CN105776407A - Environment-friendly sewage treating agent - Google Patents
Environment-friendly sewage treating agent Download PDFInfo
- Publication number
- CN105776407A CN105776407A CN201610260276.2A CN201610260276A CN105776407A CN 105776407 A CN105776407 A CN 105776407A CN 201610260276 A CN201610260276 A CN 201610260276A CN 105776407 A CN105776407 A CN 105776407A
- Authority
- CN
- China
- Prior art keywords
- parts
- activated carbon
- treating agent
- silver
- kaolin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000010865 sewage Substances 0.000 title claims abstract description 31
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 57
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 36
- 238000011282 treatment Methods 0.000 claims abstract description 22
- NXXYKOUNUYWIHA-UHFFFAOYSA-N 2,6-Dimethylphenol Chemical compound CC1=CC=CC(C)=C1O NXXYKOUNUYWIHA-UHFFFAOYSA-N 0.000 claims abstract description 20
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 18
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052709 silver Inorganic materials 0.000 claims abstract description 17
- 239000004332 silver Substances 0.000 claims abstract description 17
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 16
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 16
- 239000002270 dispersing agent Substances 0.000 claims abstract description 13
- 150000001412 amines Chemical class 0.000 claims abstract description 12
- 229910052751 metal Inorganic materials 0.000 claims abstract description 12
- 239000002184 metal Substances 0.000 claims abstract description 12
- 150000003839 salts Chemical class 0.000 claims abstract description 12
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims abstract description 10
- 229920000805 Polyaspartic acid Polymers 0.000 claims abstract description 10
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 claims abstract description 10
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims abstract description 10
- 108010064470 polyaspartate Proteins 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 10
- 229910052708 sodium Inorganic materials 0.000 claims description 10
- 239000011734 sodium Substances 0.000 claims description 10
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 9
- 239000007864 aqueous solution Substances 0.000 claims description 9
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 8
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 claims description 8
- 230000007613 environmental effect Effects 0.000 claims description 7
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical group CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- DMBHHRLKUKUOEG-UHFFFAOYSA-N N-phenyl aniline Natural products C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 4
- 229920002367 Polyisobutene Polymers 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 229960002317 succinimide Drugs 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 2
- 229960000892 attapulgite Drugs 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 239000012153 distilled water Substances 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims description 2
- 239000000395 magnesium oxide Substances 0.000 claims description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 2
- 150000002696 manganese Chemical class 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- 150000007524 organic acids Chemical class 0.000 claims description 2
- 229910052625 palygorskite Inorganic materials 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 239000013049 sediment Substances 0.000 claims description 2
- 238000007873 sieving Methods 0.000 claims description 2
- 239000006228 supernatant Substances 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims description 2
- 238000005303 weighing Methods 0.000 claims description 2
- 150000003751 zinc Chemical class 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 11
- 229920001529 polyepoxysuccinic acid Polymers 0.000 abstract description 9
- 238000001179 sorption measurement Methods 0.000 abstract description 6
- 238000005189 flocculation Methods 0.000 abstract description 3
- 230000016615 flocculation Effects 0.000 abstract description 3
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 238000007599 discharging Methods 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 6
- 238000004065 wastewater treatment Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 239000002351 wastewater Substances 0.000 description 4
- 238000011161 development Methods 0.000 description 3
- 239000003651 drinking water Substances 0.000 description 3
- 235000020188 drinking water Nutrition 0.000 description 3
- 239000012028 Fenton's reagent Substances 0.000 description 2
- 229910000519 Ferrosilicon Inorganic materials 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000008394 flocculating agent Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- -1 mercury ions Chemical class 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 229920001661 Chitosan Polymers 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000001095 inductively coupled plasma mass spectrometry Methods 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 229920005552 sodium lignosulfonate Polymers 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
- C02F1/5245—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/56—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Water Treatment By Sorption (AREA)
Abstract
The invention discloses an environment-friendly sewage treating agent which is prepared from the following components: polyepoxysuccinic acid, tetrabutyl titanate, polysilicate ferric chloride, acidized silver-loaded active carbon, 2,6-xylenol, organic amine, polyaspartic acid, kaolin, soluble metal salt and a dispersing agent. The provided treating agent is high in adsorption capacity, stable in heavy metal adsorption and free of secondary pollution, has high speed and good adsorption, flocculation and treatment effects, can meet the discharging standard, is stable in treating effect and is environment-friendly and non-toxic.
Description
Technical Field
The invention relates to the field of sewage treatment, in particular to a sewage green environment-friendly treating agent.
