CN105725033A - Nitrite-free compound color former for meat emulsion product and preparation as well as application of nitrite-free compound color former - Google Patents

Nitrite-free compound color former for meat emulsion product and preparation as well as application of nitrite-free compound color former Download PDF

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Publication number
CN105725033A
CN105725033A CN201610122903.6A CN201610122903A CN105725033A CN 105725033 A CN105725033 A CN 105725033A CN 201610122903 A CN201610122903 A CN 201610122903A CN 105725033 A CN105725033 A CN 105725033A
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CN
China
Prior art keywords
meat
emulsion product
nitrite
nitre
colour former
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Pending
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CN201610122903.6A
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Chinese (zh)
Inventor
肖朝耿
唐宏刚
陈黎洪
王复龙
叶梦迪
吴玫瑰
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Zhejiang Academy of Agricultural Sciences
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Zhejiang Academy of Agricultural Sciences
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Priority to CN201610122903.6A priority Critical patent/CN105725033A/en
Publication of CN105725033A publication Critical patent/CN105725033A/en
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

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  • Meat, Egg Or Seafood Products (AREA)

Abstract

The invention relates to a nitrite-free compound color former for a meat emulsion product. The nitrite-free compound color former for the meat emulsion product comprises the following raw materials in percentage by weight: 0.005-0.1% of coenzyme Q, 0.01-0.1% of sodium succinate, 0.005-0.1% of ethyl maltol, 0.01-0.2% of an antioxidant, 0.01-2% of a preservative and 0.05-1% of an acidity regulator; the nitrite-free compound color former and a two-stage salting method are used cooperatively for salting of a meat emulsion product, so as to achieve the required chromophoric effect. According to the nitrite-free compound color former for the meat emulsion product, provided by the invention, metal ions in the meat product can be chelated to achieve the chromophoric effect, and metmyoglobin is reduced, therefore the meat product is stable in color and luster, the color stability of the meat emulsion product during the production and storage process is improved, and the function of prolonging the shelf life of the meat emulsion product is achieved.

