CN105753380A - Waste-stone-powder artificial stone - Google Patents
Waste-stone-powder artificial stone Download PDFInfo
- Publication number
- CN105753380A CN105753380A CN201410793258.1A CN201410793258A CN105753380A CN 105753380 A CN105753380 A CN 105753380A CN 201410793258 A CN201410793258 A CN 201410793258A CN 105753380 A CN105753380 A CN 105753380A
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- CN
- China
- Prior art keywords
- stone
- artificial
- resin
- waste
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000002969 artificial stone Substances 0.000 title claims abstract description 68
- 239000000843 powder Substances 0.000 title abstract 8
- 239000004575 stone Substances 0.000 claims abstract description 120
- 239000002699 waste material Substances 0.000 claims abstract description 79
- 229920005989 resin Polymers 0.000 claims abstract description 66
- 239000011347 resin Substances 0.000 claims abstract description 66
- 239000002131 composite material Substances 0.000 claims abstract description 41
- 238000002360 preparation method Methods 0.000 claims abstract description 12
- 230000001788 irregular Effects 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 8
- 239000000428 dust Substances 0.000 claims description 74
- 230000000845 anti-microbial Effects 0.000 claims description 18
- 239000002994 raw material Substances 0.000 claims description 18
- 150000001875 compounds Chemical class 0.000 claims description 16
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 239000011435 rock Substances 0.000 claims description 13
- 229920001225 Polyester resin Polymers 0.000 claims description 9
- 238000005516 engineering process Methods 0.000 claims description 9
- 238000007666 vacuum forming Methods 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 7
- WNROFYMDJYEPJX-UHFFFAOYSA-K Aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 6
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 6
- 238000005303 weighing Methods 0.000 claims description 6
- 239000007822 coupling agent Substances 0.000 claims description 4
- 238000004381 surface treatment Methods 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N TiO Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 3
- 239000004568 cement Substances 0.000 claims description 3
- 239000000835 fiber Substances 0.000 claims description 3
- 238000007667 floating Methods 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 238000007517 polishing process Methods 0.000 claims description 3
- -1 polypropylene Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 239000003638 reducing agent Substances 0.000 claims description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910001929 titanium oxide Inorganic materials 0.000 claims description 3
- 239000010410 layer Substances 0.000 abstract description 46
- 239000002253 acid Substances 0.000 abstract description 4
- 230000000844 anti-bacterial Effects 0.000 abstract description 3
- 239000002344 surface layer Substances 0.000 abstract description 2
- 239000003513 alkali Substances 0.000 abstract 1
- 239000002585 base Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 2
- 239000002928 artificial marble Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000003247 decreasing Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000010438 granite Substances 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Abstract
Waste-stone-powder artificial stone is provided. The artificial stone comprise an inorganic artificial stone layer, a resin artificial stone with a high content of waste stone powder, a resin artificial stone with a low content of waste stone powder and a resin antibacterial surface layer in order from bottom to top. The surface of the inorganic artificial stone layer is provided with irregular jagged grooves. The mass percentage of the waste stone powder in the resin artificial stone with the high content of waste stone powder is higher than that of the resin artificial stone with the low content of waste stone powder. The layers are processed into one part through a gradient composite preparation process. The gradient composite preparation process for the waste-stone-powder composite artificial stone is also provided. The composite artificial stone adopts inorganic artificial stone as a base layer, arranges a plurality of resin artificial stone layers on the base layer, integrates advantages of the two types of artificial stone, is good in mechanical performance, light in weight and good in waterproofness, acid and alkali resistance and wear resistance, and is decorative and antibacterial.
Description
Technical field
The invention belongs to artificial stone field, relate to a kind of waste stone dust composite artificial stone, further relate to the graded composite preparation technology of waste stone dust composite artificial stone.
Background technology
Artificial stone refer to binding agent, filler and additive through certain technical process make there is natural marble or the decorating and renovating material of granite decorative pattern.Artificial stone is divided into artificial resin stone, Inorganic artificial stone and composite artificial stone, composite artificial stone is generally with the cheap and Inorganic artificial stone of stable performance for bottom, surface layer artificial resin stone, the advantage having resin artificial marble and inorganic artificial marble concurrently, it is a kind of novel artificial stone material, is the development trend of artificial stone.But intensity is low, density is big, processing technique is complicated problem that composite artificial stone there is also, and the intermediate interface adhesion of Inorganic artificial stone and artificial resin stone is more weak, and the thermal property of two kinds of artificial stones there is also bigger gap, it is easy to layering, impact uses, and these problems demand solve.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art, a kind of waste stone dust composite artificial stone is provided, this composite artificial stone is with Inorganic artificial stone for bottom, it is provided with multi-layer resinous artificial rock layers thereon, the advantage combining two kinds of artificial stones, mechanical property is good, lightweight, resistance to water, resistance to acids and bases and excellent abrasion resistance, also have dicoration and anti-microbial property.