Background
The discharge of sewage causes serious pollution to the environment, and some sewage discharges not only pollute ground water, but also pollute underground water sources, and even influence the life and life safety of people. China is one of 13 countries which are the most poor water in the world at present, and along with the increasing severity of water eutrophication, the water quality condition of China is worried. According to the report of 'Chinese environmental performance assessment' newly published by economic cooperation and development organization, more than 75% of water flowing through China city is not suitable for drinking at present, and more than 30% of detected river water quality belongs to the inferior V class. Along with the development of industry, the pollution degree of urban drinking water sources is increasingly intensified, and along with the improvement of living standard, the requirements of people on drinking water quality and drinking water quality standards are more and more strict.
Patent CN201310328285.7 discloses a wastewater treatment agent, which is simple and convenient, but the main water purification agent used in the wastewater treatment agent mainly comprises a ferrosilicon copolymer and a fenton reagent, the ferrosilicon copolymer is formed by polymerizing sodium silicate and ferrate, the fenton reagent is obtained by reacting hydrogen peroxide and ferrous sulfate, and the greatest disadvantage of the wastewater treatment agent is that:
(a) the existing sewage treatment agent is mostly developed according to specific industries, for example, the treatment agent for treating printing and dyeing wastewater is not suitable for treating wastewater of a pesticide factory, and the treatment agent disclosed above is more suitable for treating sewage with COD, high ammonia nitrogen content, turbidity, chromaticity, conductivity, odor, pH value, total hardness and chloride close to common water quality.
(b) Most of corrosion inhibitors and flocculating agents used by the existing sewage treatment agents are non-environment-friendly products, and waste residues generated by using a large amount of the corrosion inhibitors and the flocculating agents are difficult to degrade and can cause secondary pollution to the environment.
(c) The price of the existing sewage treatment agent is generally higher, which hinders the development of the environmental protection career of China.
Patent CN201110187438.1 discloses a paint wastewater treatment agent, which adopts environment-friendly water treatment reagents, namely sodium lignosulfonate aqueous solution, chitosan aqueous solution and polyacrylamide aqueous solution, but practice shows that the paint wastewater treatment agent only has certain effect on treating paint wastewater, when the paint wastewater treatment agent is used for treating wastewater of other sewage plants, the treatment effect is greatly reduced, and the using amount of the treatment agent is greatly increased.
Disclosure of Invention
The invention aims to solve the technical problem of providing a treating agent which has high adsorption capacity, stable adsorption on heavy metals, no secondary pollution, high speed, good adsorption, flocculation and sedimentation effects, thorough treatment, stable treatment effect, environmental protection and no toxicity, and can reach the discharge standard.
The technical scheme adopted by the invention is as follows: a sewage green environment-friendly treating agent comprises the following components in parts by weight:
sodium polyepoxysuccinate: 6-18 parts; tetrabutyl titanate: 4-16 parts of a solvent;
poly-ferric chloride silicate: 5-25 parts; acidifying the silver-loaded activated carbon: 7-15 parts;
2, 6-xylenol: 2-5 parts; organic amine: 1-3 parts;
polyaspartic acid: 2-5 parts; kaolin: 5-15 parts of a solvent;
soluble metal salt: 3-10 parts; dispersing agent: 1-3 parts.
Preferably, the dispersant adopts high-nitrogen polyisobutylene succinimide or low-nitrogen polyisobutylene succinimide
Preferably, the soluble metal salt is at least one selected from soluble zinc salts and manganese salts.
Preferably, the organic amine is N, N-dimethylformamide or diphenylamine.
Preferably, the production method of the silver-loaded activated carbon comprises the following specific steps:
step 1): washing the activated carbon mixture with dilute nitric acid, and then washing with clear water; wherein the activated carbon mixture is prepared from activated carbon, attapulgite clay and magnesium oxide in a weight ratio of 2.3: 1.2: 0.5 is prepared;
step 2): immersing the activated carbon mixture obtained in the step (1) into a silver nitrate aqueous solution, and after immersing for 25-55 hours, controlling the temperature at 100 ℃ and 105 ℃ for drying; wherein,
step 3): ammonia water with the concentration of 55 wt% and organic acid are mixed according to the weight ratio of 4.7: 1.3 preparing a reducing solution;
step 4): and (3) pouring the dried activated carbon in the step (2) into the reducing solution prepared in the step (3) to stir for 4-5 hours, cooling to obtain the wet silver-loaded activated carbon, and drying at the temperature of 100 ℃ and 110 ℃ to obtain the silver-loaded activated carbon.