Description

Meat emulsion product compounds colour former and preparation thereof and application without nitre
Technical field
The present invention relates to color former of meat products field, be specifically related to a kind of meat emulsion product and compound colour former and its user Method.
Background technology
Meat products tradition colour former is mainly sodium nitrite, the sodium nitrite on the one hand imparting distinctive flesh pink of meat products, Improve the organizational structure of product;On the other hand as preservative, Clostridium botulinum is had stronger inhibitory action. At present, domestic and international meat enterprises all uses nitrite as the colour former of meat, obtains preferable color and luster and local flavor, Extend the shelf life.But nitrite usage amount exceedes certain standard (> 150mg/kg) NO can be caused-A large amount of residuals, residual NO-Combine with protein metabolism product secondary amine and can generate nitrosamine.These nitroso compounds are all cancerigenic factors, can lure Leading laboratory animal generation canceration, survey data shows, the sickness rate of certain cancers and the consumption figure of pickle cured meat product have certain Dependency.Although therefore sodium nitrite effect in meat products is processed is a lot, but it is real to ambassador's meat products of harm The lowest nitrification or without nitrification and extremely urgent.
At present, the nitrite succedaneum that people seek to use has two classes: a class is partially or completely to substitute nitrite Additive, this material should by colour former, antioxidant, chelating agen and antibacterial mixing form;Another kind of be Under customary nitrites concentration can blocking nitrosamine formation formed additive.Up to now, the most do not find a kind of material can Substitute nitrite completely, but use pickling of one or more materials composition of a certain effect being equivalent to nitrite Agent substitutes whole effects of nitrite.
Summary of the invention
It is an object of the invention to provide a kind of novel meat emulsion product colour former, this colour former can be applicable to various meat paste system In product, it is possible to decrease or the use of replacement nitrite, solve the carcinogenic risk problem that meat products nitrite chromogenic causes.
An object of the present disclosure is to provide a kind of meat emulsion product to compound colour former without nitre, described compounds colour former without nitre By ubiquinone, sodium succinate, Fe3+Chelating agen, at least one antioxidant, at least one preservative, acidity regulator form.
Further, described Fe3+Chelating agen is ethylmaltol, and it forms complex is aubergine, slightly sends out for meat paste Color;Described antioxidant is at least one in ascorbic acid and tea polyphenols;Described preservative is sodium lactate, nisin (nisin), at least one in sodium diacetate;Described acidity regulator is the one of citric acid and sodium hexameta phosphate.
Further, the component of this colour former is by weight percentage:
Ubiquinone 0.005-0.1%
Sodium succinate 0.01-0.1%
Fe3+Chelating agen 0.005-0.1%
Antioxidant 0.01%-0.2%
Preservative 0.01%-2%
Acidity regulator 0.05%-1%.
The present invention the second purpose is to provide a kind of meat emulsion product to compound the preparation method of colour former, described method without nitre Complete according to the following steps:
(1) citric acid, antioxidant and preservative one are reinstated water dissolution, add in meat paste, stir, then by ethyl wheat Bud phenol dissolves and adds in meat, mixing, and in these processing links, meat paste is stably both needed to stable between 1 DEG C-6 DEG C;Now meat paste PH value is reduced between 5.35-5.55 by normal meat 5.6-6.0, is placed in 4 DEG C of refrigerators by the meat paste after mixing and pickles 24h;
(2) sodium hexametaphosphate solution is added in the meat paste pickling 24h, between regulation pH value to 5.8-6.2, then by coenzyme Q adds in meat paste together with sodium succinate solution, and mixing, these processing link meat paste temperature need to be stablized between 1 DEG C-6 DEG C; Meat paste after mixing is placed in 4 DEG C of refrigerators and pickles 12h.
The present invention the 3rd purpose is to provide a kind of meat emulsion product to compound the application of colour former without nitre, described compounding without nitre Allot toner and can be applicable to the color fixative of the meat productss such as sausage, ham sausage, jerky.
The meat emulsion product that the present invention provides compounds colour former without nitre, and this compounding colour former is when meat emulsion product is pickled middle With the use of two-period form technological proces s, reaching required hair color effect, this colour former can be applicable to color fixative in various meat emulsion product, can Reduce or substitute the use of nitrite, solve the carcinogenic risk problem that meat products nitrite chromogenic causes, allot toner energy Metal ion in chelating meat forms color development effect, and reduction MetMb Ferrimyoglobins. reaches stable color and luster of meat, strengthens meat paste system Product produce and the stability of color during storage, reach to extend the effect of meat emulsion product shelf life.
Detailed description of the invention:
Following example are used merely to explain the present invention, rather than protection scope of the present invention is not intended to be limited to following example.
Specific embodiment 1:
The present embodiment is mainly used in the color fixative of chinese-style sausage, consisting of (raw meat 1000g meter):
Ubiquinone: 0.65g
Sodium succinate: 0.37
Ethylmaltol: 0.15
Tea polyphenols: 0.3
Nisin: 0.55
Citric acid: 1.5
Sodium hexameta phosphate: 5
Pure water: 250.
The using method of above-mentioned compounding colour former is: first by ethylmaltol, tea polyphenols, nisin, citric acid It is dissolved in the meat paste that sausage is prepared in water addition, pickles 24h for 4 DEG C;Then by easy to ubiquinone, sodium succinate, sodium hexameta phosphate Water, adds in the meat paste after pickling 24h, and 4 DEG C are continued to pickle 12h;After meat paste is pickled, carry out coloclysis, after 72 DEG C of baking 3h, put Put room temperature naturally to dry 5d less than the ventilation warehouse of 25 DEG C and i.e. obtain chinese-style sausage.
Specific embodiment 2:
The present embodiment is mainly used in the color fixative of chinese-style sausage, consisting of (raw meat 1000g meter):
Ubiquinone: 0.95g
Sodium succinate: 0.70
Ethylmaltol: 0.20
Ascorbic acid: 0.3
Nisin: 0.35
Sodium diacetate: 0.95
Citric acid: 1.5
Sodium hexameta phosphate: 5
Pure water: 250.
The using method of above-mentioned compounding colour former is: first by ethylmaltol, ascorbic acid, nisin, double second Acid sodium, citric acid are dissolved in the meat paste that sausage is prepared in water addition, pickle 24h for 4 DEG C;Then by ubiquinone, sodium succinate, six inclined The easy water of sodium phosphate, adds in the meat paste after pickling 24h, and 4 DEG C are continued to pickle 12h;After meat paste is pickled, carry out coloclysis, 72 DEG C After baking 3h, the placement room temperature ventilation warehouse less than 25 DEG C naturally dries 5d and i.e. obtains chinese-style sausage.
Specific embodiment 3:
The present embodiment is mainly used in the color fixative of chinese-style sausage, consisting of (raw meat 1000g meter):
Ubiquinone: 0.70g
Sodium succinate: 0.55
Ethylmaltol: 0.15
Tea polyphenols: 0.3
Nisin: 0.45.
Sodium lactate: 1.5
Citric acid: 1.5
Sodium hexameta phosphate: 5
Pure water: 250.
The using method of above-mentioned compounding colour former is: first by ethylmaltol, tea polyphenols, nisin, sodium lactate, Citric acid is dissolved in the meat paste that sausage is prepared in water addition, pickles 24h for 4 DEG C;Then by ubiquinone, sodium succinate, sodium hexameta phosphate Easily water, adds in the meat paste after pickling 24h, and 4 DEG C are continued to pickle 12h;After meat paste is pickled, carry out coloclysis, 72 DEG C of baking 3h After, the placement room temperature ventilation warehouse less than 25 DEG C naturally dries 5d and i.e. obtains chinese-style sausage.