Present invention also offers the graded composite preparation technology of waste stone dust composite artificial stone.
For solving above-mentioned technical problem, the technical solution used in the present invention is:
A kind of waste stone dust composite artificial stone, it is characterized in that, the structure of described waste stone dust composite artificial stone is followed successively by inorganic artificial rock layers (1) from top to bottom, high-load waste stone dust artificial resin stone layer (2), low content waste stone dust artificial resin stone layer (3) and resin antimicrobial surface (4), the surface distributed of described inorganic artificial rock layers (1) irregular zigzag groove, in described high-load waste stone dust artificial resin stone layer (2), the mass percent of waste stone dust is more than described low content waste stone dust artificial resin stone layer (3), described each layer adopts graded composite preparation technology to be processed into an entirety.
Preferably, the raw material that described inorganic artificial rock layers (1) is formed number by following weight is made: cement 25 parts, waste stone dust 50 parts, 23 parts of water, polypropylene fibre 1 part, water reducer 1 part.
Preferably, the raw material that described high-load waste stone dust artificial resin stone layer (2) is formed number by following weight is made: unsaturated polyester resin 14 parts, firming agent and accelerator 0.5 part, waste stone dust 82 parts, auxiliary agent 3.5 parts.
Preferably, the raw material that described low content waste stone dust artificial resin stone layer (3) is formed number by following weight is made: unsaturated polyester resin 38 parts, firming agent and accelerator 1 part, waste stone dust 40 parts, aluminium hydroxide 18 parts, auxiliary agent 3 parts.
Preferably, the raw material that described resin antimicrobial surface (4) is formed number by following weight is made: unsaturated polyester resin 50 parts, firming agent and accelerator 3 parts, aluminium hydroxide 45 parts, nano titanium oxide 1 part, nano phase ag_2 o 1 part.
Present invention also offers the graded composite preparation technology of a kind of waste stone dust composite artificial stone, comprise the following steps:
(1) first prepare Inorganic artificial stone, and make its surface distributed irregular zigzag groove, groove is carried out coupling agent surface treatment, is then placed in mould；
(2) carry out raw material weighing, mixture according to the formula of high-load waste stone dust artificial resin stone, obtain compound, compound is laid in Inorganic artificial stone, vacuum forming；
(3) carry out raw material weighing, mixture according to the formula of low content waste stone dust artificial resin stone, obtain compound, compound is laid in high-load waste stone dust artificial resin stone, vacuum forming；
(4) finally processing resin antimicrobial surface, tile resin antimicrobial surface compound on low content waste stone dust artificial resin stone layer, through floating, vibration, vacuum forming, hot setting, surface grinding and polishing process flow process, prepares waste stone dust composite artificial stone.
Beneficial effects of the present invention has:
(1) waste stone dust composite artificial stone of the present invention has four-layer structure, and bottom Inorganic artificial stone good mechanical property, price are low and do not fire；Intermediate layer is high-load waste stone dust artificial resin stone layer and low content waste stone dust artificial resin stone layer, is resin type artificial stone, has good resistance to water and a resistance to acids and bases, and light weight；Resin antimicrobial surface contains inorganic antibacterial composition, has good anti-microbial property, and each layer compound is as a whole, the advantage combining Inorganic artificial stone and artificial resin stone, and has been assigned excellent anti-microbial property；
(2) surface distributed of inorganic artificial rock layers irregular zigzag groove, and through coupling agent surface treatment, improves and the adhesion of high-load waste stone dust artificial resin stone layer, and overall mechanical property is good；
(3) present invention adopts graded composite preparation technology preparation to obtain, in high-load waste stone dust artificial resin stone layer and low content waste stone dust artificial resin stone layer, the mass percent of waste stone dust is successively decreased, can effectively eliminate the gap of thermal coefficient of expansion between layers on the one hand, it is to avoid cause the hidden danger of layering due to temperature influence；On the other hand, this design is more high the closer to top layer resin content, it is possible to give full play to the dicoration of resin type artificial stone, resistance to compression wear-resistant, resistance to and resistance to chemical attack；
(4) with cheap Inorganic artificial stone for bottom, resin type artificial stone with the addition of again waste stone dust in a large number, so this artificial stone is less costly, it is simple to promotes.
Accompanying drawing explanation
Fig. 1 is the structural representation of waste stone dust composite artificial stone of the present invention.
In figure, 1. inorganic artificial rock layers, 2. high-load waste stone dust artificial resin stone layer, 3. low content waste stone dust artificial resin stone layer, 4. resin antimicrobial surface.