Preferably, the concentration of the silver nitrate aqueous solution in the step 2) is 7.5 g/L;
preferably, the preparation method of the kaolin comprises the following steps: weighing a certain amount of 70-mesh natural kaolin, dispersing in distilled water to prepare 10g/L suspension, uniformly stirring, standing for 30min, centrifugally separating supernatant, collecting kaolin sediment, drying, grinding, and sieving with a 180-mesh sieve to obtain high-purity kaolin.
The invention at least comprises the following beneficial effects: the method adopts the acidified silver-loaded activated carbon, the polyepoxysuccinic acid sodium and the inorganic polymeric flocculant for chemical treatment, combines various treatments, greatly reduces the cost and improves the treatment effect; the treatment agent can effectively treat domestic sewage, the treatment effect can reach the national discharge standard, the sludge discharge amount is greatly reduced, and the ecological, reduction and resource treatment of domestic sewage treatment are realized; the pollution of domestic sewage to the ecological environment is reduced, secondary pollution is avoided, the treatment effect is stable, and the method is environment-friendly and nontoxic; by adding the dispersing agent, the treating agent has the advantages of good wettability, high diffusion speed and the like, has good dispersibility in an oil-water phase, can more effectively and rapidly destroy an oil-water interface film, and has high oil-water separation, flocculation and water purification effects; the tetrabutyl titanate is added, so that the activated carbon has a synergistic effect with the acidified silver-loaded activated carbon, and metal ions can be effectively removed.
Detailed Description
The following detailed description will be given with reference to specific embodiments, so that how to apply the technical means to solve the technical problems and achieve the technical effects can be fully understood and implemented.
Unless otherwise indicated, the technical means employed in the examples are conventional means well known to those skilled in the art, and the starting materials employed are also commercially available. Various procedures and methods not described in detail are conventional methods well known in the art.
Example 1
A sewage green environment-friendly treating agent comprises the following components in parts by weight: 6 parts of polyepoxysuccinic acid sodium; 4 parts of tetrabutyl titanate; 5 parts of polymeric ferric chloride silicate; acidifying 7 parts of silver-loaded activated carbon; 2 parts of 2, 6-xylenol; 1 part of organic amine; 2 parts of polyaspartic acid; 5 parts of kaolin; 3 parts of soluble metal salt; 1 part of a dispersant.
Example 2
A sewage green environment-friendly treating agent comprises the following components in parts by weight: 12 parts of polyepoxysuccinic acid sodium; 13 parts of tetrabutyl titanate; 15 parts of polymeric ferric chloride silicate; acidifying 8 parts of silver-loaded activated carbon; 3 parts of 2, 6-xylenol; 2 parts of organic amine; 4 parts of polyaspartic acid; 10 parts of kaolin; 6 parts of soluble metal salt; and 2 parts of a dispersing agent.
Example 3
A sewage green environment-friendly treating agent comprises the following components in parts by weight: 18 parts of polyepoxysuccinic acid sodium; 16 parts of tetrabutyl titanate; 25 parts of polymeric ferric chloride silicate; acidifying 15 parts of silver-loaded activated carbon; 5 parts of 2, 6-xylenol; 3 parts of organic amine; 5 parts of polyaspartic acid; 15 parts of kaolin; 10 parts of soluble metal salt; 3 parts of a dispersing agent.
Comparative example 1
A sewage green environment-friendly treating agent comprises the following components in parts by weight: 2 parts of polyepoxysuccinic acid sodium; 2 parts of tetrabutyl titanate; 3 parts of polymeric ferric chloride silicate; acidifying 4 parts of silver-loaded activated carbon; 1 part of 2, 6-xylenol; 0.1 part of organic amine; 1 part of polyaspartic acid; 3 parts of kaolin; 2 parts of soluble metal salt; 0.1 part of dispersant.
Comparative example 2
A sewage green environment-friendly treating agent comprises the following components in parts by weight: 22 parts of polyepoxysuccinic acid sodium; 18 parts of tetrabutyl titanate; 32 parts of polymeric ferric chloride silicate; acidifying 20 parts of silver-loaded activated carbon; 15 parts of 2, 6-xylenol; 7 parts of organic amine; 8 parts of polyaspartic acid; 18 parts of kaolin; 12 parts of soluble metal salt; 6 parts of a dispersing agent.
Comparative example 3
A sewage green environment-friendly treating agent comprises the following components in parts by weight: 6 parts of polyepoxysuccinic acid sodium; 4 parts of tetrabutyl titanate; 5 parts of polymeric ferric chloride silicate; 7 parts of activated carbon; 2 parts of 2, 6-xylenol; 1 part of organic amine; 2 parts of polyaspartic acid; 5 parts of kaolin; 3 parts of soluble metal salt; 1 part of a dispersant.
