粉、交联剂和分散剂为原料，通过注凝成型制备生坯，在T＝1700℃条件下(保温2-4h)热压烧结制备，制备出来的陶瓷的强度为800～1000MPa，韧性达20～25MPa·m。
本发明提出氧化锆与饰面瓷难以匹配的关键在于二者膨胀系数的不匹配以及氧化锆相变过程中的体积突变，并通过对氧化锆陶瓷基底成分的调整解决二者匹配问题，同时降低玻璃陶瓷软化点，使其在氧化锆陶瓷相变区间处于软化状态，对陶瓷的体积变化不敏感突破以氧化锆陶瓷作为基底组分取代氧化铝的技术瓶颈，复合成新的牙科全瓷材料。
本发明具有以下有益效果及优点：
1.提出了氧化锆与饰面瓷难以匹配的关键在于二者膨胀系数的不匹配以及氧化锆相变过程中的体积突变，
2.通过对氧化锆陶瓷基底成分的调整解决二者匹配问题，从而与技术成熟的饰面玻璃陶瓷相匹配，突破以氧化锆陶瓷作为基底组分取代氧化铝的技术瓶颈，复合成新的牙科全瓷材料
具体实施方式
一种牙科用氧化锆基底饰面瓷，该基底饰面瓷为以氧化锆为基底、Y2O3、CaO为稳定剂复合基底基底饰面瓷。
各组分比例按照摩尔比为为氧化锆70％、Y2O323％、CaO7％。
一种牙科用氧化锆基底饰面瓷的制备方法，按照以下步骤进行：
(1)将氧化锆(ZrO2)细粉加入稳定剂CaO7，ZrO2制备成复合细粉，组分比例按照摩尔比为氧化锆70％、Y2O323％、CaO7％；
(2)以该复合细粉、交联剂和分散剂为原料，通过注凝成型制备生坯，在T＝1700℃条件下(保温2-4h)热压烧结制备，制备出来的陶瓷的强度为800～1000MPa，韧性达20～25MPa·m。
Claims (3)
1.一种牙科用氧化锆基底饰面瓷，其特征在于：该基底饰面瓷是一种以氧化锆为基底、以Y2O3、CaO为稳定剂的复合基底饰面瓷。
2.根据权利要求1所述的一种牙科用氧化锆基底，其特征在于：各组分比例按照摩尔比为为氧化锆70％、Y2O323％、CaO7％。
3.一种牙科用氧化锆基底饰面瓷的制备方法，其特征在于按照以下步骤进行：
(1)将氧化锆(ZrO2)细粉加入稳定剂CaO7，ZrO2制备成复合细粉，组分比例按照摩尔比为氧化锆70％、Y2O323％、CaO7％；
(2)以该复合细粉、交联剂和分散剂为原料，通过注凝成型制备生坯，在T＝1700℃条件下(保温2-4h)热压烧结制备，制备出来的陶瓷的强度为800～1000MPa，韧性达20～25MPa·m。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610118726.4A CN105801115A (zh) | 2016-03-01 | 2016-03-01 | 一种牙科用氧化锆基底饰面瓷及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610118726.4A CN105801115A (zh) | 2016-03-01 | 2016-03-01 | 一种牙科用氧化锆基底饰面瓷及其制备方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105801115A true CN105801115A (zh) | 2016-07-27 |
Family
ID=56466604
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610118726.4A Pending CN105801115A (zh) | 2016-03-01 | 2016-03-01 | 一种牙科用氧化锆基底饰面瓷及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105801115A (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109942316A (zh) * | 2019-02-01 | 2019-06-28 | 中国医科大学附属口腔医院 | 一种增强二氧化锆表面遮色瓷抗剪切强度的涂层方法 |
-
2016
- 2016-03-01 CN CN201610118726.4A patent/CN105801115A/zh active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109942316A (zh) * | 2019-02-01 | 2019-06-28 | 中国医科大学附属口腔医院 | 一种增强二氧化锆表面遮色瓷抗剪切强度的涂层方法 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6393328B2 (ja) | 酸化物セラミックの焼結動力学の制御 | |
| JP7486269B2 (ja) | 多色ガラスセラミックブランクの調製のためのプロセス | |
| RU2611809C2 (ru) | Предварительно спеченная заготовка для дентального применения | |
| KR100273953B1 (ko) | 치과용 보철물 | |
| CA2898793C (en) | Blank for dental purposes | |
| CN104736126B (zh) | 包含氧化铯的硅酸锂玻璃陶瓷和硅酸锂玻璃 | |
| JP6392203B2 (ja) | 少なくとも２つの層を有する非緻密焼結セラミック成形体の製造プロセス | |
| CN104774007B (zh) | 一种牙科玻璃部分渗透的功能梯度氧化锆陶瓷材料 | |
| MX2014013673A (es) | Blanco pre-sinterizado para propositos dentales. | |
| CN102499900B (zh) | 一种磷酸盐玻璃渗透ZrO2陶瓷齿科材料及其制备方法 | |
| CN101505679A (zh) | 牙科修复体及其制造方法、以及牙科修复体用瓷糊浆 | |
| CN103263302B (zh) | 口腔正畸用的高透明陶瓷托槽制备方法 | |
| CN108947488B (zh) | 德化雪白瓷器及其制备方法 | |
| CN103332966A (zh) | 一种复合乳浊釉的制备方法 | |
| CN101229100A (zh) | 一种牙科氧化锆/白榴石复合烤瓷粉及其制备方法 | |
| Sheng et al. | Preparation of glass-infiltrated 3Y-TZP/Al2O3/glass composites | |
| KR20150028998A (ko) | 치과 적용을 위한 착색된 소결 세라믹체를 형성시키는 방법 | |
| CN105801115A (zh) | 一种牙科用氧化锆基底饰面瓷及其制备方法 | |
| JP2015137187A (ja) | 歯科用ジルコニア質焼結体、クラウン用フレーム、ブリッジ用フレーム | |
| CN103951190B (zh) | 熔块+色料复合的颜色梯度变化的牙齿微晶玻璃 | |
| KR102651210B1 (ko) | 인성을 향상시킨 치과용 제품 | |
| CN103964688B (zh) | 硅灰石和磷灰石熔块复合的米黄色牙齿微晶玻璃 | |
| CN107352990A (zh) | 一种兼顾可塑性和强度的陶瓷材料及其制备方法 | |
| KR100853834B1 (ko) | 치아 수복용 세라믹 코핑 | |
| CN103964689A (zh) | 颜色和性能可调的新型牙齿微晶玻璃及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160727 |
|
| WD01 | Invention patent application deemed withdrawn after publication |