Detailed description of the invention
In order to make technical problem solved by the invention, technical scheme and beneficial effect clearly understand, below in conjunction with drawings and Examples, the present invention is further illustrated.Should be appreciated that embodiment described herein is only for explaining the present invention, is not intended to limit the present invention.
As shown in Figure 1, a kind of waste stone dust composite artificial stone, the structure of described waste stone dust composite artificial stone is followed successively by inorganic artificial rock layers (1) from top to bottom, high-load waste stone dust artificial resin stone layer (2), low content waste stone dust artificial resin stone layer (3) and resin antimicrobial surface (4), the surface distributed of described inorganic artificial rock layers (1) irregular zigzag groove, in described high-load waste stone dust artificial resin stone layer (2), the mass percent of waste stone dust is more than described low content waste stone dust artificial resin stone layer (3), described each layer adopts graded composite preparation technology to be processed into an entirety.
The raw material that described inorganic artificial rock layers (1) is formed number by following weight is made: cement 25 parts, waste stone dust 50 parts, 23 parts of water, polypropylene fibre 1 part, water reducer 1 part.
The raw material that described high-load waste stone dust artificial resin stone layer (2) is formed number by following weight is made: unsaturated polyester resin 14 parts, firming agent and accelerator 0.5 part, waste stone dust 82 parts, auxiliary agent 3.5 parts.
The raw material that described low content waste stone dust artificial resin stone layer (3) is formed number by following weight is made: unsaturated polyester resin 38 parts, firming agent and accelerator 1 part, waste stone dust 40 parts, aluminium hydroxide 18 parts, auxiliary agent 3 parts.
The raw material that described resin antimicrobial surface (4) is formed number by following weight is made: unsaturated polyester resin 50 parts, firming agent and accelerator 3 parts, aluminium hydroxide 45 parts, nano titanium oxide 1 part, nano phase ag_2 o 1 part.
The graded composite step of preparation process of the present embodiment waste stone dust composite artificial stone is as follows:
(1) first prepare Inorganic artificial stone, and make its surface distributed irregular zigzag groove, groove is carried out coupling agent surface treatment, is then placed in mould；
(2) carry out raw material weighing, mixture according to the formula of high-load waste stone dust artificial resin stone, obtain compound, compound is laid in Inorganic artificial stone, vacuum forming；
(3) carry out raw material weighing, mixture according to the formula of low content waste stone dust artificial resin stone, obtain compound, compound is laid in high-load waste stone dust artificial resin stone, vacuum forming；
(4) finally processing resin antimicrobial surface, tile resin antimicrobial surface compound on low content waste stone dust artificial resin stone layer, through floating, vibration, vacuum forming, hot setting, surface grinding and polishing process flow process, prepares waste stone dust composite artificial stone.
The present embodiment composite artificial stone, with Inorganic artificial stone for bottom, is provided with multi-layer resinous artificial rock layers, the advantage combining two kinds of artificial stones thereon, and mechanical property is good, lightweight, resistance to water, resistance to acids and bases and excellent abrasion resistance, also has dicoration and anti-microbial property.
Claims (6)
1. a waste stone dust composite artificial stone, it is characterized in that, the structure of described waste stone dust composite artificial stone is followed successively by inorganic artificial rock layers (1) from top to bottom, high-load waste stone dust artificial resin stone layer (2), low content waste stone dust artificial resin stone layer (3) and resin antimicrobial surface (4), the surface distributed of described inorganic artificial rock layers (1) irregular zigzag groove, in described high-load waste stone dust artificial resin stone layer (2), the mass percent of waste stone dust is more than described low content waste stone dust artificial resin stone layer (3), described each layer adopts graded composite preparation technology to be processed into an entirety.
2. waste stone dust composite artificial stone according to claim 1, it is characterised in that the raw material that described inorganic artificial rock layers (1) is formed number by following weight is made: cement 25 parts, waste stone dust 50 parts, 23 parts of water, polypropylene fibre 1 part, water reducer 1 part.
3. waste stone dust composite artificial stone according to claim 1, it is characterized in that, the raw material that described high-load waste stone dust artificial resin stone layer (2) is formed number by following weight is made: unsaturated polyester resin 14 parts, firming agent and accelerator 0.5 part, waste stone dust 82 parts, auxiliary agent 3.5 parts.
4. waste stone dust composite artificial stone according to claim 1, it is characterized in that, the raw material that described low content waste stone dust artificial resin stone layer (3) is formed number by following weight is made: unsaturated polyester resin 38 parts, firming agent and accelerator 1 part, waste stone dust 40 parts, aluminium hydroxide 18 parts, auxiliary agent 3 parts.