Claims (5)

1. meat emulsion product compounds colour former without nitre, it is characterised in that described without nitre compound colour former by ubiquinone, sodium succinate, Fe3+Chelating agen, at least one antioxidant, at least one preservative, acidity regulator form.
Meat emulsion product the most according to claim 1 compounds colour former without nitre, it is characterised in that
Described Fe3+Chelating agen is ethylmaltol, and it forms complex is aubergine, for the slight color development of meat paste;
Described antioxidant is at least one in ascorbic acid and tea polyphenols;
Described preservative is at least one in sodium lactate, nisin (nisin), sodium diacetate;
Described acidity regulator is the one of citric acid and sodium hexameta phosphate.
Meat emulsion product the most according to claim 1 and 2 compounds colour former without nitre, it is characterised in that
The component of this colour former is by weight percentage:
Ubiquinone 0.005-0.1%
Sodium succinate 0.01-0.1%
Fe3+Chelating agen 0.005-0.1%
Antioxidant 0.01%-0.2%
Preservative 0.01%-2%
Acidity regulator 0.05%-1%.
4. compound the preparation method of colour former without nitre according to the meat emulsion product described in claim 1 or 2 or 3, it is characterised in that Described method completes according to the following steps:
Citric acid, antioxidant and preservative one are reinstated water dissolution, adds in meat paste, stir, then by ethyl Fructus Hordei Germinatus Phenol dissolves and adds in meat, mixing, and in these processing links, meat paste is stably both needed to stable between 1 DEG C-6 DEG C;Now meat paste pH Value is reduced between 5.35-5.55 by normal meat 5.6-6.0, is placed in 4 DEG C of refrigerators by the meat paste after mixing and pickles 24h;
Sodium hexametaphosphate solution is added in the meat paste having pickled 24h, regulation pH value between 5.8-6.2, then by ubiquinone and Sodium succinate solution adds in meat paste together, and mixing, these processing link meat paste temperature need to be stablized between 1 DEG C-6 DEG C;Mixed Meat paste after even is placed in 4 DEG C of refrigerators and pickles 12h.
5. compound the application of colour former without nitre according to the meat emulsion product described in claim 1 or 2 or 3 or 4, it is characterised in that Described compounding without nitre is allotted toner and be can be applicable to the color fixative of the meat productss such as sausage, ham sausage, jerky.
CN201610122903.6A 2016-03-04 2016-03-04 Nitrite-free compound color former for meat emulsion product and preparation as well as application of nitrite-free compound color former Pending CN105725033A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109619386A (en) * 2018-11-06 2019-04-16 中国肉类食品综合研究中心 A kind of natural built-up color stabilizer and its application

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0668019A1 (en) * 1994-02-17 1995-08-23 Frisco-Findus Ag Colour stabilisation of communited meat
CN1931021A (en) * 2006-09-30 2007-03-21 广东省食品工业研究所 Meat product color developing agent
CN101133858A (en) * 2007-10-25 2008-03-05 上海水产大学 Low nitrite chromogenic meat food
CN101779795A (en) * 2010-03-25 2010-07-21 北京美添阳光科技有限公司 Composite colour-protecting stabilizing agent for meat product
CN102640951A (en) * 2012-05-18 2012-08-22 淮南白蓝企业集团有限公司 Preparation method of convenience beef soup

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0668019A1 (en) * 1994-02-17 1995-08-23 Frisco-Findus Ag Colour stabilisation of communited meat
CN1931021A (en) * 2006-09-30 2007-03-21 广东省食品工业研究所 Meat product color developing agent
CN101133858A (en) * 2007-10-25 2008-03-05 上海水产大学 Low nitrite chromogenic meat food
CN101779795A (en) * 2010-03-25 2010-07-21 北京美添阳光科技有限公司 Composite colour-protecting stabilizing agent for meat product
CN102640951A (en) * 2012-05-18 2012-08-22 淮南白蓝企业集团有限公司 Preparation method of convenience beef soup

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Title
郭玉华等: "发色剂及发色助剂在肉制品加工中的应用", 《肉类研究》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109619386A (en) * 2018-11-06 2019-04-16 中国肉类食品综合研究中心 A kind of natural built-up color stabilizer and its application

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Application publication date: 20160706