Comparative example 4
A sewage green environment-friendly treating agent comprises the following components in parts by weight: 6 parts of polyepoxysuccinic acid sodium; 5 parts of polymeric ferric chloride silicate; acidifying 7 parts of silver-loaded activated carbon; 2 parts of 2, 6-xylenol; 1 part of organic amine; 2 parts of polyaspartic acid; 5 parts of kaolin; 3 parts of soluble metal salt; 1 part of a dispersant.
5mg of each of the environment-friendly treating agents for a sewage treatment apparatus prepared in examples and comparative examples was mixed with 10mL of an aqueous solution having a concentration of 5ppm of mercury ions and 5ppm of lead ions, and stirred to react for 8 hours. The concentrations of mercury ions and lead ions in the treated aqueous solution were measured by inductively coupled plasma mass spectrometry (ThermoICP-MSXII), and the results are shown in Table 1.
TABLE 1 Performance test results for examples 1-3 and comparative examples 1-4
While embodiments of the invention have been described above, it is not intended to be limited to the applications set forth in the specification and illustrated in the following description, but rather, may be applied to various fields adapted for the invention, and it is to be understood that other modifications may readily occur to those skilled in the art, and that the invention is not limited to the details described herein, without departing from the general concept defined in the appended claims and their equivalents.
Claims (7)
1. The sewage green environment-friendly treating agent is characterized by comprising the following components in parts by weight:
sodium polyepoxysuccinate: 6-18 parts; tetrabutyl titanate: 4-16 parts of a solvent;
poly-ferric chloride silicate: 5-25 parts; acidifying the silver-loaded activated carbon: 7-15 parts;
2, 6-xylenol: 2-5 parts; organic amine: 1-3 parts;
polyaspartic acid: 2-5 parts; kaolin: 5-15 parts of a solvent;
soluble metal salt: 3-10 parts; dispersing agent: 1-3 parts.
2. The sewage green environment-friendly treating agent as claimed in claim 1, wherein the dispersant is high-nitrogen polyisobutylene succinimide or low-nitrogen polyisobutylene succinimide.
3. The sewage green environmental protection treatment agent according to claim 1, wherein the soluble metal salt is at least one selected from soluble zinc salt and manganese salt.
4. The sewage green environmental protection treating agent according to claim 1, wherein the organic amine is N, N-dimethylformamide or diphenylamine.
5. The sewage green environmental protection treating agent as claimed in claim 1, wherein the production method of the silver-loaded activated carbon comprises the following specific steps:
step 1): washing the activated carbon mixture with dilute nitric acid, and then washing with clear water; wherein the activated carbon mixture is prepared from activated carbon, attapulgite clay and magnesium oxide in a weight ratio of 2.3: 1.2: 0.5 is prepared;
step 2): immersing the activated carbon mixture obtained in the step (1) into a silver nitrate aqueous solution, and after immersing for 25-55 hours, controlling the temperature at 100 ℃ and 105 ℃ for drying;
step 3): ammonia water with the concentration of 55 wt% and organic acid are mixed according to the weight ratio of 4.7: 1.3 preparing a reducing solution;
step 4): and (3) pouring the dried activated carbon in the step (2) into the reducing solution prepared in the step (3) to stir for 4-5 hours, cooling to obtain the wet silver-loaded activated carbon, and drying at the temperature of 100 ℃ and 110 ℃ to obtain the silver-loaded activated carbon.
6. The sewage green environmental protection treating agent according to claim 5, wherein the concentration of the silver nitrate aqueous solution in the step 2) is 7.5 g/L.