5. waste stone dust composite artificial stone according to claim 1, it is characterized in that, the raw material that described resin antimicrobial surface (4) is formed number by following weight is made: unsaturated polyester resin 50 parts, firming agent and accelerator 3 parts, aluminium hydroxide 45 parts, nano titanium oxide 1 part, nano phase ag_2 o 1 part.
6. the graded composite preparation technology of the waste stone dust composite artificial stone described in a claim 1, it is characterised in that comprise the following steps:
(1) first prepare Inorganic artificial stone, and make its surface distributed irregular zigzag groove, groove is carried out coupling agent surface treatment, is then placed in mould；
(2) carry out raw material weighing, mixture according to the formula of high-load waste stone dust artificial resin stone, obtain compound, compound is laid in Inorganic artificial stone, vacuum forming；
(3) carry out raw material weighing, mixture according to the formula of low content waste stone dust artificial resin stone, obtain compound, compound is laid in high-load waste stone dust artificial resin stone, vacuum forming；
(4) finally processing resin antimicrobial surface, tile resin antimicrobial surface compound on low content waste stone dust artificial resin stone layer, through floating, vibration, vacuum forming, hot setting, surface grinding and polishing process flow process, prepares waste stone dust composite artificial stone.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410793258.1A CN105753380A (en) | 2014-12-20 | 2014-12-20 | Waste-stone-powder artificial stone |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410793258.1A CN105753380A (en) | 2014-12-20 | 2014-12-20 | Waste-stone-powder artificial stone |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105753380A true CN105753380A (en) | 2016-07-13 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410793258.1A Pending CN105753380A (en) | 2014-12-20 | 2014-12-20 | Waste-stone-powder artificial stone |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105753380A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106830987A (en) * | 2017-03-31 | 2017-06-13 | 三川德青科技有限公司 | A kind of artificial culture stone with stone waste sludge as raw material and preparation method thereof |
| CN107032661A (en) * | 2016-12-02 | 2017-08-11 | 天津裕丰源环保科技有限公司 | A kind of luminous waste stone dust artificial stone |
| CN108033760A (en) * | 2017-12-26 | 2018-05-15 | 广东佳居乐厨房科技有限公司 | A kind of explosion-proof, automatically cleaning synthetic quartz slabstone and preparation method thereof |
| CN109437748A (en) * | 2018-12-06 | 2019-03-08 | 南阳英良石业有限公司 | Artificial inorganic stone slab and preparation method thereof |
| CN110746144A (en) * | 2019-10-11 | 2020-02-04 | 南安市汉能环保建材有限公司 | Stone powder waste regenerated wood-like material and preparation method and application thereof |
| CN114276078A (en) * | 2021-12-10 | 2022-04-05 | 广东海龙建筑科技有限公司 | Inorganic stone plate containing artificial stone waste and preparation method thereof |
-
2014
- 2014-12-20 CN CN201410793258.1A patent/CN105753380A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107032661A (en) * | 2016-12-02 | 2017-08-11 | 天津裕丰源环保科技有限公司 | A kind of luminous waste stone dust artificial stone |
| CN106830987A (en) * | 2017-03-31 | 2017-06-13 | 三川德青科技有限公司 | A kind of artificial culture stone with stone waste sludge as raw material and preparation method thereof |
| CN106830987B (en) * | 2017-03-31 | 2020-02-18 | 三川德青科技有限公司 | Artificial culture stone using stone waste slurry as raw material and preparation method thereof |
| CN108033760A (en) * | 2017-12-26 | 2018-05-15 | 广东佳居乐厨房科技有限公司 | A kind of explosion-proof, automatically cleaning synthetic quartz slabstone and preparation method thereof |
| CN109437748A (en) * | 2018-12-06 | 2019-03-08 | 南阳英良石业有限公司 | Artificial inorganic stone slab and preparation method thereof |
| CN109437748B (en) * | 2018-12-06 | 2021-11-05 | 南阳英良石业有限公司 | Artificial inorganic stone plate and preparation method thereof |
| CN110746144A (en) * | 2019-10-11 | 2020-02-04 | 南安市汉能环保建材有限公司 | Stone powder waste regenerated wood-like material and preparation method and application thereof |
| CN110746144B (en) * | 2019-10-11 | 2021-12-03 | 南安市汉能环保建材有限公司 | Stone powder waste regenerated wood-like material and preparation method and application thereof |
| CN114276078A (en) * | 2021-12-10 | 2022-04-05 | 广东海龙建筑科技有限公司 | Inorganic stone plate containing artificial stone waste and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160713 |
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| WD01 | Invention patent application deemed withdrawn after publication |