7. The sewage green environment-friendly treating agent according to claim 1, wherein the preparation method of the kaolin comprises the following steps: weighing a certain amount of 70-mesh natural kaolin, dispersing in distilled water to prepare 10g/L suspension, uniformly stirring, standing for 30min, centrifugally separating supernatant, collecting kaolin sediment, drying, grinding, and sieving with a 180-mesh sieve to obtain high-purity kaolin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610260276.2A CN105776407A (en) | 2016-04-25 | 2016-04-25 | Environment-friendly sewage treating agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610260276.2A CN105776407A (en) | 2016-04-25 | 2016-04-25 | Environment-friendly sewage treating agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105776407A true CN105776407A (en) | 2016-07-20 |
Family
ID=56399431
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610260276.2A Pending CN105776407A (en) | 2016-04-25 | 2016-04-25 | Environment-friendly sewage treating agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105776407A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107986588A (en) * | 2017-12-14 | 2018-05-04 | 张亚欣 | A kind of sludge treating agent based on clay and its preparation method and application |
| CN109136932A (en) * | 2018-07-03 | 2019-01-04 | 南京舜业环保科技有限公司 | A kind of regeneration treatment agent and preparation method thereof for sulfur acid etching waste liquor |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5102556A (en) * | 1990-03-30 | 1992-04-07 | Union Oil Company Of California | Method for rendering ferric hydroxide sludges recyclable |
| CN102774969A (en) * | 2012-07-24 | 2012-11-14 | 浙江浙能能源技术有限公司 | Biodegradable non-phosphorous anti-scale corrosion inhibitor and preparation method thereof |
| CN105384201A (en) * | 2015-12-11 | 2016-03-09 | 马鞍山清净环保科技有限公司 | Treatment agent for treating heavy metal sewage, and preparation method and application thereof |
| CN105396554A (en) * | 2015-10-30 | 2016-03-16 | 明光市龙腾矿物有限公司 | Acidized silver loaded activated carbon-based composite material and preparation method thereof |
| CN105439220A (en) * | 2016-01-19 | 2016-03-30 | 张锐 | Sewage treatment agent and preparing method thereof |
-
2016
- 2016-04-25 CN CN201610260276.2A patent/CN105776407A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5102556A (en) * | 1990-03-30 | 1992-04-07 | Union Oil Company Of California | Method for rendering ferric hydroxide sludges recyclable |
| CN102774969A (en) * | 2012-07-24 | 2012-11-14 | 浙江浙能能源技术有限公司 | Biodegradable non-phosphorous anti-scale corrosion inhibitor and preparation method thereof |
| CN105396554A (en) * | 2015-10-30 | 2016-03-16 | 明光市龙腾矿物有限公司 | Acidized silver loaded activated carbon-based composite material and preparation method thereof |
| CN105384201A (en) * | 2015-12-11 | 2016-03-09 | 马鞍山清净环保科技有限公司 | Treatment agent for treating heavy metal sewage, and preparation method and application thereof |
| CN105439220A (en) * | 2016-01-19 | 2016-03-30 | 张锐 | Sewage treatment agent and preparing method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107986588A (en) * | 2017-12-14 | 2018-05-04 | 张亚欣 | A kind of sludge treating agent based on clay and its preparation method and application |
| CN109136932A (en) * | 2018-07-03 | 2019-01-04 | 南京舜业环保科技有限公司 | A kind of regeneration treatment agent and preparation method thereof for sulfur acid etching waste liquor |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107098485B (en) | Wastewater treatment agent and wastewater treatment method thereof | |
| CN109384276B (en) | Wastewater treatment agent for efficiently decoloring, decyanating and degrading COD (chemical oxygen demand) | |
| CN110316800B (en) | Preparation and application methods of flocculant for coking wastewater treatment | |
| CN105439217A (en) | Sewage processing agent | |
| CN105016494A (en) | Composite water treatment agent | |
| CN102153183A (en) | Nano ferric oxide-cationic polyelectrolyte coupled multielement composite flocculant | |
| CN113401996A (en) | Water treatment defluorination medicament and preparation method thereof | |
| CN112390321A (en) | Phosphorus removal agent for sewage treatment and preparation method thereof | |
| CN108217893A (en) | For the heavy metal ion adsorbed biological composite flocculation agent of heavy metal wastewater thereby and application | |
| CN105060510A (en) | Phosphor-free water treating agent | |
| CN112939170B (en) | Industrial wastewater flocculant and preparation method thereof | |
| CN105776407A (en) | Environment-friendly sewage treating agent | |
| CN107381869B (en) | Method for treating methylene blue wastewater | |
| CN106746475B (en) | Composite polymer sludge dewatering flocculant and preparation method thereof | |
| CN105439268A (en) | Preparation method of novel sewage processing agent | |
| CN105481031A (en) | Novel sewage treatment agent | |
| CN110282715B (en) | Preparation and application of polyquaternium in-situ composite modified polymeric ferric sulfate | |
| CN109775779A (en) | A kind of Water Treatment agent | |
| CN101381136A (en) | High-efficiency broadspectrum flocculant and preparation method thereof | |
| CN102206001A (en) | Composite decolorizer as well as preparation method and application thereof | |
| CN110606525A (en) | High-efficiency water purifying agent and preparation method thereof | |
| CN102633335A (en) | Sewage treatment method | |
| CN113999398B (en) | Fe-MOF composite polymer targeted flocculant, preparation method and application | |
| CN113636631B (en) | Composite water quality agglutination purifying agent and preparation method thereof | |
| CN104876314A (en) | Water treatment chemical |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160720 |
|
| RJ01 | Rejection of invention patent application after publication |